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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI


A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr. Super60 & All 2019_P2 Date: 04-04-21
Time: 02.30Pm to 05.30Pm GTA-04(Paper-2) Max. Marks: 186

04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)


Syllabus

PHYSICS : Total Syllabus

CHEMISTRY : Total Syllabus

MATHS : Total Syllabus

Name of the Student : ___________________ H.T. NO :


Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
JEE-ADVANCE-2019-P2-Model
Time: 3:00Hr’s IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 8) +1 partial marks
4 -1 8 32
Questions with Numerical Value
Sec – II(Q.N : 9 – 14) 3 0 6 18
Answer Type
Sec – III(Q.N : 15 – 18) Matching Type 3 -1 4 12

Total 18 62

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 8) +1 partial marks
4 -1 8 32
Questions with Numerical Value
Sec – II(Q.N : 9 – 14) 3 0 6 18
Answer Type
Sec – III(Q.N : 15 – 18) Matching Type 3 -1 4 12

Total 18 62

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Multiple Correct Choice 4 -1 8 32
+1 partial marks
Questions with Numerical Value
Sec – II(Q.N : 9 – 14) 3 0 6 18
Answer Type
Sec – III(Q.N : 15 – 18) Matching Type 3 -1 4 12

Total 18 62

Sec: Sr.Super60 & All Space for rough work Page 2


Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
PHYSICS Max Marks: 62
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -1 in all wrong cases
Section 1 (Max Marks: 32)
 Section 1 contains eight questions.
 Each Question has Four Options and Only One of these four will be the correct answer.
 For each question, choose the option corresponding to the correct answer
 The Marking scheme to evaluate the Answer to each question:
Full Marks: +4 (If the answer is correct)
Partial Marks: +3 (If all the four options are correct but only 3 are chosen)
Partial Marks: +2 (If THREE or More options are correct but only 2 correct answers are chosen)
Partial Marks: +1 (If TWO or More options are correct but only 1 correct answer is chosen)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
1. A spherical object which behaves as a black body is raised to the temperature T0 and
placed in an environment whose temperature is, initially 0C . While the object cools
from T0 to the temperature Te in an interval of time t   , the environment rises to the
dT
temperature t o C during the same time. The average rate of cooling of the object  
 dt 
and the net heat loss (Q) of the object during the time interval 0  t   are respectively
4
dT
given by     A and  Q    A while the same quantities during the interval 3  t  
 dt  4
dT
are     B and  Q    B . Assume Stefan’s law is valid and read the following
 dt 
statement about this system. State which of the following statement(s) is/are true, by
CORRECT choice from below :
A)  A   B ,  A   B
B)  A   B ,  A   B
C) The Newton’s law of cooling will be valid whenever Stefan’s law is valid
D) The rate of cooling decreases with time at first, reaches a minimum and then
increases with time

Sec: Sr.Super60 & All Space for rough work Page 3


Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
2. A uniform rectangular narrow U-tube has equal arm lengths and base length, each

equal to  . The vertical arms are filled with mercury up to and then one end is
2
sealed. By heating the enclosed gas all the mercury is expelled and collected at same
level as the top most point of the tube. Assume ideal gas and ideal liquid conditions. If
atmospheric pressure is P0 , the density of mercury is  and cross-sectional area is S,
then : [Neglect thermal expansion of glass and mercury, surface tension and viscosity
effects and assume 2  S ]

A) Work done by the gas against its surroundings is 5 P0S


2
7
B) Work done by the gas against the gravity is S g  2
4
5
C) Work done by the (gas + liquid) system against the atmospheric pressure is P0S
2
D) Work done by the (gas + liquid) system against the gravity is S g 2
3. Mark the correct statement(s) for the situation shown : (Assume potential at infinity is
zero)

