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Non Asbistos Organic Composits On Friction Material For Friction Material
Non Asbistos Organic Composits On Friction Material For Friction Material
Non Asbistos Organic Composits On Friction Material For Friction Material
A PROJECT REPORT
Submitted by
ARCHIT GOYAL 1404061007
AMIT BHANDARI 1404061008
SAGAR NEGI 1404061015
HAIDER HASAN 1404061051
PRADYUMN DHAMI 1404061045
BTECH
IN
MECHANICAL ENGINEERING
BONAFIDE CERTIFICATE
SIGNATURE SIGNATURE
form of sheer endurance and continual efforts of inspiring excellence from various
coordinating factor of cooperation and sincere efforts drawn from all sources of knowledge. I
providing all the facilities, which would have made it possible for me to complete the
I extend my thanks to all classmates who have given their full cooperation and
quality than its constituents. Composite materials can be used not only for structural
applications, but also in various other applications such as automobiles, aerospace, marine,
etc. Fibre reinforced plastic materials are widely used in various engineering industries
because of their superior performance and tailor made properties. Though FRPs are widely
used in various fields, they are flammable. This research work is sponsored by Naval
Research Board (NRB) to develop flame retardant fibre reinforced polyester composite with
nil or reduced smoke generation on ignition for roofing application. To meet the requirement
of NRB, the Phase I work is aimed to develop FRP composite using the general purpose
polyester resin and chopped glass fibre mat with different FRs to optimize the compositions
by studying their curing, mechanical and flammability properties. With this optimized
composition, the Phase II work is aimed at utilizing marine grade polyester resin and E- glass
fiber mat with suitable FR additive combination + halogenated and non halogenated FRs like
Melamine Cyanurate (MC) and their combinations for naval application in such a way to get
flame retardant FRP with V0 rating that will generate non toxic vapours. And also it is aimed
to achieve better curing, thermal and flammability properties compared to the current grade
1.1 INTRODUCTION....................................................................................7
1.1.1 NATURE AND MAN MADE COMPOSTS...............................................7
CHAPTER 2 APPLICATIONS............................................................................................14.
METHODOLOGY 23
GANTT CHART
25
REFERENCES 26
LIST OF TABLES
1.1 INTRODUCTION
A composite is a material that is formed by combining two or more materials to
achieve some superior properties. Almost all the materials which we see around us are
composites. Some of them like woods, bones, stones, etc. are natural composites, as they are
consisting of thread-like hollow elongated organic cellulose that normally constitutes about
60-70% of wood of which approximately 30-40% is crystalline, insoluble in water, and the
rest is amorphous and soluble in water. Cellulose fibres are flexible but possess high strength.
The more closely packed cellulose provides higher density and higher strength. The walls of
these hollow elongated cells are the primary load-bearing components of trees and plants.
When the trees and plants are live, the load acting on a particular portion (e.g., a branch)
directly influences the growth of cellulose in the cell walls located there and thereby
reinforces that part of the branch, which experiences more forces. This self-strengthening
mechanism is something unique that can also be observed in the case of live bones. Bones
contain short and soft collagen fibres i.e., inorganic calcium carbonate fibres dispersed in a
mineral matrix called apatite. The fibres usually grow and get oriented in the direction of
load. Human and animal skeletons are the basic structural frameworks that support various
types of static and dynamic loads. Tooth is a special type of bone consisting of a flexible core
and the hard enamel surface. The compressive strength of tooth varies through the thickness.
The outer enamel is the strongest with ultimate compressive strength as high as 700MPa.
Tooth seems to have piezoelectric properties i.e., reinforcing cells are formed with the
application of pressure. The most remarkable features of woods and bones are that the low
density, strong and stiff fibres are embedded in a low density matrix resulting in a strong, stiff
and lightweight composite (Table 1.1). It is therefore no wonder that early development of
aero-planes should make use of woods as one of the primary structural materials, and about
two hundred million years ago, huge flying amphibians, pterendons and pterosaurs, with
wing spans of 8-15 m , could soar from the mountains like the present�day hang-gliders.
Woods and bones in many respect, may be considered to be predecessors to modern man-
made composites.
