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Effects of Needle-Punched Nonwoven Structure On The Properties of Sandwich Flexible Composites Under Static Loading and Low-Velocity Impact
Effects of Needle-Punched Nonwoven Structure On The Properties of Sandwich Flexible Composites Under Static Loading and Low-Velocity Impact
COMPOSITE
Article M AT E R I A L S
Journal of Composite Materials
2017, Vol. 51(8) 1045–1056
! The Author(s) 2016
Effects of needle-punched nonwoven Reprints and permissions:
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structure on the properties of sandwich DOI: 10.1177/0021998316658542
journals.sagepub.com/home/jcm
flexible composites under static loading
and low-velocity impact
Abstract
The current study fabricated nylon/high-resilience bonding polyester (HRPET) nonwoven fabric with various needle-
punching parameters and investigated the effect of these variations on the response of high-density flexible foam under
static loading and low-velocity impact. The needle-punching depth and frequency are selected as variations. The HRPET
fiber generates bonding-points when being thermally treated, which provides resilience properties on the sandwich
flexible composites. The results find a substantial relationship between the temperature of thermal treatment and the
absorption of low-velocity impact energy which is mainly because of the increase of fiber connection force. The impact
force is eliminated by 8255 N at most. Needle-punching depth contributes to resistance to static loading and the highest
resistance was 2043 N.
Keywords
Nonwoven fabrics, impact absorption, high-density sandwich flexible foam
property of the composites. Therefore, needle-punching point component on the impact resistance properties was
technique endows nonwoven fabric with easy manufactur- given. Nylon fiber is considered to be an impact-resistant
ing and high mechanical property. However, needle- material26–29 but the elasticity modulus is relatively
punching fabric-reinforced composites were rarely investi- lower than high-performance fibers.30,31 Previous
gated. The properties of needle-punching fabric and the researchers found that elastic materials exhibited high
corresponding composites need increasing attention. energy capacity.32,33 Therefore, flexible composites
Staple fiber reinforcing polymer is a wise way to used for load-buffering is manufactured through the
improve mechanical property with light-weight materials, needle-punching and laminating.
which is extensively used in aerospace and automobile
industry.10–13 Fiber-reinforced composites are mostly
composed of thermoplastic polymer and stable fibers. Experimental
Polymer chips blend with staple fibers to fabricate com-
Materials and fabrication
posites panel by injection molding to enhance the impact
and compressive resistance properties. Fiber fracture can The sandwich flexible composites were manufactured in
absorb more energy and eliminate cracking.14–16and sandwich structure which was composed of center-ply
then, the matrix exhibited high compressive strength of high-density flexible PU foam and cover-ply of
and stiffness.17–19 At present, researchers mostly investi- nylon/HRPET nonwoven laminates. High-density flex-
gate the impact resistance of fiber-reinforced rigid com- ible PU foam was supplied from Kuang Lung Shing
posites and the researches on fiber-reinforced flexible Corporation, Taiwan. Nylon staple fiber was purchased
composites are very rare. from Formosa Chemicals & Fiber Corporation, Taiwan.
Previous researches show that staple fiber reinforce- HRPET staple fiber is provided by Far Eastern New
ment can enhance the impact energy absorption and the Century Corporation, Taiwan. The specifications of
needle-punching technique improves the mechanical the staple fibers are shown in Table 1. DSC analysis of
property of nonwoven fabric without complicated pro- nylon and HRPET fibers are illustrated in Figures 1
cess. This study designed needle-punched nylon/ and 2. Flexible foam was made of two-component PU.
HRPET staple fiber nonwoven fabric-reinforced flex- Agent A is composed of polyols and agent B is isocyan-
ible polyurethane (PU) foam to make flexible compos- ate. The final PU foam has a density of 333 7.56 kg/m3
ites. The reason for applying flexible PU foam in this and the cell has open structure.
study is that flexible composites were considered to The sandwich flexible composites were composed
exhibit high elongation and resilience which affected of a flexible foam core and double nonwoven cover-
the tensile and tear properties in relative references.20–23 plies. Nylon and HRPET staple fibers are prepared in
The research presented that the properties ensured the different weight blending ratio to made single-layer
flexible composites to potentially absorb impact energy. nonwoven fabric by needle-punching. The laminated
Effect of variables of needle punching process on the nonwoven fabric was laminated through three layers
impact resistant property of composites and the relation- of nonwoven fabric and manufactured with various
ship between structure and impact resistant property will needle-punching depths of 1, 3, and 5 mm and vari-
be investigated in this research. Interlayer cohesion plays ous punching frequencies of 100, 200, and 300 needles/min.
