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  • 1-Parcial Elucidación Estructural

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    Miyey Gutierrez Orduz
    165 views2 pages
    The document provides 5 NMR spectra labeled A through E and asks to identify the compound each spectrum corresponds to and label the peaks with the appropriate proton labels. The spectra are for the 6 isomers of dimethylphenol, which differ based on the position of the methyl and hydroxyl groups around the benzene ring.

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    The document provides 5 NMR spectra labeled A through E and asks to identify the compound each spectrum corresponds to and label the peaks with the appropriate proton labels. The spectra are for the 6 isomers of dimethylphenol, which differ based on the position of the methyl and hydroxyl groups around the benzene ring.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    165 views2 pages

    1-Parcial Elucidación Estructural

    Uploaded by

    Miyey Gutierrez Orduz
    The document provides 5 NMR spectra labeled A through E and asks to identify the compound each spectrum corresponds to and label the peaks with the appropriate proton labels. The spectra are for the 6 isomers of dimethylphenol, which differ based on the position of the methyl and hydroxyl groups around the benzene ring.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    of 2

    3. 300 MHz 1H NMR spectra in CDCl3 are shown below for five of the six isomers of dimethylphenol.

    Match
    each spectrum to the appropriate compound and assign the resonances of the spectrum to the appropriate
    protons in the compound. (15 points)

    OH OH OH OH OH OH
    H6 CH3 H6 CH3 H6 CH3 CH3 CH3 H6 H2 H6 H2

    H5 CH3 H5 H3 CH3 H3 H5 H3 H5 CH3 CH3 CH3


    H4 CH3 H4 H4 CH3 H4
    2,3-methylphenol 2,4-methylphenol 2,5-dimethylphenol 2,6-dimethylphenol 3,4-dimethylphenol 3,5-dimethylphenol

    SPECTRUM A. Identify the compound (here) _____________________ and label the peaks (below) with the
    corresponding proton (with labels selected among H2, H3, H4, H5, and H6 as appropriate).

    5X expansion

    8 7 6 5 4 3 2 1 0

    SPECTRUM B. Identify the compound (here) _____________________ and label the peaks (below) with the
    corresponding proton (with labels selected among H2, H3, H4, H5, and H6 as appropriate).

    5X expansion

    8 7 6 5 4 3 2 1 0

    This work by Dr. James S. Nowick, Professor of Chemistry, University of California, Irvine, is licensed under a Creative Commons Attribution 4.0 International License.
    Spectra are from Sigma-Aldrich (www.sigmaaldrich.com) under fair use.
    SPECTRUM C. Identify the compound (here) _____________________ and label the peaks (below) with the
    corresponding proton (with labels selected among H2, H3, H4, H5, and H6 as appropriate).

    5X expansion

    8 7 6 5 4 3 2 1 0

    SPECTRUM D. Identify the compound (here) _____________________ and label the peaks (below) with the
    corresponding proton (with labels selected among H2, H3, H4, H5, and H6 as appropriate).

    5X expansion

    8 7 6 5 4 3 2 1 0

    SPECTRUM E. Identify the compound (here) _____________________ and label the peaks (below) with the
    corresponding proton (with labels selected among H2, H3, H4, H5, and H6 as appropriate).

    5X expansion

    8 7 6 5 4 3 2 1 0

    This work by Dr. James S. Nowick, Professor of Chemistry, University of California, Irvine, is licensed under a Creative Commons Attribution 4.0 International License.
    Spectra are from Sigma-Aldrich (www.sigmaaldrich.com) under fair use.

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