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Polymer Testing: Robert Keqi Luo, Xiaoping Wu, Limin Peng
Polymer Testing: Robert Keqi Luo, Xiaoping Wu, Limin Peng
Polymer Testing: Robert Keqi Luo, Xiaoping Wu, Limin Peng
Polymer Testing
journal homepage: www.elsevier.com/locate/polytest
a r t i c l e i n f o a b s t r a c t
Article history: This article presents engineering approaches to evaluate creep loading response and a complete loading
Received 17 June 2015 eunloading procedure for rubber components used as anti-vibration applications. A damage function for
Accepted 27 July 2015 creep loading and a rebound resilience function for mechanical unloading are introduced into hypere-
Available online 29 July 2015
lastic models independently. Hence, a hyperelastic model can be extended for both creep and unloading
evaluations. A typical rubber product and a dumbbell specimen were selected to validate the proposed
Keywords:
approaches. It has been demonstrated that the predictions offered by the new models are consistent with
Creep
the experimental data. In addition, a loading procedure using the same final value, with and without
Rebound energy
Hyperelasticity
involving unloading, prior to a creep test can produce different results. The proposed approach can
Rubber unloading capture this phenomenon which was observed in the literature. The proposed approach can also be easily
Design incorporated into commercial finite element software (e.g., Abaqus). It is demonstrated that the proposed
method may be used for anti-vibration products at an appropriate design stage.
© 2015 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.polymertesting.2015.07.009
0142-9418/© 2015 Elsevier Ltd. All rights reserved.
R.K. Luo et al. / Polymer Testing 46 (2015) 134e143 135
measurements at low stresses and strains. The internal time-tensile and residual strain response (Dorfmann and Ogden [41] and Luo
compliance superposition of non-linear creep data was applied to et al. [42,43]). Despite the progress described above, current
construct creep master curves, which corresponded to a pseudo- hyperelastic models cannot be used for creep response because
iso-free-volume state; a Boltzmann-like superposition principle these models are not referenced to the elapsed loading time.
for multistep nonlinear tensile creep was used with three types of Rubber creep as a time dependent deformation is one of the
polypropylene. For alternative methods to the Boltzmann super- critical factors when considering engineering design and applica-
position principle, statistical analyses have been performed for tions for rubber springs. An important requirement is to control a
creep prediction. Gnip et al. [14] built long-term creep curves using rubber product to not exceed its structural limitation and to avoid
the data obtained in direct experiments with a duration of 122e183 early failure due to creep over its required service life. In industry,
and 1100e1432 days, and demonstrated that creep compliance reliable prediction of creep for rubber structures over their entire
could be approximated by power and exponential regression service lives is essential at the design stage. For many anti-vibration
equations. applications, rubber components must be checked at specified time
A number of factors affecting polymer creep have been inves- periods for safety issues; for example, rubber suspension systems
tigated in previous studies. To ensure that the equipment settings used in rail vehicles must be inspected and adjusted during their
were correct for the creep experiment, some improvements were operating service life.
made. Nitta and Maeda [15], for example, designed a creep appa- In this study, we introduce a damage concept into hyperelastic
ratus in which the external load was controlled by the transient models to predict creep for rubber materials. In addition, a dissi-
data of the cross-sectional area of the deformed specimen to make pating function is added to capture the observed stress softening
sure that a constant stress level was maintained. Tomlins et al. [16] response for unloading during a cyclic loading process. Conse-
obtained tensile creep data for vinyl chloride at a number of tem- quently, hyperelastic models based on strain energy potential can
peratures ranging from 21.5 to 58 C. It was shown that neither the be extended to predict rubber unloading and creep performance.
ageing rate nor the shape of the distribution of retardation times The remainder of this article is outlined as follows. Experimental
was affected by temperature. Further studies (e.g., Dean [17]) found results for a rubber spring and a concept for rebound energy as well
that errors in long-term properties derived from the application of as its measurement are presented in Section 2. The hyperelastic
TTS could arise unless changes in creep behaviour caused by models including unloading and creep effects with necessary
physical ageing were considered. Printer et al. [18] found that times equations are contained in Section 3. Next, simulation and valida-
to failure increase continuously with the age of the solutions on the tion results are demonstrated in Section 4. Finally, findings from
degradation of the surface's active environment. Creep failure could this investigation are summarized in Section 5.
also be predicted based on a thermally activated rate process where
the creep rate reaches its minimum value [19]. The effect of tem- 2. Experiment on rubber anti-vibration product
perature may also be important and is probably different for sec-
ondary creep. Additionally, oxidation is probably diffusion- In engineering design and applications, rubber structures are
controlled at certain temperatures. Attempts to study long-term usually loaded under compression and shear conditions. A typical
creep behaviour by accelerated tests on small samples require, industrial product (Metacone type spring) was selected for exper-
therefore, careful study to avoid false conclusions [3]. In parallel iment and validation. Two experiments (i.e., mechanical loading
with above methods mentioned, viscoelasticity models were also and creep loading) were performed. The rubber compound used
developed to predict polymer creep. The theoretical background of was a filled synthetic high cis polyisoprene with a shear modulus
the framework of viscoelasticity for polymer creep behaviour has 1.2 MPa.
been well documented [4,20e22].
