Covestro Desmodur BL 3272 Mpa

Safety Data Sheet according to GHS
DESMODUR BL 3272 MPA

Version 4.0 Revision Date 08.04.2020 Print Date 09.04.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Material number: 04109147
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use:
Hardener for coating materials for industrial or trade applications
Uses advised against:

Not suitable for use in homeworker (DIY) applications.
1.3 Details of the supplier of the safety data sheet

Covestro (India) Private Limited
Unit No - SB 801
8th Floor,Empire Tower,Cloud Campus
Thane-Belapur Road, Airoli, 400708
NAVI MUMBAI
INDIA
Tel. +91-22-6819 5504

Fax: +91-22-6819 5556
productsafetyapac@covestro.com
1.4 Emergency telephone number

In case of emergency: Tel: 0120 – 6763 333
Nicer Globe Toll Free Number: 18001213959
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

GHS Classification:
Flammable liquids, Category 3 (H226)
Specific target organ toxicity (repeated exposure), Category 1 (H372)
Specific target organ toxicity (single exposure), Category 3 (H336)
2.2 Label elements

GHS-Labelling
Danger
Hazardous components which must be listed on the label
Blocked aliphatic polyisocyanate
2-methoxy-1-methylethyl acetate
ε-caprolactam
Hazard statements:
1/16 BMS_SDS_IN / IN
H226 Flammable liquid and vapour.

H336 May cause drowsiness or dizziness.
H372 Causes damage to organs (Respiratory system) through prolonged or repeated exposure if inhaled.
Precautionary statements:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER/ doctor if you feel unwell.
P314 Get medical advice/ attention if you feel unwell.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Other hazards

Risk of absorption through the skin of 1-methoxypropylacetate-2 and 2-methoxypropyl acetate-1.
SECTION 3: Composition/information on ingredients
Type of product: Mixture
3.2 Mixtures
Blocked aliphatic polyisocyanate based on HDI
ca. 72 % in 1-methoxypropylacetate-2
Hazardous components
Concentration [wt.-%]: ca. 72
GHS Classification: STOT RE 1 Inhalative H372
Concentration [wt.-%]: ca. 26
GHS Classification: Flam. Liq. 3 H226 STOT SE 3 H336
ε-caprolactam
Concentration [wt.-%]: < 1.5
GHS Classification: Acute Tox. 4 Inhalative H332 Acute Tox. 4 Oral H302 Eye Irrit. 2 H319 STOT SE 3
H335 Skin Irrit. 2 H315
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice: Take off all contaminated clothing immediately.
If inhaled: Take the person into the fresh air and keep him warm, let him rest; if there is difficulty in breathing,
medical advice is required.
In case of skin contact: In case of skin contact wash affected areas thoroughly with soap and plenty of
water.
In case of eye contact: Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long
period of time (at least 10 minutes). Contact an ophthalmologist.
If swallowed: DO NOT induce the patient to vomit, medical advice is required.
4.2 Most important symptoms and effects, both acute and delayed
Notes to physician: Basic first aid, decontamination, symptomatic treatment.
4.3 Indication of any immediate medical attention and special treatment needed
Therapeutic measures: No information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media: Carbon dioxide (CO2), Foam, extinguishing powder, in cases of larger fires,
water spray should be used.
Unsuitable extinguishing media: High volume water jet
5.2 Special hazards arising from the substance or mixture

Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen, isocyanate vapors and traces of
hydrogen cyanide. In the event of fire and/or explosion do not breathe fumes.
5.3 Advice for fire-fighters

During fire-fighting respirator with independent air-supply and airtight garment is required.
Do not allow contaminated extinguishing water to enter the soil, ground-water or surface waters.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Put on protective equipment (see section 8). Keep away from sources of ignition. Ensure adequate
ventilation/exhaust extraction. Keep unauthorized persons away.
6.2 Environment related measures

Do not allow to escape into waterways, wastewater or soil.
6.3 Methods and material for containment and cleaning up

Take up with absorbent for chemicals or, if necessary with dry sand and store in closed containers.
6.4 Reference to other sections

For further disposal measures see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