an important role in impact energy transmission.24,25 Needle-punching depth is defined as the length between
The responses to static loading and low-velocity the needle tip and the lower surface of the fiber mesh
impact of nonwoven laminates-reinforced sandwich flex- (Figure 3(a)). Needle-punching frequency indicates the
ible composites were investigated. The effects of needle- number of punching of the needle plate per unit time
punching depth and frequency on the properties of sand- (Figure 3(b)). Then, the laminated nonwoven fabrics
wich flexible composites were explored because the two are thermal treated at different temperature for various
factors directly determined the degree of fiber entangle- durations, which were 170 C 15 min, 170 C 30 min,
ment and interlayer binding. The influence of different 180 C 15 min, and 180 C 30 min, to form the final non-
thermal-treating conditions of HRPET with low-melting woven laminates. The thermal-treating temperature
Figure 2. DSC analysis of HRPET staple fiber for the components of (a) sheath and (b) core.
Thickness of
Fiber blending the sandwich
Laminating ratio of Density of Thickness flexible Laminating
Sample structure cover-ply flexible foam of flexible composites structure of
code of cover-ply (nylon: HRPET) (kg/m3) foam (mm) (mm) composites
30N/70H A nylon nonwo- 3:7 333 7.56 20 20.76 0.41 Double nonwo-
40N/60H ven layer 4:6 333 7.56 20 20.04 0.23 ven laminates
50N/50H sandwiched 5:5 333 7.56 20 20.46 0.34 cover-plies
with double with flexible
HRPET layers center-ply
Figure 4. Schematic diagrams of testing instruments of (a) static loading and (b) low-velocity impact.
was set between the melting points between sheath and Agent B (isocyanate) were mixed up at a weight ratio
core of HRPET fiber to investigate the effect of sheath of 8:2 and stirred for 20 s to produce viscous mixture.
melting area on the impact property. Double layers The deployed viscous polymer mixture was infused
of nonwoven laminates were laid at the top and into the mold. The polyol and isocyanate blended to
bottom of the metal mold. Agent A (polyol) and generate foam reaction and cross-linking reaction.
Yan et al. 1049
Double-laminated nonwoven layers were penetrated by the response to static loading. The test was carried out
the viscous mixture and fibers and mixture stuck together by Instron 5566 Universal Testing Machine (UTM)
by own viscosity which was 2200 cps. The metal mold was (Instron, USA) according to ASTM D3787. The
sealed and stood at constant temperature and humidity sample was trimmed to a square with a dimension of
system (25 C, 65% relative humidity). Final sandwich 150 mm 150 mm. The bursting probe moved to pene-
flexible composites were obtained after curing for 2 h. trate the sample in overhead direction at a velocity of
The specification of the sandwich flexible composites 100 10 mm/min until the sample was totally perforated.
with various parameters is tabulated in Table 2. The bursting system was illustrated in Figure 4(a). Low-
velocity impact test was conducted by drop-weight
impact instrument which was supplied by Kuang Neng
Testing Factory Co., Ltd., Taiwan. The drop-weight impactor
The response to static loading and low-velocity impact of fell freely from the fixed-height of 6.5 cm to ensure a
sandwich flexible composites were investigated in this constant initial impact force of 9.0 kN. The sample
study. Bursting strength test was applied to measure was in a dimension of 100 mm 100 mm 20 mm. The
residual force was measured to evaluate the cushioning
capacity of the sandwich flexible composites. The drop-
weight impact instrument was illustrated in Figure 4(b).
Table 3. Effect of needle-punching depth on impact resistance
of sandwich flexible composites.
Figure 6. Stereomicroscope image of fiber pegs of nonwoven laminates with various needle-punching depths of (a) 1, (b) 3, and
(c) 5 mm (12, 600 dpi, fiber peg is marked by black dotted line).
1050 Journal of Composite Materials 51(8)
thermal treated at 170 C for 15 min but with various damage during the needle-punching process because of
needle-punching depths for 1, 3, and 5 mm. The its high puncture resistance and tenacity. The bursting
result shows that the sandwich flexible composites with strength was enhanced with the addition of nylon fiber
the needle-punching depth of 1 mm exhibited the when the probe contacts the middle layer. A similar phe-
highest bursting strength of 1884 N as shown in nomenon was also proposed by Martı́nez et al.5 that the
Figure 5. In terms of low-velocity impact, the sandwich degree of freedom of fiber slippage increased the energy
flexible composites with the needle-punching depth of consumption. Figure 7 depicted that load–displacement
3 mm exhibited the highest residual force range from curves in bursting test and it is evident that with the
1044 to 1066 N, which indicated that the sample elimi- increase in the nylon weight ratio of the middle layer
nated the most impact force. The residual force of sand- nonwoven fabric, the peak-load appeared at larger dis-
wich flexible composites with various needle-punching placement and the area became wide. Then, the highest
depths is shown in Table 3. bursting energy is 33.66 J (Table 4). This phenomenon
The main reason for the result of bursting test was demonstrated that fibers had large slippage during the
that the fiber pegs which exhibited in thickness direction bursting process and the sample had heavier deform-
of nonwoven laminates exhibited different lengths and ation. Although low HRPET ratio and high nylon
needle-punching depth directly influenced the peg length. fiber ratio provided higher deformation degree, the
Fiber pegs are made of entangled fibers which are gen- bursting-end deformed the foam layer with large area
erated by numeral puncture of needles. The plate needles because of the high resilience and elongation properties.