r
r1
C
R

Neutral isolated spherical


conductor with spherical cavity

Sec: Sr.Super60 & All Space for rough work Page 4


Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
A) If a point charge q is placed inside the cavity but not at centre, then potential of the
q
conductor is
4 0 R
B) If a point charge q is placed at the centre of cavity, then potential of the conductor
will be zero
C) If a point charge q is placed inside the cavity but not at centre, then potential of the
q 1 1 1
conductor will be    
4 0  R r r1 
D) If a point charge q is placed inside the cavity but not at centre, then potential at the
q
centre of the conductor due to charges on the outer surface of conductor is
4 0 R
4. Shown below are the essentials of a commercial mass spectrometer. This device is
used to measure the composition of gas samples, by measuring the abundance of
species of different masses. An ion of mass m and charge q   e is produced in source
S, a chamber in which a gas discharge is taking place. The initially stationary ion
leaves S, accelerated by a potential difference V  0 , and then enters a selector

chamber, S1 , in which there is an adjustable magnetic field B1 , pointing out of the page

and a deflecting electric field E , pointing from positive to negative plate. Only

particles of a uniform velocity v1 travel undeflected and leave the selector. The

emerging particles at S2 , enter a second magnetic field B2 , also pointing out of the
page. The particle then moves in a semicircle, striking an electronic sensor at a
distance x from the entry slit S2 . Mark the CORRECT statement(s)

Electronic sensor

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
eB22 x 2
A) the mass of the particle is
8 V
eB22 x 2
B) the mass of the particle is
4 V
C) the magnetic field in the selector chamber that is needed to ensure that the particle
ExB2
travels straight through is
2V
D) the magnetic field in the selector chamber that is needed to ensure that the particle
ExB2
travels straight through is
4V
5. Two alike discharge lamps operated from the mains, 220 V and 50 Hz, and they are
both connected to inductors in series. The inductors are alike and considered ideal. A
condenser is connected in series to one of the discharge lamps. With this arrangement
it is ensured that when the instantaneous current through one of the lamps is
maximum, then the current through the other one is minimum and vice-versa. (Anti
stroboscopic navigation.) The average value of the power dissipated in each discharge
lamp is 8 W. Then which of the following is/are correct? (Assume discharge lamps as
resistors)
A) The value of resistance of discharge lamp is 3.025 k
B) The capacitance of condenser is 6.6  F (upto one decimal place)
C) The total ohmic resistance of the discharge lamp and the inductor together is
4.28 k (upto two decimal places)
D) The capacitive reactance is double of inductive reactance
6. Highly excited states for hydrogen like atoms (also called Rydberg states) with
nuclear charge Ze are defined by their principal quantum number n, where n >> 1.
Which of the following statement(s) is (are) true ?
A) Relative change in the radii of two consecutive orbitals (from n to n + 1) does not
depend on Z
1
B) Relative change in the radii of two consecutive orbitals (from n to n + 1) varies as
n
C) Relative change in the energy of two consecutive orbitals (from n to n + 1) varies as
1
n3
D) Relative change in the magnitude of angular momentum of two consecutive
1
orbitals (from n to n + 1) varies as
n
Sec: Sr.Super60 & All Space for rough work Page 6
Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
7. A candle of small height h is being moved along the axis from u = 3f towards a thin
converging lens of focal length f. The adjacent graph represents the height of image
 hi  as a function of the position of image w.r.t. lens as shown in figure. (At
u  3f , v  v1 )

hi

of image)
+ve

(Height
h2
h1

v1 v2
3f V (image position)
A) The value of h 2 is h B) The value of h 2 is 2h
h v1 3
C) The value of h1 is D) The ratio is
2 v2 4
8. Consider the situation shown in the figure. Two slits S1 and S2 are placed symmetrically
about the line OP which is perpendicular to screen. The space between screen and slits is
filled with a liquid of refractive index 3 . A plate of thickness t and refractive index 2 is
placed in front of one of the slit. A source S is placed above OP at a distance d. Choose
the correct alternatives. [Given that D = 1 m, d = 2 mm, t  6 106 m , 2  1.2 , 3  1.8 ]
Screen

