BIODEMIC – Academic Club of school of Biotechnology

FINAL REVIEW CLASS – EXERCISE OF CHEMISTRY FOR ENGINEERING

17/06/2020

CHAP 8

1. Gas law: Boyle’s law

A sample of helium gas in a balloon has a volume of 10.L at a pressure of 0.90 atm. At
1.40 atm (T constant), is the new volume represented by A,B, or C?

2. Gas law: Charles’s law

A ballon is filled with 25 liters helium at 25oC.
What is the same balloon volume outside at -15oC?

3. Gas law: Gay-lussac’s law

A bicycle tire is filled to 103kPa in the morning, at 17oC. What is the tire pressure when it
is 35oC outside?

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CHAP 9

1. Henry’s law
What pressure of carbon dioxide is required to keep the carbon dioxide concernitration
in a bottle of club soda at 0.12M at 25oC?

2. Using parts by mass in calculation

What volume (in mL) of a soft drink that is 10.5% sucrose (C12H22O11) by mass contains
78.5g of sucrose? (The density of the solution is 10.4 g/mL)

3. Freezing point depression

Calculate the freezing point of a 1.7m aqueous ethylene glycol solution.

4. Boiling point elevation

What mass of ethylene glucol (C2H6O2) in grams, must be added to 1.0kg of water to
produce a solution that boils at 105.0oC?

5. Osmotic pressure
The osmotic pressure of a solution containing 5.87 mg of an unknown protein per
10.0mL of solution is 2.45 torr at 25oC. Find the molar mass of the unknown protein.

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6. Calculating the packing efficiency of a unit cell

Calculate the packing efficiency of a simple unit cell

7. Relating unit call volume, edge length, and atomic atomic radius
A body-centered cubic unit cell has a volume of 4.32 x 10-23 cm3. Find the radius of the
atom in pm.

CHAP 11

1. Determine whether the following compounds are soluble or insoluble in water

a. NaBr
b. Ba(OH)2
c. Calcium carbonate

2. Write a net ionic equation for each of the following molecular equations
a. 2HClO4(aq) + CA(OH)2(aq) → Ca(ClO4)2(aq) + 2H2O(l)

b. HC2H3O2(aq) + NaOH(aq) → NaC2H3O2(aq) + H2O(l)

3. Use the half-reaction method to balance the equation

Ca(s) + Cl2(g) → CaCl2(s)

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CHAP 12

1. Determine the order and rate constant of a reaction

Consider the reaction between nitrogen dioxide and carbon monoxide:
NO2(g) + CO(g) → NO(g) + CO2(g)
The initial rate of the reaction is measured at several different concerntrations of the
reactants, and the tabulated results are shown here.

[NO2] (M) [CO] (M) Initial Rate (M/s)

0.10 0.10 0.0021
0.20 0.10 0.0082
0.20 0.20 0.0083
0.40 0.10 0.033
From the data, determine:
(a) The rate law for the reaction

(b) The rate constant (k) for the reaction

2. Half-life
Molecular iodine dissociated at 625K with a first-order rate constant of 0.271 s-1. What is
the half- life of this reaction?