01 - CPT - 2 - (89) XII Pass - MPC - Q.P. - (04-08-08)

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CODE JAI MATA DI

NA
Common Practice Test – 2
XII PASS
Test Date: 4th August 2008.

Time : 3 ho urs M ax imum mark s : 2 46


Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
INSTRUCTIONS 13. Section II contains 4 multiple correct answer type questions.
Each questions has 4 choices (A), (B), (C) and (D), out of which
A. General:
one or more answers are correct.
1. This booklet is your Question Paper containing 69 questions. 14. Section III contains 4 Reasoning type questions. Each question
The booklet has 21 pages. contains STATEMENT–1 AND STATEMENT–2.

I I T
2. The question paper CODE is printed on the right hand top Bubble (A) if both the statements are TRUE and STATEMENT–
corner of this booklet. 2 is the correct explanation of STATEMENT–1.
3. Blank papers, clipboards, log tables, slide rules, calculators, Bubble (B) if both the statements are TRUE but STATEMENT–
cellular phones, pagers, and electronic gadgets in any form are 2 is NOT the correct explanation of STATEMENT–1.
not allowed to be carried inside the examination hall. Bubble (C) if STATEMENT–1 is TRUE and STATEMENT–2 is
4. The answer sheet, a machine–readable Objective Response FALSE.
Sheet (ORS), is provided separately. Bubble (D) if STATEMENT–1 is FALSE and STATEMENT–2 is
5. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE TRUE.
BOOKLET. 15. Section IV contains 3 sets of Linked–Comprehension type
B. Filling the ORS question. Each set consists of a paragraph followed by 3
6. On the lower part of the ORS, write in ink, your name in box L1, questions. Each question has 4 choices (A), (B), (C) and (D),
your Registration No. in box L2 and Name of the Centre in box out which only one is correct.
L3. Do not write these anywhere else. D. Marking Scheme:
7. Write your Registration No. in ink, in the box L4 provided in the 16. For each questions in Section I, you will be awarded 3 marks
lower part of the ORS and darken the appropriate bubble if you have darkened only the bubble corresponding to the
UNDER each digit of your Registration No. with a good quality correct answer and zero mark if no bubble is darkened. In all
HB pencil. other cases, minus one (–1) mark will be awarded.
8. The ORS has a CODE printed on its lower and upper parts. 17. For each question in Section II, you will be awarded 4 marks if
9. Make sure the CODE on the ORS is the same as that on this you have darkened all the bubble(s) corresponding to the
booklet and put your signature in ink in box L5 on the ORS correct answer and zero mark for all other cases. If may be
affirming that you have verified this. noted that there is no negative marking for wrong answer.
10. IF THE CODES DO NOT MATCH, ASK FOR A CHANGE OF 18. For each question in Section III, you will be awarded 3 marks
THE BOOKLET. if you darken only the bubble corresponding to the correct
C. Question paper format: answer and zero mark if no bubble is darkened. In all other
11. The question paper consists of 3 parts (Part I: Mathematics, cases, minus one (–1) mark will be awarded.
Part II: Physics, Part III: Chemistry). Each part has 4 19. For each question in Section IV, you will be awarded 4 marks
sections. if you darken only the bubble corresponding to the correct
12. Section I contains 6 multiple choice questions. Each question answer and zero mark if no bubble is darkened. In all other
has 4 choices (A), (B), (C) and (D), out of which only one is cases, minus one (–1) mark will be awarded.
correct.

Name of the Student Roll Number

I have read all the instructions and shall abide by I have verified all the information filled in by
them the Candidate

……..……………………………………………………… ………………………………………………………..
Signature of the Candidate Signature of the Invigilator

South Delhi : 47-B, Kalu Sarai, New Delhi – 110016 • Ph.: 011-46080612/13/14
North/West Delhi : 15, Central Market, West Punjabi Bagh, New Delhi – 110026 • Ph.: 011-45062651/52/53
Extension Std. Centres: Pitampura: 373, 3rd floor, Kohat Enclave, New Delhi – 34. Ph. 01147062998
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Ghaziabad : C-5, BPM Plaza, RDO, Raj Nagar, Ghaziabad • Ph.: 0120-3270291/9891702567
NIITA-DEL-PB-CODE- JAI MATA DI-CPT-2-89_XII Pass 2

