Single Answer Type KMn0, reacts with oxalic acid according to the equatior 2MnO; +5C,0; +16H* > 2Mn** +10CO, +8H,O Chiao - . er | rd Here 20 mL of 0.1 M KMn(, is equivalent to — eS (a) 20 mL of 0.5 MH,C,0, (b) 50 mL of 0.5 MH,C,O, (©) 50 mL of 0.1 MHC,0, (d) 20 mL of 0.1 MHLC,0, Excess of KI reacts with CuSO, solution and then Na,S,O, solution is added to it. Which of the statement is incorrect for this reaction — (a) Na,S,0, is oxidized (&) Cul, is formed (© Cul, is formed (@) Evolved I, is reduced Calculate the number of moles of KMnO, which will react with 180 gm H,C,0, according to given reaction KMn0O, + H,C,0, —> 2CO, + Mn* (a) 4/5 (&) 2/5 (© us @43 Calculate the mass of K,Cr,O, required to produced 254 gm I, from KI solution. Given K,Cr,0, + 2KI—+ 2Cr++1, @) 492 ©) 88 © 98g @498 Calcualte volume of 0.05 M KMnO, which will react with 50 ml of 0.1 M HLS in acidic medium (H,S ——> SO,) (@) 60 ml () 6m (©) 12 ml @ 120 mi Calculate mass of Fe,O, if it reacts completely with 25 ml of 0.3 M K,Cr,0,, (@) 144g (b) 10.44 g (0) 104.4 g @i44g | Calculate the concentration of H,O, soluiton of 20 ml of HO, solution reacts completely with 10 ml of 2M KMn0, in acidic medium. (@) 125M ()5M ()25M (d) 25M Calculate the moles of KCI required to produced 10 mol Cl, by the reaction with KCIO,. (a) 1.66 mole —(b) 13.33 mole (c) 0.66 mole (d) 16.66 mole Calculate the moles of KMnO, required for complete oxidation of 1.25 mol Cu,S. CuS —> Cu? +S0, (a) 1 mole (b) 3 mole (c) 2 mole (@) 5 mole10. Calculate volume strength of HO, of its 11.2 ml requires 30 ml of 0.5 M K,Cr,0,. (a)35 b) 55 (c) 25 @45 50 ml KMn0, is mixed completely with excess KI, The I, liberated required 250 mlof0.1 MNa,S,0, soluiton, calculate molarity of KmnO, solution. (a) 0.2 6) 0.3 ©@0.1 @os The oxidation number of oxygen in O,PtF, is : (a0 (b) 112 ©+H @-12 Consider the following reaction : 5H,O, +xClO, +20H- > xCI +O, +6H,0 ‘The reaction is balanced if— (a)x=5,y=2 (b)x=2,y=5_ (C) x=4,y=10 (d)x=5,y=5 Which of the following can act as both reducing agent and oxidising agent @so, (© KMn0, © % = @HS anprpye “Numerical “Answer Type The Eq. weight of Na,HPO, when it reacts with excess of HClis The number of gm of anhydrous Na,CO, Peace in 250 ml of 0,25 N solution is. ml of 0.1 MH,SO, is required to neutralize 50 ml of 0.2 MNaOH solution. Value of n-factor of H,CO, in presence of NaOH if product is NaHCO,. The oxidation state of oxygen atom in potassium super oxide is.... It requires 40 ml of 1 M Ce** to titrate 20 ml of 1 M Sn* to Sn‘. What is the oxidation state of the cerium in the product, In the standarization of Na,S,0, using K,Cr,O, by iodometry what is the equivalent of Na,S,0, and K,Cr,0,. Calculate the number of c.c. of potassium dichromate solution containing 4.9 g per litre of the salt, required to oxidize 0.5 g of iron dissolved in dilute sulphuric acid. (K=39, Cr=52, O = 16, Fe = 56) A solution of KMnO/H' containing 3 gm/L is used to titrate H,O, solution contain- ing 2. gm/L, What volume of KMnO, will be required to react with 20 mL of H, O, solution. Also find the volume strength of H,O,. A1.0 g sample of H,O, solution containing x % HO, by mass requires x cm? of a KMn0, solution for complete oxidation under acidic conditions. Calculate the normality of KMnO, solution.16. 17. 19. 20. Calculate the number of millimoles of ‘K,Cr,0, which will completely react with 50 ml 0.1 M KI soluiton. Calculate volume of 0.4 M KMnO, required to react wi acidic medium. KHC,O, (1 mol) +H,C,0, (2 mol) Certain amount of KIO, was mixed with excess KI solution the liberated 1, was titration with 50 ml, 0.2 M Na,S,O, solution, calculate mols of KIO, mixed. A volume of 10.0 ml of 1 M SeO, reacted with exactly 20 ml of 2M CrSO,. In the Teaction, Cr* was oxidized to Cr**. To what oxidation state was selenium converted by the reaction. Potassium acid oxalate K,C,0, - 3H,C,0,-4H,0 can be oxidized by MnO,- in acid medium. Calculate the volume of 0.1M KMnO, reacting