Test ID : 615

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LT & XII – 2ND 50% PORTION TEST (2ND YEAR) CHEMISTRY - IIB (ANSWER KEY) - 02.07.2021
Choose the correct answer : 125 x 4 = 500
1. 4) Zn 10. 1) Np
Solution : Solution :
Zn does not show variable oxidation state due Transuranic elements are the elements having
to 3d104s2 configuration (very stable) atomic number greater than 92.
2. 1) +7 Atomic number of Np = 93
Solution : Transuranic element begin with Np
KMnO4, oxidation state of Mn = +7
11. 3) 12
3. 4) All of these
Solution :
Solution :
In[Pt(en)2Cl2], there are 2 monodentate and 2
E oM2+ /M depends on all the given factors
bidentate ligands
4. 1) Cr+ Hence, electrons donated by ligands
Solution : =2x2+2x4
Cr+ = 3d5, µ = 5.92 BM =4+8
5. 1) Pm
= 12
Solution :
12. 4) NH3
Pm is radioactive
Solution :
6. 1) Ce(OH)3
NH3 can bind only from “N” side, so NH3 is
Solution :
not an ambidentate ligand
As we go right to period, basic nature of
hydroxides decreases. 13. 2) 2, 4
Ce(OH)3 is most basic among the given Solution :
2−
7. 4) CrO3, CrO 4 [Cu(NH3)4]SO4 ⇌ [Cu(NH3)4]2+ + SO 24 −
Solution : Primary valencies = oxidation state = 2
OH − 2−
2CrO3 + H2O → H2Cr2O7 
→ CrO 4 Secondary valencies = coordination number = 4
(X) (Y) 14. 3) Potassium tetrafluoridoborate (III)
8. 1) CrO5 Solution :
Solution : IUPAC name of K[BF4] is potassium
K2Cr2O7 + H2SO4 + 4H2O2 tetrafluoridoborate (III)
→ 2CrO5 + K2SO4 + 5H2O 15. 4) All of these
(Blue) Solution :
9. 4) Misch metal Homoleptic complexes are the complexes
Solution : having all the ligands are identical
Misch metal contains 95% Lanthanide metal All the given complexes are homoleptic
and 5% iron and trances of S, C, Ca and Al.
 2 Test ID : 615
4-
16. 1) 3, 6 22. 4) [Fe(CN)6]
Solution : Solution :
3 moles of white ppt ⇒ 3 moles of AgCl [Fe(CN)6]4-, Fe2+ = 3d6
3Cl- are outside the coordination sphere, hence
primary valency is 3
6NH3 are coordinated with cobalt, in the CN- is strong field ligand
coordination sphere hence secondary valency No unpaired electron, zero magnetic moment,
is 6 Diamagnetic nature.
17. 2) Ionisation isomerism 23. 4) -1.8 ∆o
Solution :
Solution :
[Cr(H2O)5Cl]Br and [Cr(H2O)5Br]Cl are the
d7 configuration is strong field ligand
complexes which forms different ions in
solution having same molecular formula are
ionization isomers
18. 4) [Co(en)3]3+ CFSE = [-0.4 x 6] + [0.6 x 1] ∆o
Solution :
= -1.8 ∆o
[Co(en)3]3+ will not show geometrical
24. 2) [Ni(CN)4]2-
isomerism, because only one structure is
possible Solution :
19. 1) sp3 [Ni(CN)4]2-, Ni2+ = 3d8
Solution :
Ni(CO)4, Ni = 3d10

25. 3) [Pt(NH3)4] [CuCl4]