MATHEMATICS

PART – I
SECTION – I
Straight Objective Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

1. A function f from the set of natural numbers to integers defined as


 n −1
 2 , where n is odd
f (n) =  is
− n , where n is even
 2
(A) one-one but not onto (B) onto but not one-one
(C) both one-one and onto (D) neither one-one nor onto

2. The function f (x) = log(x + x 2 + 1) is


(A) neither an even nor an odd function (B) an even function
(C) an odd function (D) a periodic function

3. If f : R → S defined as f(x) = sin x − 3 cos x + 1, is onto, then S is


(A) [0, 3] (B) [−1, 1]
(C) [0, 1] (D) [−1, 3]

4. If f(x) is an odd periodic function with period 2, then f(4) equals


(A) 0 (B) 2
(C) 4 (D) −4

5. Which of the following functions is non–invertible? If f : R → R.


(A) f(x) = 2x + 3 (B) f(x) = 2x – 5
(C) f(x) = x3 + x (D) none of these
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| sin x |
6. If f(x) = ln then period of f is
sin x
(A) 2π (B) π
(C) π /2 (D) not defined

SECTION – II
Multiple Correct Answers Type
This Section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D) out of which ONE OR MORE is/are correct.

7. Which one of the following is a bijective function on the set of real number?
(A) f(x) = 2x – 5 (B)f (x) = x3
2
(C) f(x) = x (D) f(x) = x2 + 1

8. Which of the following functions is an even function?


a x + a −x ax +1
(A) f (x) = (B) f (x) =
x −x
a −a ax −1
ax −1 f (x) = x
x x
+ +1
(C) f (x) = x x (D)
a +1 e −1 2

9. f : R → R, f(x) = sin|x| is
(A) one-one (B) many one
(C) into (D) onto

10. π is period of the function


1 + sin x
(A) f (x) = (B) f(x) = |sinx| + |cosx|
cos x(1 + cos ecx)
(C) f(x) = sin2x + cos3x (D) f(x) = tan 3x + cot x

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SECTION – III
Assertion and Reasoning
This Section contains 4 reasoning type questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

(A) Statement-1 is True Statement-2 is True and Statement-2 is correct explanation of


Statement-1.
(B) Statement-1 is True Statement-2 is True and Statement-2 is not a correct explanation of
Statement-1
(C) Statement-1 is True and Statement-2 is False
(D) Statement-1 is False and Statement-2 is True

2 π  π 
STATEMENT 1: f ( x ) = cos x + cos  + x  − cos x cos  + x  is an even function
2
11.
3  3 
Because
STATEMENT 2: f(x) is periodic function

12. Let f(x) = ax + b, where a, b ∈ R, a.b ≠ 0.


STATEMENT –1: f is invertible.
and
STATEMENT –2: Range of f is R

13. Let f be an invertible function


STATEMENT –1: Range of f = Domain of f–1.
and
STATEMENT –2: If f is defined from A → B, then f–1 is defined from B → A.

 1
( )  
1/100 1
14. STATEMENT 1 : If f ( x ) = 2 − x100 , x > 0 then f ( f ( x ) ) +f f  = x+
  x x
Because
  1 
STATEMENT 2 : f ( f ( x ) ) + f  f    ≥ 2
  x 

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SECTION – IV
Linked Comprehension Type
This Section contains 3 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions Nos. 15 to 17


Function is said to be onto if range is same as co-domain otherwise it is into.
Function is said to be one-one if for all x1 ≠ x2 ⇒ f(x1) ≠ f(x2) otherwise it is many one.

15. Function f : R → R, f(x) = x2 + x, is


(A) one-one onto (B) one-one into
(C) many one onto (D) many one into

16. Let function f : R → R be defined by f(x) = 2x + sin x for x ∈ R. Then f is


(A) one-one and onto (B) one-one but not onto
(C) onto but not one-one (D) neither one-one nor onto
x
17. A function f : [0, ∞) → [0, ∞) defined as f (x) = is
1+ x
(A) one-one and onto (B) one-one but not onto
(C) onto but not one-one (D) neither one-one nor onto

Paragraph for Question Nos. 18 to 20

A function is defined if each and every value of x has one and only one value of y.
Function is said to be onto if range is same as co-domain otherwise it is into.
Function is said to be one one if for all x1 ≠ x2 ⇒ f(x1) ≠ f(x2) otherwise it is many one.