The precautions required in the handling of solvents must be taken. Ensure adequate ventilation and, if
necessary, exhaust ventilation when handling or transferring the product.
The threshold limit values noted in section 8 must be monitored. In all workplaces or parts of the plant where
aerosols and/or vapors maybe generated, appropriately located exhaust ventilation must be provided in order
to prevent occupational exposure limits from being exceeded. The air should be drawn away from the
personnel handling the product The efficiency of the exhaust equipment should be periodically checked.
Explosion protection required.
The personal protective measures described in section 8 must be observed. Avoid contact with skin and eyes
and the inhalation of vapor.
Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at the end of workday. Keep
working clothes separately. Change contaminated or soaked clothing.
7.2 Conditions for safe storage, including any incompatibilities

Keep container dry and tightly closed in a cool and well ventilated place. Further information on the storage
conditions which must be observed to preserve quality can be found in our product information sheet.
7.3 Specific end use(s)

No information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Respiratory protection
Respiratory protection required in insufficiently ventilated working areas and during spraying.
Hand protection
Suitable materials for safety gloves; EN 374:
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Recommendation: contaminated gloves should be disposed of.
Eye protection
Wear eye/face protection.
Skin and body protection

Wear suitable protective clothing.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance: liquid
Colour: yellowish
Odour: solvent-like
Odour Threshold: not established
pH: not applicable
Boiling point/boiling range: ca. 140 °C at 1,013 hPa
Flash point: ca. 50 °C DIN 53213
Evaporation rate: not established
Flammability (solid, gas): not applicable
Burning number: not applicable
Upper/lower flammability or explosive limits:
2-methoxy-1-methylethyl acetate upper: 10.8 %(V) / lower: 1.5 %(V)
ε-caprolactam upper: 11.9 %(V) / lower: 1.6 %(V)
Vapour pressure: not established
Vapour pressure of ingredients:
2-methoxy-1-methylethyl acetate ca. 5 hPa at 20 °C
Vapour density: not established
Density: ca. 1.12 g/cm³ at 20 °C DIN EN ISO

2811
Miscibility with water: immiscible at 15 °C
Water solubility of ingredients:
2-methoxy-1-methylethyl acetate ca. 200 g/l at 20 °C
Surface tension: not established
Partition coefficient not established
(n−octanol/water):
Auto-ignition temperature: not applicable
Ignition temperature: ca. 315 °C
Decomposition temperature: not established
Viscosity, dynamic: ca. 2,700 mPa.s at 23 °C DIN EN ISO
3219/A.3
Explosive properties: not established
Dust explosion class: not applicable
Oxidising properties: not established
9.2 Other information

The indicated values do not necessarily correspond to the product specification. Please refer to the technical
information sheet for specification data.
SECTION 10: Stability and reactivity
10.1 Reactivity
This information is not available.
10.2 Chemical stability

Under stoving conditions (e.g. 140 °C) caprolactam is split off. Also when stoving coatings containing these
product, traces of monomeric diisocyanate may be released. Stoving gases should be extracted.
10.3 Possibility of hazardous reactions

No hazardous reactions when used as directed.
10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

No hazardous decomposition products when stored and handled correctly.
SECTION 11: Toxicological information
Please find below the data available to us:
11.1 Information on toxicological effects

Acute toxicity, oral
LD50 rat: > 1,800 mg/kg
Method: OECD Test Guideline 423
Assessment: The substance or mixture has no acute oral toxicity
LD50 rat, male/female: 6,190 mg/kg

ε-caprolactam
LD50 rat: 1,660 mg/kg
Acute toxicity, dermal

Study scientifically not justified.
LD50 rat: > 5,000 mg/kg
ε-caprolactam
LD50 rat: > 2,000 mg/kg
Acute toxicity, inhalation

LC50 rat, male/female: > 3.069 mg/l, 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhalation toxicity
LC50 rat, male:
> 2000 ppm, 3 h
Test atmosphere: gas
Assessment: The substance or mixture has no acute inhalation toxicity
ε-caprolactam
LC50 rat: 8.16 mg/l, 4 h
Test atmosphere: dust/mist
Assessment: Harmful if inhaled.
Primary skin irritation

Species: rabbit
Result: non-irritant
Classification: No skin irritation
Species: rabbit
Result: non-irritant
Classification: No skin irritation
ε-caprolactam
Result: irritating
Classification: Causes skin irritation.
Primary mucosae irritation

