SCI ED 4 – ANALYTICAL CHEMISTRY

Name: Date: September 14, 2020

Course&Block:

Problem:
An ethanol-water solution is prepared by dissolving 10.00 ml of ethanol, C2H5OH
(d= 0.7829 g/ml), in a sufficient volume of water to produce 100.0 ml of solution with a
density of 0.982 g/ml. What is the concentration of ethanol in this solution, expressed as
:
A. Volume percent
B. Mass percent
C. Mass/volume percent
D. Mole fraction
E. Mole percent
F. Molarity
G. Molality
Given:
Volume = 10.00 ml
Density = 0.7829 g/ml
Volume of Solution = 100.0 ml
Density of Solution = 0.982 g/ml

Solute:
Volume C2H5OH = 10.00 ml (given)

Mass C2H5OH = 10.00 ml × density = 10.00 ml × 0.7829 g/ml = 7.829 g C 2 H 5 OH

Mass C2 H 5 OH 7.829 g C 2 H 5 OH
Moles C2H5OH = = = 0.170 mol C 2 H 5 OH
Molar MassC 2 H 5 OH 46.07 g /mol
Solution:
Volume of Solution = 100.0 mL (given)
Mass of Solution = Volume of Solution × Density of Solution
 = 100.0 g solution × 0.982 g/mL
= 98.2 g solution
Solvent:
Mass H2O (Solvent) = Mass Solution - Mass Solute
= 98.2 g - 7.829 g
= 90.4 g H2O
1 mol H 2 0
Moles H2O (Solvent) = 90.4 g H2O ×
18.02 g H 2 0

= 5.02 mol H2O

Answers:
v Vol . of Solute 10.00 ml C2 H 5 OH
A. %Volume= = x 100 = x 100 = 10.00% C 2 H 5 OH
v % Vol . of Solution 100.00 ml solution

w mass of Solute 7.829 g C 2 H 5 OH

B. %Mass= = x 100 = x 100 = 7.97% C 2 H 5 OH
w % Massof Solution 98.2 g solution

Mass m mass of Solute 7.829 g C 2 H 5 OH

C. % = = x 100 = x 100 = 7.82% C 2 H 5 OH
Volume v % mL of Solution 100.0 ml solution

moles of Solute 0.170 mol C2 H 5 OH

D. % Mole fraction = of moles of ( solute+ solvent )¿ = =
total ¿ 5.19 mol H 2 0
0.0328
0.170 mol C2 H 5 OH
E. % mole = Mole fraction x 100 = x 100 = 3.28%
5.19 mol H 2 0

moles of solute 0.17 o mol C 2 H 5OH

F. molarity = M = ×100 ¿ × 100 = 1.70 M C 2 H 5 OH
Liters of Solution 0.1000 L solution

moles of solute 0.17 o mol C 2 H 5OH

G. molality = m = × 100¿ × 100 = 18.05m C 2 H 5 OH
Kg Solvent 00904 kg H 2 0