18. Which of the following are functions ?


(A) {(x, y) |y2 = 4ax, x, y ∈ R} (B) {(x, y) |y = |x|, x, y, ∈ R}
(C) {(x,y) |x2 + y2 = 1, x, y ∈ R} (D) {(x, y) |x2 – y2 = 1, x, y ∈ R}

19. The function f : R → R given by f(x) = 5 – 2 sin x is


(A) one-one (B) onto
(C) bijective (D) many one

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20. Which of the following is one-one and onto?


(A) f : R → R and f(x) = sin x (B) f : R+ → R and f(x) = 2 x + 5
(C) f : [0, π ] → [−1, 1] and f(x) = cos x (D) f : R → R and f(x) = x2

Paragraph for Questions Nos. 21 to 23

f(x) is non–zero real valued function such that f(x + y) + f(x – y) = 2f(x) f(y), then

21. f(0) =
(A) 0 (B) –1
(C) 1 (D) 2

22. f(x) is
(A) even (B) odd
(C) neither even nor odd (D) none of these

23. One of the function satisfying the above equation is


(A) sinx (B) cosx + x
(C) cosx (D) ex

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NIITA-DEL-PB-CODE- JAI MATA DI-CPT-2-89_XII Pass 7

PHYSICS
PART – II
SECTION – I
Straight Objective Type
This section contains 6 multiple-choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which Only One is correct

24. A projectile is given an initial velocity of 1iˆ + 2ˆj . The Cartesian equation of its path is
(g = 10 m/sec2)
(A) y = 2 x − 5 x (B) y = x − 5 x
2 2

(C) 4y = 2 x − 5 x (D) y = 2 x − 25 x
2 2

25. The horizontal range is four times the maximum height attained by a projectile. The angle of
projection is
(A) 90° (B) 60°
(C) 45° (D) 30°

26. The speed of a projectile when it is at its greatest height is 2 / 5 times its speed at half the
maximum height the angle of projection is
(A) 30° (B) 60°
−1  3 
(C) 45° (D) tan  
4

27. A boat man can row with speed of 10 km/h in still water. If the river flows at 5 km/h, the
direction in which the boat man should row to reach a point on the other bank directly
opposite to the point from where he started is (width of the river is 2 km)
(A) in a direction inclined at 90° to the direction of river flow
(B) in a direction inclined at 60° to the direction of river flow
(C) in a direction inclined at 120° to the direction of river flow
(D) Should row directly along the river flow
(E) None of the above

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NIITA-DEL-PB-CODE- JAI MATA DI-CPT-2-89_XII Pass 8
28. Two bullets are fired simultaneously, horizontally and with different speeds from the same
place. Which bullet will hit the ground first ?
(A) the faster one (B) the slower one
(C) depends on their mass (D) both will reach simultaneously

29. A projectile is fired with a speed u at an angle θ with the horizontal. Its speed when its
direction of motion makes an angle ‘α ’ with the horizontal is :
(A) u sec θ cos α (B) u sec θ sin α
(C) u cos θ sec α (D) u sin θ sec θ

SECTION – II
This section contains 4 multiple-correct answer(s) type questions. Each question has 4 choices (A), (B), (C)
and (D), out of which One or More is/are correct

30. Two balls are projected from the same point with the same speed at different angles α 1 and
α 2 with the horizontal. Their respective times of flight are T1 and T2 they have the same
horizontal range. Which of the following is correct ?
T1 sin α1
(A) α 1 + α 2 = 90° (B) =
T2 sin α2
T1 T1
(C) = tan α1 (D) = tan α2
T2 T2

31. In case of projectile motion if two projectile A and B are projected with same speed at angles
15° and 75° respectively to the horizontal then
(A) H A > H B (B) H A < H B
(C) TA > TB (D) TA < TB

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32. A man who can swim at a speed v relative to the water wants to cross a river of width d,
flowing with a speed u. The point opposite him across the river is P.
(A) The minimum time in which he can cross the river is d/v
(B) He can reach the point P in time d/v
d
(C) He can reach the point P in time
v − u2
2