in acid solution with 5.08 gm of the acid oxalate, Metallic tin in the presence of HCI is oxidized byK,Cr,0, to stannic chloride, SnCl,. ‘What volume of deci-normal dichromate solution would be reduced by 11.9 gm of tin, [Sn = 119] Calculate volume of 0.4 M KMnO, required to react with following in acidic medium. KHC,0, (1 mol) + H,C,0, (2 mol) Calculate volume of 0.4 M NaOH required to react with following mixture. KHC,O, (1 mol) + H,C,O, (2 mol) Calculate volume of 0.2 MKMn0O, required to react with following mixture in acidic medium. ; KHC,O, (128 gm) + H,C,O, (180 gm) Calculate the millimoles of Br, produced when 10 ml of 0.1 M BrO, reacts with Previous Years Questions For the redox reaction MnO, + C,0,-+H* -> Mn**+ CO, +H,0 ‘The correct coefficient of the reactants for the balanced reaction are : MnO, co2 H Oc 2 5 16 O16 5 2 © 5 16 2 ® 2 16 5Among the following find the number of elements showing only one non-zero oxida- tion state O, Cl, F, N, P, Sn, Tl, Na, Ti. What is the difference in the oxidation numbers of the two types of sulphur atoms in Na,S,0,? 2.68 x 10> moles of a solution containing an ion A”* require 1.61 x 107 moles of MnO; for the oxidation of A"* to AO,” in acidic medium. What is the value of n ? Inareaction, Na,S,O, is converted to Na,S,O,. The equivalent weight of Na,S,O, for this reaction is (mol. wt. of Na,S,O, = M). (a)M (b) M/4 (c) M/2 (@ M3 From the following statements regarding HO, choose the incorrect statement. (a) It can act only as an oxidising agent (b) It decomposed on exposure to light (c) It has to be stored in plastic or wax lined glass bottles in dark (@) It has to be kept away from dust Consider a titration of potassium dichromate solution with acdified Mohr’s salt solution ‘using diphenylamine as indicator. The number of moles of Mohr’s salt required per mole of dichromate is (@)3 (0) 4 ©5 @6 In the standardisation of Na,S,O, using K,Cr,O,, by iodometry, the equivalent weight of K,Cr,0, is : (2) (molecular weight) / 2 (b) (molecular weight) / 6 (6) (molecular weight) /3 (d) same as molecular weight The reaction, 3CIO~(aq) > C1O;- (aq) + 2CF (ag) is an example of (@ oxidation reaction (b) reduction reaction (c) disproportionation reaction (d) decomposition reaction An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH required to completely neutralise 10 mL of this solution is (a) 40 mL (6) 20 mL (c) 10 mL (d) 4 mL. Among the following the species in which the oxidation number of an element is +6 (@) Ma0,- () CCN) (@) NF (a) CrO,Cl, The oxidation number of sulphur in Sg, S,F,, H,S respectively are (@)0,+1 and—2 () 42, +1 and -2 (c) 0, +1 and +2. (d)-2, +1 and-216. 17. 18. 19. The number of moles of KMnO, that will be needed to react completely with one mole of ferrous oxalate in acidic medium is z a s @F OF OF @1 ‘The number ofmoles of KMn0, that will be needed to react with one mole of sulphite ion in acidic solution is @z 2 o4 @. The volume strength of 1.5 N'H,0, is (@48 84 (©) 3.0 @8.0 ‘The oxidation number of phosphorus in Ba(H,PO,), is (43 (b) +2 @H @-1 ‘The equivalent weight of MnSO, is half of its molecular weight, when it converts to (@) Mn,0, (b) Mn0, (© Mn0,- @ Mno?- For the reaction, I+ ClO,-+ H,SO, > Cr +HSO,- +I, the correct statement(s) in the balanced equation is/are (@) stoichiometric coefficient of HSO, is 6 (b) iodide is oxidised (©) sulphur is reduced (@ H,0 is one of the products The volume of 0,3 M ferrous ammonium sulphate solution required for the comple- tion ofredox titration with 20 mL of 0.1 M potassium dichromate solution is mL.EXERCISE I Le 2b 3a 4.b 5d 6.b Ke "Bd 9. 10.4 Ihe 12.6 13,b 4c : EXERCISE - I 1 Ma” 2 33125 3. 50 a 5-2 6 8B MM 1. T6 8. 89.28 cc 9, 24.78 mL, ‘0.658 V’ 10. 0.58N i. 5/6 12, 31 13. 3x10? : 14. 0 15. 160ml 16. 4L 17, sab 18. 12.5L 19. 6L 20. 3 EXERCISE I la 2.2 oe 4.n=42 Sia 6.a 1a 8.b Xe 10.2 ld 1a 13.b l4a 15.b 16.¢ 17.0 18. a,b,d 19.40 www.chemfact.com 8882481674 ee /, EDUCATION @ EDUCATION FORALL