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2-Rao - 2000 - A Modeling and Experimental Study of The Influence of Twist On The Mechanical Properties of High-PerformanceFiber Yarns
2-Rao - 2000 - A Modeling and Experimental Study of The Influence of Twist On The Mechanical Properties of High-PerformanceFiber Yarns
2-Rao - 2000 - A Modeling and Experimental Study of The Influence of Twist On The Mechanical Properties of High-PerformanceFiber Yarns
Polymer Science and Engineering Department, University of Massachusetts Amherst, Amherst, Massachusetts 01003
ABSTRACT: Little data exist on how twist changes the properties of high-performance
continuous fiber yarns. For this reason, a study was conducted to determine the
influence of twist on the strength and stiffness of a variety of high-performance
continuous polymeric fiber yarns. The materials investigated include Kevlar 29威, Kev-
lar 49威, Kevlar 149威, Vectran HS威, Spectra 900威, and Technora威. Mechanical property
tests demonstrated that the initial modulus of a yarn monotonically decreases with
increasing twist. A model based on composite theory was developed to elucidate the
decrease in the modulus as a function of both the degree of twist and the elastic
constants of the fibers. The modulus values predicted by the model have good agree-
ment with those measured by experiment. The radial shear modulus of the fiber, which
is difficult to measure, can be derived from the regression parameter of experimental
data by the use of the model. Such information should be useful for some specialized
applications of fibers, for example, fiber-reinforced composites. The experimental re-
sults show that the strength of these yarns can be improved by a slight twist. A high
degree of twist damages the fibers and reduces the tensile strength of the yarn. The
elongation to break of the yarns monotonically increases with the degree of twist. © 2000
John Wiley & Sons, Inc. J Appl Polym Sci 77: 1938 –1949, 2000
sembly of single fibers to behave as a single unit. Let the yarn extension ⫽ 1 ⫽ ␦h/h; then,
For conventional fibers such as nylon and polyes- the fiber path length ⫽ l ⫽ h/cos and the
ter, only a small amount of twist is used because fiber displacement ⫽ ␦l ⫽ ␦h ⫻ cos . Con-
twist damages critical yarn properties. However, sequently,
for some high-performance fibers, twist affects
the yarn properties such as modulus, strength, the filament extension
and elongation to break in a more complicated ␦l ␦h
way. There are few reports describing the influ- ⫽f⫽ ⫽ cos2 ⫻
l h
ence of twist on the properties of high-perfor-
mance polymeric fiber yarns.11–13 One of the pur-
Thus,
poses of this article was to illustrate and model
the influence of twist on high-performance fiber the yarn extension ⫽ 1 ⫽ f /cos2
yarns.
2. Axial tensile force.
As early as 1907, Gegauff14 proposed a simple
The stress along a filament in the yarn is
analysis to correlate the twist angle of a yarn with
the yarn modulus. Gegauff’s derivation is given
below and forms an excellent basis to expand this f ⫽ Ef ⫻ f
type of model.
The geometry of a twisted yarn is shown in the
and an equivalent area perpendicular to
following:
the filament axis ⫽ 2rdr cos .
None of the models described above provides unsatisfactory. In this article, the composite the-
good agreement with the experimental data, es- ory is used to incorporate the anisotropy of the
pecially when yarns made from high-performance material into a new model that accurately de-
fibers are considered. All these models imply that scribes the influence of twist on the yarn modulus
the change in the Young’s modulus of a material for all polymeric fibers.
depends only upon the angle between the mate-
rial axis and the stress direction regardless of
other material properties. The first drawback of
these models lays in the fact that, for an isotropic EXPERIMENTAL
material, the modulus does not change with the
relative direction of the stress with the material Commercial fiber yarns of Kevlar 29威, Kevlar
axis. Second, as shown later in this article, yarns 49威, Kevlar 149威 (DuPont, Richmond, VA, USA),
made from different fiber materials behave differ- Vectran HS威 (Hoechst Celanese, Wilmington,
ently at the same twist angle, which is not con- DE, USA), Technora威 (Teijin, Japan), and Spec-
tained in any of the previous models. Therefore, tra 900威 (Allied Signal, Petersburg, VA, USA)
the omission of important material characteris- were used in this study. The chemical structures
tics, such as anisotropy, yields models that are of these fibers are illustrated below:
Kevlar威 (Dupont)
Technora威 (Teijin)
Twisted yarns were made by anchoring one end of meters of yarn. The fiber density was measured
a fixed length of yarn and, while maintaining a using a density-gradient column. By knowing the
slight tension, rotating the other end about the denier and density, the cross-sectional area of the
yarn direction a predefined rotation. The length of yarn was calculated.
the yarn after twisting was recorded and the twist Tensile testing of the twisted yarn was done us-
in these yarns was calculated according to ASTM ing an Instron威 Model 5564 testing machine accord-
D 1432-92. Several terms were used to character- ing to ASTM D 2256-90. All the tests were per-
ize the degree of twist in a yarn. Twist in turns formed at standard conditions of 21oC (1oC) and
per inch (tpi) was directly counted. A term called 65% (2%) relative humidity. Pneumatic yarn/cord
the twist multiplier (TM) is related to the yarn grips were used for these tests, with the effective
twist in tpi and yarn denier by the equation gauge length set at 150 mm and a crosshead speed
of 10%/min. The initial modulus was calculated
tpi ⫻ 冑denier from the slope of the stress–strain curve in the
TM ⫽ . strain range from 0.05 to 0.5%. Griping effects were
73
corrected by adjusting the gauge length.
