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'S' Block NCERT Digest Questions
'S' Block NCERT Digest Questions
Level-1
1. s-subshell can accommodate maximum number of
(a) zero electron (b) two electrons
(c) one electron (b) None of these
2. Group I elements are collectively known as
(a) alkali metals (b) alkaline earth metals
(c) Both (a) and (b) (d) None of these
3. Group II elements with exceptions of beryllium are known as alkaline earth metals. These are so
called because their ....A… and ...B... are alkaline in nature. Here, A and B refer to
(a) oxides, halides (b) oxides, hydroxides
(c) halides, hydroxides (d) None of these
4. Among the alkali metals ...A... and ......B are relatively more abundant in nature. Here, A and B refer
to
(a) sodium and rubidium (b) lithium and sodium
(c) sodium and potassium (d) lithium and potassium
5. Francium has half-life of
(a) 21 minutes (b) 21 second
(c) 21 hours (d) None of these
-10
6. ...A... is the rarest of all comprising only 10 percent of igneous rocks. Here, A refers to
(a) Barium (b) Radium
(c) Caesium (d) Beryllium
7. General electronic configuration of alkali metals is
1 2
(a) [Noble gas] ns (b) [Noble gas] ns
0
(c) [Noble gas](n-1)s (d) None of these
8. General electronic configuration for alkaline earth metals is
1 2
(a) [Noble gas] ns (b) [Noble gas] ns
(c) Both (a) and (b) (d) None of the above
9. Which of the following does not belong to alkaline earth metal?
(a) Beryllium (b) Strontium
(c) Francium (d) Calcium
10. ...X… and ...Y... shows diagonal similarity. Here, X and Y refer to
(a) Lithium and magnesium (b) Lithium and beryllium
(c) Sodium and magnesium (d) None of these
11. Which of the following shows diagonal relationship?
(a) Magnesium and aluminium (b) Beryllium and aluminium
(c) Lithium and magnesium (d) None of the above
12. The diagonal relationship of elements arises due to the similarity in
(a) ionic sizes (b) charge/radius ratio
(c) Both (a) and (b) (d) None of the above
Level-2
13. Among the following elements the non-radioactive element(s) is/are
(a) francium (b) radium
(c) Both (a) and (b) (d) None of these
14. Which of the following statement(s) is/ are incorrect regarding the s-block elements?
I. Francium is highly radioactive element.
II. Oxides and hydroxides of alkali metals and alkaline earth metals are not alkaline in nature.
III. Sodium and potassium are the only two s-block elements are found in large proportion in biological fluids.
IV. Biological function of s-block elements is due to maintenance of ion balance and nerve impulse
condition.
(a) Only I (b) II and III
(c) II and III (d) Only III
“s”-BLOCK CHEMISTRY ASSIGNMENT (NCERT)
15. Match the Column I with Column II and choose the correct option from the codes given below.
Column I Column II
A. Sodium 1. Present in biological fluid
B. Beryllium 2. Radioactive element
C. Francium 3. Lower abundance
D. Calcium 4. Alkali metals
5. Alkaline earth metal
Codes
A B C D
(a) 1 4 2 5
(b) 1 2 3 4
(c) 3 1 2 5
(d) 4 5 2 1
16. Which of the following is/are correct pair(s) regarding diagonally related elements?
(a) Beryllium and aluminium
(b) Lithium and magnesium
(c) Sodium and aluminium
(d) Both (a) and (b)
17. Which of the following ion(s) is/are responsible for biological functions such as maintenance of
ion balance and nerve impulse conduction?
(a) Sodium (b) Potassium
(c) Magnesium (d) All of these
72. Lithium being very small in size, which ...A... a large CO ion leading to the formation of more
stable ...B… and ...C... Here A, Band C refer to
(a) polarises, up and CO .
