gnou eT T, T Rl- 110068

(S THE PEOPLE'S
UNIVERSITY
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Enrolment Number: 2005606078

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Name of the
BSCG: Bachelor of Science
Programme:
Name SANJAY CHAURASIYA
Mother's Name MALTI CHAURASIYA 2005606078
Address
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The
 Annexure-

lignou
THE PEOPLE'S
| UNIVERSITY
faafaere
INDIRA GANDHI NATIONAL OPEN UNIVERSITY
REGIONAL CENTRE DELHI-1
Assignment Submission for Term End Exam June 2021
(Please read the instrutions given below carefully betore submitting assignments)

1. Name of the Student

SANJAY CHAURASIYA
2. Enrollment Number 2005606078
3. Programme Code BSCG
4. Course Code BCHCT-133
S. Study Centre Code
:07189
6. Name of the Study Centre
Sri Aurobindo College. Maviya
With complete address Nagar, New Delhi 110017. -

7. Mobie Number : 7011974520

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sanjay04chaurasia@gmail.com
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Assignment
 ASSIGNMENT

CHEMICAL ENERGETICS, EQUILIBRIA AND FUNCTIONAL ORGANIC

CHEMISTRYI
Core Course in Chemistry

Course Code: BCHCT-133

Assignment Code: BCHCT-133/TMA/2021
Maximum Marks: 100

Note: Attemptall questions. The marks for each question areindicated against it.
PART A: CHEMICAL ENERGETICS AND EQUILIBRIA

1. a) 192 J of heat was supplied to a thermodynamic system and its internal energy was
found to decrease by 22 J. Calculate the amount of associated work and state
whether the work was done by the system or done on the system? (2)
b) Derive the relationship between the temperature and volume for a reversible
adiabatic process. (3)
c) Define heat capacity; molar heat capacity and specific heat capacity of a substance
and give relations between them. (5)
2. a) State Hess' law of constant heat summation and give its importance. (2)
b) The enthalpy of formation of NH(g) as per the following reaction is -46.11 kJ/mol
at 298 K.
Ng)+3H(g) =2 NH(g
Calculate the value of enthalpy of formation of NH3(g) at 100 °C. The c^ (JK1 mol')
values are given as: Na(g) = 29.12; Ha(g) = 28.82; NH3(g) = 35.06. Assume the

given heat capacity values to be temperature independent in the range. (3)

c) What is residual entropy? What kind of species show residual entropy? (2)
d) What are spontaneous reactions? Give an example of a spontaneous reaction and
state the criterion of spontaneity of a reaction? (3)
3 a) What is a state function? Is work a state function? (2)
b) Give the statistical definition of entropy and calculate the entropy of a system
having 6.9x 10" microstates. (3)
c) What is meant by the equilibrium constant K,? Give the relation where it is shown
in terms of partial pressure.
4. a) State Ostwald's dilution law. How can this law be experimentally verified? (2)
b) Give Bronsted and Lowry's definition of an acid and a base with a suitable
example for each. 3
C) For the equilibrium
2S0(g+O(g)=2S0:(g) K-245 (at 100 K)
The equilibrium concentrations are [SO2]=0.204 M,[O:]=0.0264 M and
[SO1-0.368 M. Suppose that the concentration of SO, is suddenly halved caleulate
Qe and use it to show that the forward reaction takes place to reach a new
equilibrium. (5)
5. a) Define a buffer solution. Explain the buffer action with the help of a suitable
example. 6)
 b) Define degree of hydrolysis and hydrolysis constant, and derive a relationship
between them. (5)
PART B: FUNCTIONAL GROUP ORGANIC CHEMISTRY-I

Write chemical equation(s) for following conversions: (5)

1) Acetophenone to ethylbenzene

ii) Benzene to ethylbenzene

ii) Bromobenzene to ethylbenzene

iv) Phenylmagnesium bromide to ethylbenzene

v n-Octane to ethylbenzene

b) What are the limitations of Friedel-Crafts alkylation reactions? (5)

7. a) What do you understand by Meta-directing deactivator? Explain with the help of (5)
a suitable example.