Solution :
20. 1) 3 BM
[Pt(NH3)4] [CuCl4] and [Cu(NH3)4] [PtCl4]
Solution :
are one of the possible isomers for same
K3[Fe(CN)6], Fe3+ = 3d5 chemical formula having different
CN- is strong field ligand coordination spheres.
one unpaired electron, n = 1 26. 2) dx2-y2, dz2
µ= n(n + 2) = 1(1 + 2) = 3 BM Solution :
In the formation of octahedral complexes,
21. 2) I < II < III
ligand approaches the metal ion along the
Solution :
coordination axes
→ With the increases of the size of central
27. 4) All of these
metal ion, d-d splitting increases
Solution :
→ CFSE increases
Stability of complex depends on all the given
→ The correct order should be I < II < III
factors
 3 Test ID : 615
3+
28. 4) [M(en)3] 34. 1) XY2O4
Solution : Solution :
Stability of complex ∝ Chelation 1 1
O2- → ccp = 8 x +6x =4
29. 3) d2sp3 8 2
Solution : 1 1
[Cr(NO2)4(NH3)2]-, Cr3+ = 3d3 X2+ → of Td = x 8 = 1
8 8
1 1
Y3+ → of oct = x 4 = 2
2 2
X1Y2O4
35. 4) 8, 4
30. 3) 9
Solution : Solution :
AB2, CaF2 type of crystal which has
Coordination number = 8:4
36. 3) 8
Solution :
rRb+ 148
Coordination number of M is 6 = = 0.75
rBr − 195
oxidation state of M is +3
Sum of coordination number and oxidation This ratio (0.75) is more than 0.732, so it has
number of the metal (M) is 9 cubic structure and has coordination number = 8
31. 1) 5 and 14 37. 4) All of these
Solution : Solution :
Two dimensional lattices are 5[square, a
For SC r=
rectangle, Rhombus, parallelogram, 2
Hexagonal]
For BCC 4r = 3a
Three dimensional lattice are = 14 [Bravais
lattices] For FCC 4r = 2a
32. 3) Cu4Ag3Au 2a a
r= =
Solution : 4 2 2
1 1 38. 1) 265 pm
Cu, ccp = 8 x + 6 x = 4 atoms of Cu
8 2 Solution :
1
Ag, Edge centres = 12 x = 3 atom of Ag a 530 pm
4 (r+ + r-) = = = 265 pm
2 2
Au, at body centre = 1 x 1 = 1 atom of Au
39. 3) Zinc oxide shows metal excessive defect
Cu4Ag3Au
Solution :
33. 2) Covalent solids
∆ 1
Solution : ZnO  → Zn2+ + O2 + 2e-
2
Network (or) covalent solids have highest
melting point due to network structure, in It causes excess of Zn in lattice causing
which bonds are tightly held like SiO2 metal excess defect
 4 Test ID : 615
1 44. 1) A, B
40. 1)
4 Solution :
Solution : On increasing temperature co-ordination
number decreases
ZxM
d= (M, NA are constants) On increasing pressure co-ordination number
NA x a 3
increases
d Fcc ZFcc a 3Bcc 45. 2) Frenkel defect
= x
d Bcc ZBcc a 3Fcc Solution :
Density remains same in Frenkel defect
4 (2)3 1
= x = 46. 3) Specific conductance increases with
2 (4)3 4 dilution
1.5 Solution :
41. 1) x 1024
58.5 Specific conductance not increases with
Solution : dilution because on dilution number of ions
decreases per unit volume, so specific
1 unit cell → 4 NaCl molecules
conductance decreases.
1 mole unit cell → 4 moles of NaCl molecules 47. 3) 104/r
23
6 x 10 unit cells = 4 x 58.5 g Solution :
x unit cells = 10g C = 0.1 M
6 x1023 x10 1.5 x10 24 k x1000 1 1
x= = Λm = k= =
4 x 58.5 58.5 M ρ r

2) 2 x 10-22 cm3 1 
 r  x1000
42.
 1
Solution : Λm = ∴ k = 
0.1  r
a3 = volume [Z = 4]
Λm = 104/r
ZxM 48. 1) 3.71 x 10-5
d=
NA x a3 Solution :
ZxM CaF2 + H2O → CaF2 solution
d= -5
NA x V x 0.15 x 10 3.86 x 10-5
x + 0.15 x 10-5 = 3.86 x 10-5
ZxM 4 x 60.23
V= = x = 3.71 x 10-5
d x N A 2 x 6.023 x1023
49. 2) 0.043
2 x10 Solution :
= 23
= 2 x 10-22 cm3
10 NH4Cl + NaOH → NaCl + NH4OH
43. 4) Ionic solids show Schottky defects only 3 3 3 3
Solution : 130 218 120 x
Ionic solids must always maintain electrical 130 + 218 = 120 + x
neutrality. Ionic solids show vacancy or x = 228 of Λ ∞NH4OH
interstitial defects as Frenkel and Schottky Λ Cm 10
defect α= = = 0.043
Λ ∞m 228
 5 Test ID : 615
50. 3) 50 54. 3) x = y, K = K2 2
1
Solution :
Solution :
Ect
W= Eo remain same if reaction is multiplied by or
96500
divided by any coefficient because, Eo is
E x 9.65 x10 x 60
3= intensive property. [independent on amount]
96500
3 = E x 0.06 So x = y
3 K1 =
[ C][ D]
E= = 50
0.06 [ A ][ B]
51. 3) 33.6 L
[ C] [ D ]
2 2