3
S
air
S1
d
O d P
air S2 2 3

D 2D
A) Position of central maxima from point P is 2 mm
2
B) Position of central maxima from point P is mm
9
20
C) Thickness of glass slab (if changed) so that central maxima forms at point P is m
3
D) If glass slab in the problem statement is removed, the central maxima shifts by a
distance of 2 mm
Sec: Sr.Super60 & All Space for rough work Page 7
Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
SECTION – II
(NUMERICAL VALUE TYPE)
This section contains 6 questions. Each question is numerical value type. For each question, enter the correct
numerical value (e.g. 003.2343, 6.250023, 7.000000, ‐0.33, ‐.30, 30.27000, ‐127.0030).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Section 2 (Max Marks: 18)
 Section two contains six (6) questions. The answer to each question is a NUMERICAL VALUE
 For each question enter the correct numerical value of the answer using the mouse and the on-screen
virtual numerical keypad in the place designated to enter the answer. If the numerical values has more
than two decimal places, truncate/round off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme
Full Marks: +3 (If only the correct numerical value is entered)
Zero Marks: 0 (In all other cases)
9. When the system shown in the diagram is in static equilibrium, the right spring is
stretched by 1 cm. The coefficient of static friction between the blocks is 0.3. There is no
friction between the bottom block and the supporting surface. The force constants of the
springs are 150 N/m and 450 N/m (refer figure). The blocks have equal mass of 2 kg
each. Find the maximum amplitude (in cm) of the oscillations of the system shown in the
figure that does not allow the top block to slide on the bottom.  g  10 m / s2 

450 N/m
m
150 N/m
m
 GM 
10. A ring of mass m and radius 3R is rotating with constant angular speed     
 9R 3 
around a planet of mass M and radius R. Center of ring and planet coincide with each
GMm
other. Tension in the ring is given as T  . Find value of n. (Assume elements of
3n R 2
the ring don’t gravitationally interact with each other)

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
11. In the figure shown below, the maximum possible unknown resistance X (in  ), that
can be measured by the post office box is given by a 10b  in scientific notation, then
find the value of a  b ? (in this experiment, we take out only one plug in arm AB and
only one plug in arm BC, but in arm AD we can take out many plugs).

A C

12. ABCD is a square frame of conductor of electrical resistivity  . The frame lies in a
vertical plane. PQ is an imaginary boundary separating space into two parts. Left of

PQ, a hypothetical uniform gravitational field g exists (see figure) whereas no
gravitational field is present right of PQ. The electrical potential difference between A
k mgh
and B will be . e is charge on an electron and m is mass of electron. Find k.
8 e
P

A D

g h

B C
Q

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
13. The ratio of the components in a mixture, which consists of two elements, is to be
determined. The atomic number of the elements are big, their atomic mass numbers
are the same and the amount of the sample is only 58 mg. We know that both elements
undergo  decay when they are bombarded by neutrons. They behave similarly when
absorbing neutrons. The half-life of element A is half an hour and the half-life of
element B is an hour. Right after the neutron irradiation the  emission is measured.
At this time 80 particles are measured in 2 seconds, and after an hour only 29 particles
are measured during 2 seconds. Determine the mass of the element A
(in mg) in the sample. Assume that spontaneous decay statistical law is obeyed by
nuclei of both the elements.
14. A spring is placed between the jaws of screw gauge such that the spring is not at all
compressed. The main scale reads 2 divisions and circular scale reads 28 divisions.
Now we turn the circular scale by 18 such that the spring is compressed. The circular
scale has 200 divisions and the least count of the main scale is 1 mm. What is the
force exerted (in mN) by the spring on the jaws if the spring constant is 100 N/m?

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Section 3 (Max Marks: 12)
 This Section contains two (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple-choice Questions
 Each List-Match set has two lists: List 1 and List 2
 List 1 has four entries (I), (II), (III), (IV) and List 2 has six entries (P), (Q), (R), (S), (T) and (U)
 Four options are given in each multiple choice question based on List 1 and List 2 and Only ONE of
these four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme
Full Marks: +3 (If only the option corresponding to the correct combination is chosen) )
Zero Marks: 0 (If none of the options is chosen (i.e. the question is unanswered)
Negative Marks: -1 (In all other cases)
Answer Q.15 and Q.16 by appropriately matching the list based on the
information given in the paragraph
A solid body of mass m and radius ‘R’ is placed on a rough horizontal surface. When
a horizontal force ‘F’ is applied to the body at a height ‘h’ above the centre level, the
body starts rolling without slipping on the horizontal surface as shown.
Sec: Sr.Super60 & All Space for rough work Page 10
Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P

List – I gives the four different shapes of the given solid body and corresponding
values of F and h while List – II gives the magnitude of some quantities.