What product(s) would you expect from each of the following reactions? Write
b)
the mechanism of the reactions and also mention the reason for the relative
(5)
amount of products formation where necessary.
(CH3)3C-ÇH-CH3+ HBr
OH

Strong base
i ii) CH CH2-¢-CH3

8. a) Explain following: (5)

i) Phenols are acidic in nature, while alcohols are almost neutral

i) Oxiranes are more reactive than open chain ethers.

b) Complete the following reactions and write their mechanisms: (5)

i) CHCoCH, + CH,MgBr i) Ether
i) H,O,H*

ii) CH,coCH, +Br,OH

9. a) Complete following reactions: (5)
i) KCN i) H,O+ H
Br
i)HC
SOCl%
i) HC OH

-cHs + HI
273 K

NaOH

iv) HC H

i) CHCNa/H

- i) Hgso,, H

A
 b) How will you carried out following conversion:

CH3 CH3
CHa (5)
cH
10. a) Write the products for the reaction of iodoethane with sodium nitrite and silver (5)
nitrite. Explain why two different types of products are formed?

b) Taking suitable example write the mechanism of benzoin condensation. (5)

5
 BCHCT

Topic ********** * Date ************************)

PART A CHEMICAL ENE RUAETICS AND EQUTLIBRTA

Ja) 9tJ huat Nad Aupplitd to a tumudynamits Aystm Che

t inkunal anuuq N a auwnd to dututalt hy . Llulat
omuut oaslatiattd hUk ond Alati hhethu s uYk
a dm by th Aysltna 01 dm m tu Ayskm l
=|ACCox dingt t i t lan ottwmodnabils
du- du-tds
AA huat is supplied toth Atltm Ab ttal d: 4 YJ-
AAnkxnal enuqychanga is neqativa duu to dututaje
uniteunal enug d o - J = dn: du-da
dw-J-19 d J = hnu dNEO So, NoYk dona.
bythSyam
b Dtivet 1clationship btnttn kmpenatuue.
and Valum x_a Xtvehl adiabatic prul.
Kno that du: Cydt_and du-pdv
Chang in uatral entwqy Ail! be negative un adiahatic
prouM.Thuukert, Cydt-pávanddu-pdv
hy on ideal qas ea n NI A-nRT/V
Cdt ndv

los the adiobaticchanga T [VT, and aisiog

that Cy (oná tant fa th a0nq a mpeuadeue
he Cay he Jntt raleabaul qiathng
dtn
T
d y =V G TnT nRInV
In :In a :
In
nR T
Wsing th popoutyalugonthu TTT In
Aidas
Taking algorithna both ne gut

Name-Sanjau Chaunaauya ASHOKA

tnreUmerl no- doo560 o3

 Pano ()
Topic. ********* * * * *

******************** Date.*****************
C

/ T
SuhatitutJn n:1and Re (p-Cy I: In
Tin
T
hh - C2
Cv

OmaTunging t
e Tv-TVd Ty onstaat
Tus givs te
gives ydatimuhip beaen valumu and Hmpuut
es evehihla adiahatic prou.
CDein hat Cpauity
3- molahe (apaiky on ApeciHe
huat apatity a Aubstunu anal que relatins
betatLn-
ns-Hat (spatity: Th hat epatity oaAuha tant un he
dtintd athamaunt o heal Yquiutdo
change
tmpetuu by c deqree. C:
AT

Nola hetat
Ca patitylunulax ht at lpatity u t tu imaun.
a nuqy Rqui ued to thRmpeuatuu o ne mela
ShAtanle
h Cmi deqrae, Cn:C
Spetipic hut Capaiy Specie ht Cepa.cit is
dulined as tu amauut oheattequnel to nalte the
ftmpeuoatue of Kilogram aa Aulstan by
C C_
klain

P-()Att Hm law omitont huat Summation _and oqine it

umY tontu
HUM lan: T Ataka that t enthalby clanga asMotialed
with
Aith thu givenChamital fattiom i the Aäme hethuu
i t OCGu vna Ains Ataq O r un many Sttyts,
kuAlaw a h t Aummaticm donpantat he lause it
dimannkdeh1mitally he Cmienvatrive aenua and
Nume Sanjay CKawhaAy ASHOKA

tn70llment ho- oo S6o5o1?