(D) He cannot reach P if u > v

33. A projectile is projected at an angle of elevation α . After t second, it appears to have an


angle of elevation β as seen from point of projection. Which of the following is correct ?
1
(A) The y co-ordinate of the position of projectile at time t is ν sin α t − gt2, where ν is
2
the
velocity of projection.
(B) The x co-ordinate of the position of projectile at time t is ν cos α t, where ν is the
velocity
of projection.
gt
(C) tan β = tan α −
νcos α
gt cos β
(D) Velocity of projection is
2 sin(α − β)

SECTION – III
This section contains 4 Assertion& Reasoning type questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

CODE :

A. Statement – 1 is True, Statement – 2 is True ; Statement – 2 is a correct explanation for


Statement – 1.
B. Statement – 1 is True, Statement – 2 is True ; Statement – 2 is NOT a correct explanation
for Statement – 1.
C. Statement – 1 is True, Statement – 2 is False.
D. Statement – 1 is False, Statement – 2 is True.

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34. STATEMENT – 1 : Two particles of different mass, projected with same velocity at same
angles. The maximum height attained by both the particles will be same.
and
STATEMENT – 2 : The maximum height of projectile is independent of particle mass.

35. STATEMENT – 1 : A coin is allowed to fall in a train moving with constant velocity. Its
trajectory is parabola as seen by observer attached with train.
and
STATEMENT – 2 : An observer on ground will see path of coin as a parabola.

36. STATEMENT – 1 : Horizontal velocity in projectile motion remains constant.


and
STATEMENT – 2 : Acceleration due to gravity is vertical.

37. STATEMENT – 1 : A particle is moving on a horizontal surface. It’s path will be straight
line if initial velocity and acceleration are along same horizontal surface.
and r
r
STATEMENT – 2 : Angle between u and a determine path therefore, it may be accelerated
or retarded curvilinear.
SECTION – IV
Linked Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Questions Nos. 38 to 40



A projectile is thrown with a velocity of 50 ms 1 at an angle of 53° with the horizontal.

38. Choose the incorrect statement :



(A) It travels vertically with a velocity of 40 ms 1

(B) It travels horizontally with a velocity of 30 ms 1

(C) The minimum velocity of the projectile is 30 ms 1
(D) None of these

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39. Determine the instants at which the projectile is at the same height
(A) t = 1 s and t = 7 s (B) t = 3 s and t = 5 s
(C) t = 2 s and t = 6 s (D) All the above

40. The equation of the trajectory is given by


(A) 180 y = 240 x − x2 (B) 180 y = x2 − 240 x
(C) 180 y = 135x − x2 (D) 180 y = x2 − 135 x

Paragraph for Questions Nos. 41 to 43

A projectile crosses two walls of equal height H symmetrically as shown.

t = 2 s
t = 6 s
v0 H H

d = 1 2 0 m

41. The time of flight T is given by


(A) 8 s (B) 9 s
(C) 7 s (D) 10 s

42. The maximum height of the projectile is


(A) 120 m (B) 80 m
(C) 160 m (D) Cannot be obtained

43. If the horizontal distance between the two walls is d = 120 m, then the range of the projectile
is
(A) 240 m (B) 160 m
(C) 300 m (D) cannot be obtained

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NARAYANA IIT ACADEMY


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Paragraph for Questions Nos. 44 to 46

A man can swim at a speed of 3 km/h in still water. He wants to cross a 500 m wide river flowing at
2 km/h. He keeps himself always at an angle to 120° with the river flow while swimming.