Early men used rocks, woods and bones effectively in their struggle for existence
against natural and various kinds of other forces. The primitive people utilized these materials
to make weapons, tools and many utility-articles and also to build shelters. In the early stages
they mainly utilized these materials in their original form. They gradually learnt to use them
in a more efficient way by cutting and shaping them to more useful forms. Later on they
utilized several other materials such as vegetable fibres, shells, clays as well as horns, teeth,
Fibres
Composites
Woods, stones and clays formed the primary structural materials for building shelters.
Natural fibres like straws from grass plants and fibrous leaves were used as roofing materials.
Stone axes, daggers, spears with wooden handles, wooden bows, fishing nets woven with
vegetable fibers, jewelleries and decorative articles made out of horns, bones, teeth,
semiprecious stones, minerals, etc. were but a few examples that illustrate how mankind, in
early days, made use of those materials. The limitations experienced in using these materials
led to search for better materials to obtain a more efficient material with better properties.
This, in turn, laid the foundation for development of man-made composite materials.
The most striking example of an early man-made composite is the straw-reinforced
clay which molded the civilization since prehistoric times. Egyptians, several hundred years
B.C., were known to reinforce the clay like deposits of the Nile Valley with grass plant fibres
to make sun baked mud bricks that were used in making temple walls, tombs and houses. The
watchtowers of the far western Great Wall of China were supposed to have been built with
straw-reinforced bricks during the Han Dynasty (about 200 years B.C.). The natural fibre
reinforced clay, even to-day continues to be one of the primary housing materials in the rural
The other classic examples are the laminated wood furniture used by early Egyptians
(1500 B.C.), in which high quality wood veneers are bonded to the surfaces of cheaper
woods. The origin of paper which made use of plant fibres can be traced back to China (108
A.D.). The bows used by the warriors under the Mongolian Chief Djingiz Chan (1200 A.D.)
were believed to be made with the adhesive bonded laminated composite consisting of
buffalo or anti-lope horns, wood, silk and ox-neck tendons. These laminated composite bows
Potteries and hydraulic cement mortars are some of the earliest examples of ceramic
composites. The cloissone ware of ancient China is also a striking example of wire reinforced
ceramics. Fine metallic wires were first shaped into attractive designs which were then
covered with colored clays and baked. In subsequent years, fine metallic wires of various
types were cast with different metal and ceramic matrices and were utilized in diverse
applications. Several other matrix materials such as natural gums and resins, rubbers,
bitumen, shellac, etc. were also popular. Naturally occurring fibres such as those from plants
(cotton, flux, hemp, etc.), animals (wool, fur and silk) and minerals (asbestos) were in much
demand. The high value textiles woven with fine gold and silver threads received the
patronage from the royalty and the rich all over the world. The intricate, artful gold thread
embroidery reached its zenith during the Mughal period in the Indian subcontinent. The glass
fibres were manufactured more than 2000 years ago in Rome and Mesopotamia and were
abundantly used in decoration of flower vases and glass wares in those days.
The twentieth century has noticed the birth and proliferation of a whole gamut of new
materials that have further consolidated the foundation of modern composites. Numerous
synthetic resins, metallic alloys and ceramic matrices with superior physical, thermal and
mechanical properties have been developed. Fibres of very small diameter (<10�m) have
been drawn from almost all materials. They are much stronger and stiffer than the same
material in bulk form. The strength and stiffness properties have been found to increase
dramatically, when whiskers (i.e., single crystal fibers) are grown from some of these
materials. Figure1.1 illustrates the specific tensile strength and the specific tensile modulus
properties are obtained by dividing the strength (M Pa) and modulus (G Pa) by either the
density (kg m-3) or the specific gravity of the material. Because of the
superior mechanical properties of fibers, the use of fibers as reinforcements started gaining
momentum during the twentieth century. The aerospace industries took the lead in using fiber
reinforced laminated plastics to replace several metallic parts. The fibres like glass, carbon,
boron and Kevlar, and plastics such as phenolics, epoxies and polyesters caught the
imagination of composite designers. One major advantage of using fibre reinforced plastics
(FRP) instead of metals is that they invariably lead to a weight efficient design in view of
of deriving any characteristic material behavior. This unique flexibility in design tailoring
plus other attributes like ease of manufacturing, especially molding to any shape with
effectiveness, etc. have attracted the attention of many users in several engineering and other
disciplines. Every industry is now vying with each other to make the best use of composites.
