PHYSICS

1 ACD 2 BD 3 CD 4 ABD 5 ABD

6 ABCD 7 ABC 8 5 9 4 10 4

11 6 12 4 13 C 14 D 15 B

16 A 17 C 18 A

CHEMISTRY
19 BC 20 ABC 21 AD 22 AB 23 ABC

24 CD 25 ACD 26 3 27 5 28 4

29 8 30 4 31 B 32 A 33 D

34 D 35 C 36 C

MATHS
37 BC 38 D 39 AC 40 BC 41 ABC

42 ABD 43 BCD 44 8 45 7 46 4

47 9 48 4 49 D 50 A 51 D

52 B 53 C 54 A
 SOLUTIONS
PHYSICS
1. (A, C, D)
5R 15 15
QAB  nC p T  n  4T0  T0   nRT0  PV0 o
2 2 2
Molar hear capacity of process BC is
R 3R R
C  CV    R
1 x 2 1 3
C  R
 QBC  nC T  nR TC  TB 
 nR T0  4T0   3nRT0
 3PV0 0
The work done by the gas during the process BC is
nRT nR T0  4T0  3nRT0
WBC   
1 x 1 3 2
3PV
WBC  0 0
2
Hence A, C, D are correct.
2. (B,D)
  90  i
tan   cot i ... 1
From snell’s law
1 sin 90   sin i
1 1
sin i  
 1  e y/a
cot i  e y /2 a from (i)
dy
 e y /2a
dx
y x

 e dy   dx  x  2a 1  e 
 y /2 a  y /2 a

0 0

Where x  a, y  2a ln 2
 P  a, 2a ln 2 
Hence B, D are correct.
3. (C, D)
General Theory
4. (A, B, D)
 q  CBvl
dq dv
i  CBl
dt dt
dv
m   Bil  Kx
dt
dv dv
m  CB 2l 2  Kx
dt dt
 m  CB 2l 2  dv
dt
  Kx
dv K
 x
dt  m  CB 2l 2 
d 2x Kx
 
dt 2
 m  CB 2l 2 
K
 
m  CB 2l 2
2 m  CB 2l 2
T   2
 K
The amplitude of SHM is A = d
K
 Maximum velocity of rod is vmax   A  d
m  CB 2l 2
 Maximum charge on the capacitor is qmax  CBlvmax
K
 CBld
m  CB 2l 2
5. (A, B, D)
Limiting frictional force on the block B, f B   B mg  0.2  2  10  4 N
aB   B g  0.2  10  2m / s 2
The block A and plank will move together with acceleration
F  f B 34  4
aA    3m / s 2
M m 82
Frictional force on the block A, f A  ma A  2  3  6 N
 a A, B x   a A x   aB x 
 3  2  1m / s 2
1
x A, B  u A, B x t  a A, B x t 2
2
1
8  0   1 t 2
2
 t  4sec
6. (A, B, C,D)
Z1  R1  X Li  10  10i  10 1  i 
Z2  R 2  X Ci  20  20i  20 1  i 
1 1 1 1 1
   
Z Z1 Z2 10 1  i  20 1  i 
1 1 i 1 i 3  i
  
Z 20 40 40
40
Z  Z  43  i 
3i
 Net impedance of circuits Z  4 10
 50 5
rms current through resistor 'R 1 ' is I1  rms   A
Z1 2  10 2 2
 rms 5
rms current through resistor 'R 2 ' is I 2   A
2  20 2 4
2
5 25
Power developed in resistor R 1 is P1  I R 1     10   10  62.5watt
2
1
2 4
7. (A, B, C)
Process AB is an isobaric process
5R
 QAB  nCP T  2   300  1500 R
2
During process BC,
VT  constant
VPV  constant
PV  constant
2