List – I List – II
R
(I) For a ring, F  2 mg, h  (P) 1
2
3R 1
(II) For a disc, F  mg, h  (Q)
4 3
5 mg R 7
(III) For a hollow sphere, F  ,h (R)
8 3 9
mg 3R 8
(VI) For a solid sphere, F ,h (S)
2 5 21
1
(T)
4
1
(U)
7

15. If acceleration of the ring is 'a 0 ' then the acceleration of the different shapes of the
body in a 0 units will be correctly matched in
A) I  P, II  R, III  Q, IV  S B) I  Q, II  P, III  S, IV  U
C) I  P, II  T, III  R, IV  S D) I  T, II  Q, III  R, IV  U
16. If magnitude of frictional force acting on the ring is 'f0 ' then the magnitude of
frictional force acting on the different shapes of the body in 'f0 ' units will be
A) I  P, II  Q, III  R, IV  S B) I  Q, II  P, III  S, IV  U
C) I  P, II  Q, III  T, IV  U D) I  T, II  Q, III  R, IV  U

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
Answer Q.17 and Q.18 by appropriately matching the list based on the
information given in the paragraph

Two point sound sources of same frequency ‘f’ amplitude 2A and 4A are situated at
x = 0 and x = 20  respectively (  = wavelength of wave) on the x-axis. These
sources are vibrating in same phase. Four observers A, B, C and D are situated at
x A  4 , x B  8 , x C  12 and x D  16 respectively. The value of intensity observed by
another observer O situated exactly at midpoint of location of two sources is I0 .
Observers A, B, C and D are tabulated in first List and in second List some quantities
36A 2 k
are given. (Given I0  where k is a constant). List – I gives the above four
100
observers while List – II lists the magnitude of some quantity.

List – I List – II
9
(I) Observer A (P)
16
49
(II) Observer B (Q)
144
4
(III) Observer C (R)
9
5
(VI) Observer D (S)
16
81
(T)
64
10
(U)
36
17. List – I constains observers and List – II contains the values of intensity observed by
respective observers in unit kA 2 . Pick the correct option.
A) I  Q, II  R, III  S, IV  P B) I  P, II  Q, III  R, IV  T
C) I  P, II  Q, III  T, IV  S D) I  Q, II  P, III  R, IV  T
18. In separate experiment location of sources are interchanged. The values of intensity
observed by the observers now in units of kA 2 are given in List – II. Match respective
intensities observed by the observers.
A) I  T, II  R, III  S, IV  Q B) I  Q, II  S, III  R, IV  P
C) I  P, II  Q, III  T, IV  S D) I  T, II  R, III  Q, IV  P

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -1 in all wrong cases
Section 1 (Max Marks: 32)
 Section 1 contains eight questions.
 Each Question has Four Options and Only One of these four will be the correct answer.
 For each question, choose the option corresponding to the correct answer
 The Marking scheme to evaluate the Answer to each question:
Full Marks: +4 (If the answer is correct)
Partial Marks: +3 (If all the four options are correct but only 3 are chosen)
Partial Marks: +2 (If THREE or More options are correct but only 2 correct answers are chosen)
Partial Marks: +1 (If TWO or More options are correct but only 1 correct answer is chosen)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
19. The ground state energy of He ion is -54.4 eV. Consider an electronic state  of Li 2
whose energy, azimuthal quantum number and magnetic quantum number are -30.6
eV, 1 and 0, respectively. Which of the following statements is/are correct for the state
?
A) It is a 2p state
B) It has one angular node
C) It has zero radial node
D) The nuclear charge experience by the electron in this state is 3e, where e is the
magnitude of the electronic charge
20. In the decay sequence
238  x1 234  x2 234  x3 234 x4 230
92 U  90
Th  91
Pa  Z  90
Th
and x 4 are particles/ radiation emitted by the respective isotopes. The correct
x1 , x 2 , x 3
option(s) is(are)
A) x1 will deflect towards negatively charged plate
B) x 2 is 
C) x 3 is  -ray
D) Z is an isotope of uranium

