CM Test-XI - Paper-1 - Answer & Solutions - 23-08-2021

CM Test-PT-I-(Paper-1)-PCM-IITJEE_XI-2123
14
FIITJEE MONTHLY ASSESSMENT TEST-1

PHYSICS, CHEMISTRY & MATHEMATICS
IIT-JEE, 2022-23
QP CODE:
ANSWERS
PHYSICS C.CODE CHEMISTRY C.CODE MATHEMATICS C.CODE
1 BD P110308 1 AD C111204 1 ABCD M111401
2 B P110304 2 C C111101 2 AB M111403
3 ABD P110202 3 BC C111206 3 ABC M111401
4 ACD P110301 4 C C110105 4 BCD M111701
5 ABC P110304 5 D C110103 5 ABCD M111803
6 AB P110307 6 BD C110101 6 CD M111402
7 BD P110310 7 AD C111201 7 BC M120307
8 B P110304 8 B C110102 8 B M111402
9 B P110307 9 B C110103 9 B M111401
10 C P110305 10 C C111101 10 B M111601
11 C P110304 11 B C111104 11 B M120701
12 D P110302 12 B C111204 12 D M110604
13 B P110302 13 B C111206 13 D M111404
14 C P110309 14 B C111203 14 B M111401
15 C P110308, 15 D 15 B
C111103 M111402
P110305
16 D P110308, 16 A 16 A
C111103 M111402
P110305
17 B P110305 17 B C111103 17 C M111304
18 D P110305 18 D C111103 18 B M111304
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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15
HINTS OR SOLUTION
Physics
1. BD
1. At the instant of maximum separation both have same velocity
Maximum separation
 2  2  1 1
1 1 
 2  2  2  2  1 1 = 5 – 2.5 = 2.5 m
 
2 B
54 5
2.   3m / s
5 18
72 5
  4m / s
5 18
For A and C colide at D
u sin  = 3 ….… (1)
For A and B collide at D
u cos  = 4 ……. (2)
(1)2  (2)2  u2  3 2  4 2
u = 5 m/s
3 ABD
3. Let A = B = C = D = 2

A  2 ˆj

C  2 î

B  î  ˆj

D  î  ˆj
 
A  C  2 ˆj  2 î

  2D
  
b. BD 2C
 î  ˆj  î  ˆj  2 2 î
16

0
 
AC 2 ˆj  2 î

2 2

 
 î  ˆj  B
4. ACD
4.
1
g6
2
h  u(6) 
2
1
g  2
2
 u(2) 
2
 u  20m / s
 h  60m
5. ABC
u sin 60º
5. (a) 2
g
u 3 40
2u m/s
20 3
2
 40 
2   sin120º
u sin2  3 
(b) 
2g 20
40  40 3 40
   m
20  3 2 3
1 2 u sin2 
(c) h gt 
2 2g
2 2
1 2  40  sin 60º
  10  2    
2  3 2g
2
 40 3 1
 20   
 3 2  20
 
= 20 + 20 = 40 m
17
6. AB
dv v 2

dt R
v t dt
 v 0
v 2 dv   0 R
v
 v 21  t0
    
 2  1   R 
 v0
 1 1  t
  
 v v  R
 0
1 1 t R  v0t
  
v v0 R Rv 0
Rv 0
v
R  v0t
dv ds dv v2
 
dt dt ds R
vdv v2

ds R
v dv s ds
0 v
 0 R
 v  S
ln  
 v  R
 0
V  V0 e S / R
7. BD
8. B

8. v  î  6t ˆj
2
x  vxt  t  sec
3

 dv
a  0  6ˆj
dt
18
v  12   6t 
2
v  1  36t 2
dv
at 
dt
1
 
1 1
 1  36t 2 2 (72t)
2
36t

1  36t 2
 2
36  
at   3 
2
 2
1  36  
 3 
12 2
at 
1 8
at = 4 2 m/s2
a c2  a 2t  a 2
ac  36  32  2m / s
v2
ac 
R
2
 2
1  36  
 3 
R
2
1 8
R  4.5m
2
9. B
 