Species: rabbit
Result: slight irritant
Classification: No eye irritation
Species: rabbit
Result: slight irritant
Classification: No eye irritation
ε-caprolactam
Result: irritating
Classification: Causes serious eye irritation.
Sensitisation
Skin sensitization (local lymph node assay (LLNA)):
Species: Mouse
Result: negative
Classification: Does not cause skin sensitization.
Respiratory sensitization
No data available.
Skin sensitisation according to Magnusson/Kligmann (maximizing test):
Species: Guinea pig
Result: negative
Respiratory sensitization
No data available.
ε-caprolactam
Skin sensitisation:
Species: Guinea pig
Result: negative
Subacute, subchronic and prolonged toxicity

NOAEL: 9,2 mg/m³
Application Route: inhalation (dust/mist/fume)
Species: rat, male
Dose Levels: 0 - 10 - 100 mg/m³
Exposure duration: 9 d
Frequency of treatment: 6 hours a day, 5 days a week
Subsequent observation period: 14-day
LOAEL (Lowest observable adverse effect level): 0,3 mg/m³

Species: rat, male/female
Dose Levels: 0 - 0,3 - 1,5 - 7,4 mg/m³
Frequency of treatment: 6 hours a day, 5 days a week
Subsequent observation period: 90-day
Studies of a comparable product.
NOAEL: 1,000 mg/kg
Application Route: Oral
Dose Levels: 100 - 300 - 1000 mg/kg/day
ε-caprolactam
NOAEL: 29 mg/kg
NOAEL: 0.245 mg/l

Dose Levels: 0,025 - 0,075 - 0,250 mg/l
Exposure duration: 13 wk
Carcinogenicity
No data available.
NOAEL (Toxicity): >= 11.07 mg/l
Application Route: Inhalative
Exposure duration: 24 month(s)
Frequency of treatment: 6 hours/day, 5 days/week
ε-caprolactam
NOAEL (Toxicity): > 2,143 mg/kg body weight/day
Species: Mouse, male/female
Exposure duration: 103 week(s)
Animal testing did not show any carcinogenic effects.
NOAEL (Toxicity): > 375 mg/kg body weight/day

Exposure duration: 103 week(s)
Animal testing did not show any carcinogenic effects.
Reproductive toxicity/Fertility
NOAEL - Parents: 300 ppm
NOAEL – F1: 1000 ppm
NOAEL – F2: 1000 ppm
Test type: Two-generation study
Frequency of treatment: 6 hours/day 7 days/week
ε-caprolactam
NOAEL - Parents: 500 mg/kg
NOAEL – F1: 100 mg/kg
NOAEL – F2: 100 mg/kg
NOAEL (parents, fertility): 1000 mg/kg body weight/day
Test type: Three-eneration study
Application Route: (feeding study ) oral
Dose Levels: 300, 500, 1000 mg/kg bw/day
Frequency of treatment: daily
No toxicity to reproduction
Reproductive toxicity/Teratogenicity
NOAEL (teratogenicity): 1500 ppm
NOAEL (maternal): 1500 ppm
Species: rat, female
Dose Levels: 0 - 500 - 1500 - 3000 ppm
Frequency of treatment: 6 hours/day (Exposure duration: 10 days (day 6 - 15 p.c.))
ε-caprolactam
NOAEL (teratogenicity): > 250 mg/kg
NOAEL (maternal): 150 mg/kg
Species: rabbit, female
Dose Levels: 50 - 150 - 250 mg/kg body weight/day
NOAEL (teratogenicity): 1,000 mg/kg

NOAEL (maternal): 100 mg/kg
Species: rat, female
Dose Levels: 100 - 500 - 1000 mg/kg body weight/day
Genotoxicity in vitro
Test type: Salmonella/microsome test (Ames test)
Metabolic activation: with/without
Result: No indication of mutagenic effects.
Test type: In vitro mammalian cell gene mutation test

Test system: Chinese hamster V79 cell line
Result: negative
Test type: Chromosome aberration test in vitro

Test system: Chinese hamster ovary (CHO) cells
Result: negative
Test type: Ames test
Result: No indication of mutagenic effects.
Test type: Unscheduled DNA synthesis (UDS)

Result: negative
ε-caprolactam
Test type: Ames test
Result: negative
Test type: Chromosome aberration test in vitro

