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UV Photoreactor
UV Photoreactor
UV Photoreactor
( )
bottom of the reactor, a quartz sleeve was attached to hold
n m
∫ ∑∫
a large UV lamp (low pressure, 200 W, arc length 1.07 m,
∏T
4π 1
G) n
I0(Ω) exp[- ki(s, Ω) ds] i dΩ with more than 90% of its emission at 255 ( 5 nm, from
0 overLi
( ∑
i)1
Li)2
i)1 i)1
Emperor Aquatics). A hole at the end of the sleeve with air
suction at the other end, with flow rate of 0.0013 ( 0.003
(4) m3/s and inlet/outlet temperatures of 22 ( 1/25 ( 1 °C,
maintained an ambient skin temperature on the surface
where Li, I0, ki, and Ti are the path length of a ray through of the sleeve and maintained isothermal conditions. Figure
the ith medium, intensity at source, absorption coefficient S1 (of the Supporting Information) shows the dimensions
of medium i, and fraction of the ray transmitted from one and configuration of the pilot-scale reactor.
medium to another, respectively. The fluence rate is the key 3.2. Material. A fluorescent chemical, Rhodamine WT,
parameter in the photoreaction rate correlation. abbreviated as RhWT, was selected as the chemical candidate
concentration of RhWT to determine a linear correlation for the inlet average Reynolds number. As a result, in case A, the
that pixel. This resulted in a two-dimensional (2D) calibration flow regime is laminar throughout the entire reactor length;
map. in case B, however, the area close to the bottom of the reactor
A stock solution of hydrogen peroxide (10.30 ( 0.05 ppm) (near the sleeve) is in the transition regime, whereas the area
and RhWT (126 ( 1 ppb) at 21.4 ( 0.3 °C was fed into the far from the sleeve is laminar. The aforementioned observa-
reactor while the UV lamp was stabilized. Two different flow tions were modeled using different viscous models (laminar,
rates of 0.006 ( 0.002 and 0.015 ( 0.002 kg/s were tested. For transitional,andturbulent)withdifferentnumericalapproaches.
each operating condition, the inlet, middle, and outlet of the The CFD results from laminar and standard k-ω tran-
reactor were studied, and 400 images were captured for each sitional flow simulations using the first-order discretization
section. The average of the normalized images, after sub- method yielded the best fit of the PIV data for cases A and
tracting the glowing background image, was used to calculate B, respectively (Figure 2). Overall, the flow patterns were
the RhWT concentration profiles inside the flow-through UV well-predicted by the model.
photoreactor. This procedure was applied for three zones In order to show the deviation of the simulation results
through the entire length of the reactor. from the experimental measurements (PIV), the velocity
vectors of the simulation results were subtracted from the
4. CFD Model Setup PIV measurement for each corresponding point for the two
The details of the CFD model set up are provided in the different cases (see Figure S6 of the Supporting Information).
Supporting Information. Considering the scale of the images, the error corresponding
to the PIV measurements, and the instrumental errors, there
5. Results and Discussion is a good correspondence for both cases, although with better
5.1. Evaluation of the Hydrodynamic Model. 5.1.1. Velocity agreement for case B. In the inlet zone, none of the models
Field Measurement (PIV). The results of the PIV measurement could predict the high circulation flow accurately. In addition,
for the two flow rates for the entrance region of the reactor there is a narrow band below the contour of the turning
are shown in Figure 1. For each image, the length of the points for which both models predicted a smaller velocity
arrows is proportional to the velocity magnitude. The value field than was found experimentally. The overall degree of
of R2 (the square of the correlation coefficient between two agreement can be evaluated using the coefficient of deter-
observed data values) for the average of 400 and 350 images mination (R2) between the PIV velocity vectors and those of
for each of the two flow rates was close to 1, suggesting that simulation, which is expressed as
400 images were statistically sufficient for averaging.
The flow pattern within the UV reactor begins at the inlet
R2 ) 1 -
∑ (Vx - Vx PIV SIM)
2
+ (VyPIV - VySIM)2
jet and passes over the hemisphere of the sleeve in the inlet
section where it diverts to the main section of the reactor. ∑ (Vx - Vx
PIV PIV,Ave)
2
+ (VyPIV - VyPIV,Ave)2
Due to the high gradient of momentum in different directions (6)
of the jet stream, a back-circulation of the fluid at the inlet
zone is produced causing recycle of fluid near the top of the where Vx and Vy are the x and y components of the velocity
reactor. Higher inlet velocities (with higher gradients) result vector, respectively, and indices PIV, SIM, and Ave represent
in greater vorticity and flow rate of the recycled flow and, the PIV measurements, simulation results, and the average
consequently, reduce the path height of the main fluid at the of the measured values (PIV) throughout the entire domain,
bottom of the reactor (close to sleeve)(see Figure S5 of the respectively. The R2 for cases A and B are 0.86 and 0.92,
Supporting Information). respectively (a perfect match would result in R2 ) 1.0). Better
5.1.2. Simulation of Hydrodynamics. The average Rey- statistical agreement was found between the simulation
nolds numbers corresponding to the flow rates over the entire results and experimental values for case B. It is expected that
cross-section at the round inlet of the photoreactor (Figure the simulation and experimental concentration profiles,
S1 of the Supporting Information) are 530 ( 230 and 1480 which are highly affected by the velocity field, will show better
( 280 for cases A and B, respectively. Due to variations in agreement in case B, as well.