44. The time taken to cross the river is:


3 1
(A) hr (B) hr
2 6
1
(C) hr (D) None
3 3

45. The drift of the man along the direction of flow, when he arrive at the opposite bank is :
1
(A) km (B) 6 3 km
6 3
1
(C) 3 3 km (D) km
3 3

46. Find the angle θ due to which man row to reach the point P on the other bank directly
opposite to the point O.
P

2 k m / h

3 k m θ/ h

O
− 2
(A) 30° (B) sin 1
3
−1 3
(C) sin (D) 60°
2

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CHEMISTR
Y
PART – III
SECTION – I
Straight Objective Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

M M
47. In an experiment, 50 mL of solution of metallic salt is reacted with 20 mL of
10 2
solution of sodium nitrite. In the reaction NaNO2 oxidised into NaNO3, if the original
oxidation number of the metal in the salt is +5, then what will be its new oxidation number ?
(A) + 1 (B) +4
(C) + 3 (D) + 2

48. 5 × 10-5 moles of KMnO4 in acidic medium is completely consumed to oxidise 5 × 10-5

moles of Xn+ into XO4 , then what is the value of n?
(A) 3 (B) 4
(C) 5 (D) 2

49. 100 mL of a 0.2 M of solution of transition metal ion reacts completely with 6 mL of 1M
Ba(MnO4)2 in acidic medium, then which of the following is the correct representation of
change in oxidation state of metal ion?
(A) M+  → M+2 (B) M+2  → M+3
(C) M+2  → M+4 (D) M+2  → M+5

50. In the mixture of NaHCO3 and Na2CO3, the volume of HCl required is V1 mL, when
phenolphthalein is used as indicator and further V2 mL is used when methyl orange is used as
indicator after the first end point. Then what is the volume of HCl required for complete
reaction of original NaHCO3?
(A) 2V1/mL (B) V2mL
(C) V1/2 mL (D) (V2 – V1) mL

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51. The number of moles of KMnO4 that will be needed to react completely with one mole of
ferrous oxalate in acidic solution is
(A) 3/5 (B) 2/5
(C) 4/5 (D) 1

52. If 100 mL of each of 0.5 N NaOH, N/5 HCl and N/10 H2SO4 are mixed, then the nature of the
resulting solution will be
(A) acidic (B) basic
(C) neural (D) can not be predicted.

SECTION – II
Multiple Correct Answer Type
This section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE is/are correct.

53. When FeS2 is oxidised with sufficient O2, then its oxidation products are found to be Fe2O3
and SO2. If the molecular weight of FeS2, Fe2O3 and SO2 are M, M′ and M″ respectively,
then which of the following statements are correct ?
(A) equivalent wt. of FeS2 is M/11 (B) The molar ratio of FeS2 to O2 is 4 : 11
(C) The molar ratio of FeS2 to O2 is 11 : 4 (D) The molar ratio of Fe2O3 and SO2 is 11 : 4

M
54. 150 mL Ba(MnO4)2 in acidic medium can oxidise completely
10
(A) 150 mL 1M Fe+2 (B) 50 mL 1M FeCrO4
−2
(C) 75 mL 1 M C2O4 ions (D) 25 mL 1M K2Cr2O7 solution.

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55. HOOC – COOH and KOOC – COOK behave as acid as well as reducing agent. Then which
of the following are the correct statements regarding HOOC – COOH and KOOC – COOK
(A) When HOOC – COOH and KOOC – COOK behaves as reducing agent, then its
equivalent weights are equal to half of its molecular weight respectively ?
(B) 50 mL of 1 N solution of each is neutralised by 100 mL 1N Ca(OH)2 seperately.
(C) 1000 mL of 1M solution of HOOC – COOH is neutralised by 1000 mL of 1M Ca(OH)2.
(D) 100 mL of 1M solution of KOOC – COOK is oxidised by 20 mL 2M of KMnO4 in
acidic medium.

56. For the reaction


H3PO4 + Ca(OH)2  → CaHPO4 + 2H2O
1 mole 1mole
Then which of the following statements are correct ?
(A) The equivalent weight of H3PO4 is 49.
(B) The resulting solution is neutralized by 1 mole of KOH
(C) 1 mole of H3PO4 is completely neutralized by 1.5 mole of Ca(OH)2
(D) The equivalent weight of Ca(OH)2 is 37.

SECTION – III
Reasoning Type
This section contains 4 reasoning type questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
CODE
(A) STATEMENT–1 is True, STATEMENT–2 is True; STATEMENT–2 is a correct explanation for
STATEMENT–1
(B) STATEMENT–1 is True, STATEMENT–2 is True; STATEMENT–2 is NOT a correct explanation
for STATEMENT–1
(C) STATEMENT–1 is True, STATEMENT–2 is False
(D) STATEMENT–1 is False, STATEMENT–2 is True

57. STATEMENT–1: For the redox reaction Cu2S  → CuO + SO2, y mole of Cu2S is equal
to 8y equivalents of Cu2S.
STATEMENT–2: Since the n-factor of Cu2S is 8 and number of equivalents = n-factor ×
number of moles.