One can now notice the application of composites in many disciplines starting from sports
goods to space vehicles. This worldwide interest during the last four decades has led to the
prolific advancement in the field of composite materials and structures. Several high
performance polymers have now been developed. Substantial progress has been made in the
development of stronger and stiffer fibres, metal and ceramic matrix composites,
techniques, test methods as well as design and analysis methodology. The modern man-made
composites have now firmly established as the future material and are destined to dominate
Table 1.2 Comparative mechanical properties of some man-made structural
composites and metallic alloys
Materials Specific Tensile Tensile Compressive Specific Specific
Specific
gravity modulus strength strength tensile tensile
compressive
modulus strength
strength
S E Xt Xc E/S Xt/S Xc/S
G Pa M Pa M Pa G Pa M Pa M Pa
Unidirectional Fibre Reinforced Plastics
GFRP 2.0 40 1650 1400 20.00 825.0 700.0
CFRP 1.6 140 1450 1050 87.50 906.3 656.3
KFRP 1.5 90 1650 300 60.00 1100.0 200.0
Metals
Steel 7.8 206 400-2500 400-2500 26.40 50-320 50-320
Ti alloy 4.5 103 360-1400 360-1400 22.90 80-310 80-310
Al alloy 2.8 69 55-700 55-700 24.60 20-250 20-250
Mg alloy 1.8 47 150-300 150-300 25.00 83-166 83-166
Beryllium 1.8 303 400 400 168-33 222 222
CHAPTER-2
APPLICATION
of using composites in the exterior body panels, frameworks/chassis, bumpers, drive shafts,
suspension systems, wheels, steering wheel columns and instrument panels of automotive
vehicles. Ford Motor Co. experimented with the design and development of a composite rear
floor pan for an Escort model using three different composites: a vinyl-ester-based SMC and
XMC and a glass fibre reinforced prolypropylene sheet material. Analytical studies, static and
dynamic tests, durability tests and noise tests demonstrated the feasibility of design and
frame, developed by the Convair Division of General Dynamics in 1979, using graphite and
Kevlar fibres (2:1 by parts) and epoxy resin (32% by wt) not only performed satisfactorily
but reduce the weight by 62% in comparison to steel for the same strength and stiffness. The
hybrid glass/carbon fibre composite drive shafts, introduced around 1982 in Mazdas,
provided more weight savings, lower maintenance cost, reduced level of noise and vibration
and higher efficiency compared to their metal counterparts. The more recent pickup truck
GMT-400 (1988 model) carries a composite driveshaft that is pultruded around a 0.2cm thick
and 10cm diameter aluminium tube. The composite driver shaft is 60% lighter than the
original steel shaft and possesses superior dampening and torsional properties. Chevrolet
Corvette models carry filament wound composite leaf springs (monoleaf) in both rear
suspension (1081) and front suspension (1984). These springs were later introduced during
1985 on the GM Chevrolet Astro van and Safari van. Fibre glass reinforced polypropylene
bumper beams were introduced on Chevrolet Corvette Ford and GM passenger cars (1987
models). Other important applications of composites were the rear axle for Volkswagen
Auto-2000, Filament wound steering wheels for Audi models and composite wheels of
Pontiac sports cars. Composites are recognized as the most appropriate materials for the
corrosion resistant, lightweight, fast and fuel efficient modern automobiles, for which
components like space frames, exterior and interior body panels, instrument panel assemblies,
power plants, power trains, drive trains, brake and steering systems, etc. are now being
fabricated with a wide variety of composites that include polymer, metal and ceramic matrix
composites. The latter two composites will be of significance in heated engine components
and brake pads. The pistons and connecting rods of modern diesel and IC engines are
invariably made of composites with alumina fibres and aluminium or magnesium alloy
matrices. The Ford`s probe V concept car is a classical example of multiple applications of
composites in an automobile car. The present trend is to use composites even in the design of
The interest in the use of glass fibre reinforced polyesters in building structures started
as early as sixties. The beautiful GFRP dome structure in Benghajj was constructed in 1968.