Solution : K2 =
[ A ] [ B]
2 2
Dil.H2SO4 electrolysis
At cathode 2H+ + 2e- → H21 K2 = K12
22.4
Equivalent volume = = 11.2 L for 1F 55. 3) Velocity of K+ and NO3− are nearly same
2
At anode 4OH- → O21 + 2H2O + 4e- Solution :
22.4 Velocity of K+ and NO3− are nearly same, so
Equivalent volume = = 5.6 L for 1F
4 that neutralization of opposite ions take place
Total volume of gases for 1F = 11.2 + 5.6 L at same rate (or) at same time by which
= 16.8 L current flows with same rate.
So, 2F = ? 56. 4) +1.56 V
16.8 x 2 = 33.6 L
Solution :
2+ 2+
52. 2) Zn (s) | Zn (0.002M ) || Cu (0.2M) | Cu (s)
Zn + Cu2+ → Zn2+ + Cu ∆G1o = -nF E ocell ,
Solution :
∆G1o = -2F (1.1), ∆G1o = -2.2F
0.0591 Cu 2+ 
E = E cell +
o
log
n  Zn 2+  Cu + 2Ag+ → Cu2+ + 2Ag ∆G o2 = -nF E ocell

Cu 2+  = -2F (0.46) = -0.92 F

0.0591
E= E o
cell + log Addition
2  Zn 2+ 
Zn + 2Ag+ → Zn2+ + 2Ag ∆G 3o = ∆G1o + ∆G o2
If [Cu2+] > [Zn2+], Ecell will increases
x ∆G 3o = -2.2F + (-0.92F)
53. 1)
2
-2F E ocell = -2.2F – 0.92F
Solution :
∆G is an extensive property i.e depends upon -2F E ocell = -(2.2F + 0.92F)
number of moles 2 E ocell = 3.12
+ - 2+ 2-
A +B →A +B , ∆G = x
3.12
1 + 1 - 1 1 x E ocell = = 1.56 V
A + B → A2+ + B2-, ∆G = 2
2 2 2 2 2
 6 Test ID : 615
57. 3) Fuel cell +0.0591
= log 10-6
Solution : 2
In fuel cell combustion of gases produces +0.0591
electricity = x −6
2
58. 1) Y > Z > X
= -0.177 V
Solution :
61. 2) 1037
SRP → X Y Z
Solution :
0.52 -3.303 -1.18
0.059
SRP Y<Z<X Eo = log Kc
1 2
Reducing power α 0.059
SRP values 1.1 = log Kc
Reducing power Y > Z > X 2
59. 4) 0.194 M 1.1x 2
log Kc = = 37.29
Solution : 0.059
it Kc = 2 x 1037, order = 1037
Number of eq = number of faraday =
96500 62. 4) Q
0.965 x10 x 60 Solution :
=
96500 cell constant
Conductivity (k) =
= 6 x 10-3 R
Wt of Zn deposited = number of eq x GEW 1
65 ∴k α
= 6 x 10-3 x R
2 (Q) has minimum conductivity, so maximum
= 195 x 10-3 resistance
= 0.195 g
63. 4) I and IV
Initial wt of Zn
Solution :
M x mol wt x V 0.2 x 65 x 500
= = = 6.5 g Leclanche cell and mercury cell are primary
1000 1000
cells.
Remaing wt of Zn = 6.5 - 0.195 = 6.305 g
64. 4) Galvanization
Wt 1000 6.305 1000
M= x = x Solution :
Gm Wt V 65 500
= 0.194 M Prevention of corrosion of iron by zinc coating
called as galvanization.
60. 3) -0.177 V
Solution : 65. 1) 4.5 g
2H+ + 2e- → H2 pH = 3 Solution :
2 W1 E1
H+  =
log  
o 0.0591 + -3
Ecell = E cell + [H ] = 10 W2 E 2
2 PH2
54 108 /1
−3 2 =
10  W2 27 / 3
log 
0.0591
=0+
2 1 54 x 9
W2 = = 4.5 g
108
 7 Test ID : 615
66. 4) 4-bromo-3-methylheptanal 72. 2) IV < III < I < II
Solution : Solution :
Boiling point ∝ molecular weight
Boiling point ∝ H-bonding
∝ Dipole-dipole forces

73. 4) 
i)CrO 2 Cl2
ii) H O +
→
3

Solution :
67. 3)
This is Etard’s reaction
Solution :