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58. STATEMENT–1: For the reaction Na2CO3 + HCl  → NaCl + NaHCO3 the equivalent
weight of Na2CO3 is 106.
STATEMENT–2: Because the n-factor of Na2CO3 is 1 and equivalent
molecualr wt.
weight =
n-factor

59. STATEMENT–1: The number of moles of KMnO4 that will be needed to react with 1 mole
−2 −
of HCN (While HCN oxidises into CO3 and NO3 ) in acidic medium is 2.
STATEMENT–2: Because the n-factor of KMnO4 in acidic medium is 5 and the n-factor of
HCN is 10. So, molar ratio of KMnO4 to HCN is 1 : 2.

60. STATEMENT–1: The oxidation number of “S” in H2S2O8 is 7.


STATEMENT–2: The maximum oxidation number of S is +6, because the maximum
possible oxidation state of element is its no. of valence electron (s) or, group number.

SECTION – IV
Linked Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
Paragraph for Questions Nos. 61 to 63

Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as
iodine titration. It is of two kinds:
(i) Iodometric titration.
(ii) Iodimetric titration
(i) Iodometric titrations : It is nothing but an indirect method of estimating the iodine. In this type of
titration, an oxidizing agent is made to react with excess of KI, in acidic medium or basic

medium in which I gets oxidized into I2. Now the liberated I2 can be titrated with Na2S2O3
solution.
KI 
Oxidising agent
→ I 2 
Na2 S2O3
→ I - + Na2 S4 O6

Although solid I2 is black and insoluble in water, but it is converted into soluble I3 ion.
I2(s) + I

I 3−
black dark brown

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Starch is used as indicator near the end point or equivalence point. Even small amount of I2 gives
blue colour with starch. The completion of the reaction can be detected when blue colour disappears
at the end point. In iodimetric titration, the strength of reducing agent is determined by reacting it
with I2.

61. When 79.75 g of CuSO4 sample containing inert impurity is reacted with KI, the liberated I2
−2
is reacted with 50 mL ( 1M) Na2S2O3 in basic medium, where it is oxidized into SO 4 ions,

and I2 is reduced into I : What will be the % purity of CuSO4 in sample ?
(A) 60% (B) 81%
(C) 50% (D) 95%

62. When 214 g of KIO3 reacts with excess of KI in presence of H+, it liberates I2. Now I2 is
completely reacted with 1M Na2S2O3 solution in basic medium, where it is converted into
SO −42 ions. What volume of Na2S2O3 is needed to reach the end point of the reaction ?
(A) 500 mL (B) 800 mL
(C) 1500 mL (D) 750 mL

−2
63. A solution containing Cu+2 and C 2 O 4 ions on titration with M/10 KMnO4 requires 50 mL.
The resulting solution is neutralized with K2CO3 and then treated with excess of KI. The
liberated I2 requires 25 mL M/10 Na2S2O3 in acidic solution. What is the difference between
−2
the number of m mole of C 2 O4 and Cu+2 ions in the solution ?
(A) 40 (B) 10
(C) 30 (D) 50

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Paragraph for Questions Nos. 64 to 66

H2O2 acts as both oxidising as well as reducing agent. As oxidising agent, its product is H 2O, but as
reducing agent, its product is O2. The strength of H2O2 is expressed in many ways like molarity,
normality, % strength and volume strength. But out of all these form of strengths, volume strength
has great significance for chemical reactions. The decomposition of H2O2 is shown as under.
H2O2(l)  → H2O (l) + 1/2 O2(g)
X “vol” strength of H2O2 means 1 volume (litre or mL) of H2O release x volume (litre or mL) of O2
at NTP.
x
1 litre H2O2 releases x litre of O2 at NTP = mole of O2.
22.4
From equation it is very clear that
1 mole of O2 produces from 2 moles of H2O2.
x x
moles of O2 produces from moles = 2 × moles of H2O2
22.4 22.4
x
= moles of H2O2.
11.2
x
Since moles of H2O2 is present in 1 litre of H2O2.
11.2
x
∴ molarity of H2O2 =
11.2
Normality = n-factor × Molarity
x x
∴ Normality of H2O2 = 2 × =
11.2 5.6
Percentage strength of H2O2 is nothing but, it is the weight of H2O2 in gramme per 100mL of H2O2
solution. By volume strength of H2O2, we can predict the percentage purity of the substance and
many more information can be known.

