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Bachelors - Project Report 1
Bachelors - Project Report 1
Bachelors - Project Report 1
CHAPTER-I
INTRODUCTION
Today every vital sector of the economy starting from agriculture to packaging,
automobile, building construction, communication or information technology has been
virtually revolutionized by the applications of plastics. Use of this non-biodegradable
product is growing rapidly and creating problem of disposal of plastic waste. It’s dumping
in the dustbin, clogging of drains, reduce soil fertility and aesthetic problems etc. If a ban
is put on the use of plastic on emotional ground, the real cost would be much higher, the
inconvenience much more, the chances of damage or contamination much greater.
The phenomenal increase in the volume of vehicular traffic on our roads, including
commercial vehicle combined with perpetual overloading by transport vehicles and
significant variation in daily and seasonal temperature in various parts of the country calls
for the improved performance of the road pavement and consequently better quality of
bitumen. Since natural materials being exhaustible in nature, its quantity is declining
gradually. Also, cost of extracting good quality of natural material is increasing.
In the construction of flexible pavement, bitumen plays the role of binding the aggregate
together by coating over the aggregate. It also helps to improve the strength of the road.
But its resistance towards water is poor. Anti-stripping agents are being used. A common
method to improve the quality of bitumen is by modifying the rheological properties of
bitumen by blending with organic synthetic polymers like rubber and plastics. If these
materials can suitably utilize in highway construction, the pollution and disposal
problems may partly reduced.
An issue of particular concern is that giant masses of plastic waste have discovered in the
North Atlantic and Pacific oceans, the full environmental impacts of which not yet fully
understood but which cause severe damage to seabirds, marine mammals and fish. Plastic
waste generation is set to continue growing and the development of new materials
continues apace. As for recycling, it also expected to grow in absolute terms and innovate
technologically, but it will not keep up on current trends and so other solutions needed.
The plastic constitutes two major category of plastics; (i) Thermoplastics and (ii) Thermo
set plastics. The thermoplastic constitutes 80% and thermo set constitutes approximately
20% of total post consumer plastics waste generated.
The following table describes the average municipal solid waste production from 0.21 to
0.50 Kg per capita per day in India. Table 1.1 provides the data on total plastics waste
consumption in India during last decade. Municipal solid waste has been increases as
population range increases.
Table 1.1: Municipal Solid Waste in Indian Cities for Last Decade
As the table 1.2 shows plastic consumption in India for last decade, it has been increasing
year by year and demand for plastic is too high.
1 1996 61,000
2 2001 4,00,000
3 2006 7,00,000
4 2011 13,50,000
5 2013 17,40,000
174000 1740000
Due to the change in scenario of life style, the polymer demand is increasing everyday
across the globe. Following table gives the polymer demand in India from 1995 to 2011.
The comparison of per capita plastic consumption in India with rest of the world is as in
Table 1.4.In India the consumption of plastic for the packaging, bottling etc, increases
day by day. Therefore, comparing to East Europe and South East Asia nations India is
utilizing more plastic per capita per year for different purpose. In addition, comparing to
other nations from below table India is using comparatively less plastic per capita per
year.
3 India 14.0
4 China 24.0
India has among the lowest per capita consumption of plastics and consequently the
plastic waste generation is very low as seen from the Figure 1.3 and Figure. 1.4
90
80
70
% Plastic waste
60
50
India
40
World
30
20
10
0
Recycling Plastic in Solid Waste
30
25
20
15 World
India
10
0
Per-capita per year consumption of plastic (kg)
Plastic waste generation is set to continue growing and the development of new materials
continues space. As for recycling, it also expected to grow in absolute terms and innovate
technologically, but it will not keep up on current trends and so other solutions needed.
Table 1.6 gives the source of waste plastic generation.
1.7 OBJECTIVES
Cast various trial mixes with varying percentages of plastic waste and compare for the
compressive strength. The major objective of the project is to reduce bitumen content in
the mixture, increase bond strength, increase life span and reduce the disposal of plastic.
To study the strength & stability characteristics of BC mix for 80/100 grade
bitumen.