Test system: Human lymphocytes
Result: positive
Genotoxicity in vivo
No data available.
ε-caprolactam
Test type: Micronucleus test
Species: Mouse, male
Application Route: intraperitoneal
Result: negative
STOT evaluation – one-time exposure

Based on available data, the classification criteria are not met.
May cause drowsiness or dizziness.
ε-caprolactam
May cause respiratory irritation.
STOT evaluation – repeated exposure

Route of exposure: Inhalative
Target Organs: Respiratory system
Causes damage to organs through prolonged or repeated exposure.
ε-caprolactam
Aspiration toxicity
ε-caprolactam
CMR Assessment
Carcinogenicity: Based on available data, the classification criteria are not met.
Mutagenicity: Tests on bacterial or mammalian cell cultures did not show mutagenic effects. On the basis of
this data, the substance is not classified as mutagenic.
Teratogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity/Fertility: Based on available data, the classification criteria are not met.
Carcinogenicity: No data available.
Mutagenicity: Based on available data, the classification criteria are not met.
ε-caprolactam
Carcinogenicity: Based on available data, the classification criteria are not met.
Mutagenicity: Based on available data, the classification criteria are not met.
Toxicology Assessment
Acute effects: Based on available data, the classification criteria are not met.
Sensitization: Based on available data, the classification criteria are not met.
Repeated dose toxicity: Based on available data, the classification criteria are not met.
Acute effects: Based on available data, the classification criteria are not met.
ε-caprolactam
Acute effects: Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.
Additional information
Risk of cutaneous absorption.
SECTION 12: Ecological information
Do not allow to escape into waterways, wastewater or soil.
Please find below the data available to us:
12.1 Toxicity
Acute Fish toxicity
LC50 > 100 mg/l
Species: Danio rerio (zebra fish)
Exposure duration: 96 h
Studies at the product containing solvent
LC50 > 100 mg/l
Species: Oryzias latipes (Orange-red killifish)
ε-caprolactam
LC50 500 - 1,000 mg/l
Species: Salmo gairdneri
Chronic Fish toxicity

NOEC 47.5 mg/l
Species: Oryzias latipes (Orange-red killifish)
ε-caprolactam
Acute toxicity for daphnia

Species: Daphnia magna (Water flea)
No toxic effects in the water-soluble range.
EC50 > 500 mg/l

Method: Directive 67/548/EEC, Annex V, C.2.
ε-caprolactam
EC50 > 500 mg/l
Chronic toxicity to daphnia

NOEC > 100 mg/l
ε-caprolactam
NOEC (Reproduction) > 100 mg/l
Acute toxicity for algae

ErC50 > 100 mg/l
Test type: Growth inhibition
Species: Desmodesmus subspicatus (Green algae)
ErC50 > 1,000 mg/l
Species: Pseudokirchneriella subcapitata (green algae)
ε-caprolactam
IC50 > 1,000 mg/l
Species: Pseudokirchneriella subcapitata (green algae)
Acute bacterial toxicity

EC50 > 1,000 mg/l
Test type: Respiration inhibition
Species: activated sludge
EC20 > 1,000 mg/l
Species: activated sludge
Exposure duration: 0.5 h
ε-caprolactam
EC50 4,200 mg/l
Species: Pseudomonas putida
Ecotoxicology Assessment

Acute aquatic toxicity: Based on available data, the classification criteria are not met.
Chronic aquatic toxicity: Based on available data, the classification criteria are not met.
Toxicity Data on Soil: Adsorbs on soil.
Impact on Sewage Treatment: Because of the low bacterial toxicity, there is no risk of an adverse effect on the
performance of biological waste water treatment plants.
ε-caprolactam
12.2 Persistence and degradability

Biodegradability
Inoculum: activated sludge
Biodegradation: 0 %, 28 d, i.e. not readily degradable
Method: OECD Test Guideline 301 F
Biodegradation: 100 %, 8 d, i.e. inherently degradable
Method: OECD Test Guideline 302 B
Biodegradation: > 90 %, 28 d, i.e. readily biodegradable

Method: OECD Test Guideline 301 F
ε-caprolactam
Biodegradation: 82 %, 14 d, i.e. readily biodegradable
Method: OECD Test Guideline 301 C
Stability in water
Test type: Hydrolysis
Half life: > 1 Years at 25 °C (pH: 4)
The substance is hydrolytically stable.