64. What is the percentage strength of 10 “vol” H2O2?


(A) 11% (B) 5%
(C) 7% (D) 3.03 %

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65. A 100 mL H2O2 liberates 25.4 g of I2 from an acidified KI solution, then what is the volume
strength of H2O2 ?
(A) 5 (B) 5.6
(C) 10 (D) 11.2

66. 100 mL of a H2O2 solution were diluted to 400 mL, and 20 mL of this diluted solution
M 
required to reduce 10 mL   KMnO4 solution then what is the “volume” strength of
 10 
H2O2?
(A) 20 (B) 11.2
(C) 8.4 (D) 5.6

Paragraph for Questions Nos. 67 to 69

A water is said to be a soft water if it produces sufficient foam with the soap and water that does not
produce foam with soap is known as hard water. Hardness has been classified into two types (i)
Temporary hardness (ii) Permanent hardness.
Temporary hardness is due to presence of calcium and magnesium bicarbonate. It is simply removed
by boiling as
Ca(HCO3)  ∆
→ CaCO3 ↓ + CO2↑ + H2O
Mg(HCO3)2  ∆
→ MgCO3 ↓ + CO2↑ + H2O
Temporary hardness can also be removed by addition of slaked lime, Ca(OH)2
Ca(HCO3)2 + Ca(OH)2  → 2CaCO3 ↓ + 2H2O
Permanent hardness is due to presence of sulphate and chlorides of Ca, Mg, etc. it is removed by
washing soda as
CaCl2 + Na2CO3  → CaCO3 ↓ + 2NaCl
CaSO4 + Na2CO3  → CaCO3 ↓ + Na2OS4
Permanent hardness also removed by ion exchange resin process as
2RH + Ca2+  → R2Ca + 2H+
2− −
2ROH + SO4  → R2SO4 + 2OH
The degree of hardness of water is measured in terms of ppm of CaCO3. 100 ppm means 100 g of
CaCO3 is present in 106 g of H2O. If any water contain 120 ppm of MgSO4, its hardness in terms of
CaCO3 = 100 ppm.

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67. One litre of a sample of hard water (d = 1 g/mL) contains 136 mg of CaSO4 and 190 mg of
MgCl2. What is the total hardness of water in terms of CaCO3 ?
(A) 100 ppm (B) 200 ppm
(C) 300 ppm (D) 500 ppm

68. What is the weight of Ca(OH)2 required for 10 litre of water to remove temporary hardness of
100 ppm due to Ca(HCO3)2?
(A) 1.62 g (B) 0.74 g
(C) 7.4 g (D) 0.4567 g

69. A 200 g sample of hard water is passed through the column of cation exchange resin , in the
which H+ is exchanged by Ca2+. The outlet water of column required 50 mL of 0.1 M NaOH
for complete neutralization. What is the hardness of Ca2+ ion in ppm
(A) 250 ppm (B) 500 ppm
(C) 750 ppm (D) 1000 ppm

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SYLLABUS FOR NEXT TEST (CPT- 3) TO BE HELD ON 11-08-08

MATHEMATICS PHYSICS CHEMISTRY


Functions (domain, FBD, equilibrium, constraint Rutherford model: Bohr’s
functional equations, relation, connected body model of atom – merit and
inverse of a function problems demerits. Bohr’s
range) & composite expressions for energy and
functions velocity of electron, radius
of orbit, hydrogen spectrum

If you have any genuine question paper problems please contact the following subject concerned
persons.
Paper Setter : Punjabi Bagh Delhi Centre
Mathematics : Mr. Nitya Nand Mishra Mobile: 9811559641
Physics : Mr. Rishi Jha Mobile: 9999972017
CHEMISTRY : DR. K. K. SHARMA MOBILE: 9868916368

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