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Long Term - Cumulative Test ANSWER KEY - 20.12.2020: 2v cos 2 θ 2 7 5 7
Long Term - Cumulative Test ANSWER KEY - 20.12.2020: 2v cos 2 θ 2 7 5 7
1 4 16 1
1−
4
Here FA = FB
6 Test ID : 511
+
(∵ sum of the infinite terms in G.P is 50. 1) H9O4
a 4 Solution :
Sα = ) = Gm 2
1− r 3 H3O+ H2O
→ H5O2+
H2O
→ H7O3+
H2O
→
H9 O4 +
51. 2) trigonal pyramidal
Solution :
42. 2)
O sp3, 1 lp, trigonal pyramidal
H
H H
Solution:
52. 3) HSO4-, SO4-2
4
g in = πρG r ⇒ g in ∝ r Solution :
3 Single proton differed
GM 1 53. 4) I2 is insoluble in aqueous KI
g out = 2 ⇒ g out ∝ 2
r r Solution :
43. 4) it is an independent constant I2 is soluble in aqueous KI due to the
Solution: formation of KI3 (Ionic compound)
G is independent 54. 4) 2.0 M
44. 3) same as at other places Solution :
w 1000
Solution: Molarity (active mass) = x
GMW V(ml)
Mass remains same for given body based on
8.5 1000
‘g’ weight of the body varies. = x ⇒2
45. 4) gravitational attraction between the sun and 17 250
55. 4) Esterification reaction in acidic medium
planets
Solution :
Solution:
Esterification reaction in acidic medium is
Gravitational attraction between the sun and reversible.
planets 56. 3) 16 atm
46. 4) constant pressure, ∆n ≠ 0 type of reaction Solution :
Solution : (P )2 8 x 8
K p = CO = = 16.0 atm
The addition of an inert gas at constant PCO2 4
volume does not change partial pressure (or)
57. 4) 4
the molar concentration.
Solution :
47. 4) all the above
A(g) + B(g) ⇌ C(g) + D(g)
Solution :
1 1 0 0
Conceptual
1-x 1-x x x
48. 3) N3-
2
Solution : At eq. ⇒ x = 2 (1-x) ⇒ x = 2 – 2x ⇒ x =
3
N3 H → N3 - + H+ 2 1 2 1 2 2
Acid Conjugative base 1− = 1− =
3 3 3 3 3 3
49. 4) AlCl3
2 2
Solution : x
In AlCl3, Al has vacant orbital (<8e-). So kc = 3 3 = 4
1 1
x
AlCl3 acts as lewis acid. 3 3
7 Test ID : 511
-
58. 2) 68% 63. 1) 2/3 mole of MnO4 and 1/3 mole of MnO2
Solutions : Solutions :
PCl5 ⇌ PCl3 + Cl2 MnO4- disproportionate as
+6 +7 +4
1 0 0 Mn O 24− → Mn O −4 + Mn O 2
1-α α α
We can consider the two half reactions
Normal mol. wt.
or =1+α separately
Exp.mol. wt
MnO42- → MnO4- + e- --- (i)
∴ α = 0.68 or 68%
MnO42- + 2e- + 2H2O → MnO2 + 4OH- --- (ii)
59. 3) more with K2Cr2O7
Solutions : Multiplying (i) by 2 and adding (i) and (ii)
The n-factor of KMnO4 is 5 while that of 3MnO42- + 2H2O → 2 MnO4- + MnO2 + 4OH-
K2Cr2O7 is 6. So for the same number of (or)
moles, K2Cr2O7 will have greater equivalence 2 2 1 4
than KMnO4. MnO42-+ H2O→ MnO4-+ MnO2+ OH-
3 3 3 3
60. 1) 2, 5, 16
2
Solutions : Thus, 1 mole of MnO42- disproportionate to
( +7 )
3
( +3) ( +4 )
2 MnO 4− + 5C 2 O 24− + 16H + → 10 CO 2 + 8H 2O mole of MnO4- and
1
mole of MnO2.
+ 2 Mn 2+ 3
2 64. 1) x = 4, y =11
61. 1)
5 Solutions :
Solutions : 4FeS2 + 11O2 → 2Fe2O3 + 8SO2
65. 1) P4 + 8H2O + 8OH-→4H2PO2- + 8H2O + 4e-
Solutions :
P4 + 8H2O + 8OH-→4H2PO2- + 8H2O + 4e-
66. 2) 3 on left side
∴ 5 moles SO3−2 requires 2 mole KMnO4.