(b) polarise, Li2O and CO2
(c) dissociate, Li2O and CO
(d) dissociate, Li2O and CO2
Level-2
73. Which of the following is/are less soluble in water?
LiF, CsI, NaCl, KCl
(a) LiF, NaCl (b) Csl, LiF
(c) KCI, NaCl (d) CsF, NaCl
74. Hydrogen carbonate? of lithium doesn’t exist in solid state due to
+
(a) low polarisation value of Li
+
(b) low hydration energy of Li
+
(c) high hydration energy of Li
+
(d) high polarisation value of Li
75. On moving top to bottom the negative value of formation ...A... for fluoride of alkali metals. Here,
A refers to
(a) becomes less negative (b) becomes more negative
(c) remains constant (d) None of the above
Codes
A B C D A B C D
(a) 4 2 1 3 (b) 1 2 3 4
(c) 4 3 2 1 (d) 3 2 4 1
106. Which of the following is characteristic of baking soda?
(a) It is used as an antiseptic for skin infections
(b) It is used as fire extinguisher
(c) it is used in preparation of cakes and bakery product
(d) All of the above are correct
107. In the synthesis of sodium carbonate, the recovery of ammonia is done by treating NH 4Cl with
Ca(OH)2. The byproduct obtained in this process is
(a) CaCl2 (b) NaCl
(c) NaOH (d) NaHCO3
108. KO2 is used in space and submarines because it
(a) absorbs CO2 and increases O2 Concentration
(b) absorbs moisture
(c) absorbs CO2
(d) produces ozone
109. The ease of adsorption of the hydrated alkali metal ions on an ion-exchange resins follows the
order
+ + + + + + + +
(a) Li < K < Na < Rb (b) Rb < K < Na < Li
+ + + + + + +
(c) K < Na <Rb <Li (d) Na > Li < K < Rb
110. Which one of the alkali metals forms only the normal oxide M2O on heating in air?
(a) Rb (b) K (c) Li (d) Na
111. What is the best description of the change that occurs when Na 2O(s) is dissolved in water?
(a) Oxidation number of sodium decreases
(b) Oxide Ion accepts sharing in a pair of electrons
(c) Oxide ion donates a pair of electrons
(d) Oxidation number of oxygen increases
C. Milk of Magnesia 3.
D. Magnesium carbonate 4.
Codes
A B C D
(a) 1 2 3 4
(b) 4 3 2 1
(c) 1 4 2 3
(d) 1 2 4 3
► Level-2
146. Along the group atomic and ionic radii are ...X... and along the period atomic and ionic radii are
Y... . Here, X and Y refer to
(a) increases and decreases
(b) decreases and increases
(c) decreases and decreases
(d) remain constant and decreases
147. The correct reason for smaller size of alkaline earth metals than that of alkali metal is that
(a) alkali metals have high value of nuclear charge than alkaline earth metal
(b) alkali metals have low value of nuclear charge than alkaline earth metal
(c) alkali metal has high value of screening constant than alkaline earth metals
“s”-BLOCK CHEMISTRY ASSIGNMENT (NCERT)
(d) Both (a) and (c)
148. Which of the following order is correct regarding electropositive character of alkaline earth
metals?
(a) Be < Mg > Ca < Sr < Ra
(b) Be > Mg > Ca > Sr > Ba
(c) Be < Mg < Ca < Sr < Ba
(d) None of the above
149. Assertion (A) Ba, Ca and Sr produces individual characteristic colour to flame test.
Reason (R) This is due to excitation of loosely held electrons from outermost orbit to excited state
of orbital.
(a) Both A and R are correct; R is the correct explanation of A
(b) Both A and R are correct; R is not the correct explanation of A
(c) A is correct; R is incorrect
(d) R is correct; A is incorrect
150. Property of the alkaline earth metals that increases with their atomic number
(a) solubility of their hydroxides in water
(b) solubility of their sulphates in water
(c) ionisation energy
(d) electronegativity
(b) Gypsum
CaSO4.2H2O
A B C D
(a) 1 2 3 4
(b) 3 3 2 1
(c) 2 1 3 4
(d) 2 1 4 3
201. A chemical (A) is used for the preparation of washing soda to recover ammonia. When CO2 is
bubbled through an aqueous solution of A, the solution turns milky. It is used in white washing due
to disinfectant nature. What is the chemical formula of (A)?