This is a polytropic process with polytropic constant x = 2

R 3R R R
C  CV    
1 x 2 1 2 2
R
QBC  nC T  2   300   300 R
2

WBC 
nRT

2  R  300   600 R
1 x 1 2
V  1
WCA  nRT ln  A   2 R300ln    1200 R ln 2
V  4
 C
8. (5)
Final configuration
 1m
R=

0.4 m

Let  be the angular velocity just after collision then by conservation of mechanical energy:
1 3
mg  0.4   m  12  2
2 2
4
 rad s 1
3
Now conserving angular momentum about point of impact:
1 v 3 4 11 6 60 12n
mv  0.6  m  12     m  12  or v v  n5
2 l 2 3 10 3 11 3 11 3
9. (4)
Sol. If is be the velocity just before collision uo  2gl
 Velocity after nth collision  e n uo    60 0
l/ 2 l
2
v1  euo  2gl
5 l/ 2
2n
 2 
 
5
 2gl  l
 
2g 2
n
4 l
   l 
5 2
4n 1
 
5n 2
n4

10. (4)
Balanced Wheatstone bridge will occur when
40
 10 
n
40
As  10 
n
40 50
As 
80   40
 
 n 
n  4
11. (6)
12. (4)
120
Rapprox.   60
2
120 15
iX  i  iV  2   A
960 8
 120
 R  64
 15 
 
 8 
 R  4
13. (C)
Concept Based
14. (D)
Concept Based
15. (B)
Concept Based
16 to 18.
N
mv 2
m R
f


mg
At maximum velocity:
mv 2
mg cos   sin   N (1)
R
mv 2
mg sin   cos    N (2)
R
Solving:
tan   
We get vmax  gR
1   tan 
tan   
Similarly, vmin  gR
1   tan 
For critical velocity:
v0  Rg tan 
If velocity is greater than this, friction acts inwards
If velocity is more than this, friction acts outwards.
16. (A)
For zero friction, the centripetal acceleration is provided by the horizontal component of normal
reaction by the road.
17. (C)
For sliding to occur, horizontal component of normal reaction + limiting friction should be less than
centripetal force required
18. (A)
Centripetal force = NHorizontal + FrictionHorizontal
 CHEMISTRY
22. A) Li  K  Rb  CS
B) Li 2CO3  Na 2CO3  K 2CO3  Rb 2CO3  CS2CO3
C) Li  Na  K  CS
D) BeCl2  MgCl2  CaCl3  SrCl 2  BaCl 2
23. A) K 4  Fe  CN 6   Fe 2 - White ppt
K 4  Fe  CN 6   Fe3 - blue ppt
B) CaCl2  CO32 - White ppt
CaCl2  HCO32 - no effect
C) Hg 2  HCl - no effect
Ag 2  HCl - White ppt
D) Al3  NaOH  ex  -Soluble complex
Zn 2  NaOH  ex  - Soluble complex
1
1
24. (B)TV  cons tan t,VT  cons tan t 1

 dV  1 V
   slope    
 dT   1 T 
(C)PV   cons tan t
 dP  P
   slope    
 dV  V
1 

(D)TP  k,PT  k
 1

 dP   P
   slope    
 dT  1   T 
26.
(1) Pu(OH) 4 (s)  Pu 4 (aq)  4OH  (aq);  G10  RT lnK sp
(2) Pu 4 (aq)  4e  
 Pu(s); G 02  nFE 0Pu 4 |Pu

(3)Pu(OH) 4 (s)  4e  
 Pu(s)  4OH  (aq); G 30   nFE 0OH |Pu (OH) |Pu
4

Applying Nernst equation to reaction 3;

2.303RT 4
2.03  E 0OH |Pu (OH) |Pu  log OH   ;E  2.03V
4
4F
RT
E 0OH |Pu (OH) |Pu  E 0Pu 4 |Pu  ln K sp
4
4F
RT
2.03  1.28  ln K sp
4F
 3F
ln K sp 
RT
x  3
27. HA  NaOH 
 NaA  H 2O
3.612 mmol 3.612 mmol  
  3.612 

NaA  HCl 
 HA  NaCl
3.612 mmol 1.806 mmol  
1.806mmol  1.806 1.806

pH  pKa  log
 NaA   5.0
 HA 
 pKa  5.0
31,32 & 33:
P) Pb  NO3 2(i) 
673K
 PbO  NO 2  O 2
Q) HNO3  P4O10S 
 N 2O5  HPO3
 Cu  NO3 2  NO  H 2O
R) Cu  dil.HNO3 

