Nama : Nanda Adin Nisa

NIM : B2C018003

Tugas Kimia Analisis Instrumen

Dosen Pengampu : Dr. Endang Tri Wahyuni Maharani, M.Pd

Kurva Kalibrasi
1.2
f(x) = 0.11 x − 0.01
R² = 0.96
1

0.8
Absorbansi

0.6

0.4
Absorbansi
Linear (Absorbansi)
0.2
Linear (Absorbansi)

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Konsentrasi

1. Menghitung Kadar Awal Cr

Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,665−0,1570
= x 10
1,020
= 4,980 ppm
y−b
Kadar Cr2 = x Fp
a
0,663−0,1570
= x 10
1,020
= 4,960 ppm
 y−b
Kadar Cr3 = x Fp
a
0,659−0,1570
= x 10
1,020
= 4,921 ppm
y−b
Kadar Cr4 = x Fp
a
0,655−0,1570
= x 10
1,020
= 4,882 ppm
4,980+ 4,960+4,921+ 4,882
Jadi Kadar Cr =
4
= 4,9357 ppm
a. Menghitung Kadar Akhir Cr Konsentrasi 0,75% b/v
1. Waktu perendaman 30 menit
Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,545−0,1570
= x 10
1,020
= 3,803 ppm
y−b
Kadar Cr2 = x Fp
a
0,541−0,1570
= x 10
1,020
= 3,764 ppm
y−b
Kadar Cr3 = x Fp
a
0,543−0,1570
= x 10
1,020
= 3,784 ppm
 y−b
Kadar Cr4 = x Fp
a
0,542−0,1570
= x 10
1,020
= 3,774 ppm
3,803+3,764+3,784+ 3,774
Jadi Kadar Cr =
4
= 3,7812 ppm
2. Waktu perendaman 60 menit
Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,539−0,1570
= x 10
1,020
= 3,745 ppm
y−b
Kadar Cr2 = x Fp
a
0,532−0,1570
= x 10
1,020
= 3,676 ppm
y−b
Kadar Cr3 = x Fp
a
0,535−0,1570
= x 10
1,020
= 3,705 ppm
y−b
Kadar Cr4 = x Fp
a
0,536−0,1570
= x 10
1,020
= 3,715 ppm
 3,745+3,676+3,705+3,715
Jadi Kadar Cr =
4
= 3,7102 ppm
3. Waktu perendaman 90 menit
Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,444−0,1570
= x 10
1,020
= 2,813 ppm
y−b
Kadar Cr2 = x Fp
a
0,445−0,1570
= x 10
1,020
= 2,832 ppm
y−b
Kadar Cr3 = x Fp
a
0,448−0,1570
= x 10
1,020
= 2,852 ppm
y−b
Kadar Cr4 = x Fp
a
0,446−0,1570
= x 10
1,020
= 2,833 ppm
2,813+2,832+ 2,852+ 2,833
Jadi Kadar Cr =
4
= 2,8325 ppm
4. Waktu perendaman 120 menit
Persamaan garis:
 y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,333−0,1570
= x 10
1,020
= 1,725 ppm
y−b
Kadar Cr2 = x Fp
a
0,338−0,1570
= x 10
1,020
= 1,774 ppm
y−b
Kadar Cr3 = x Fp
a
0,337−0,1570
= x 10
1,020
= 1,764 ppm
y−b
Kadar Cr4 = x Fp
a
0,332−0,1570
= x 10
1,020
= 1,715 ppm
1,725+ 1,774+1,764+ 1,715
Jadi Kadar Cr =
4
= 1,7445 ppm

b. Menghitung Kadar Akhir Cr Konsentrasi 1,00% b/v

1. Waktu perendaman 30 menit
Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
 y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,529−0,1570
= x 10
1,020
= 3,640 ppm
y−b
Kadar Cr2 = x Fp
a
0,527−0,1570
= x 10
1,020
= 3,627 ppm
y−b
Kadar Cr3 = x Fp
a
0,534−0,1570
= x 10
1,020
= 3,696 ppm
y−b
Kadar Cr4 = x Fp
a
0,531−0,1570
= x 10
1,020
= 3,666 ppm
3,640+3,627+3,696+3,666
Jadi Kadar Cr =
4
= 3,657 ppm

