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Units - Basic Ideas - Composition: GP-CPC-01
Units - Basic Ideas - Composition: GP-CPC-01
Prof.G.Prabhakar
Chem Engg, SVU
GP-CPC-01
UNITS – CONVERSION (1)
➢ A two term system is followed. A base unit is chosen and the number of base units that
represent the quantity is added ahead of the base unit. Number Base unit
Eg : 2 kg, 4 meters , 60 seconds
➢ Manipulations Possible :
• If the nature & base unit are the same, direct addition / subtraction is permitted
2 m + 4 m = 6m ; 5 kg – 2.5 kg = 2.5 kg
• If the nature is the same but the base unit is different , say, 1 m + 10 c m
both m and the cm are length units but do not represent identical quantity, Equivalence
considered
2 options are available. 1 m is equivalent to 100 cm So, 100 cm + 10 cm = 110 cm
0.01 m is equivalent to 1 cm 1 m + 10 (0.01) m = 1. 1 m
Even if there is divergence in the nature, multiplication / division can be carried out.
Eg : Velocity ( length divided by time )
Mass flow rate (Mass divided by time)
Mass Flux ( Mass divided by area (Length 2) – time).
Force (Mass * Acceleration = Mass * Length / time 2)
Units of b : Since it is being subtracted from V, b will have the same units as V
Units of a : Since a/V2 is being added to P,
this group shall have the units of P. Further a is divided by V2 and
V is not available in the units of the group, units of a will be P – V2
Equations that have equal units on either side are labelled dimensionally consistent
Mass Transfer Flux = Coefficient * Driving Force ; Coefficient will carry the units of flux
divided by driving force
Reaction Rate = Rate Constant * Concentration n
Units of Rate constant = Rate / Concentration n
Certain equations developed from experimental data are called empirical equations. Constants present in
such empirical equations will have dimensions and they must be strictly adhered to.
Proper representation of quantities / conditions , number followed by base unit, is a good habit.
It helps to check the correctness of the calculational approach.
Sometimes , they even suggest the direction of calculation
GP-CPC-01
Concept of ‘Mole’
➢ Certain events in chemical processing happen in direct proportion to the number of molecules of the
system.
Eg : Molecular diffusion , Chemical Reaction…
It is convenient and purposeful to use a dimension in such cases. MOLE
➢ Avagadro’s number defines a mole of a substance , that contains 6.022 *1023 units ( molecules) of that substance.
Further, it is related to mass through molecular weight by a simple relation
1 Mole = Mass / Molecular weight
➢ Conversion of one to another is possible with the conversion factors used for mass
1 kg = 2.205 lb = 1000 grams
1 k mol = 2. 205 lb mol = 1000 g mol
GP-CPC-01
COMPOSITION
➢ All steps in industrial processing involve mixtures of substances
➢ All the members ( components) of a mixture are in the same phase - A homogeneous
mixture or solution.
If they remain in different phases - A heterogeneous mixture.
COMPOSITION
➢ Composition is specified in a number of ways.
A clear understanding of the ideas and their inter relationship is of paramount importance.
For any specification, a basis is necessary. Hence, different ways
Ratio is considered to be independent of temperature & pressure . Default for gas mixtures.
It is to be reiterated that a good grasp of composition specification will be of great help in all process
calculations, mass transfer, reaction, everywhere…
GP-CPC-01
28.84
• 28.84 obtained in this calculation is the mass of 1 mol of air. For mixtures, such values are called Average
Molecular Weight. They are useful to convert moles to mass or vice versa of mixtures.
Average Molecular Weight = Σ xi * wi ( mole fraction of a component multiplied by its molecular weight,
summed over all the components)
• Atmospheric nitrogen is a mixture of nitrogen, argon, carbon dioxide…. Its molecular weight is usually taken as 28.2
GP-CPC-01
➢ An aqueous solution has 25 g of salt per g water. What is the mole fraction of the salt?
Use Molecular weight of salt = 40 Molecular weight of water = 18
Data provided is mass of salt / mass of water . Mole per total moles is required. Moles = Mass / Mol.wt
26 g ( 25 g salt + 1 g water ) are equivalent to 0.68 g moles. Average Mol.Wt = 26 / 0.68 = 38.23
➢ An aqueous solution has 25 g of salt per 100 g of solution. What is the mole fraction of the salt?
Use Molecular weight of salt = 40 Molecular weight of water = 18
1) Data provided is mass of salt / Total mass of solution. Mole per total moles is required. Moles = Mass / Mol.wt
Component Mass Mol.wt Moles Mole fraction
Salt 25 40 25/40 = 0.625 0.625 / 4.792 = 0.13
Water 100 – 25 = 75 18 75/18 = 4.167 4.167 / 4.792 = 0.87
4.792
Average Mol. Wt = 100 / 4.792 = 20.87 Molecular weight is mass of 1 mole of a substance
GP-CPC-01
➢ A commercial acid at 20O C, has 36.8 mole percent H2SO4 and the balance water. Express the composition in Molarity, Molality
and Normality. Take density of the solution as 1.14 g /cc
Basis : 1 mol of solution
Component Moles Mol.Wt Mass, in g
H2SO4 0.368 98 36.064
H2O 0.632 18 11.376
TOTAL 47.44
1 kmol of solution has a mass of 47.44 Its volume is 47.44 g = = 41.61 cc ( 0.04161 L)
1.14 g/cc
➢ It is desired to prepare 5 L of 2.8 m ( molal ) solution of sodium chloride. What mass of sodium chloride needs to be taken
Density, ρ = 1 + 0.0044 w, where ρ is in g / cc and w is the weight percent
Basis of Calculation : 2.8 molal NaCl solution - 5 L Molecular weight of NaCl = 58.5
2.8 mol NaCl = 2.8 * 58.5 = 163.8 g NaCl
1000 g water ( Solvent)
➢ A gas mixture containing A, B and C analyses 40 mole % A, 18.75 mass % B and 20 mol % C. If the molecular weights of A and C
are 40 and 50 respectively, what is the molecular weight of B ?
Basis : 1 mol of mixture
mole fraction of A = 0.4 mole fraction of C = 0.2 mole fraction of B = 1 – (0.4 + 0.2) = 0.4
Equiv. mass = 0.4 * 40 = 16 Equiv. Mass = 0.2 * 50 = 10
Since mass fraction of B = 0.1875 , mass fraction of ( A + C ) = 1 – 0.1875 = 0.8125
0.8125 mass fraction corresponds to 26 (= 16 + 10) Total mass = 26 / 0.8125 = 32
0.4 * 40 + 0.2 * 50 + 0.4 * MB = 32 MB = 15
GP-CPC-01
➢ A liquid mixture of components A, B & C is found to contain 10 kg of A, 25 mass % of B and 1.5 moles of C per
mole of B. Molecular weights of A, B & C are 56, 58 & 72 , respectively.
What is the molecular weight of the mixture?
Mass of 0.558 kmol is 35.21 Kg Mass of 1 mol = 35.21 / 0.558 = 63.1 = Average Molecular weight
GP-CPC-01
Good Day…
Discussion : prabhakarg14@gmail.com