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Safety Data Sheet: Identification of The Substance/Mixture and of The Company/Undertaking 1
Safety Data Sheet: Identification of The Substance/Mixture and of The Company/Undertaking 1
Safety Data Sheet: Identification of The Substance/Mixture and of The Company/Undertaking 1
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2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Xn; R22
Human health hazards : Harmful if swallowed.
See section 11 for toxicological information and section 12 for ecotoxicological information.
See Section 16 for the full text of the R phrases or H statements declared above.
2.2 Label elements
Hazard symbol or symbols :
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture : Mixture
Classification
Ingredient name Identifiers % 67/548/EEC Regulation (EC) No. Type
1272/2008 [CLP]
1,2-ethanediol EC: 203-473-3 60 - 100 Xn; R22 Acute Tox. 4, H302 [1] [2]
CAS: 107-21-1 STOT RE 2, H373o
Index: 603-027-00-1
Hexanoic acid, 2-ethyl-, EC: 243-283-8 1-5 Repr. Cat. 3; R63 Repr. 2, H361d [1]
sodium salt CAS: 19766-89-3
Bitrex, Denatonium EC: 223-095-2 < 0.01 Xn; R22 Acute Tox. 4, H302 [1]
benzoate CAS: 3734-33-6
3. COMPOSITION/INFORMATION ON INGREDIENTS
See Section 16 for the See Section 16 for the
full text of the R-phrases full text of the H
declared above. statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
Occupational exposure limits, if available, are listed in Section 8.
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable : Recommended:, alcohol-resistant foam, CO2, powders
Not suitable : Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Hazardous combustion : Decomposition products may include the following materials:
products Hydrocarbon.
carbon oxides
5.3 Advice for firefighters
Special precautions for : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
fire-fighters (SCBA) with a full face-piece operated in positive pressure mode.
7.2 Conditions for safe : Keep container tightly closed in a cool, well-ventilated place. Do not store in unlabeled containers.
storage, including any
incompatibilities
7.3 Specific end use(s)
Recommendations : Coolant and antifreeze.
Industrial sector specific : Not available.
solutions
Relevant information for the mixture and/or the ingredients is presented below.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
1,2-ethanediol LD50 Oral - 500 mg/kg -
Bitrex, Denatonium benzoate LD50 Oral Rat 584 mg/kg -
Harmful if swallowed. Ingestion: kidney abnormalities. Contains material which can cause birth
defects.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
1,2-ethanediol Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Mild irritant Rabbit - 1 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 6 hours 1440 -
milligrams
Skin - Mild irritant Rabbit - 555 milligrams -
Packaging
Methods of disposal : Waste packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Empty containers or liners may
retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
14.2 UN proper - - -
shipping name
14.3 Transport - - -
hazard class(es)
Full text of classifications : Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4
[CLP/GHS] Repr. 2, H361d TOXIC TO REPRODUCTION [Unborn child] - Category 2
STOT RE 2, H373o SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE): ORAL [kidneys] - Category 2
History
Date of issue / Date of : 2011-12-12.
revision
Version : 1.01
Conforms to 1907/2006/EC, Article 31