The other inspiring example is the GFRP roof structure of Dubai Airport. This was built in
1972 and is comprised of clustered umbrella like hyperbolic paraboloids. Several GFRP shell
structures were erected during seventies. Another striking example is the dome complex at
Sharajah International Airport, which was constructed during early eighties. The primary
advantage of using composites in shell structure is that any complex shell shape, either
aesthetic value, can be easily fabricated. The composite folded plate system and skeletal
structures also became popular. The roof of Covent Garden Flower Market at Nine Elms,
London covering an area of 1ha is an interesting example which was based on a modular
construction. In this, pyramidal square modules were connected at their apices and bases to
two-way skeletal grids. The modular construction technique helps to build a large roof
structure which is normally encountered in the design of community halls, sports complexes,
marketing centres, swimming pools, factory sheds, etc. Several other applications, where
GFRP has been successfully used, include movable prefabricated houses, exterior wall
panels, partition walls, canopies, stair cases and ladders, water tanks, pipes and drainages and
led to its wide use in radomes and antenna towers. In one particular construction, the top 100
ft of a radar microwave link tower was built with GFRP and the guys were Kevlar fibres (also
radio transparent) to reduce unwanted disturbances in air traffic control radar signals.
methods for structural plastics, both reinforced and unreinforced. However, the major
deterrent for the popularity of composites in civil engineering structures is the material cost.
But, in many applications, GFRP and KFRP may be cheaper considering the cumulative cost.
The low structural weight will have direct bearing in lowering the cost of supporting skeletal
structures and foundation. Moreover, ease of fabrication and erection, low handling and
transportation cost, less wear and corrosion, simpler maintenance and repairing procedures,
cumulatively reduce the cost in the long run. The Living Environment house, developed by
building.
applications. GFRPs are being used for the last 3-4 decades to build canoes, yatchs, speed
boats and other workboats. The hull of a modern racing yatch, New Zealand, is of sandwich
construction with CFRP faces. There is currently a growing interest to use composites, in a
much larger scale, in ship industries. A new cabin construction material that is being tried in
facing, that may lead to substantial weight saving. The Ulstein water jet has a long moulded
inlet tract for better control of dimensional accuracy. The carbon/aluminium composite has
been used for struts and foils of hydrofoils, and the silicon carbide/aluminium composite has
been employed in pressure hulls and torpedo structures. The composites are also being
increasingly used in the railway transportation systems to build lighter bogeys and
fabrication of energy related devices such as wind-mill rotor blades and flywheels.
The light artificial limbs and external bracing systems made of CFRP provide the
required strength, stiffness and stability in addition to lightness. Carbon fibres are medically
biocompatible. Composites made with carbon fibres and biocompatible metals and polymers
carbon�carbon composite hip joint with an aluminium oxide head has performed
with carbon fibres are also being used to produce orthopaedic implants.
Composites also have extensive uses in electrical and electronic systems. The
performance characteristics of CFRP antennas are excellent due to very low surface
distortion. Composite antenna dishes are much lighter compared to metallic dishes. Leadless
ceramic chip carriers are reinforced with Kevlar or Kevlar-glass coweave polyimides to
reduce the incidence of solder joint microcracking due to stresses induced by thermal
cycling. The stress level is reduced by matching the low coefficient of thermal expansion of
important sports accessories. A light CFRP golf shaft gives the optimum flexural and
torsional strength and stiffness properties in terms of accuracy and the distance travelled by
the ball. All graphite and graphite hybrid composite archery bows and arrows enhance arrow
speed with a flattened trajectory and increased efficiency. The reduction in weight of a CFRP
bobsleigh permits ballast to be added in the nose of the sleigh and thereby improves the
aerodynamic characteristics due to the change in the position of the centre of gravity with
respect to the centre of aerodynamic pressure. There are several other interesting composite
leisure time items such as skis, tennis and badminton rackets, fishing rods, vaulting poles,
hockey sticks, surf boards, and the list is likely to be endless in the twenty-first century. The
day is not far when common utility goods will be made with composites
CHAPTER-3
Failure in composites
Failure theory is the science of predicting the conditions under which solid
materials fail under the action of external loads. The failure of a material is usually classified
into brittle failure (fracture) or ductile failure (yield). Depending on the conditions (such as
temperature, state of stress, loading rate) most materials can fail in a brittle or ductile manner
or both. However, for most practical situations, a material may be classified as either brittle
or ductile. Though failure theory has been in development for over 200 years, its level of
In mathematical terms, failure theory is expressed in the form of various failure criteria which
are valid for specific materials. Failure criteria are functions in stress or strain space which
separate "failed" states from "unfiled" states. A precise physical definition of a "failed" state
is not easily quantified and several working definitions are in use in the engineering
community. Quite often, phenomenological failure criteria of the same form are used to
Material failure
In materials science, material failure is the loss of load carrying capacity of a material unit.
