A.

ANALISIS DATA
1. Titrasi I
Diketahui:
V CHCl3 = 1,5 mL
V H2O = 2,5 mL
V CH3COOH = 4,0 mL
ρ CHCl3 = 1,498 g/mL
ρ H2O = 1,01 g/mL
ρ CH3COOH = 1,05 g/mL
Mr CHCl3 = 119,5 g/mol
Mr H2O = 18 g/mol
Mr CH3COOH= 60 g/mol
Ditanyakan:
X CHCl3 =…?
X H2O =…?
X CH3COOH =…?
Penyelesaian:
 m CHCl3 = V CHCl3 x ρ CHCl3
= 1,5 mL x 1,498 g/mL = 2,247 gram
mCHCl3 2,247 gram
n CHCl3 = = = 0,018 mol
Mr CHCl3 119,5 g /mol
 m H2O = V H2O x ρ H2O
= 2,5 mL x 1,01 g/mL = 2,525 gram
m H2O 2,525 gram
n H2O = = = 0,140 mol
Mr H 2 O 18 g /mol
 m CH3COOH = V CH3COOH x ρ CH3COOH
= 8,5 mL x 1,05 g/mL = 8,925 gram
mCH 3 COOH 4,0 gram
n CH3COOH = = = 0,067 mol
Mr CH 3 COOH 60 g /mol
n total = n CHCl3 + n H2O + n CH3COOH
= 0,018 mol + 0,140 mol + 0,067 mol = 0,225 mol
 n CHCl3 0,018 mol
X CHCl3 = = = 0,080
n total 0,225 mol
n H 2 O 0,140 mol
X H2O = = = 0,622
n total 0,225 mol
n CH 3 COOH 0,067 mol
X CH3COOH = = = 0,298
n total 0,225 mol
2. Titrasi II
Diketahui:
V CHCl3 = 2 mL
V H2O = 2,5 mL
V CH3COOH = 5,8 mL
ρ CHCl3 = 1,498 g/mL
ρ H2O = 1,01 g/mL
ρ CH3COOH = 1,05 g/mL
Mr CHCl3 = 119,5 g/mol
Mr H2O = 18 g/mol
Mr CH3COOH= 60 g/mol
Ditanyakan:
X CHCl3 =…?
X H2O =…?
X CH3COOH =…?
Penyelesaian:
 m CHCl3 = V CHCl3 x ρ CHCl3
= 2,5 mL x 1,498 g/mL = 3,745 gram
mCHCl3 3,745 gram
n CHCl3 = = = 0,031 mol
Mr CHCl3 119,5 g /mol
 m H2O = V H2O x ρ H2O
= 2,5 mL x 1,01 g/mL = 2,525 gram
m H2O 2,525 gram
n H2O = = = 0,140 mol
Mr H 2 O 18 g /mol
 m CH3COOH = V CH3COOH x ρ CH3COOH
= 5,8 mL x 1,05 g/mL = 6,090 gram
 mCH 3 COOH 6,090 gram
n CH3COOH = = = 0,101 mol
Mr CH 3 COOH 60 g /mol
n total = n CHCl3 + n H2O + n CH3COOH
= 0,031 mol + 0,140 mol + 0,101 mol = 0,272 mol
n CHCl3 0,031mol
X CHCl3 = = = 0,114
n total 0,272mol
n H 2 O 0,140 mol
X H2O = = = 0,515
n total 0,272 mol
n CH 3 COOH 0,101mol
X CH3COOH = = = 0,371
n total 0,272mol
3. Titrasi III
Diketahui:
V CHCl3 = 2,5 mL
V H2O = 2,5 mL
V CH3COOH = 5,1 mL
ρ CHCl3 = 1,498 g/mL
ρ H2O = 1,01 g/mL
ρ CH3COOH = 1,05 g/mL
Mr CHCl3 = 119,5 g/mol
Mr H2O = 18 g/mol
Mr CH3COOH= 60 g/mol
Ditanyakan:
X CHCl3 =…?
X H2O =…?
X CH3COOH =…?
Penyelesaian:
 m CHCl3 = V CHCl3 x ρ CHCl3
= 2,5 mL x 1,498 g/mL = 3,745 gram
mCHCl3 3,745 gram
n CHCl3 = = = 0,031 mol
Mr CHCl3 119,5 g /mol
 m H2O = V H2O x ρ H2O
= 2,5 mL x 1,01 g/mL = 2,525 gram
 m H2O 2,525 gram
n H2O = = = 0,140 mol
Mr H 2 O 18 g /mol
 m CH3COOH = V CH3COOH x ρ CH3COOH
= 5,1 mL x 1,05 g/mL = 5,355 gram
mCH 3 COOH 5,355 gram
n CH3COOH = = = 0,089 mol
Mr CH 3 COOH 60 g /mol
n total = n CHCl3 + n H2O + n CH3COOH
= 0,031 mol + 0,140 mol + 0,089 mol = 0,260 mol
n CHCl3 0,031 mol
X CHCl3 = = = 0,119
n total 0,260 mol
n H 2 O 0,140 mol
X H2O = = = 0,538
n total 0,260 mol
n CH 3 COOH 0,089 mol
X CH3COOH = = = 0,342
n total 0,260 mol