Isobutyraldehyde - 
i)CrO 2 Cl2
ii) H O +
→
3

⇒
74. 1) Acetophenone
So cyclopropane carbaldehyde is not a isomer
of isobutyraldehyde. Solution :
68. 1) O3/Zn dust – H2O Reactivity towards nucleophilic addition of
Solution : Aldehydes > Ketones
Reactivity ∝ EWG on carbonyl carbon
1
∝
69. 4) Stephen reaction EDG on carbonyl carbon
Solution :
In Stephen reaction alkane nitriles are
converted into aldehydes using SnCl2 + HCl 75. 1)

followed by hydrolysis.
SnCl2 + HCl + Solution :
R-CN  → R-CH=NH 
H 3O
→ R-CHO
70. 1) Benzaldehyde
Solution :

71. 2) Propiophenone
Solution :

CH3CH2CN 
C6 H5 MgBr
Ether
→

+

H3O
→
 8 Test ID : 615

76. 2)

Solution :
CH3CH2CH(OH)CH3 PCC
(oxidation )
→

CH 2 OH
| 82. 1) Fehling’s reagent
CH3CH2COCH3 → CH 2 OH
HCl Solution :
Generally aliphatic aldehydes and ketones are
77. 3) HCN distinguished by using Fehling’s reagent.
Solution :
Aldehydes and ketones form eliminated 83. 2)
products with ammonia derivatives.
Solution :
They form only addition product with HCN.
Given reaction is a crossed aldol condensation
−
C6H5CHO + CH3CH2CHO 
OH
→
OH CH 3
| ∆
|
78. 2) CH3CH=N-NHCONH2 C6 H 5 − CH − CH − CHO  → C6 H5 − CH = C − CHO
Solution : |
CH 3
CH 3CHO + H 2 NNHCONH 2 →
Acetaldehyde Semicarbazide CHO
CH 3CH = NNHCONH 2 + H 2 O
Acetaldehydesemicarbazone 84. 3)
79. 4) Hydrazine, Glycol and Alkali
NO2
Solution :
Aldehydes and ketones converted into alkanes Solution :
by Wolff-Kishner reduction using hydrazine,
glycol and alkali.
80. 2) CH3CH2COC2H5
Solution :
Only Acetaldehyde, ethanol, methyl ketones
and secondary alcohol in which –CHOH
group attached to –CH3 group only gives
haloform test. 85. 4) Disproportionation reaction
CH3CH2COC2H5 ⇒ CH3CH2COCH2CH3 is Solution :
not a methyl ketone so it does not respond to Cannizzaro reaction of formaldehyde is a
haloform reaction. disproportionation reaction, since aldehyde
undergo both oxidation and reduction.
81. 3) CH3CH2CH2CH2COOH −

Solution : 2HCHO 

OH
→ CH3OH + HCOO-
 9 Test ID : 615
+
86. 4) Mg, CO2, H3O 93. 1) electrophile
Solution : Solution :
+ − ••
CH3CH2Cl 
Mg
Ether
→ CH3CH2MgCl 
CO 2
→ C6 H 5 SO 2 Cl+ R − N H 2 →
Pyridine
R − NH − SO 2 − C6 H 5
94. 4) All the above
H 3O +

→ Solution :