exhibited groove structure, which rub the fibers to move Bursting energy dissipated, and the rising curve in the
up and down and form entanglement with the recipro- load–displacement figure expanded; 50N/50H sample
cating motion of the plate. When the needle-punching with a needle-punching depth of 1 mm had short fiber
depth was small, the fibers entangled to fabricated short pegs and low-treated temperature which generated delam-
pegs as shown in Figure 6. Nylon fiber had less punching ination of nonwoven laminates.
Figure 7. Load–displacement curves in bursting test of sandwich flexible composites of (a) 30N/70H, (b) 40N/60H, and (c) 50N/50H
with various needle-punching depths.
Yan et al. 1051
The difference between the testing results of low-velo- energy was absorbed by the foam area. PU foam exhibited
city impact and bursting is generated by the interlayer high energy storage ability in another research because the
cohesion which is caused by the instant impact. The inter- foam cells absorbed the energy by deformation.20
layer cohesion of the sample with 1 mm depth exhibited
lower value because the fiber pegs performed low support- Effect of needle-punching frequency of nonwoven
ing force. Partial delamination appeared when the sample
was impacted by the drop-weight impactor. Relative
laminates on sandwich flexible composites
research indicated that delamination resulted in fiber Figure 8 shows that the bursting strength was the
breakage and low energy absorption.34,35 The sample highest when the needle-punching frequency was 100
with 3 mm needle-punching depth exhibited higher cush- needles/min and decreased with the needle-punching
ioning capacity than the sample with 5 mm depth. The frequency increasing to 300 needles/min. In terms of
main reason was that fiber pegs of 5 mm depth were low-velocity impact (Table 5), the cushioning capacity
longer and the cohesion between fiber pegs and the showed the highest value when the needle-punching fre-
fibers in the adjacent nonwoven layer was stronger. quency is 200 needles/min.
Then, laminated structure was more compact and the The main reason was that the friction between
fibers in laminates tended to break and elongation to fiber pegs and the bursting probe. Fiber pegs number
have less deformation, instead of slippage. Fiber elong- became lower when needle-punching frequency tended
ation and breakage consumed the impact energy and less to decrease. Then, the number of fiber pegs in unit area
Table 4. Bursting energy of sandwich flexible composites with Table 5. Residual force of sandwich flexible composites with
various needle-punching depths. various needle-punching frequencies.
1 21.62 17.16 33.66 100 1066.2 7.2 1110.7 7.4 1099.5 5.5
3 18.78 15.24 24.26 200 1044.0 7.0 1038.4 6.7 1066.2 6.8
5 17.94 13.21 22.42 300 1088.4 7.0 1055.1 7.6 1116.2 6.6
Figure 8. Bursting strength of sandwich flexible composites with various needle-punching frequencies.
1052 Journal of Composite Materials 51(8)
Figure 9. Load–displacement curve in bursting test of sandwich flexible composites of (a) 30N/70H, (b) 40N/60H, and (c) 50N/50H
with various needle-punching frequencies.
Figure 10. Effect of thermal-treating temperature on the bursting strength of the sandwich flexible composites.
Figure 11. Load–displacement curve in bursting test of sandwich flexible composites of (a) 30N/70H, (b) 40N/60H, and (c) 50N/
50H at various thermal-treating temperature.
31. Dehkordi MT, Nosraty H, Shokrieh MM, et al. Low used for snow sports protective equipment. Procedia
velocity impact properties of intra-ply hybrid composites Eng 2014; 72: 678–683.
based on basalt and nylon woven fabrics. Mater Design 34. Song JH. Pairing effect and tensile properties of lami-
2010; 31: 3835–3844. nated high-performance hybrid composites prepared
32. Oliveira-Salmazo L, Lopez-Gil A, Silva-Bellucci F, et al. using carbon/glass and carbon/aramid fibers. Compos
Natural rubber foams with anisotropic cellular struc- Part B-Eng 2015; 79: 61–66.
tures: mechanical properties and modeling. Ind Crop 35. Sarasini F, Tirillò J, Valente M, et al. Hybrid composites
Prod 2016; 80: 26–35. based on aramid and basalt woven fabrics: Impact
33. Nicotra M, Moncalero M, Messori M, et al. Thermo- damage modes and residual flexural properties. Mater
mechanical and Impact properties of polymeric foams Design 2013; 49: 290–302.