CHAPTER-II
LITERATUER REVIEW
2.1 General
The concept of utilization of waste plastic in construction of flexible road pavement has
been doing since 2000A.D. In the construction of flexible pavements, bitumen plays the
role of binding the aggregate together by coating over the aggregate. It also helps to
improve the strength of the road. But its resistance towards water is poor. Anti-stripping
agents are being used. A common method to improve the quality of bitumen is by
modifying the rheological properties of bitumen by blending with organic synthetic
polymers like rubber and plastics. Use of plastic waste in the bitumen is similar to
polymer-modified bitumen. The blending of recycled LDPE to asphalt mixtures required
no modification to existing plant facilities or technology. Polymer modified bitumen
which has good resistance to temperature, water etc. This modified bitumen is one of the
important construction materials for Flexible Road pavement.
This study aimed to investigate the effects of adding plastic bottles in road pavement.
Marshall Properties as well as specific gravity of asphalt mixture containing different
percentages of plastic bottles evaluated. 80-100 penetration-grade asphalt cement used for
this investigation. Aggregate particles that were prepared from Kajang quarry in Malaysia
sieved and packed according to JKR (Malaysian Standard) specification for Stone Mastic
Asphalt (SMA). Waste plastic bottles that used in this study obtained from waste PET
bottles. In order to, provide appropriate plastic particles the bottles cut to small parts then
crushed and sieved. The particles, which were smaller than 2.36 mm, considered for this
investigation. It should notice that different percentages of crushed plastic bottled
designated for this study namely: 0 %, 0.2 %, 0.4 %, 0.6 %, 0.8 % and 1 % by weight of
aggregate particles. As seen in Figure. 3.1.1, in many cases, Marshal stability (MS) value
increases by adding waste plastic bottles into asphalt mixtures up to 0.6 % plastic;
however, at higher plastic contents MS decreases. It also noted that MS value decreases at
higher asphalt amount. This result may indicate that better adhesion provided between
asphalt binder and aggregate particles by adding waste plastic bottle.
Figure 2.1: Typical graph of Marshall Stability vs. plastic waste (percentage)
Figure 3.1.2 Shows that Marshall Flow (MF) increases by adding waste plastic bottles,
and that specimen constructed at higher asphalt content showed higher MF value. Thus,
maximum MF value observed at the specimen made at 1% and 7% plastic and asphalt
content, respectively. Obtained results may indicate that internal friction of mixture
would decreased by adding plastic into mixture, which eventually results in higher flow.
It is good to notice that high-density polyethylene (HDPE), which is another type of
plastic, had the same results on mixture flow.
Figure 2.2: Typical graph of Marshall Flow vs. plastic waste (percentage)
This paper discusses about basic properties as well as mix design of SMA mixture
containing waste plastic bottle particles, and results summarized as follows:
Mixtures containing waste plastic bottles had more stability values compared to
conventional mixture and the stability trends initially increased by adding lower
percentages of plastic bottles and decreased at higher amount of plastic.
Bulk Specific Gravity at lower amount of plastic bottles, and then decreased at
higher percentages of plastic.
Prof. C.E.G. Justo states that addition of 8% by weight of processed plastic for the
preparing of bitumen results in a saving of 0.4% bitumen by weight if mix or about 9.6kg
bitumen of SDBC mix. Modified bitumen improves stability or strength, life and other
desirable properties of bituminous concrete mix.
Dr. R. Vasudevan states that the polymer bitumen blend is a better binder compared to
plain bitumen. Blend has increased softening point and decreased penetration value with a
suitable ductility. When it used for road construction, it can with stand higher temperature
and load. The coating of plastic reduces porosity absorption of moisture & improves
soundness. The polymer mixed bitumen forms better material for flexible pavement
construction as the mix shows better higher Marshall Stability value & suitable Marshall
Coefficient. Hence, the use of waste plastic for flexible pavement is one the best method
for easy disposal of waste plastic.
Rahman and Wahab (2013) used recycled polyethylene terephthalate (PET) as partial
replacement of fine aggregate in modified asphalt in their investigation. In term of
economic value, it shows that this recycled PET could reduce cost of road construction
because this recycled material is cheaper than bitumen and easy to obtain, which also
from their study that the application of recycled PET modified asphalt gives more
Ahmadinia et al. (2012) carried out an experimental research on the application of waste
plastic bottles (Polyethylene Terephthalate (PET)) as an additive in stone mastic asphalt
(SMA). Wheel tracking, moisture susceptibility, resilient modulus and drain down tests
were carried out in their study on the mixtures that included various each cases.