S) NH 4 NO3   N 2O  H 2O
NO  NO 2 
 N 2 O3
 Zn  NO3 2  N 2O  H 2O
Zn  dil.HNO3 

MATHS
37. Consider p : Point satisfies the conditions in C, q : Point is on the curve L. Then we mustensure
p  q , i.e. both p  q and q  p .
Now,
option A: q  p and  q  ~ p  p  q
option B:  p  ~ q  q  p and q  p which is not sufficient
option C: p  q and  q  ~ p  p  q which is not sufficient
option D:  p  ~ q  q  p and p  q
38.   
Let d  x b  c  y c  a  z a  b   
a d bd cd
where x  , y ,z
a b c  a b c  a b c 
     
       
  a b c  d  a  d b  c  b  d c  d  c  d a  b  d  1 
x y
39. Tangent to circle is   1 (0, b)
a b B A
 radius
1 a
  (a, 0)
1 1 2
 C D
a 2 b2
 a2
 4  1 2
b
2
b 1 2
 2   1  e2  e 
a 3 3
Let point A is (h, k)
h  0 k  0   1
 
1/ a 1/ b 1 1

a 2 b2
a a2
 h  ,k 
4 4b
 Area of rectangle ABCD
a a2 3 2
 4, ,  a
4 4b 4
dx 1  y 2 cos y  xy
40. 
dy 1  y2
dx y cos y
  x 
dy 1  y 2
1  y2
y
 1 y2 dy ydy
  e  1 y 
cos y
x e
2
dy
1  y2
1

n 1 y 2 
 x  e2   cos ydy

 x  1  y 2  sin y  c
 x  1, y  0  c  1
sin y  1
x
1  y2
a b c a b c
a   a 3  b3  c3  3abc 
2
41.  b c a b c
c a b c a b
  a  b  c   a 2  b 2  c 2  ab  bc  ac 
2 2


1
4
a  b  c
2
 a  b  2
 b  c  c  a 
2

2 2

  0  a  b  c  0 or  a  b    b  c    c  a   0
2 2 2

when  a  b    b  c    c  a   0
2 2 2

then a  b  c
t
42. y2  2  cos t and x  2 cos 2  x   0, 2
2
t
 2  2 cos 2 1
2
 y2  3  x  x  3  y2

A
0, 3 
C B(2, 1)
y  mx  2y  x
(0, 0)O

3
req area   xdy  OBC
1
3

  3  y  dy  2  2 1
1
 2

6 3 8 6 3 5
 1 
3 3
e x
(x  1) 2 e x (x  1)(x 3  3x 2  5x  1) x
43. f(x) = , g(x)  f (x)  , g (x)  e
1 x2 (1  x 2 ) 2 (x 2  1)3
Let h(x) = x3 – 3x2 + 5x + 1, h(x) = 3x2 – 6x + 5, D  0 so h(x) has only one real roots. Also g(–1)
g(0)  0. So the root (–1, 0). Clearly g(x) has two points of extremum. Maxima at x(–1, 0) and
minima at x = 1.
44. 8
sin x tan x  cos2 x  cos3 x  sin 2 x  1  cos2 x
 cos 2 x 1  cos x   1  1  cos x  sec 2 x
1 1 cos x
Now the terms are sin x, cos x, tan x,1, cot x, , , 2  sec 2 x
cos x sin x sin x
Hence the 8th term is 1  cos x
45. 7
a b 
46. Let A i   
c d 
a b  a b  1 2  a 2  bc ab  bd  1 2 
    or  2
 
 c d   c d   0 4   ac  cd bc  d  0 4 
 a 2  bc  1,  a  d  b  2,  a  d  c  0, bc  d 2  4
 c  0, a 2  1, d 2  4,  a  d  b  2
 4 possible sets of a,b,c,d are possible
1 2 / 3 1 2   1 2   1 2 / 3
Hence Ai are  , , ,
0 2  0 2   0 2   0 2 
4
  det  A i   8
l 1