2. Waktu perendaman 60 menit

Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
 0,515−0,1570
= x 10
1,020
= 3,509 ppm
y−b
Kadar Cr2 = x Fp
a
0,516−0,1570
= x 10
1,020
= 3,519 ppm
y−b
Kadar Cr3 = x Fp
a
0,513−0,1570
= x 10
1,020
= 3,490 ppm
y−b
Kadar Cr4 = x Fp
a
0,514−0,1570
= x 10
1,020
= 3,50 ppm
3,509+3,519+3,490+3,50
Jadi Kadar Cr =
4
= 3,5045 ppm

3. Waktu perendaman 90 menit

Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,425−0,1570
= x 10
1,020
= 2,627 ppm
y−b
Kadar Cr2 = x Fp
a
 0,424−0,1570
= x 10
1,020
= 2,617 ppm
y−b
Kadar Cr3 = x Fp
a
0,423−0,1570
= x 10
1,020
= 2,607 ppm
y−b
Kadar Cr4 = x Fp
a
0,422−0,1570
= x 10
1,020
= 2,598 ppm
2,627+2,617+2,607+ 2,598
Jadi Kadar Cr =
4
= 2,6122 ppm

4. Waktu perendaman 120 menit

Persamaan garis:
y= 1,020x + 0,1570
Rumus umum y = ax + b
y−b
x=
a
y−b
Kadar Cr1 = x Fp
a
0,342−0,1570
= x 10
1,020
= 1,813 ppm
y−b
Kadar Cr2 = x Fp
a
0,344−0,1570
= x 10
1,020
= 1,833 ppm
y−b
Kadar Cr3 = x Fp
a
 0,341−0,1570
= x 10
1,020
= 1,803 ppm
y−b
Kadar Cr4 = x Fp
a
0,343−0,1570
= x 10
1,020
= 1,823 ppm
1,813+ 1,833+1,803+1,823
Jadi Kadar Cr =
4
= 1,818 ppm

2. Persentase penurunan kadar Cr

I. Konsentrasi 1,00% b/v

1. Waktu perendaman 30 menit
( konsentrasi Cr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−3,7812 ) x 100 %
%= = 23,39 %
4,9357
2. Waktu perendaman 60 menit
( konsentrasi Cr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−3,710 2 ) x 100 %
%= = 24,82 %
4,9357
3. Waktu perendaman 90 menit
( konsentrasi Cr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−2,8325 ) x 100 %
%= = 42,61 %
4,9357
4. Waktu perendaman 120 menit
( konsentrasi Cr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
 ( 4,9357−1,7445 ) x 100 %
%= = 64,66 %
4,9357

II. Konsentrasi 1,00% b/v

1. Waktu perendaman 30 menit
( konsentrasiCr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−3,657 ) x 100 %
%= = 25,90 %
4,9357
2. Waktu perendaman 60 menit
( konsentrasiCr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−3,5045 ) x 100 %
%= = 28,99 %
4,9357
3. Waktu perendaman 90 menit
( konsentrasiCr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−2,6122 ) x 100 %
%= = 47,07 %
4,9357
4. Waktu perendaman 120 menit
( konsentrasiCr awal−konsentrasi Cr akhir ) x 100 %
%=
Konsentrasi Cr awal
( 4,9357−1,818 ) x 100 %
%= = 63,16 %
4,9357

Tabel Persentase Penurunan Kadar Cr

Konsentrasi Konsentrasi berdasarkan lama perendaman

30 menit 60 menit 90 menit 120 menit
0,75% b/v 23,39% 24,82% 42,61% 64,66 %
1,00% b/v 25,90% 28,99% 47,07% 63,16%

3. Grafik Penurunan Kadar Cr

 Prosentase Penurunan Kadar Cr
Prosentase Penurunan Kadar Cr (%) 7000%
6000%
5000%
4000%
3000%
2000%
1000%
0%
30 60 90 120
Waktu Perendaman (Menit)

0,75% b/v 1,00% b/v