Mechanical loadingeunloading processes strongly affect rub-
ber's creep behaviour. Drozdov [23] demonstrated that the loading 2.1. Mechanical loading experiment
process significantly influences rubber creep due to unloading. In
his experiments, specimens were subjected to stretching up to Mechanical loading was performed before each creep experi-
various maximum strains followed by retraction to various smaller ment began to ensure that the product was compliant with real
strains, creep tests were then performed and it was found that the engineering applications and had the correct material properties.
creep curves were strongly affected by the unloading increments. This component, which measured maximum 230 mm in diameter
Additionally, Khan and Yeakle [24] found that a loading history
prior to the creep test consisting of loading to a maximum stress or
strain followed by partial unloading to a target stress could
significantly modify strainetime behaviour, which was consistent
with the findings from Omans and Nagode [25]. It was established
that unloading the specimen between two different stress levels
had a substantial influence on creep results.
For mechanical loadings on anti-vibration components, rubbers
are widely modelled as hyperelastic materials based on strain en-
ergy density [22,26,27] (e.g., the Mooney-Rivlin, Ogden and Yeoh
models). These models are generally used to predict the loading
response and fatigue life of rubber products used in industry (Luo
et al. [28e34] and Zerrin and Fatemi [35]). However, these models
can only be used for the loading portion of a loadingeunloading
cycle. To include unloading effects on the hyperelastic models, a
single additional (i.e., softening) variable was added to model a
complete loadingeunloading process (Ogden and Roxburgh [36,37]
and Luo et al. [38e40]). Additionally, two more variables were used
in the energy function so that it captured the observed softening Fig. 1. A Metacone spring.
136 R.K. Luo et al. / Polymer Testing 46 (2015) 134e143
and 140 mm in height, is used in industrial mounts, as shown in 2.3. Measurement of rebound energy: rubber resilience test
Fig. 1. Three layers of rubber and two metal interleaves are used in
this part. Compression loading in the vertical direction was applied Luo et al. [38e40] introduced rubber rebound energy (i.e., resil-
to the component. In this procedure, a force of approximately 58 kN ience) as a single function in a strain energy density expression. The
was loaded along the vertical direction within a specified working rebound energy or rebound resilience, which is the ratio between
compression range at a loading rate of 10 mm per minute. Fig. 2 (a) the rebound energy and the initial loading energy, is a property of
shows the load deflection response of this rubber component for rubber materials and a parameter for a given rubber. It can be used to
this loadingeunloading procedure. Different paths between predict characteristics of the material during unloading after cyclic
loading and unloading were observed. A reduction in the load loadingeunloading processes. Measurement of the rebound resil-
during unloading (i.e., stress softening) was observed at a given ience (i.e., the resilience test) is standardised in BS ISO 4662:2009
deflection between the loading and unloading conditions. [44]. The test method involves hitting a standard test piece with a
falling mass, which is free to rebound after impact. There are two
2.2. Creep experiment methods to determine the rebound resilience of rubber: the
pendulum method and the tripsometer method. In this study, the
A creep experiment was performed in a controlled laboratory. tripsometer method was used, and a layout of the equipment is
The ambient temperature was maintained at 27 ± 1 C. An shown in Fig. 3. In this method, a flat test piece was impacted with a
approximately constant load of 46 kN along the vertical direction hemisphere. The hemisphere was mounted on the periphery of a
was applied to the rubber spring. The creep experiment lasted 553 disc, which was supported on an axle and caused to rotate by an off-
days, and the creep result was recorded into a database. The creep- axis mass. The kinetic energy of the impacting mass was measured
time history is shown in Fig. 2(b). In the first few days, the gradient immediately before and after impact. The impact angle was set to
of the creep curve was maximum in the loading response. After that 45 . The ratio of the rebound height to the drop height, which is
period, the slope of the creep curve changed gradually to a lower expressed as a percentage, is equal to the rebound resilience of the
value as time progressed. tested rubber compound. More details can be found in Refs. [44,45].
2 2 2 qðbÞ ¼ 1 ð1 q0 Þb (7)
I 2 ¼ l1 þ l2 þ l3 ; (3)
From a mathematical perspective, the function of the proposed
where li are the deviatoric stretches and Jel is the elastic volume model is continuous at both loading and unloading points. From an
ratio. engineering perspective, the required parameters above are phys-
The corresponding stresses may be written as: ically meaningful concepts.