9. e1  e 2  12  12  2 11 cos 
 1  1  2cos 
 2 1  cos  
 2  2sin2  / 2
 1 
sin  e1  e 2
2 2
10. C
10. v x  10 sin 45º 10 sin 45º  2 
19
= 10 sin 45º
v y  10cos 45º
v  v 2x  v 2y  10m / s
11 C
11. u cos60º = v cos30º
u
V=
3
 v sin30º 2  usin60º 2  2gh

2
3u2  u 
 2gh   
4 2 3 
9u2  u2
2gh 
12
u  3gh
12 D
12. a  k1  k1t
3
at t = 0, a =  k1
4
3
a  k 2t
4
3
0   k 2 3
4
1
k2  
4
dv 3 t
a 
dt 4 4
t
3 t2 
 v 10  t 
 4 8 
0
3 t2
10  t
4 8
t 2  6t  80  0
6  36  4  80
t
2
= 12.43 sec
20
13 B
13. a  v1/ 2
0 t
v 0
v 1/ 2 dv   0 dt
0
  1 1 
v 2 
     t 0 
  1  1
 2  v 0
0
 
 v1/ 2 
    t
  1  1
 2  v
0
2 v0
t=

14. C
After t = 4s, velocity of the car up the incline is
-1
VC = u + at = 0 + 2 × 4 = 8 ms
  
v RC  v R    v C 
 
vRC cannot be vertical if v R is in the direction shown in (a) above. In this case, we cannot have

vRC in the vertical direction.
Hence, the correct direction of rainfall is as shown in (b) above.
  
In the diagram shown, vRC is vertical and v R makes  = 37º with it. Hence, v R is normal to the
incline.
21
vC
  tan37º
vR
8 3 32
   vR   10.67ms 1
vR 4 3
15. C
16. D
Sol. 15-16
(i) Consider the x and y-directions as shown in the figure below. Acceleration of the particle is g()
and can be resolved as :
a x  gsin ,a y  gcos 
Relative to the box, the componenets of acceleration are

a xb   g sin     g sin    0
a yb  gcos   0   cos 
Relative to the box, the componenets of initial velocity of the particle are
u xb  ucos 
u Yb  u sin 
In RF of the box, the time of flight can be calculated using
22
y  u yb t  a yb t 2
1 
 0   usin   T   gcos  T 2
2 
2u sin 
 T
gcos 
PQ = Range of the projectile in RF of the box
1
u xb .T  a T2
2 xb
  u cos   T  a sb  0 
2usin 
 ucos 
gcos 
(ii) Taking x and y as horizontal and vertical,

Velocity of the box can be written as

v b   v cos  î  v sin ˆj
Initial velocity of the particle relative to the box is


uPb  ucos      î  usin      ˆj
 
 uP  v b  ucos      î  u sin      ˆj

 uP  ucos      î  usin      ˆj
 v cos  î  v sin  ˆj
 ucos       v cos   î  u sin       v sin   î
If the particle does not move horizontally, it means that the x componenet of the
above velocity is zero.
 u cos       v cos 
ucos     
 v
cos 
23
17. B
Vx = ux + axt
 80 – 40 = 40 m
Ans. D
CHEMISTRY
1. AD
 an2 
 P  2   V  nb   nRT
 V 

 a 
 P  2   V  b   RT
 V 
2. C
As 2S 3  SO 24
As3   As 5 ; S 2  S 6

4 24
n-factor = 28 for As 2S 3
3. BC
3PV 3
K.E.   RT
2 2
K.E.  P at constant volume
K.E.  T at constant – pressure
Ans. C
hc 6.6  10 34  3  108

E 
 854  10 10
For 1 mole
24
6.6  10 34  1018  3  6.022  10 23

Emole 
854
6.6  107  3  6.022


854
7
= 0.139 0 × 10 J/mole
3
= 1.39 × 10 KJ/mole
5. D
6. BD
7. AD
8. B
Balmer means transition
to n = 2
1. line  3 to 2
2. line  4 to 2
3. line  5 to 2
9. B
1  1
 RH  1  
1  4
25
1 3
 RH 
1 4
4
1 
3RH
9
2 
8RH
1  9 16 
1   2    
RH  8 15 
1  32  27 
  