 Paro-3
Topic *** ***************** ****** *** *** * *******
-
Date. **********

|tha lawA a tdhu mo

dunanuth.
D thalby o t vation o M4, L) s p t telosng
Otin Ja-Y6.iiks /'mela qsk

lLaleli t a valu of enthalpy o oxmatim of nt, lg) a

Joo'C Th C (Jkmor") valu 0 giutn as: N lq): 24.N ,_
Hlgl ( 2 , NH,g)35.06. AMuu. th qiven huat opatih
Valus to be ttmpeatue indendan úo t 1ong.
uen N, q)=ia.1 H I.î NH, 3So6
Cp Yi35.06 3 R:{3 9, 1

=LUO- YS.16A 15): 47 11.751Imul

4Lllo-uS1K5).y7914.7 SJImal
-x4, llo-4s1615): 41 214.75JImal
-47.1 kilmal
C h a d s yuidual entso.py whatkind of Apeuies Ahew
TeAidualntrophy
hi Ruidual entaopy Th ceidual: tnopu relus tu tu
Enopo a Auhs tan ta f abdcuat ztuo (ak).
Axrangmi krCofolaand.0.cCoC AhanA xtmidual
vtph
d Apontunt 1tattion{ A iu on exumnp& oaApontanea
Ca on_cind Atat Th ileion o Apentantiy 0a

hd-Spo ntanta a t i o n 1 Spontantaus tattion is a ntattion

that to.auns th1oxmaton opoduttaat the (md~tion.

unduu ich th Yeadamis0C(unq(xample af

Spantanta Xacton_axu
BuwiningNooc i u nonk ond alkali meheus addeol to
Buaing
wak (aibha n1gy
enyy i tu uiloien_ox th
Apontantss ytauam 0010 prots u nonSpontantaul

ASHOKA
Nae- San |au chanay
fna9LmPh n 2005606ot
 Topic. ** ********* ***** s************ eeesnenass.***sa
he-4)
Date.. e**nssaraus*****

3o)Nhat i aAtati fundion (

Alu fundion2 T ka
Atatt untm : A Propely hwhaAt valuts dont dptnd
en the poth taktn to reah att that Speti ic Volus i
Knonn a Atettuntta'em.
uxk Ja not a Alect untoon beCewe i t is
pnputionu
to u oiltanu on objet JA movte, whih dyptnod n
putth ultel to go cw tu Jnti to t e nt
Atat
b)|uiv u totiitoul dahinitbon o tntop4 Ond alulbl
tintbuphy oa ltm havin xlomoohe.
Akutis tucal Xntu ph Tis diined oA o miaiue oti
numbtr o p h l motuAlepicAtak mituAhekta) o-h4
Auttmua Bumudyncumis Rqulihnum, CmAnsttnt with
t matHo Aopic tuumoclncunuts propeub, Which
mA titut mauesar o t h
ehha smtant by h equilbnum ankent kp uiue
relatuem nhuu i t hen J n kumd o pautial pruwe
h T Equiihmum Citant dsdltiht4 thr ratio cs pYoout
ane xeaLdinl mtuntyutidm ot e quilibum va Hums u
PautalhiMulRejauLunq to thi eqlLetr'dn
Pautaal

aAbB cCtd0 kp LL,

.ua) Aitu 0stnld's diution lan. Hon Can this law he

be
etpeuntntally vuisiad
An-stmld 'S clilutim law: OStcld didution las Alake
that l y at uninit diution th Neak
eluduyte
Undngoes pmpltt Jonizcctm..
Knu at ka: (x
-
Expuumtntal yeuhat on oh Ostud oliluton lan Fox
RE N
Ruaqth taualddilution la. th
Name hanjay chaaa
olsgxee akSHOKA*
Enyelumud no 20056d60
 no (5)
Topic Date. reennnnssgdg

diuoiatin (x) ohany eltd volyt ot diktun

dilub'onus dlunined d h ualuts alu plotasd
un abuv eatian and thu Valus af k ol d t r d
oli.lutuoms 0 Calulated, T valus Cenu aut t he.
htalyCostont t lawJA recd.
bi Brunaltd and Lus dalinitim af an otid ond
a base Nith a 3uitakl exampleor tath
ndBonAkd
kd-Lony- Atue
TK Brndlcd-uny aud a Aubstant uhuth denoles
autonaputcr HtJon to thu atun tomnund.
EcumpleH, Sou HtaHSo
ronAkd-luntuy ba
T unstsl - t u h a t i s a Auhslanu hhuich altupt
a pokan0YHtJdn t u CompounelA.
Exumplu Co +H12 HC HCO3-
fox th equihriuna
VSO,g)+ 0, (g) So,a) k ?4s lat look
T Lquiubrum Cm Centantiomj a (SoJ:0ou MCo,
O.064M and LS0,J036ÍN Suppod hat tu lonuntrati
Juddundy haluael Calulati e and uwe it to
hun at h x rd ta tion ak plau to reuch a
ne quilihium.
h ha Sa, (g)t 0,g) 2 So, S o , ] 0.2o4 M, Co]
0.06uN So,] o36S M