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
21. The correct sequence of reagent for the following conversion
COOH
O is 
COOH
LiAlH 4
SOCl 2  i  KCN  2 Ca OH
A)    
 ii  H3O
 


LiAlH 4 HI Mg/ether Ca  OH  CaO/ 
B)        2
ii  H 3O 
  
LiAlH 4 PBr3  i  KCN CaO
C)     
 ii  H3O 
 


LiAlH 4 HCl Mg:excess  2 i CO BaO/ 
D)   
ZnCl2
 
ether
 
 ii  H3O
  
22. The compound(s), which give(s) benzoic acid on oxidation with KMnO4 , is(are)
CH3 CH3
CH3
CH3 CH3
A) B)
H3C

CH3
H3C CH3
C) D)
23. In the form of dichromate, Cr(VI) is a strong oxidizing agent in acidic medium but
Mo  VI  in MoO3 and W(VI) in WO3 are not because
A) Cr(VI) is more stable than Mo(VI) and W(VI)
B) Mo(VI) and W(VI) are more stable than Cr(VI)
C) Higher oxidation states of heavier members of group-6 of transition series are more
stable
D) Lower oxidation states of heavier members of group-6 of transition series are more
stable
24. Which of the following relationships are correct.
A) Ionization energy of neutral ceasium atom is greater than ionization energy of F 
anion
B) In the groups of p-block elements the decrease in 1st ionization energy is large
between 1st and 2nd elements but there after the decrease is minor
C) The second ionization energy of Lithium is more than the second ionization energy
of oxygen
D) In case of d-block elements, down the group, ionisation enthalpy decrease in all the
groups.
Sec: Sr.Super60 & All Space for rough work Page 14
Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
25. A diamagnetic complex, with molecular formula Ni  NO3 2  4Py  2H 2 O is formed by the
reaction of Ni  NO3 2  aq  with excess of pyridine. Select the incorrect statements about
the complex (Assume the given complex exists)
A) It exhibits geometrical isomerism
B) Ni 2 is sp3d 2 hybridized
C) The complex is square planar type
D) In aqueous solution, it produces three ions per formula unit of the complex
26. Identify how many “Ore names”, “Type of Anion”, “Metal(s) present in mineral” are
correctly related
A) Copper pyrite Sulphide Fe
B) Asbestos Silicate Al
C) Dolomite Carbonate Ca
D) Bauxite hydroxide Al

SECTION – II
(NUMERICAL VALUE TYPE)
This section contains 6 questions. Each question is numerical value type. For each question, enter the correct
numerical value (e.g. 003.2343, 6.250023, 7.000000, ‐0.33, ‐.30, 30.27000, ‐127.0030).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Section 2 (Max Marks: 18)
 Section two contains six (6) questions. The answer to each question is a NUMERICAL VALUE
 For each question enter the correct numerical value of the answer using the mouse and the on-screen
virtual numerical keypad in the place designated to enter the answer. If the numerical values has more
than two decimal places, truncate/round off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme
Full Marks: +3 (If only the correct numerical value is entered)
Zero Marks: 0 (In all other cases)
 xz 
27. Among the given carbonates/bicarbonates, find the value of  
 y 
KHCO3 , NaHCO3 , CaCO3 , Ca  HCO3 2 , K 2CO3 and Mg  HCO3 2
No. of compounds almost insoluble in water = x
No. of compound which liberate CO 2 on reaction with HCl =z
No. of compounds that undergo decomposition on heating to give respective
carbonate = y
28. How many of the following give precipitate with excess of aqueous ammonia
AlCl3 , FeCl3 , CuSO 4 , CdSO 4 , NiSO 4 , ZnSO 4 , AgNO 3 , HgCl 2

