Answer the following questions.

1. What is the molecular formula for the following compound? (1 pt.)

Answer: CH8H18

2. Which of the following compounds are constitutional isomers? (3 pts.)

(i) (ii) (iii)

Answer: (i) (ii) (iii)

3. Which of the following is (are) constitutional isomer(s) of hexane, CH 3(CH2)4CH3? (2 pts.)

a. b
.

Answer: A

4. Determine the molecular and empirical formula of decane. (2 pts.)

Answer: Molecular formula- C10H22
Empirical Formula- C5H11

5. What is the molecular formula and condensed formula of heptane? (2 pts.)

Answer: Molecular Formula- C7H16
Condensed Formula – CH3CH2CH2CH2CH2CH2CH3

6. Determine the IUPAC name of the given alkane structure and classify the labelled C atoms in the
chain. (5 pts.)

1 3
2

IUPAC Name: 2- methylpropane

C-atom classification: 1. Primary
2. Tertiary
3. Primary
4. Primary

7. In the given alkanes in the table below, write their IUPAC name and Common name (if applicable).
(12 pts.)
 Condensed Structural formula IUPAC name Common name

Hexane n-hexane
1. CH3CH2CH2CH2CH2CH3

2.
1,3-dimethylcyclopentane

3. 3-methylheptane

4. CH3 CH3
cis-1,2-dimethylcyclopropane
H3C CH3 H3 C H
or or
H H H CH3
CH3 CH3
5. cis-1,2-Dimethylcyclopropane 2,4-dimethylpentane
trans-1,2-Dimethylcyclopropane

6. 2,4-dymethylhexane

7. Isopropylcyclopentane

8. 2-methylpentane isohexane

9. 1,2-diiodo
1methylcyclohexane

10 1-ethyl-3-methylcyclohexane
.

8. Which of the following is the correct line-angle structure for 3-ethylheptane? (1 pt.)
  a.  b. 

  c.  d. 

Answer: C

9. Which of the following line-angle structures is 4-isopropyloctane? (1 pt.)

  a.  b. 

  c.  d. 

Answer: A
10. What is the IUPAC name of the following compound? (1 pt.)

  a. diethylcyclopentane b. butylcyclopentane
  c. 1,1-diethylcyclopentane d. none of these
Answer: C