NUw LSo ACardinq quLAtim

ol So 12
Tlonunbatim o S0 Js halk ten.
Ne Cmnlundutim oSouill h (S0J: 0.2oy0.lo2
R
Nor = y93.05
0.02Cu &(00R)
AA huu mantanbon oa tafunt So u eduted So a

he Cmalaug a n kSa tat tu tatadm meve,

ASHOKA
Name- Saunja Chana4iya
fnollment mo- 2o56o60%
 no-6)
Date
Topic ****************************** ** ************************* ****************

batkard to xeate k and rudutu Ye utant t prodd

.Sa) 0eint a hutu Aolution Caplain tu hultu ad/on nit
t hulp Autohb Rxumpl.
Bul Aalution A hulu Aation is dltintd al
Aodution huh yAidt oy da n iti PH valu
en wle Amall dnaunt a ouc ox hae a adolud to

Bu Action
|ut u mncdex t aticlic cctaiom o audic hult
ContuiaingCHCaHonel CH,CooNa. Atutic áud_dtetut
cliuociak to a Small xknt khtuas Aocium atuli
jA almdt Complute CHCcuHt H gCH, Cct H01
CHCaoNc CH Cc t Nat
By
By Conmmun uon_ eljtd the donidatuen_oCH, LooH il
kuthen AupprtmeeTusn th Anlution, thit a
xle aauiccti inS and a Amals Cumaunt oH0t

htn a t dopa o an atid asa adelud to ts abo

mixtu Aulutaom, he H, 0t Jan gavtn bs thi a tid
Cmhin th CH Co um to htakyJcnized
Ymaletta a CH, CouH.

h HH0t ucn CenCentxatuim and hene the pt o t

Aalution meuinsalmusttConjteat
6)Delin duqre ohudrolns and hydvolytin Cmitant,
and
and deuv a tlatoonahip betttn t
Degree oydulyia: is dijintd a s tk actienLox pechent-
ag t i totnl Aalt hith JA hyddlysad at equilbn
xo mp i A01, a a Ault AaluniA hudrolysed,
it deqree o hydhebyaid is 0.40 ox as q07
HycolyA
O ondtantE A ydaolysid Codtast jsan i4uiliiu
Name Sanjay thauh0uy ASHOKA

Enpollmont nn o0Khbk0a6
 ** ************** Date . ********"||
no-)
veaction.
nltaut for ahydelysid
Relatiovhetwten degseeo hudrobpms ond hydrolzis Contlv
tha
ut
ut Centid - hud e yma oOn Anim,A
htak aud HA, taktn in 4qutau Aalud o

A laq)+ Hou)HA (aq) +oH(a9)

eadim tor
Th eqili brium mitant tor tahudrobpns
Thaniom Can he tten a
k HA LOHT
CATJ
mut rotim Alag)t H0l)= HA (ag)t oH (a4)
mol dm3
-C C C
Chang du to hudrlna
At equihnum
C
at
Aubatittiag tha Cntentartien ol di4Luert SpeLies
Aquilibium rtm th above tahle ve get
xx Co=S Ca
k
ell-<)_
fuumu
fMumiag hat ,uAnal asCmate to 1, he Can ignoy
i t in h dineminator oohov& quatbtn e qet
K=Cx=_x Kn Thi i h e requiued elatin..
VC

.6hrib ch1milalequatuon ) a t fallonuing (mvtuAims

1Atophanon to ethq benzenn

CH CHCH
2nH.andH
Cmminsen_
ve duc Gn

ACclo phunone Ethy bentenx

i Benzens fo Ethylbenz&ne
Anhy Alcl,

Benzene l be nme n Num-Sany Chauksi yqASHOKA

Gnrolitmunt no. PouS6O 6078
 Pgnos)
Topic
e*****o
**** ******************** ************* **** *************
Date...

iRt|
Bromo berent to Ethylhenzen
Nutz-fitttng eattiom
By
fH2CH3
+N-t CHCH, Br dy ethu T) +YNaB3r