(a) Ca(HCO3)2 (b) CaO
(c) Ca(OH)2 (d) CaCO3
202. Chemical clinker can be obtained by the reaction of
(a) clay and lime (b) lime and gypsum
(c) clay and Fe2O3 (d) All of these
203. ‘A’ is an important constituent of cement which is responsible for setting of cement. What is the
number of water of crystallisation present in ‘A’ ?
(a) 2 (b) 1 (c) 0 (d)
۩ Miscellaneous Questions
214. Which of the following choice is most correct regarding regular decrease in ionisation enthalpy
along the group?
(a) Increase in atomic number
(b) Increase in nuclear charge
(c) increase in atomic size
(d) Increase in atomic size overweigh the increase in nude charge
215. What is the atomic number of element present in the compound which is responsible for the
absorption of light of green leaves?
(a) 12 (b) 24 (c) 19 (d) 11
216. Thermal decomposition of ammonium tetrafluoro beryllate produces
(a) BeF2 (b) Be(NH4)2
(c) Both (a) and (b) (d) None of these
217. Which of the following is correct property of hydroxides of alkaline earth metals which
increases top to bottom?
(a) Thermal stability (b) Basic character
(c) Solubility in water (d) All of the above
218. The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy
of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due
to
(a) ionic nature of lithium fluoride
(b) high lattice enthalpy
(c) high hydration enthalpy for lithium ion
(d) low ionisation enthalpy of lithium atom
219. Low solubility of LiF in water is due to ...X... and low solubility of CsI is due to …Y... . Here X and
Y refer to
(a) low lattice energy, high hydration energy
(b) low lattice energy, low lattice energy
(c) high lattice energy, low hydration energy
(d) tow hydration energy, high lattice energy
220. Which of the following is/ are correct statement(s) regarding preparation of cake and pastries?
I. Baking soda is used.
II. Caustic soda is used.
III. Baking soda is used because on heating it produces CO2 bubbles.
IV. Caustic soda is used because on heating it produces CO2 bubbles.
(a) I and IV are correct (b) I and III are correct
(c) II and III are correct (d) Only III is correct
221. Structure of compound obtained after dissolution of beryllium hydroxide and aluminium
hydroxide in the presence of sodium hydroxide solution produces two compound X and Y.
Hybridisation of X and Y are respectively
2 2 2 2
(a) sp and sp (b) sp and dsp
3 2 3 3
(c) sp and dsp (d) sp and sp
“s”-BLOCK CHEMISTRY ASSIGNMENT (NCERT)
222. Dehydration of hydrates of halides of calcium, barium and strontium i.e., CaCl 2.6H2O,
BaCl2 .2H2O, SrCl2 .2H2O, can be achieved by heating. These become wet on keeping in air.
Which of the following statements is correct about these halides?
(a) Act as dehydrating agent
(b) Can absorb moisture from air
(c) Tendency to form hydrate decreases from calcium to barium
(d) All of the above
223. Average composition of metal oxides in Portland cement in decreasing order is
(a) CaO > SiO2 > Al2O3 > MgO > Fe2O3
(b) CaO > Al2O3 > SiO2 > MgO > Fe2O3
(c) Al2O3 > CaO > SiO2 > MgO > Fe2O3
(d) CaO > MgO > SiO2 > Al2O3 > Fe2O3
224. Leblanc process is employed in the manufacture of
(a) baking soda (b) washing soda
(c) potash (d) plaster of Paris
225. Which of the following sequence of chemical reaction is correct?
(a) Na + O2 Na2O → NaCl → Na2CO3 → Na
(b) Na → Na2O → NaOH → NaCO3 → Na
(c) Na + H2O NaOH → NaCl → Na2CO3 → Na
(d) Na + H2O NaOH → Na2CO3 → NaCl → Na + Cl
226. A substance which gives brick red flame and breaks down on heating to give oxygen and a
brown gas is
(a) magnesium nitrate (b) calcium nitrate
(c) barium nitrate (d) strontium nitrate
227 An inorganic compound (A) made up of two elements. Out of which one is the most
electropositive metal and one has maximum value of electron affinity. Which of the following is
correct regarding (A) ?