the velocity at each cross-section, the local Reynolds number 5.2. Evaluation of the Radiation Model. Considering the
differs on any vertical line (from top to bottom) within the UV lamp as a line or volume source (I0 modeling in eq 4),
reactor, but the maximum Reynolds number cannot exceed the UV radiant emission from the source can be modeled
FIGURE 3. Irradiance rate at different distances indicated by ], 0, ×, ∆, and * for distances 1, 10, 20, 30, and 50 mm from the
surface of the lamp, respectively. Experimental values for the radiation power (symbols) vs the 1D model-predicted values
(continuous lines) and the 3D model, cylindrical emitter with 7 mm diameter, values (dashed lines).
using measured boundary conditions. It is important to note the presence of UV is the summation of the three primary
that the UV lamp does not behave as a uniform emission rates of direct oxidation, direct photolysis, and reaction with
source because the moving air (used in this experiment as hydroxyl radicals (generated from UV photo oxidation of
a coolant in the gap of the sleeve and lamp to maintain hydrogen peroxide). The rate of direct oxidation and direct
ambient temperature on the outer sleeve surface) changes photolysis were found to be insignificant. The total photo-
the temperature gradient along the side of the lamp plasma initiated oxidation rate of RhWT and hydrogen peroxide after
dramatically. This causes a nonuniform emission that is lower receiving H J/m2 UV fluence was measured to be (21)
closer to the lamp tip, where air enters the gap. As a result,
radiant power should be measured close to the surface of
the lamp/sleeve to calculate the intensity of the UV lamp at
the source (boundary conditions). In addition, for a more
ln ( CRhWT
130 )) (-4.757 ( 0.092) × 10-3H (7)
FIGURE 5. Concentration profile of rhodamine WT in the UV photoreactor calculated by the integrated model for two different mass
flow rates: 0.006 (A) and 0.015 (B) kg/s. Concentrations less than 80 ppb are shown as white.
5.4. Evaluation of the Integrated Model. The concen- of RhWT was very low. In other words, higher concentrations
tration profile of RhWT is the result of the interaction of of RhWT are expected in this zone, in contrast to what was
hydrodynamics, fluence rate, and reaction rate. Therefore, observed experimentally (Figure 4). This can be explained
measuring the concentration profile throughout the entire by considering the flow pattern in the reactor (Figure 1),
reactor is the best indicator for the evaluation of the which plays a major role in controlling the concentration.
photoreactor model performance. As far as the authors are Low velocity (flow) of fluid at the reactor inlet zone increases
aware, no experimental measurement of the concentration the residence time of chemicals and consequently enhances
profile in a photoreactor has been reported in the open the conversion consequently. In addition, the recycled flow
literature. Figure 4 shows the measured concentration of the of low concentration fluid from downstream to upstream
RhWT profile through the midcross-section of the photo- dilutes the concentration of the inlet stream. As a result,
reactor. The concentration profile through the entire length lower concentrations levels of RhWT are expected at the inlet
of the reactor was studied by investigating three sections of zone. In the area closer to the lamp (sleeve) where the fluence
the reactor from inlet to outlet separately. The three images rate is at its maximum level, a minimum concentration of
(averaged from 400 images for each zone) were combined RhWT should be observed. These features are clearly
and stitched together. Due to the technical limitations in demonstrated in Figure 4. Error in concentration can occur
keeping the setup perfectly consistent while studying different where the concentration gradient is high, with higher
zones, it was not possible to obtain a perfect match in the concentration at top is higher (due to a high absorption of
areas where two adjacent images overlapped. The values laser light at the reactor exit) than at the bottom. Therefore,
close to the boundaries of the reactor walls were masked the measurements in the outlet sections are expected to have
because they did not represent the true concentrations (as a relatively high degree of uncertainty for all cases and this
a consequence of reflections from the white glue joints in explains the similar concentration profiles found for both
these regions of the reactor). For all images, a horizontal cases in Figure 4, at the end of the reactor.
median filter of rank 40 was applied to remove the shadowing The integrated model of reactor performance simulated
effects of the laser sheet in the images. the concentration profile in the UV reactor by solving the
Radiation measurement in the inlet zone (-5 to 1 cm governing equations of mass, momentum, radiant energy,
from the tip of the lamp) showed a very low level of radiant and species conservation. The results are shown in Figure
energy (almost zero). This implies that the rate of conversion 5. The main features of the concentration profile through
FIGURE 6. Concentration difference (CPLIF - CSimulation) in parts per billion for two different mass flow rates: 0.006 (A) and 0.015 (B) kg/
s. Concentration differences higher than 30 ppb are shown as white.