Brome-benTtneBumethune. E l benunt
) PhenyLmaq husium bromid1 to ethylhenz ent

+CH CHBr dy etin

Bvomoethont

Fhany maqnrsium bumidl Ethylhenzens

) ockann to ethylhenrenk
CH3 H CH3
H3 CH CH H
nOctant
CH3 hql benzent
imitoms a
t-xytn
htdlel- (ualA alkylatitn ractim{
limutatina oEriedelHalts alkylotim
LThmain dticulty ith the biedel- alta alkylatrn
isthat thi Auh~tihution o the tut alkyt gmup attiits
toarda uthu Aubtitutim.

tRAIClt)ACh R
T|Fsitdel-(HaA_alkydctidn eatims aue Lnnikd fo alky halide
ary halides and alkenl halidda not eact, Thi di
belauAe 0tul and alken Casholatims ane to ustakla
to undu Fmedel- t Yeachian Cmditade

A 3yl halicde. ASHOKA

AaeSanj ay chawtanga
Enlumunt no. 20056060+9
 Pg no-(9)
Topic***************************************************************************************** Da . ***)|

CH- CHC AIC S Ng stactuon

ALKeny helida
T t t th aomi
Cmpaunel has an elkden nithdxaminc
hnt
substitut, ut dotsnot undeuyo frids- tajt alkyatim
clecativatedingMng not stadiveto ottackk
Catbo Catims.

R x RX Afth N o ste«tion elrdom ithdsanin

TVAromafa o.mints.
to uneluugoalkqlatien, pobakl a
belaLeCminoqup ox a lmplex ith n u oud. hnu.
t mpler_ haA a itdu_chaugeomnihe n , u
eltrophile Suhdtituitie
dLatovaks t oYOmtit
NH NHALCI
AICl Jo e a t a m
Aiclh
V. Semetmes duwunq th alkylalim h attatkiaq eltaphil
UnduquRA AYnYeminl hy 1,shift HoxR fo
xam, t atkytaticn obenltntnih -chloxoprop.ans
n-popyl benzenR and mtthy)
he nz enl.
Ao earyancRmunl.
Alcly CH, CH,CH,
ACl

Reay xangemenY
CH,cHCH, COAlcl Aiclu CH,HC4, ttALcl
Acl

ASHOKA
NamaSangay ehawnas iy a

CnTodument n.- Po05 6 o 60K

 P.9-10)
T o p i c***********************
.. ********************** Date... *

+Chg-CH-CH,
ma 13

a hat do yauundustand hsNta-diueding diadivator

Erplain uth thhilp o a Suiakl aamplu.
huse TLA all elhchrontqoliveqJa u p bnithau
a
on Anshau
an atoa adjaun to the beuzeh q . In all
eletaon_paiy
thi henaening hauld he d<adivatd, (utt
us
ese Casti,
tak a m p l e itaatimonitn henztn.h ponile
Ao nan Å t u t u s o t aubotatin tormed au aj
u l lo v s

a_oNtho-aftu O -O fo
NOo

6Nhat pandudt Nuld qau expect om ladh_o thi allain=

rit t mechanian s tatm and also mentim th
KfaAm ox tha rlative amaunt apndutaomaim
h heu hRCASALY.

i| CCH)4C-CH-CH4,t HBx ?LCHC CH-t1, H0

OH- B
Nechanmi AlkpL Ao_aucd base reatalcn, Pm tonatian o L
th olcohulic oryqen to makt a htttar tauin qkuup.Thisakep
ost nd tVeuihl.ThLm paixs mthr orygn-
mak t a lui baR
LCH),C CH-cu CCH,)CCH-(H3

AkplClaoua- the C-0 bemd altondth Ja_co tqoad

aving 4ruuf a nur k u moluuls to give a
Cathafatim inltumiditnLa s t h ytu dekuaiag ASHONA
Namu-Sanj ay ehaut asi yq
Gn rol mund no. Po05 6 o6 0+
 Py)
Topic. *********************************************"*****'***************************** *** Jate .
* *********

Akp bmd breakinq ndutuwmic)

3kp Atat af t nutluphilit bromids im hm tha.

ele ctrophlic atbocation cAeats u alk om d

LCH,)y--CH3 HO

when
Rexanal rtated ith HydrosenBomd B
Auhstiholt OH ond osmHexan Bromud.