RH  24 
1 5 
  
RH  24 
9/8
2 
RH
16
3 
15RH
1 4 9
2  3  
RH  3 8 
1  135  128 

RH  120 
1 7
 
RH 120
5 / 24
Ratio =  3.5
7 /120
10. C
2
10e 
N2H4 
 Y : N should be in +3 or - 7
N2  N3   5e 
(N can’t be in – 7, because it should be oxidation)

11. B
m. mole of NaHC2O4 = 2; m.mole of H2C2O4 = 2
m.eq. of KMnO4 = 0.05 × V × 5 V
 0.05 × V × 5 = (2 × 2) + (2 × 2) = 8
8
 V  32ml
0.05  5
12. B
b = 4 Vm
4
b = 4 × NA  r
3 3
26
 V1  V  nb
 nb  V  V1
V  V1 4 3
b  4  NA  r
h 3
 3  v  V1  
 r 
 16 nNA 
 8  3  V  V1  
1/ 3
diamater = 2r   
 16 nNA 
13. B
2R T 3R  700
M.P.S. =   R.M.S
MO MN
2 2
On solving  T = 1200 K
= 927ºC
14. B
PV
If z> 1 then 1
nRT
P  22.4
1
1 273  0.0821
P > 1.
15. D
16. A
Sol. 15-16
When HPh is used : Na 2CO 3  NaHCO 3
Eq. of Na2CO3 = Eq. of HCl

mole of Na2CO3 × 1 = mole of HCl × 1
–3 –4
mole of Na2CO3 = 0.12 × 8 × 10 = 9.6 × 10 mole
 9.6 × 10 mole of NaCO3 present in 25 ml diluted solution
–4
 Orignal mole of Na2CO3 present = 9.6 × 10 in 250 ml of diluted solution.

-3
n
When MeOH is used (20 ml sol is used)
Eq. of Na2CO3 + Eq. of NaHCO3 = Eq. of HCl
-3 20 -3
9.6 × 10 × 2 + mole of NaHCO3 = 0.12 × 18 × 10
250
-4
mole of NaHCO3 6.24× 10
 6.24 × 10 mole NaHCO3 present in 20 ml of solution
-4
250
 In 250 ml NaHCO3 present = 6.24 × 10 ×
-4
20
27
-3
7.8 × 10 mole
 In original 25 ml stock the mole of compounds are
-3
NaHCO3 = 7.8× 10 mole = 0.6552 g.
-3
Na2CO3 = 9.6 × 10 mole = 1.0176 g.
1000
NaHCO3 (g/lt) = 0.6552   26.208
25
* In 100ml stok
100
mole of NaHCO3 = 7.8  10 3   31.2  10 3
25
reaction would be
 NaOH required = 31.2 × 10 mole
-3
-3
= 31.2 × 10 × 40 g
= 1.248 g
17. B
Pe v / 2  nCT
T = 500 K
N = 2 moles
P = 1 atm
On solving
1 e 0
C=  0.001
500  2
18. D
P.e v / 2  nCT
nC
P T
ev / 2
nC
Slope 
ev / 2
C = 0.001 & V = 2L
N=2
2
P e 1
1000
28
MATHEMATICS
1. ABCD
 
A. For x   0,  , tanx < cotx
 4
Also ln(sinx) < 0
 (tanx)
ln(sinx) ln(sinx)
> (cotx)
 
B. For x   0,  , cosecx  1
 2
 ln(cosecx)  0
4
ln(cosecx) ln(cosecx)
<5
 
C. x   0,   cos x  (0, 1)
 2
 ln(cosx) < 0
 
D. For x   0, 
 2
Since sinx < tanx, we get ln(sinx) < ln(tanx)
2
ln(sinx) ln(tanx)
<2
2. AB
    
For    0,    , 
 4 4 2
1
Let cos 4 
3
1  cos 4 2
 cos 2   
2 3
 1 2 2cos2  1
f     1
 3  2  sec  2cos   1 cos 2
2 2
 1 3 3
 f    1 or 1 
 