Solutions :
Hence 1 mole SO3−2 require 2/5 mole KMnO4.
62. 1) 35 mL
Solutions :
Cr2 O 27− + 6Fe2+ + 14H+ → 6Fe3+ + 2Cr3+
+ 7H2O NO3- + 4H+ + 3e- → 2H2O + NO
Hence, 1 mole of Cr2 O 27 − = 6 moles of Fe2+ 67. 4) M/10
M1V1 M 2 V2 Solutions :
=
1 6 0 +5
0.1x V1 0.6 x 35 For the given reaction I 2 → 2IO3− change in
=
1 6 oxidation number of I2 = 10
0.6 x 35
V1 = = 35 mL ∴ Eq. wt. of I2 = M/10
6 x 0.1
8 Test ID : 511
3M 71. 1) Bromine is a stronger oxidant than iodine
68. 3)
4 Solutions :
Solutions : Bromine is stronger oxidizing agent than
iodine. Hence it gives different behavior
towards thiosulphate.
72. 4) 2
Solutions :
n1 x n 2 4 x 2 4
n – factor = = =
n1 + n 2 4 + 2 3
M 3M
Ewt = = 5 x 1.2 x 10-3 = (5 – n)2 x 10-3
n − factor 4
6 = 10 – 2n
69. 1) 1
2n = 4
Solutions :
n=2
73. 3) 15 ml of 0.1 M KMnO4
Solutions :
meq. of KMnO4 = 15 x 0.1 x 5 = 7.5
(nf = 5)
meq. of FeC2O4 = 25 x 0.1 x 3 = 7.5
M 28 14 (nf = 3)
G.E.W of N2 = = = = E2
6 6 3 74. 3) x = 3, y = 5
M 17 Solutions :
G.E.W of NH3 = = = E1
3 3 Balance the equation
−
E1 – E2 =
17 14
− =1 3Cl2 + 6 O H → ClO3s + 5Cls + 3H2O
3 3 75. 4) M/5
70. 4) 0.6, 0.5 Solutions :
Solutions : For one mole of BrO3-1 number of electrons
10FeC2O4 + 6KMnO4 + 24H2SO4 → 6MnSO4 gained = 5
+ 3K2SO4 + 5Fe2(SO4)3 + 20CO2 + 24H2O M
Equivalent weight of KBrO3 =
5
K2Cr2O7 + 2FeC2O4 + 7H2SO4 → Cr2(SO4)3 +
76. 3) 16
Fe2(SO4)3 + K2SO4 + 4CO2 + 7H2O
Solutions :
10 mole of FeC2O4 oxidized by 6 mole KMnO4 0
K12 =
[ N 2 ][ O2 ] Solution :
[ NO]
2
H2(g) + I2(g) ⇌ 2HI(g) ; Kc = 57
=
(1.5 x10 ) ( 3 x10 )
−2 1 −2 3
At equilibrium, when ∆G = 0 & Q = Kc
[ NH3 ] (1.2 x10 )
2 −3 2
∆G = ∆G° + RT ln K = 0
= 28.125 x 10-2 ∆G° = -RT ln K
82. 1) 2 bar ∆G °
ln K = −
Solution : RT
∆G °
Kp = p CO2 (for solids no pressure) −
RT
K= e
= 2 x 105 Pa ∆G °
5 If ∆G° < 0 then − = +ve ∴ K > 1
= 2 bar (1 bar = 10 Pa) RT
83. 3) N2O4(g) ⇌ 2NO2(g) ∆G °
If ∆G° > 0 then − = -ve ∴ K < 1
RT
Solution :
∆G °
Kp value increases with increasing If ∆G° = 0 then − = 0 ∴ K = 1 (e0 = 1)
RT
temperatures for endothermic reaction.
10 Test ID : 511
4
88. 1) -7.64 x 10 107. 4) Centromere
Solution : 108. 1) Nuclear division
= -8.314 x 300 ln (2 x 1013) 110. 4) The actual shapes of these can be seen
100. 1) Both the statements are correct 136. 4) all of the above
101. 3) ER 137. 4) both 1 and 2