Attaelmanan et al. (2011) carried out Laboratory evaluation of HMA with high density
polyethylene as a modifier. The analyses of test results show that the performance of
HDPE-modified asphalt mixtures are better than conventional mixtures because the
moisture susceptibility and temperature susceptibility can be reduced by the inclusion of
HDPE content of 5% by weight of asphalt in the conventional asphalt mixture.
V. S. Punit (2001), some encouraging results reported in the study that there is a
possibility to improve the performance of bituminous mixes of road construction. Waste
plastics on heating softens around 130 degree c. thermo gravimetric analysis has shown
that there is no gases evolution in the temperature ranges from 130-180’c. Soften plastic
have a binding property. Hence, it used as a binding material for road construction.
Sundaram and Rojasay (2008) studied the effective blending technique by using plastic
waste into bitumen for road laying and polymer bitumen mixture for different
composition were prepared and used carrying out various tests.
Verma S.S. (2008) concluded that plastic would increase the melting point of the
bitumen. This technology not only strengthens the load construction but also increase the
road life.
Mohammad Imthiyas (2002) concluded that the mix prepared with modifier shows
higher resistance to permanent deformation at higher temperature.
the life of pavement surfacing using waste plastic expected to increase substantially in
comparison to use of conventional bituminous mix.
The concept of utilization of waste plastic in construction of flexible road pavement has
done since 2000 in India. In the construction of flexible pavements, bitumen plays the
role of binding the aggregate together by coating over the aggregate. It also helps to
improve the strength and life of road pavement. However, its resistance towards water is
poor. A common method to improve the quality of bitumen is by modifying the
rheological properties of bitumen by blending with synthetic polymers like rubber and
plastic.
Use of plastic waste in the bitumen is similar to polymer-modified bitumen. The blending
of recycled low-density polyethylene (LDPE) to asphalt mixtures required no
modification to existing plant facilities or technology. Polymer-modified-bitumen has
better resistance on temperature, water etc. This modified bitumen is one of the important
construction materials for flexible Road pavement. Since 90’s, considerable research has
been carried out to determine the suitability of plastic waste modifier in construction of
bituminous mixes.
Zoorab & Suparma reported the use of recycled plastics composed predominantly of
polypropylene and low-density polyethylene in plain bituminous concrete mixtures with
increased durability and improved fatigue life. Dense bituminous macadam with recycled
plastics, mainly low density polyethylene (LDPE) replacing 30% of 2.36-5 mm
aggregates, reduced the mix density by 16% and showed a 250% increase in Marshall
Stability; the indirect tensile strength (ITS) was also improved in the ‘Plastiphalt’
mixtures.
D.N. Little worked on the same theme and he found that resistance to deformation of
asphaltic concrete modified with low-density polythene was improved in comparison with
unmodified mixes. It found that the recycled polyethylene bags might be useful in
bituminous pavements resulting in reduced permanent deformation in the form of rutting
and reduced low temperature cracking of pavement surfacing.
Bindu, et al investigates the benefits of stabilizing the stone mastic asphalt (SMA)
mixture in flexible pavement with shredded waste plastic. Conventional (without plastic)
and the stabilized SMA mixtures subjected to performance tests including Marshall
Stability, tensile strength and compressive strength tests. Triaxial tests also conducted
with varying percentage bitumen by weight of mineral aggregate (6% to 8%) and by
varying percentage plastic by weight of mix (6% to 12% with an increment of 1%).
Plastic content of 10% by weight of bitumen recommended for the improvement of the
performance of Stone Mastic Asphalt mixtures. 10% plastic content gives an increase in
the stability, split tensile strength and compressive strength of about 64%, 18% and 75%
respectively compared to the conventional SMA Mix. Triaxial test results show a 44%
increase in cohesion and 3% decrease in angle of shearing resistance showing an increase
in the shear strength.