3 2 2
3. ABC
3 = 4  log2 3 = (x – 1)log2 4 = 2(x – 1)
x x-1 x
or xlog2 3 = 2x – 2
2
or x =
2  log2 3
Rearranging, we get
2 2log3 2
x 
2
1 2log3 2  1
log 3 2
4. BCD
5. ABCD
6. CD
7. BC
Square and add
29
8. B
Let the radius of the smaller circle be x. Here

OP = x cosec 30º
And OQ = r = x + x cosec 30º
r
x=
3
9. B
For maximum value,
 cos x = 2a – 1
2 2
 sin x = 1 – cos x = (2 – 2a )
2 2 2
 2a + sin x = 2
2 2
 Maximum value of sin2 x  2a2  2a2  1  cos2 x
= 2 0  2
10. B
Since  <  <  <  and sin = sin = sin = sin = k, we have
 =  - ,  = 2 + ,  = 3 - 
   
 4 sin  3 sin  2 sin  sin
2 2 2 2
   
= 4 sin  3cos  2sin  cos
2 2 2 2
 
= 2sin  2cos  2 1  sin   2 1  k
2 2
11. B
12. D
13. D
14. B
15. B
16. A
30
15-16
A B    
Sol. In given ABC both and lie strictly in  0,  and sinx is always increasing in  0,  whereas
2 2  2  2
 
cosx is always decreasing in  0,  .
 2
A B
So, if 
2 2
A B
 sin  sin
2 2
1 1
or x1 > x2 and x3 < x4 or 
x3 x 4
So, x12007 x 2006
4  x 2007
2 x 32006 is not valid
A B
Similarly for 
2 2
A B
 sin  sin
2 2
1 1
 x1 < x2 and 
x3 x 4
For this also x12007 x 2006
4  x 2007
2 x 32006 is not valid.
2007 2006
x  x  A B
So  1   3   0 is possible only when  .
 x2   x4  2 2
1 1
 x1 = x2 and 
x3 x 4
Hence, ABC is isosceles with ABC = CAB
 BC = AC = 1 unit
If C = 90º
1 1
Area, A = BC  AC  sq. units
2 2
17. C
18. B
3x  a
f(x)  2
(i) We have x 3
3 3x  a
Now,  2  3x 2  9  6x  2a
2 x 3
 3x 2  6x  9  2a  0
This must be a perfect square, so
D  0  36  12(9  2a)  a  3
3x  3
(ii) y  f(x)   x 2 y  3y  3x  3
x2  3
 x 2 y  3x  3  3  0
As x  R, so D  0
 9  4y(3y  3)  0
 (2y  3)(2y  1)  0
 1 3 
Hence y   , 
 2 2
1   
Hence minimum value of f(x) is  sin  
2  6

CM Test-XI - Paper-1 - Answer & Solutions - 23-08-2021

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CM Test-PT-I-(Paper-1)-PCM-IITJEE_XI-2123

FIITJEE MONTHLY ASSESSMENT TEST-1

 v sin30º 2  usin60º 2  2gh

Hence, the correct direction of rainfall is as shown in (b) above.

Relative to the box, the componenets of acceleration are

In RF of the box, the time of flight can be calculated using

PQ = Range of the projectile in RF of the box

(ii) Taking x and y as horizontal and vertical,

Initial velocity of the particle relative to the box is

 ucos       v cos   ˆi  u sin       v sin   ˆi

As3   As 5 ; S 2  S 6

hc 6.6  10 34  3  108

6.6  10 34  1018  3  6.022  10 23

6.6  107  3  6.022

(N can’t be in – 7, because it should be oxidation)

When HPh is used : Na 2CO 3  NaHCO 3

Eq. of Na2CO3 = Eq. of HCl

 Orignal mole of Na2CO3 present = 9.6 × 10 in 250 ml of diluted solution.

Let the radius of the smaller circle be x. Here

 Maximum value of sin2 x  2a2  2a2  1  cos2 x

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