(a) (A) is a covalent solid
(b) (A) is soluble in organic solvent
(c) (A) has coordination number equal to six for each of its ions
(d) None of the above
228. Slaked lime on treatment with chlorine produces a compound, What is the oxidation state of
chlorine in product?
(a) +1 (b) -1
(c) Both (a) and (b) (d) None of these
229. Gypsum on heating about 120°C forms a compound. What is the mass of water of crystallisation
in compound obtained?
(a) 18 (b) 36 (c) 42 (d) 9
230. The correct order of solubility of the sulphates of alkaline earth metals in water is
(a) Be > Ca > Mg > Ba > Sr
(b) Mg > Be > Ba > Ca > Sr
(c) Be > Mg > Ca > Sr > Ba
(d) Mg > Ca > Ba > Be > Sr
231. Which of the following pair represents pair of amphoteric oxides?
(a) Al(OH)3.LiOH (b) Be(OH)2.Mg(OH)2
(c) B(OH)3. Be(OH)2 (d) Be(OH)2. Zn(OH)2
232. The product recycled during Solvay process is/are
(a) CO2 (b) NH3
(c) Both (a) and (b) (d) NaCI
“s”-BLOCK CHEMISTRY ASSIGNMENT (NCERT)
233. When slaked lime is treated with chlorine gas it produces an inorganic compound (A) which
when treated with sulphuric acid produces an acid (B). What will be (A) and molecular mass of (B)
respectively?
(a) CaCl2 and 38.5 (b) CaCl2 and 52.5
(c) CaOCl2 and 52.5 (d) CaOCl2 and 38.5
234. Which of the following trend is correct regarding reactivity of alkali metal oxide?
(a) Li2O < Na2O < K2O < Rb2O < Cs2O
(b) Li2O > Na2O > K2O > Rb2O > Cs2O
(c) Li2O < Cs2O < K2O < Rb2O < Na2O
(d) Na2O < K2O < Li2O < Rb2O < Cs2O
235. Which of the following does not undergo disproportionation reaction?
(a) Li2O (b) K2O (c) Na2O (d) All of these
236. Which of the following on reaction with oxygen produces paramagnetic oxide?
(a) K (b) Na (c) Be (d) Li
237. The decomposition temperature is maximum for
(a) MgCO3 (b) CaCO3
(c) BaCO3 (d) SrCO3
238. Which of the following represent correct composition of sorel’s cement?
(a) Portland cement + MgO
(b) CaSiO3.MgCO3
(c) MgCl2.CaSiO3
(d) MgCl2.5MgO.xH2O
239. Which of the following metal salt has highest conductivity m aqueous medium?
+ + + +
(a) Li (b) CS (c) Na (d) K
240. Solvay process is not used to prepare KHCO 3. Which of the following reaction will produce
KHCO3?
(a) KHSO4 + KCl
(b) Magnesia process
(c) KNO3 + H2O
(d) Calcium carbonate and silver chloride
241. In case of alkali metals, the covalent character decreases in the order
(a) MI > MBr > MCI > MI
(b) MCI > Ml > MBr > MF
(c) MF > MCI > MBr > MI
(d) MF > MCI > Ml > MBr
242. Correct order of thermal stability of K2CO3, CaCO3, MgCO3 and BeCO3 is
(a) BeCO3 < MgCO3 < CaCO3 < K2CO3
(b) K2CO3 < MgCO3 < CaCO3 < BeCO3
(c) MgCO3 < BeCO3 < CaCO3 < K2CO3
(d) BeCO3 < MgCO3 < K2CO3 < CaCO3
243. Borade of an element, whose mass number is just double of atomic number and contains 12
neutrons produces [X] on treatment with acid.
Here, [X] is
(a) B2O3 (b) MgB2O4
(c) B4H10 (d) MgB4. H10
244. Which of the following is incorrectly matched?
Column-I Column-II
(a) Pearl ash 1. Not prepared by Solvay process
(b) Calcitonin and parathyroid 2. Control Ca extent in plasma
(c) K and Na 3. Present in interstitial fluid
(d) BeF2 4. Soluble in water