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
29. NH3 reacts with a gas fumes produced when methanol is passed through Cu tube at
573K. The compound obtained is polycyclic. No of rings it contain = [X]. i.e., if it is
monocyclic then X = 1, of bicyclic X = 2 or X cyclic. The number of Nitrogen atoms
it has = [Y]. Find values of X & Y & Report your answer as X
Y
30. A tetrapeptide has –COOH group on alanine. This produces glycine(Gly), valine
(Val), phenyl alanine (Phe) and alanine (Ala), on complete hydrolysis. For this
tetrapeptide, the number of possible sequences (primary structures) with  NH 2 group
attached to a chiral center is
31. On dissolving 0.5 g of a non-volatile and ionic electrolyte solute having vant’s hoff
factor (i = 2) to 39 g of benzene, its vapour pressure decreases from 650 mm of Hg to
640 mm Hg. The depression of freezing point to benzene (in K) upon addition of the
solute is _____________.
(Given data: Molar mass and the molal freezing point depression constant of benzene
are 78g/mol and 5.12 K kg/mol, respectively)
32. Consider a 70% efficient hydrogen – oxygen fuel cell working under standard
conditions at 1 bar and 298K. Its cell reaction is
1
 H 2O   
H 2  g   O 2  g  
2
The work derived from the cell on the consumption of 2.0  103 mol of H 2  g  is used to
compress 1.00 mol of a monoatomic ideal gas in a thermally insulated container. What
is the change in the temperature (in K) of the ideal gas?
The standard reduction potentials for the two half – cells are given below
 2H 2O    ,
O 2  g   4H   aq   4e  E  1.23V .
2H   aq   2e  
 H2  g  , E  0.00V
Use F  96500 C mol 1 , R  8.314 J mol1 K 1

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Section 3 (Max Marks: 12)
 This Section contains two (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple-choice Questions

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
 Each List-Match set has two lists: List 1 and List 2
 List 1 has four entries (I), (II), (III), (IV) and List 2 has six entries (P), (Q), (R), (S), (T) and (U)
 Four options are given in each multiple choice question based on List 1 and List 2 and Only ONE of
these four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme
Full Marks: +3 (If only the option corresponding to the correct combination is chosen) )
Zero Marks: 0 (If none of the options is chosen (i.e. the question is unanswered)
Negative Marks: -1 (In all other cases)
Answer Q.33 and Q.34 by appropriately matching the list based on the
information given in the paragraph
List – I includes starting materials and products of selected chemical reactions. List-II
gives reagent that may be used to carry out reactions of List –I.
List – I List – II
O

O
(I) (P) NaOH  Br2 / 

CH3
H3C H3C CH3
O H3C
CH3

(II) CH2
H3C (Q) conc H 2SO 4 / 
H3C
CH3
O
O H3C
Me CH3

O
(III) OH (R) NaIO 4
O
H3C CH3
O

NH2
(IV) (S) dil.cold KMnO 4
N

O
(T) NaOH / 
(U) Heat
33. Which of the following options has correct combination of Reagents required in
correct sequence to carry out List I reactions?
A) I- RTQ B) III- T S U C) II-USRT D)IV- TRU
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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
34. Which of the following options has correct combination of Reagents required in
correct sequence to carry out List I reactions?
A) III-QSU B) I-SRTQ C) IV-PS D) II-QTU

Answer Q.35 and Q.36 by appropriately matching the list based on the
information given in the paragraph

List-I (Components) List – II(Nature)


(P) Ethanol  cyclohexane (1) Negative deviation
(Q) Water  HNO 3 (2) Ideal solution
(R) Ethyl bromide  ethyl iodide (3) Henry’s Law
(S) N 2  g   H 2O    (4) Positive deviation