Photodegradation
Test type: Phototransformation in air
sensitizer: OH-radicals
Concentration sensibilisator: 500,000 1/cm3
Rate constant: 9.28524E-11 cm3/s
Half-life indirect photolysis: 4.15 h
Method: SRC - AOP (calculation)
After evaporation or exposure to the air, the product will be rapidly degraded by photochemical processes.
Volatility (Henry's Law constant)

Calculated value = 0.001 Pa*m3/mol at 20 °C
The substance has to be scored as being slightly volatile from water.
Adsorbed organic bound halogens (AOX)

Product does not contain any organic halogens.
12.3 Bioaccumulative potential

Bioaccumulation
Bioaccumulation is unlikely.
Accumulation in aquatic organisms is unlikely.
ε-caprolactam
Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected.
Partition coefficient (n−octanol/water)

ε-caprolactam
log Pow: 0.12
12.4 Mobility in soil

Distribution among environmental compartments
Adsorption/Soil
Koc value: 11200
log Koc value: 4.05
immobile
Environmental distribution
medium air: 0.01 %
Medium water: 19.38 %
Medium soil: 39.73 %
Medium sediment: 40.17 %
Medium suspended sediment: 0.26 %
Medium biota: 0.03 %
Medium aerosol: 0.42 %
Method: Calculation according to Mackay, Level I
The target compartements are soil and sediment.
12.5 Results of PBT and vPvB assessment

No data available.
12.6 Other adverse effects
No data available.
SECTION 13: Disposal considerations
Dispose in accordance with applicable international, national and local laws, ordinances and statutes. For
disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be
used.
13.1 Waste treatment methods

After containers have been emptied as thoroughly as possible (e.g. by pouring, scraping or draining until
"drip-dry"), they can be sent to an appropriate collection point set up within the framework of the existing
take-back scheme of the chemical industry. Containers must be recycled in compliance with national
legislation and environmental regulations.
None disposal into waste water.
SECTION 14: Transport information
Land transport India

14.1 UN number : 1866
14.2 UN proper shipping name : RESIN SOLUTION
14.3 Transport hazard class(es) : 3
Hazchem Code : 3Y
14.4 Packing group : III
14.5 Environmental hazards : no
IATA
14.1 UN number : 1866
14.5 Environmental hazards : no
IMDG
14.1 UN number : 1866
14.5 Marine pollutant : no
EmS Code : F-E - S-E
Segregation Group IMDG : not applicable
14.6 Special precautions for user

See section 6 - 8.
Additional information : Combustible.
Keep dry.
Keep away from foodstuffs, acids and alkalis.
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
SECTION 16: Other information
Full text of the hazard statements of the CLP classification (1272/2008/CE) referred to under sections 2, 3
and 10.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H372 Causes damage to organs through prolonged or repeated exposure.
Relevant changes since the last version are highlighted in the margin. This version replaces all previous
versions.
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.

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Safety Data Sheet according to GHS

DESMODUR BL 3272 MPA

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

DESMODUR BL 3272 MPA

Uses advised against:

1.3 Details of the supplier of the safety data sheet

Tel. +91-22-6819 5504

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

2.2 Label elements

H226 Flammable liquid and vapour.

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Type of product: Mixture

SECTION 4: First aid measures

4.1 Description of first aid measures

If swallowed: DO NOT induce the patient to vomit, medical advice is required.

Notes to physician: Basic first aid, decontamination, symptomatic treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing media: High volume water jet

5.2 Special hazards arising from the substance or mixture

5.3 Advice for fire-fighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environment related measures

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Explosion protection required.

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Skin and body protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Density: ca. 1.12 g/cm³ at 20 °C DIN EN ISO

9.2 Other information

SECTION 10: Stability and reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

Please find below the data available to us:

11.1 Information on toxicological effects

Assessment: The substance or mixture has no acute oral toxicity

LD50 rat, male/female: 6,190 mg/kg

Acute toxicity, dermal

Acute toxicity, inhalation

Assessment: The substance or mixture has no acute inhalation toxicity

Primary skin irritation

Primary mucosae irritation

Subacute, subchronic and prolonged toxicity

LOAEL (Lowest observable adverse effect level): 0,3 mg/m³