This definition per se introduces the fact that material failure can be examined in different
response may be beyond the initiation of nonlinear material behaviour, material failure is of
profound importance for the determination of the integrity of the structure. On the other hand,
Material failure can be distinguished in two broader categories depending on the scale in
Microscopic failure
Microscopic material failure is defined in terms of crack propagation and initiation. Such
methodologies are useful for gaining insight in the cracking of specimens and simple
structures under well defined global load distributions. Microscopic failure considers the
initiation and propagation of a crack. Failure criteria in this case are related to microscopic
fracture. Some of the most popular failure models in this area are the micromechanical failure
microvoids nucleate and grow until a local plastic neck or fracture of the intervoid matrix
occurs, which causes the coalescence of neighbouring voids. Such a model, proposed by
and thermodynamics. Both models form a modification of the von Mises yield potential by
introducing a scalar damage quantity, which represents the void volume fraction of cavities,
the porosity f.
Macroscopic failure
Macroscopic material failure is defined in terms of load carrying capacity or energy storage
categories:
Damage failure
Empirical failure.
Five general levels are considered, at which the meaning of deformation and failure is
interpreted differently: the structural element scale, the macroscopic scale where macroscopic
stress and strain are defined, the mesoscale which is represented by a typical void, the
microscale and the atomic scale. The material behavior at one level is considered as a
collective of its behavior at a sub-level. An efficient deformation and failure model should be
Energy-based methods
METHODOLOGY
As manufacturing technology has improved structural material requirement in built
environment have become more demanding, there has been marked prevalence of engineered
polymers and composite material replacing more conventional material. These materials
provide improvement to the built environment in terms of structural ability and costs
1. Plastic
2. Additives
Additives improve performance and/or reduce production costs. Stabilizing additives include
fire retardants to lower the flammability of the material. Plastic composites contain filler
relatively inert and inexpensive material that makes the product cheaper by weight. Typically
fillers are materials that makes the product cheaper by weigh. Typically filler are origin, e.g.
chalk, wood. Some additives are more chemically active and are called reinforcing agents.
Other additives include zinc oxide, wood flour, ivory dust, cellulose and starch.
3. Colorant
Forming process
1. Bladder moulding
2. Compression moulding
4. Mandrel wrapping
Design consideration
The primary design concentration for using reinforced plastic is to ensure that the material is
used economically and in a manner that takes advantage of its structural enhancement
specifically. This however not always the case, the orientation of fibers also creates some
material weakness perpendicular to the fibers. Thus the use of firber reinforcement and there
orientation affects the strength, rigidity, elasticity of a final form and hence the operation of
the final product itself. Orienting the direction fibers either, unidirectional, two dimensionally
or three dimensionally during production affects the degree of strength, flexibility and
elasticity can also be magnified or diminished through the geometric shape and design of the
final product. These include such design concentration such as ensuring proper wall thickness
and creating multifunctional geometric shapes that can be moulding as single pieces, creating
shapes that have more material and structural integrity by reducing joints, connections and
hardware.
GANTT CHART
PHASES DURATION
1 Study of composite material 15 days
Chart Title
70 60 60
60
50
40 30 30 30 30
30
2015 15
10
0
Series 1
REFERENCES
1. GOOGLE SCHOLAR
2. SCI-HUB
6. WWW.SPRINGER.COM
7. Sonti SS, Davalos JF, Zipfel MG, Gang Rao HVS. A review of wood cross tie
Press, 1946.
9. Adali S, Verijenko VE, Galileev SM, Matrosov AV. Method of initial function in
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