35. Which of the following matching is correct:

A) P-2 B) Q-4 C) R-1 D) S-3

36. Which of the following is incorrectly matched:

A) P-4 B) Q-4 C) R-2 D) S-3

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
MATHEMATICS Max Marks: 62
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -1 in all wrong cases
Section 1 (Max Marks: 32)
 Section 1 contains eight questions.
 Each Question has Four Options and Only One of these four will be the correct answer.
 For each question, choose the option corresponding to the correct answer
 The Marking scheme to evaluate the Answer to each question:
Full Marks: +4 (If the answer is correct)
Partial Marks: +3 (If all the four options are correct but only 3 are chosen)
Partial Marks: +2 (If THREE or More options are correct but only 2 correct answers are chosen)
Partial Marks: +1 (If TWO or More options are correct but only 1 correct answer is chosen)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
37. If the function f : R  R is defined by f  x   x   x   sin x  , [.] is greatest integer
function then which of the following statements is/are true?
A) f is one – one
B) f is onto
C) f is not one-one
D) f is neither one-one nor onto
38. At a point P on the parabola y2  4ax  a  0  tangent and normal are drawn. Tangent
intersects the x-axis at Q and normal intersects the parabola at R such that chord PR
subtends 90 at its vertex. Then which of the following is/are TRUE?
A) PQ  2a 6
B) P R  6a 3
C) Area of PQR  18 2 a 2
D) PQ  3a 2
 1 1
g ' n   g ' 
2 2
39. Let g  x   ef  x  and f  x  1  x  f  x   x  R . If n  N , then     is
 1 1
gn   g 
 2 2
always equal to
 1 1 1  1 1 1 
A) 2  1    ...   B) 2 1    ...  
 2 3 n  3 5 2n  1 
C) n D) 1
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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
40. 5 boys & 5 girls sit in a row at random, then
56
A) Probability that 5 girls sit together =
10
55
B) Probability that boys & girls sit alternately =
10
C) Probability that all boys are together & all girls are together given that all girls are
1
together =
3
9
D) A particular boy & girl sit together given that boys & girls sit alternately =
25
41. Let f : R  R , be a continuous function satisfying f  2x   f  x   x  R & f  2   1 ,
then
A) f  3  1 B) y  f  x  is many one and into
2
C) y  f  x  is one-one and into D)  f  f  x   dx  4
2
42. Let P1 : 2x  y  z  3 and P2 : x  2y  z  2 be two planes. Then, which of the
following statement(s) is(are) TRUE ?
A) The line of intersection of P1 and P2 has direction ratios 1, 2, -1
3x  4 1  3y z
B) The line   is perpendicular to the line of intersection of P1 and P2
9 9 3
C) The acute angle between P1 and P2 is 60
D) If P3 is the plane passing through the point (4, 2, -2) and perpendicular to the line of
intersection of P1 and P2 , then the distance of the point  2,1,1 from the plane P3 is
2
3
43.  
Let y(x) be a solution of the differential equation 1  e x y ' ye x  1 . If y  0   2 , then
which of the following statements is(are) true?
A) y  4   0
B) y  2   0
C) y  x  has a critical point in the interval  1,0 
D) y  x  has no critical point in the interval  1,0 
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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
44. For 3  3 matrices M and N, which of the following statement(s) is (are) correct ?
A) N T MN is symmetric or skew symmetric, according as M is symmetric or skew
symmetric respectively.
B) MN – NM is skew symmetric for all symmetric matrices M and N
C) There exist infinite number of matrices M, N such that MN-NM is a unit Matrix
D) (adj M)(adj N) = adj(MN) for all invertible matrices M and N

SECTION – II
(NUMERICAL VALUE TYPE)
This section contains 6 questions. Each question is numerical value type. For each question, enter the correct
numerical value (e.g. 003.2343, 6.250023, 7.000000, ‐0.33, ‐.30, 30.27000, ‐127.0030).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Section 2 (Max Marks: 18)
 Section two contains six (6) questions. The answer to each question is a NUMERICAL VALUE
 For each question enter the correct numerical value of the answer using the mouse and the on-screen
virtual numerical keypad in the place designated to enter the answer. If the numerical values has more
than two decimal places, truncate/round off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme
Full Marks: +3 (If only the correct numerical value is entered)
Zero Marks: 0 (In all other cases)