The drain down value decreases with an increase in plastic content and the value is only
0.09 % at 10% plastic content and proves to be an effective stabilizing additive in SMA
mixtures [9]. Stone Mastic Asphalt is a gap graded bituminous mixture containing a high
proportion of coarse aggregate and filler. It has low air voids with high levels of macro
texture when laid, resulting in a waterproof layer with good surface drainage. Stabilizing
additives needed in the mastic, which is rich in binder content to prevent the binder from
draining down from the mix. Polymers and fibres are the commonly used stabilizing
additives in SMA. Based on many research reports and engineering case studies has been
shown that the use of Stone Mastic Asphalt (SMA) on road surfaces can achieve better
rut-resistance and durability. Recycled low density polyethylene (LDPE) of a size
between 0.30 and 0.92 mm replacing 15% aggregates in asphalt surfacing nearly doubled
the Marshall quotient, and increased the stability retained (SR) by 15%, implying
improved rutting and water resistance. A 20% increase of binder content was required in
this case.
Shankar et al (2009), crumb rubber modified bitumen (CRMB 55) was blended at
specified temperatures. Marshall’s mix design was carried out by changing the modified
bitumen content at constant optimum rubber content and subsequent tests have been
performed to determine the different mix design characteristics and for conventional
bitumen (60/70) also. This has resulted in much improved characteristics when compared
with straight run bitumen and that too at reduced optimum modified binder content
(5.67%).
CHAPTER-III
MATHODOLGY
3.1 Materials
Materials used for the construction of bituminous concrete (BC) are bitumen, aggregates,
waste plastic and filler material. The waste plastic, which is used, is in shredded form.
Further information of materials mentioned as below.
3.1.1 Aggregate
Aggregate constitutes the granular part in bituminous concrete mixtures, which
contributes up to 80-90% of the mixture weight and contributes to most of the load
bearing & strength characteristics of the mixture. Hence, the quality and physical
properties of the aggregates should be under control to ensure a good pavement. The
aggregates of different grades were sieved through different IS Sieves and were kept in
different containers with proper marking. Aggregates used for mix were of two types:
Coarser Aggregates, Fine Aggregates and mineral fillers may be cement or stone dust.
3.1.2 Bitumen
Bitumen is commonly used binder for flexible road construction. Different grades of
bitumen like 30/40, 60/70 and 80/ 100 are available based on their penetration values. The
selected bitumen penetration grade for this study is 80/100 used as a Paving Grade
Bitumen for construction of flexible pavements with superior properties.
Modified Bitumen: Blend of bitumen with waste plastics & or crumb rubber
Water Effect: Due to water, bitumen strips off from the aggregate forming
pothole on roads as being water repellent material and reduces life of roads.
3.1.3 Plastic
Low Density Polyethylene (LDPE) is the type of plastic bottles and containers, which is
commonly used to Carry bags, sacks, milk pouches, bin lining, cosmetic and detergent
bottles Waste plastic of water cans made up of either High Density Polyethylene (HDPE)
or Polyethylene Terephthalate (PET). These waste plastic bottles are shredded and used in
the present study.
Plastics waste (bags, cups, thermocol) made out of PE, PP and PS cut into a size between
2.36mm and 4.75mm using shredding machine, (PVC waste should eliminated). At the
mixing chamber, the shredded plastics waste too added. It mixed with bitumen and coats
uniformly over the aggregate within 30 to 60 seconds, giving an oily look.
Selection of proper gradation for the mix is one of the most important parameter. Ministry
of Road Transport and Highway [MoRT&H] has given some of the grading specifications
for all the bituminous and non-bituminous layers used in road construction. In this study
Bituminous Concrete (BC), which considered as the wearing course or the surface course,
selected. As per IRC 29-1988 Specification for bituminous concrete of mix designation
Grade II, nominal aggregate size 9.5mm and layer thickness of 40-50mm selected.
Grading specification for the bituminous concrete course given in Table 3.1
11.2 80 100
5.6 55 75
2.36 40 55
0.6 20 30
0.3 15 25
0.15 10 20
0..075 6 9
1. Wet process
2. Dry process
temperature reaches 45.50C but when plastic is mixed, it remains stable even at 55 0C. the
vigorous tests at the laboratory level proved that the bituminous concrete mixes prepared
using the treated bitumen binder fulfilled all the specified Marshal mix design criteria for
surface course of road pavement. There was a substantial increase in marshal stability
value of the mix, of the order 1 to 2 time higher value in comparison with untreated or
ordinary bitumen. Another important observation was that the bituminous mixes prepared
using the treated binder could withstand the adverse soaking conditions under water for
longer duration.