CH3CH2COOH
87. 2) 2, 1 +

Solution : CH 3CH 2 CH 2 CH 2 NH 2 

3CH3 I
→ CH 3CH 2 CH 2 CH 2 N(CH3 )3 I −
+
3CH3COOH + PCl3 → 3CH3COCl + H3PO3 CH 3 NHCH 2 CH 2 CH 3 
2CH 3 I
→(CH 3 )3 N CH 2 CH 2 CH 3 I −
(A) NH2
CH3COOH+PCl5→ CH3COCl + POCl3 + HCl Cl
95. 2)
(B)
H3PO3 is a dibasic acid and HCl is a Solution :
monobasic acid. Basic strength of substituted anilines ∝ EDG
88. 4) NaOH 1
Solution : ∝
EWG
Esterification reaction takes place between Due to steric inhibition of protonation always
carboxylic acid and alcohol in presence of an o-substituted is less basic
acid. 96. 2) CH3CH2CH2NH2
89. 1) D > B > C > A Solution :
Solution : Only 1° amines liberate nitrogen gas on
Acidic strength of carboxylic acid ∝ EWG treatment with nitrous acid due to formation of
1 highly unstable diazonium ion.
∝ 97. 1) Prop-2-en-1-amine
EDG
Solution :
90. 3) A, B & C
Allyl amine CH2=CH-CH2-NH2
Solution :
3 2 1
Statements A, B and C are correct; D is Prop-2-en-1-amine
incorrect. Heavier carboxylic acids are less 98. 1) 4
volatile.
Solution :
91. 4) Hydrolysis of cyanides For C4H11N isomeric primary amines are
Solution : CH3CH2CH2CH2NH2, CH 3CH 2 CHCH 3 ,
Hydrolysis of cyanides gives carboxylic acids. |
NH 2
92. 2) phenyl isocyanide
CH 3 CH 3
Solution :
| |
C6H5NH2 + CHCl3 + 3KOH 
alc.KOH
→ CH 3CHCH 2 NH 2 and CH 3 − C − CH 3
C6H5NC + 3KCl + 3H2O |
NH 2
A B C
 10 Test ID : 615
99. 3) CH3CH2CH2CONH2 Reactivity of diazonium ions towards coupling
Solution : reaction ∝ EWG
Br2 + KOH
CH3CH2CH2CONH2  → 1
∆
∝
CH3CH2CH2NH2 EDG
104. 4) Benzene carbonitrile
Solution :
100. 3)

Solution :

105. 3)
AgCN
Solution :
CH3CH2I + AgCN 
EtOH
→
101. 4) iii < iv < ii < i CH3CH2NC + CH3CH2CN
Solution : (Major) (Minor)
Basic strength of aliphatic amines > Aromatic 106. 2) 7σ and 5π
amines
Solution :
In case of methyl substituted amines 1° is
more basic than 3° amine. NC-CH=CH-CN
∴ Order of basic strength :
C6H5NH2<C6H5CH2NH2<(CH3)3N<CH3NH2
102. 2) Benzene diazonium chloride
Solution :
107. 3)
Benzanilide
Solution :
NH2 NHCOC6H5

C6H5COCl

Benzanilide

108. 4) sec.butyl amine

Solution :

103. 1) 109. 1)Dacron

Solution :
Dacron is a condensed polymer of terphthalic
Solution : acid and ethylene glycol.
 11 Test ID : 615
110. 4) Orlon 116. 4) Buna-N
Solution : Solution :
Chain growth polymer ⇒ Addition polymer Buna-N is belongs to elastomer category so it
Orlon (Poly acrylonitrile) is a chain growth has weakest intermolecular forces.
polymer.
117. 3)
Natural rubber is more resistant to attack by
111. 2) Aromatic electrophilic substitution
oxidizing agent
Solution :
Solution :
Natural rubber is not-resistant to attack by
oxidants.
118. 1) 2-chloro-1,3-butadiene
Solution :
Neoprene is a homopolymer of monomer
chloroprene i.e.
⇒ 2-Chloro-1, 3-butadiene
112. 3)
Free radical polymerization
Solution : 119. 4) Aspirin
Solution :
Aspirin has antiblood clotting action, so
aspirin finds use in prevention of heart attacks.
120. 2) Tetracycline
Solution :
Tetracycline, chloromphenicol and
Above steps are chain initiation steps of Erythromycin are bacteriostatic antibiotics.
radical mechanism. Penicillin, Aminoglycosides and Oflaxacin are
113. 2) 1.125
Bactericidal (Killing) antibiotics.
Solution :
121. 1) non-ionic detergents
M w 13500
PDI = = = 1.125 Solution :
M n 12000
Non-ionic detergents used in liquid
114. 4) A, B & C
dishwashing detergents.
Solution :
122. 3) B, D
A, B & C statements are correct.
But statement D is wrong because PHBV is a Solution :
co-polymer. B & D statements are incorrect.
115. 1) Melamine-formaldehyde polymer * The active site of receptor proteins opens on
Solution : outside region of cell.
Melamine-formaldehyde polymer is used in * Shape of receptor changes during attachment
the manufacture of unbreakable. of messenger.
 12 Test ID : 615
123. 3) A-iii, B-v, C-i, D-ii 125. 4) Syphilis
Solution : Solution :
A) Ranitidine - Antacid Arsphenamine is known as salvarsan was the
B) Furacine - Antiseptic first medicine used for effective treatment of
C) Phenelzine - Tranquilizer syphilis.
D) Chloramphenicol - Antibiotic
124. 3) Sulphur dioxide
Solution :
Sulphur dioxide is used as antioxidant for
wine, beer, sugar syrups and cut, peeled or
dried fruits.
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