45. If a a a  b and a, b > 1 are integers Minimum value of a + b is ____


46. The coordinates of a ship are x = 2, y = 0. The shoreline is given by the curve of
equation y  2x  1 . At what angle(in degrees) should the ship deviate from the
direction due north in order to reach the closest point of the shore in a straight line ?
(Assume that the +ve x – axis points towards the east.) Answer should be in degrees
47. Let f be real function defined on R (the set of real numbers) such that
2 3 100
f '  x   100  x  1 x  2   x  3  ......  x  100  , for all x  R . If g is a function
x x
f  t
defined on R such that  e dt   g  x  t  dt  2x  3 , If sum of all the values of x for
a 0


which g(x) has a local extremum be  then find
5

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P
48. Let A={ n  N : n is a 3- digit number}
B = { 9k  2;k  N }
and C = { 9k   : k  N } for some   0    9 

If the sum of all the elements of the set A   B  C  is 274  400 , then l is equal to

2 7 4 1 x7  x 4 
49. I   x  2  x  dx; J   13
dx If I  J ;   R , is equal to_______
0 0
1  x  8

2  10 
50.  
Let f  x   x 3  5x 2  6x   a i x i  ; a i  R . Let f ' , f '' , f ''' denotes first, second, third
 i 0 
order derivatives respectively. Let r1 , r2 , r3 denotes minimum number of distinct real
roots of f ',f '',f ''' respectively. Then value of r1  r2  r3 is _____

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Section 3 (Max Marks: 12)
 This Section contains two (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple-choice Questions
 Each List-Match set has two lists: List 1 and List 2
 List 1 has four entries (I), (II), (III), (IV) and List 2 has six entries (P), (Q), (R), (S), (T) and (U)
 Four options are given in each multiple choice question based on List 1 and List 2 and Only ONE of
these four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme
Full Marks: +3 (If only the option corresponding to the correct combination is chosen) )
Zero Marks: 0 (If none of the options is chosen (i.e. the question is unanswered)
Negative Marks: -1 (In all other cases)
Answer Q.51 and Q.52 by appropriately matching the list based on the
information given in the paragraph

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P

Column I Column II
In a triangle ABC, let
A B C
sin A  sin B  sin C  12cos cos cos , then the value of
(I) 2 2 2 (P) 3
2 2 2
 sin A sin B sin C 
 2  2
 2  , is
 sin B sin C sin A 
If inside a bigger circle S of radius 3, n  n  3  smaller circles
S1 ,S2 ,S3 ,.....,Sn , each of unit radius are placed in such a way that
each smaller circle touches the bigger circle and also tangent to both
(II) its adjacent smaller circles as shown in figure, then value of n (Q) 4

Let
A   log 2 cos 24    log 2 cos 48    log 2 cos96    log 2 cos192 
(III) (R) 5
log 41 23.log 21 56.log 23 91.log 56 41
and B  . The value of (AB), is
log11 91.log 21 11
1
Let L denotes the value of cos2      , if sin 2  sin 2  and
2
3
(IV) cos 2  cos 2  . If M denotes the value of expression (S) 6
2
1 1 1
 
log xy xyz log yz xyz log zx xyz

, then the value of 16L2  M 2 , is 
(T) 1
(U) 2

51. Which of the following is the only CORRECT combination?


A) (II),(S) B) (I)(U) C) (II) , (T) D) (I), (R)
52. Which of the following is the only CORRECT combination?
A) (IV),(P) B) (III), (Q) C) (IV),(Q) D) (III),(R),(U)

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Sri Chaitanya IIT Academy 04-04-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-04(Paper-2)_Q’P

Answer Q.53 and Q.54 by appropriately matching the list based on the
information given in the paragraph

3
The equation of the ellipse with area passing through the point of intersection of
2
x 2  4y 2  4 and x  1  0 , having x –axis as its major axis and eccentricity equal to
3
, is ax 2  2hxy  by 2  2gx  2fy  2  0 . There are some expressions given in the
2
list – 1 whose values are given in list – II below

Column I Column II
(I) a (P) 0
(II) b (Q) 1
(III) 2h + f (R) - 1
(IV) g (S) 4
(T) 6
(U) 6

53. Which of the following is the only correct combination?


A) II – P B) II – S C) I – T D) I – R
54. Which of the following is the only incorrect combination?
A) IV – U B) III – P C) II – S D) I – Q

Sec: Sr.Super60 & All Space for rough work Page 24

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