This process can utilized for recycling of any type, size, and shape of waste
material.
Figure 3.4: Flow Diagram of Plastic Modified Bitumen Mix Road Process
(Wet Mix Process)
Shredded polymer waste is added to heated stone aggregate for 30-40 sec.
and mixed for uniform coating at surface of aggregate
The Composite (waste plastic aggregate-bitumen mix) used for road laying at
temperature between 110-140 °C
Figure 3.5: Flow Diagram of Plastic Modified Bitumen Mix Road Process (Dry Mix Process)
CHAPTER-IV
Testing of aggregate is easy and simulates the field condition better, as such these are
generally preferred. In order to decide the suitability of the road plastic coated aggregate
for use in construction of pavement, following tests carried out.
the u.s.army corps of engineers and formulated as the mix design criteria ASTMD 1559
and AASHTO T 245(TAI 2001).
The Marshall method is used to determine the optimum bitumen content which satisfies a
given design criteria of stability, deformation or flow, density, minimum air void, V MA
and VFB of hot mixed mineral aggregate and bitumen under standard test conditions.
per minute. The maximum load at failure (on the proving ring) is taken as the stability
value (k N) and the corresponding deformation value obtained from the dial gauge is
taken as the flow value (mm). The flow value is expressed in units of 0.25 mm.
Voids in mineral aggregates, VMA % should fulfil the requirements based on the
nominal maximum size of aggregates in the selected mix, as given below:
Table 4.3: VMA for different sizes of aggregate as per MoRT&H Specification
Nominal Maximum
Minimum VMA, %
Size of the
for Design Air Voids
Aggregates in the
of 3 To 5 %
Mix, mm
12.5 13 To 15
19 12 To 14
25 11 To 13
37.5 10 To 12
Many tests are conducted on the materials of flexible pavements for finding various
parameters like stability, flow of bitumen, grade of bitumen, types of aggregates etc.The
following tests are analysed and documented.
Cumulative
Sieve size Wt Retained % retained % passing
retained
13.2 0 0 0 100.00
11.2 0 0 0 100.00
retained
13.2 0 0 0 100.00
11.2 0 0 0 100.00
13.2 0 0 0 100.00
11.2 0 0 0 100.00
5.6 0 0 0 100.00
2.36 0 0 0 100.00
The following table 4.7 shows the trial mix gradation for total amount of mould for the
test specimen
Table 4.7: Combined gradation for the mix
size, TRAIL
2.36mm Cement Grade Grade
mm 10mm 6mm MID
dust filler I II
100.00
90.00
80.00
70.00
% PASSING
60.00
50.00
40.00
30.00
20.00
10.00
0.00
0.01 0.1 1 10 100
SIEVE SIZE IN mm
Cf – Correction factor
2.4
2.3
Density (g/cc)
2.2
2.1
2
1.9
4 4.2 4.4 4.6 4.8 5 5.2 5.4 5.6 5.8 6
Bitumen content (%)
Figure 4.3(a): Typical graph for bulk density vs. bitumen content
1400
1200
Marshall (kg) 1000
800
600
400
200
0
4 4.5 5 5.5 6 6.5
Bitumen content (%)
Figure 4.3(b): Typical graph for Marshall Flow vs. bitumen content
25
20
Air Voids (%)
15
10
0
4 4.2 4.4 4.6 4.8 5 5.2 5.4 5.6 5.8 6
Bitumen content (%)
.
Figure 4.4: Typical graph for air voids vs. bitumen content
60
40
30
20
10
0
4 4.5 5 5.5 6 6.5
Bitumen content(%)
Figure 4.5: Typical graph for Voids filled bitumen vs. bitumen content
3.5
3
2.5
Flow (mm)
2
1.5
1
0.5
0
4 4.5 5 5.5 6
Bitumen content (%)
Figure 4.6: Typical graph for Marshall Flow vs. bitumen content
Waste
value Kg
plastic
11.65
01 10 2.307 9.403 21.056 55.345 6.5 0.98 1972.982
4
11.69
02 15 2.315 9.112 20.803 56.199 6.7 0.953 1974.973
1
03 20 2.039 19.928 10.30 30.228 34.074 6.4 0.963 2184.174
10.11
04 30 2.003 21.346 31.463 32.156 6.0 0.868 1782.895
7
Table 4.11: various test results for bitumen with and without plastic
Grade 80/100
S.