2
2 41 vW vW vW vW dij 3.3. Damage approach model for creep prediction
sij ¼ þ þ I 1 B ij I 1 þ 2 I 2
Jel J 23 v I1 v I2 v I2 v I2 3
el To determine the creep behaviour of the rubber materials under
3
1 vW vW constant loading, an additional function is introduced into equation
4 Bik Bkj 5 þ d (1). This function should relate the creep behaviour with both the
J 3 v I 2 v Jel ij
el material structure change under loading and the time elapsed.
(4) Hence, two variables are required. A time-decay function Rc with a
damage concept is proposed and incorporated into equation (1).
where Bij is the component of the left Cauchy-Green deformation The principle is to link the rubber creep to the material loading
tensor B, and dij is the Kronecker delta. condition and to the elapsed loading time. It is assumed that the
138 R.K. Luo et al. / Polymer Testing 46 (2015) 134e143
creep effect from loading on the material is related to invariant I 1 , loadingeunloading processes under the experimental conditions. A
I 2 and the elapsed loading time T. Therefore, a hyperelastic model polynomial form of the strain energy density function was selected
is not only related to the loading condition of the polymer material for demonstration. The proposed approach was incorporated into
through the invariant I 1 , I 2 but also to the elapsed time T: the selected N ¼ 3 model.
Equation (1) without unloading capability can be expressed by
the following polynomial series:
W ¼ WI I þ WJ ðJel Þ þ Rc I; T (8)
where:
W ¼ WI I þ WJ ðJel Þ
X
N i j XN
1
Rc I; T ¼ kT z I 1 þ I 2 (9) ¼ Cij I 1 3 I 2 3 þ ðJel 1Þ2i (10)
iþj¼1 i¼1
D i
where T is the time elapsed from the end of a mechanical loading,
T ¼ 0 when an initial loading ends, and k and z are parameters to be where Cij and Di are material constants for a given rubber
defined. compound.
From a mathematical perspective, the proposed function (9) is If N ¼ 3, equation (10) becomes:
continuous. From a scientific perspective, the above parameters
2 2
W ¼ C10 I 1 3 þ C01 I2 3 þ C20 I 1 3 þ C11 I1 3 I 2 3 þ C02 I 2 3
3 2 2 3
þC30 I 1 3 þ C21 I 1 3 I 2 3 þ C12 I 1 3 I 2 3 þ C03 I 2 3 (11)
1 1 1
þ ðJ 1Þ2 þ ðJel 1Þ4 þ ðJel 1Þ6
D1 el D2 D3
have physically meaningful concepts. k is an amplitude parameter After integrating the resilience approach model, equation (11)
that describes the strength of the creep damage, z can be consid- becomes:
ered to be a hardening parameter that describes how quickly creep
h 2 2 3
W ¼ ½1 ð1 q0 Þba C10 I 1 3 þ C01 I 2 3 þ C20 I 1 3 þ C11 I 1 3 I 2 3 þ C02 I 2 3 þ C30 I 1 3
2 2 3 i
þC21 I 1 3 I 2 3 þ C12 I 1 3 I 2 3 þ C03 I 2 3 (12)
1 1 1
þ ðJ 1Þ2 þ ðJel 1Þ4 þ ðJel 1Þ6
D1 el D2 D3
damage develops with the elapsed time T, I 1 and I 2 are the The material data (Cij and Di), which are typically either deter-
deformation state of rubber material. Thus, we can define k as an mined by a company or externally contracted, were obtained from
amplitude indicator for creep damage and define z as a hardening the manufacturer's database, whose accuracy and suitability for
index for creep damage. The application of the proposed approach engineering design and applications have been verified. The ma-
is shown in the following section. terial coefficients may also be directly obtained by testing the real
products (Luo et al. [46]). Rebound resilience q0 was set equal to 0.7
4. Simulation and validation from the tripsometer experiment.
For the Metacone rubber spring, an axisymmetric model was
Mechanical and creep experiments were simulated based on the generated due to the geometry and loading condition. The total
constitutive models described above with the finite element soft- number of elements was approximately 660, and the total number
ware Abaqus. Due to symmetry of the components' geometries and of degrees of freedom was approximately 1900. The rubber ele-
the loading conditions, models for the rubber components can be ments used a four-node bilinear axisymmetric quadrilateral and
simplified to perform the simulation more efficiently. hybrid elements with constant pressure. The type of metal ele-
We will investigate the mechanical loadingeunloading model ments used was a four-node bilinear axisymmetric quadrilateral
and the creep model in detail in the following sub-sections. element. A full finite element model of the component is shown in
Fig. 4 (a). The main dimension of the cross-section of the compo-
4.1. Mechanical loading simulation and validation nent is shown in Fig. 4(b). During mechanical loading, the
maximum deflection along the vertical direction was approxi-
The proposed model based on the rebound energy concept mately 40 mm. Fig. 4(c) shows this deformed shape; for clarity, the
was used to simulate the response of the mechanical results of the entire component are displayed. The rubber parts of
R.K. Luo et al. / Polymer Testing 46 (2015) 134e143 139
2
W ¼ C10 I 1 3 þ C01 I2 3 þ C20 I 1 3
2 3
þC11 I 1 3 I 2 3 þ C02 I 2 3 þ C30 I 1 3
2
þC21 I 1 3 I 2 3
2 3
þC12 I 1 3 I 2 3 þ C03 I 2 3
1 1 1
þ ðJel 1Þ2 þ ðJel 1Þ4 þ ðJel 1Þ6 þ kT z I 1 þ I 2
Fig. 6. Stress profiles of the Metacone spring during loadingeunloading. D1 D2 D3
(13)
Fig. 7. Dumbbell specimen and finite element model. Fig. 9. Stress profiles of the Metacone spring during the creep process.