4. Titrasi IV
Diketahui:
V CHCl3 = 3 mL
V H2O = 2,5 mL
V CH3COOH = 5,7 mL
ρ CHCl3 = 1,498 g/mL
ρ H2O = 1,01 g/mL
ρ CH3COOH = 1,05 g/mL
Mr CHCl3 = 119,5 g/mol
Mr H2O = 18 g/mol
Mr CH3COOH= 60 g/mol
Ditanyakan:
X CHCl3 =…?
X H2O =…?
X CH3COOH =…?
Penyelesaian:
 m CHCl3 = V CHCl3 x ρ CHCl3
 = 3 mL x 1,498 g/mL = 4,494 gram
mCHCl3 4,494 gram
n CHCl3 = = = 0,037 mol
Mr CHCl3 119,5 g /mol
 m H2O = V H2O x ρ H2O
= 2,5 mL x 1,01 g/mL = 2,525 gram
m H2O 2,525 gram
n H2O = = = 0,140 mol
Mr H 2 O 18 g /mol
 m CH3COOH = V CH3COOH x ρ CH3COOH
= 5,7 mL x 1,05 g/mL = 5,985 gram
mCH 3 COOH 5,985 gram
n CH3COOH = = = 0,099 mol
Mr CH 3 COOH 60 g /mol
n total = n CHCl3 + n H2O + n CH3COOH
= 0,037 mol + 0,140 mol + 0,099 mol = 0,276 mol
n CHCl3 0,037 mol
X CHCl3 = = = 0,134
n total 0,276 mol
n H 2 O 0,140 mol
X H2O = = = 0,507
n total 0,276 mol
n CH 3 COOH 0,099 mol
X CH3COOH = = = 0,358
n total 0,276 mol
5. Titrasi V
Diketahui:
V CHCl3 = 3,5 mL
V H2O = 2,5 mL
V CH3COOH = 5,9 mL
ρ CHCl3 = 1,498 g/mL
ρ H2O = 1,01 g/mL
ρ CH3COOH = 1,05 g/mL
Mr CHCl3 = 119,5 g/mol
Mr H2O = 18 g/mol
Mr CH3COOH= 60 g/mol
Ditanyakan:
X CHCl3 =…?
 X H2O =…?
X CH3COOH =…?
Penyelesaian:
 m CHCl3 = V CHCl3 x ρ CHCl3
= 3,5 mL x 1,498 g/mL = 5,243 gram
mCHCl3 5,243 gram
n CHCl3 = = = 0,044 mol
Mr CHCl3 119,5 g /mol
 m H2O = V H2O x ρ H2O
= 2,5 mL x 1,01 g/mL = 2,525 gram
m H2O 2,525 gram
n H2O = = = 0,140 mol
Mr H 2 O 18 g /mol
 m CH3COOH = V CH3COOH x ρ CH3COOH
= 5,9 mL x 1,04 g/mL = 6,136 gram
mCH 3 COOH 6,136 gram
n CH3COOH = = = 0,102 mol
Mr CH 3 COOH 60 g /mol
n total = n CHCl3 + n H2O + n CH3COOH
= 0,044 mol + 0,140 mol + 0,102 mol = 0,286 mol
n CHCl3 0,044 mol
X CHCl3 = = = 0,154
n total 0,286 mol
n H 2 O 0,140 mol
X H2O = = = 0,490
n total 0,286 mol
n CH 3 COOH 0,102 mol
X CH3COOH = = = 0,357
n total 0,286 mol

TITRASI TITIK X CHCl3 X H2O X CH3COOH

I a 0,080 0,622 0,298

II b 0,114 0,515 0,371

III c 0,119 0,538 0,342

IV d 0,134 0,507 0,358

V e 0,154 0,490 0,357