Properties Normal Plastic modified
No.
bitumen bitumen
Chart Title
Normal bitumen
0 20 40 60 80 100 120
Penetration grade
Figure 4.7: Typical graph differentiating penetration grade of normal and modified bitumen
Chart Title
Normal bitumen
0 10 20 30 40 50 60 70
Softening point
Figure 4.8: Typical graph differentiating softening temperature of normal and modified bitumen
Chart Title
Plastic modified bitumen
Normal bitumen
Figure 4.9: Typical graph differentiating flash temperature of normal and modified bitumen
Normal Bitumen
Figure 4.10: Typical graph differentiating fire temperature of normal and modified bitumen
Chart Title
Normal bitumen
0.9 0.91 0.92 0.93 0.94 0.95 0.96 0.97 0.98 0.99 1
Specific Gravity
Figure 4.11: Typical graph differentiating specific gravity of normal and modified bitumen
The polymer bitumen blend is a better binder comparing to plain bitumen. The blend has
increased softening point and decreased penetration value with a suitable ductility. When
used for road construction it can with stand higher temperature. Hence, it is suitable for
tropical regions. Hence, its load carrying capacity is increased. The blend with aggregate
has no stripping value. Therefore, it can resist the effect of water. The Marshall Stability
value is high. The bitumen required can reduce depending upon the percentage of
polymer added. It is a good saving too. No toxic gas produced. Disposal of waste plastic
will no longer be a problem. The use of waste plastics on the road has helped to provide
better place for burying the plastic waste without causing disposal problem.
7. The load withstanding property increases and it helps to satisfy today’s need of
increased road transport.
Table 4.13: Comparison between ordinary and plastic modified bituminous road
CHAPTER-V
CONCLUSION
Plastic roads would be a boon for India’s hot and extremely humid climate, where
temperatures frequently cross 50°C and torrential rains create havoc, leaving most of the
roads with heavy distresses. This adversely affects the life of the pavements. The polymer
modified bitumen show better properties for road construction and plastics waste which
otherwise are considered to be a pollution menace. It can find its use in this process and
this can help in solving the problem of pollution because most of the plastic waste is
polymers.
The following conclusions drawn based on the results obtained in the present study
The optimum dose of the plastic found to be 20 per cent of the bitumen.
From the Marshall Test results, it concluded that the Marshall Stability value
increases with an increase in bitumen content from 4.5% to 5.0% then it
decreases. The optimum binder content found to be 5.0% .Also higher value of
Marshall Stability found for a modified mix as compared to an unmodified one.
The properties of bitumen such as penetration softening point improved with the
addition of the waste plastic. There is a significant decrease in penetration values
for modified blends, indicating the improvement in their temperature
susceptibility resistant characteristics.
The softening point increases with increase in percentage of fiber and this is so
because the bitumen becomes increasingly viscous. These results show that
bitumen modified with lower percentage of fibers can used in road construction
satisfactorily.
From an environmental and economic standpoint, the use of waste plastic as a
bitumen modifying agent contribute to solving a waste disposal problem and to
improving the quality of road pavements.
The properties of bitumen can enhance by adding small amounts of the modifier.
Therefore, modified bituminous materials can bring real benefits to highway
construction, maintenance, in terms of better and longer lasting roads, and savings
in total road life costing.
The problems like bleeding reduced in hot temperature region.
REFERENCES
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Coated Aggregates-Bitumen Mix Composite for Road Application – Green
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p-ISSN: 2320-0936 Volume-02, Issue-11, pp-01-13.
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of penetration”, Bureau of Indian Standards, New Delhi.
[3] IS: 1205 (1978), “Methods for testing tar and bituminous materials: determination
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and shape”, Bureau of Indian Standards, New Delhi.
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Delhi.
[6] IS: 2386 (1963), “Methods of test for aggregates for concrete (P-IV): Mechanical
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[7] IRC 29-1988,”Specification for bituminous concret (AC): Indan road congress,
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[8] ASTM D 1559, “Test method for resistance of plastic flow of bituminous mixtures
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