R.K. Luo et al. / Polymer Testing 46 (2015) 134e143 141
Fig. 11. Creep comparisons between the simulation and experimental data for the dumbbell specimen.
142 R.K. Luo et al. / Polymer Testing 46 (2015) 134e143
well with the experimental data. To test the parameter in an rubber components used as anti-vibration applications. For the
extreme loading condition, a tensile loading equivalent to stress unloading modelling, the theory is based on the elastic energy (i.e.,
level 3.0 MPa was applied to the dumbbell specimen. k ¼ 0.01785 rebound energy) remaining in the rubber material during unload-
and z ¼ 0.12 were assigned to the model. The creep simulation ing. The form of the rebound resilience function q(b) ¼ 1(1q0)ba
result was compared with the experimental data, as shown in is suitable for the unloading prediction and validated with the
Fig. 11 (b). The comparison demonstrated good agreement between experimental result.
the two results except for some deviations at the very beginning of For creep modelling, there is no universal method to predict
the test period. creep response for rubber anti-vibration products. The hyperelastic
The patterns of the creep curves from the simulations for the models based on strain energy density are widely used to predict
dumbbell specimen are very similar to that from the Metacone the mechanical loading response without reference to the time
spring. Furthermore, the overall creep behaviour predicted was effect. To extend the capability of the hyperelastic models and to
qualitatively consistent with the experimental data using dumbbell provide a method for creep evaluation of rubber suspension sys-
specimens in literature (see Refs. [5,11,13,25]). These comparisons tems, the damage function Rc ðI; TÞ ¼ kT z ðI 1 þ I 2 Þ is introduced into
indicate the flexibility of the parameters suggested in the model. the strain energy density expression. The theory is based on the
The proposed approach may need to be further verified using more elastic energy change of the rubber material over the time elapsed
engineering cases. and on the concept of material damage. The proposed approach
was validated by considering a Metacone rubber component, which
is not a simple component. The method has been shown to provide
4.3. Creep loading simulation under mechanical unloading good agreement between predicted and experimental results. In
condition addition, the loading condition of the rubber product is neither
uniaxial tension nor uniaxial compression; instead, the loading
From experimental observations, it has been found that the condition is a combination of shear and compression, which is
creep response of rubber structures is different between loading typical of a real application of anti-vibration systems. One impor-
and unloading conditions [23e25]. This phenomenon can be tant outcome from this proposed approach is the combination of
simulated and explained using the proposed approach. unloading and creep, which has revealed that a creep loading
To combine creep with an unloading process, equations (5) and procedure may produce different results even with the same load is
(8) are merged to form the following expression for the strain en- applied; this agrees with the published literature. The proposed
ergy potential: approach can also be easily incorporated with commercial finite
element software (e.g., Abaqus). It is shown that the proposed
W ¼ qðbÞWI I þ WJ ðJel Þ þ Rc I; T (14) method may be used for anti-vibration products at an appropriate
design stage. However, the proposed approach should be verified
To keep the analyses consistent, the same polynomial expression
further using more engineering cases.
(N ¼ 3) and the same values for WI and Rc ðI; TÞ are used. Creep
loading is approximately 23 kN, which is 50% of the maximum load.
Fig. 12 shows the creep prediction under these two conditions: one Funding
is loading from 0 to 23 kN, and the other is from 0 to 46 kN and then
unloading to 23 kN. The creep response from the unloading creep is The authors would like to acknowledge the funding support of
found to be above that of the loading creep; an approximately 30% the National Natural Science Foundation of China (51078361) and
difference between the two responses at day 553 is shown. This the Key Grant Science and Technology Research Planning Projects
result is qualitatively consistent with the experimental observations of the Ministry of Railway of the Peoples Republic of China
from the published literature [23e25] and verifies the suitability of (2014G005-A; 2008G017-C).
the combined approach for creep prediction during unloading.
Acknowledgements
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