CHC4 CH CHg ba CH,cH C-CH,

CH3 CH
Mechauniam AtpilAlo): Tonisatim_o t e xbmd qivs
Aall GhoCtoen
Cn3 Slow.rt
H,C tRx
ditu
mun
CHCH3
CHCH
Bkp?1_outom uns er n Cabu auonnleu mtelialr to ferm
alk na
H
CHCH

0.3.la) xplain folloning

Phanals aU cic in_ nutwe whila oltohuls aam
nutsd
i Cmp lutu h olloning a d imy and Niti their
mechanidmi
) Ettu
CCDEH3 CH Rgsx J H0,4
Ho,HT
iiJHCoCH tBr o
nA a{ bancd
Sint in ph1nala benzens ing lmtnbuka turd bane!
Name-Sanya chawtajiya ASHOKA

Enomant Ho.YooS6 608

 .9-14)
Topic**********
. ****************************** *** * * ********
Date... es************

oloiaation 0- hond. And 8takitiiati on a phenatrd1.

um s onedA ion7afion a phana moxt
auclic DuncukuMe phenals.
0LLE mo1& ative be CaAe o Baye Atrain
0Aatiacktal ithSmall ings that 1tuL Jato hiqha
XLottivity 0ixuns al mpantd to athu eths.
CHCocttCH Br (Cit),CoH
Nethanism atha abov Yeadim
AtptNe boncloxmatien hthten nutdeophil ond on 9xT
O:(H
sledanphil -Eqxt O
R
Akp m ton cuto an.
N R- R H,0
=R H- H

H R :R,: R CH, anal y : Ba

Nak Atudanta a u adviaeo fo_ pu taveus a R
R R and X un ahue Medhaniim.
i C 4 ,Co CH1B1 CH CG Cu ßr

-H

notutr 40
c0
H
Yeactuoml
.q. a lonp lutr llaniny
HC RKwiy Hot H VEN
HC Soch ct SoztHet SPCabon
ii) OH
Nam- Sanjay chawtsiyq ASHOKA

Roll-no Po95<o60+ No eacGm

 P.9-(13)
Topic.... L
Date.. * *******J

Naol CH CH- -H
HtHz C H
3-pha n * rOP-?enal
OH Cunna maldthyds)
CHCNAEHCNa/H
V ii) HgSoy. Ht
b)Ho Ni yu Casuiedaut lloina Co veun'
CH3
CN-CH
c
r CH3
HRY HR CH3
h
VMCPHA
-CH3
ou Met o
CH AoH
OH o t

-1o10) r i t t pmduts ar the reacticn o soduethana

uith sodiumniit ond Aibv nitnt Eplaun Why
th diHtun Tyesa PTdu c aue m
med
e?

PpsReattim aiacuethant bith Aocdium nitt1

CHCHT tNaNO CH,CHa-0-N0t NaI
Keact' on
oiodo ethant Hh Alut nitntu
CH CHI +Aq No CH CH No2t Ag
Tro pxoclu a
eittRntheCede
on otetay iuolattheua Nith nlye nitiat (Aq-0-nao),_
nityeetant iaorned be.caue Aan Tu hunc! hehuten
Aq- s Covalt Th lmtpar nituen a t a ala
otto ckin mUter ntulaphilic_ Suhabtuitim
But o n th athu h1ncd ucdatha nt. ús teatel i
Sadium rnithate Nan alkyl ntntu u Tmed as
prmdct beCaue AanC Th bund heheen Na-O . mar
Nam Sunj au chauUt i9a ASHOKA
Gnuunt nu
 9-(14)
Topic.********** ************************************************** **** ************* Date
L&*****s**********]

h nlqaliye chauqon oxyen SeuvRA 0A Cm

attockiag tt.
b Taking Suutabl lrample. Nnt mechanidm o hen Zoin
|Cmdiniation.
h MechaniAm a benzin Cnd1niatlen
JAdditima th tynaicls v'dm fo cutatt a yanohudsin
elcta an umpalung othe nusmaul lubny (haus akiauys-
and th tltetaepelic oladrhyd nuhan betemnA
aucituphlicatt dspmttnatitni Atizulina Sast
my als heut_adthu Callystia thi eartion
,O

H
A Abmq bauea nonablu to drprotonat af
ht omat (wuhuny = OH
OH
-
CN
e-
A SeCad Rqwvcll aldthycd att uth ths
Lnbanioen Rlininatlnath lalealyat xeqtiLualla
tt luba1y Compaun at h i egd a t xtactiin-
H

N
OH

Nou-Sanja chaut asiqHa ASHOKA

Enrolle n r no. Poo56ð6o78