The surface twist angle is the angle between the
filament at the most outer layer of a twisted yarn Notation
and the yarn axis. The linear density of the yarn Given below is a list of the principal symbols and
was measured by a microbalance to determine the notation used in the text. To avoid confusion and
yarn denier, that is, the weight in grams of 9000 complexity, all the symbols are defined here. Re-
INFLUENCE OF TWIST ON PROPERTIES OF FIBER YARNS 1941
ferring to Figure 1, different structural compo- For the layer of flattened twisted yarn, that is,
nents—a single filament, a layer of flattened the unidirectional composite, the on-axis consti-
twisted yarn composed single filaments resem- tutive equation can be expressed by the following
bling a unidirectional composite, and a twisted matrix:
冉 冊冉 冊冉 冊
yarn—are utilized in this article. The properties
of a single filament are transformed first into z S zz S zy 0 z
on-axis properties and further into off-axis prop- y ⫽ S yz S yy 0 y
erties of the unidirectional composite. s 0 0 S ss s
冢 冣冉 冊
For a single filament and twisted yarn, the 1 ⫺ zy
symbols follow what was previously defined: 0
Ez Ey
⫺ yz 1 z
Ef, f, and f characterize the behavior of a ⫽ 0 y
Ez Ey s
single filament.
1
1 and 1 characterize the behavior of a twisted 0 0
Es
yarn.
Ê(␣) is the apparent Young’s modulus of a and the off-axis constitutive equation can be ex-
twisted yarn with the surface twist angle of ␣. pressed by the following matrix:
1942 RAO AND FARRIS
冉 冊冉
1
2
6
⫽
S 11 S 12 S 16
S 21 S 22 S 26
S 31 S 32 S 66
冊冉 冊 1
2
6
was taken. The open-up structure of this
layer resembles a unidirectional composite.
At the radial position of r, the off-axis angle
is , and at the radial position of R, the
冢 冣
1 ⫺ 12 16
off-axis angle is ␣.
冉 冊
E1 E2 E6 According to composite theory,20 under
⫺ 21 1 26 1
⫽ 2 uniaxial stress, a unidirectional composite
E1 E2 E6 6 responds as
⫺ 61 62 1
E1 E2 E6 1
1 ⫽ S 11 1 ⫽
E1
in which z and y are principal terms of the on-axis
behavior; 1 and 2, principal terms of the off-axis
behavior; s and 6, shear terms; i, the strain; i, Therefore, the off-axis modulus of a single
the stress; Sij and Ei, the compliance and engi- layer E1 ⫽ 1/S11
neering Young’s modulus; and ij, Poisson’s ratio. and the off-axis stress
On-axis properties of a twisted yarn layer are
the same as the properties of a single filament, Ez 1
⫽ Ef; Es ⫽ Erz; and Ey ⫽ Er, in which Erz is the 1共 兲 ⫽ (1)
S 11 1
shear modulus and Er is the transverse radial
modulus in a filament. , ␣, r, and R have the 2. Yarn mechanics by layer assembly.
same meanings as previously defined in the ideal
twist geometry and dominate the characteristic Assuming no slippage between layers be-
off-axis behavior of different yarn layers. T0 is a cause of the integrity of a twisted yarn,
function of the surface twist angle, cos2␣; d, the each layer has the same extension ⫽ 1
anisotropic ratio, Ez/Es; Ezc , Eyc, and Esc, the on- under uniaxial stress. Also, assuming con-
axis Young’s moduli and shear modulus of an tinuous layers along the radial direction in
unidirectional composite; and Em and Gm, the a twisted yarn, the axial force in a yarn is
Young’s modulus and shear modulus of the ma-
trix in a composite.
F⫽ 冕 1共 兲dA ⫽ 冕0
R
1共 兲2 rdr (a)
The approach used to model how the yarn modu- If the yarn is treated as one body, the axial force
lus is influenced by the degree of twist is quite can also be expressed as
straightforward. A strategy was taken as shown
schematically by Figure 1. The notation in the F ⫽ R 2Ê 1 (b)
following discussion will follow that in Figure 1.
The twisted yarn was first dissected into individ- in which Ê is the apparent yarn Young’s modulus.
ual loading elements, which are a series of thin- Utilizing the ideal twist geometry,
wall tubes. A tube is hypothetically cut and
opened up to be a sheet structure with a preferred
orientation different from that of the planar ma- 2r 2R
tan ⫽ and tan ␣ ⫽
terial axes. The stress–strain response of the h h
plane was solved using orthotropic composite the-
ory.20 The responses of the individual elements as well as the equality of eqs. (a) and (b) and the
were added via integration of the layered struc- expression of 1() by eq. (1), the apparent
tures and this yields the stress–strain behavior of Young’s modulus of a twisted yarn can be calcu-
the yarn. In this way, the yarn modulus was lated as
derived from the single-filament properties.
S 11 ⫽
1
Ey
⫹
1
⫺
2
Es Ey
⫺冉2 yz
Ez
cos2 冊 For , Syy ⬃ Sss,
⫹ 冉 1
⫹
1
⫺
Ez Ey Es
1
⫹
2 yz
Ez
cos4 冊 共4兲
n 4S yy ⫹ m 2n 2S ss ⫽ n 2共n 2S yy ⫹ m 2S ss兲 ⬇ m 2n 2S ss
Then,
Substitution of eq. (4) into eq. (2) yields after
integration S 11 ⫽ m 4S zz ⫹ m 2n 2S ss (6)
冤
the shear modulus of the filament.
1 b 共a ⫹ b ⫹ c兲T 02 T0 ⫺ 1
Ê共 ␣ 兲 ⫽ ln ⫺ Through integration,
tan ␣ 2c
2 2
共aT 0 ⫹ bT 0 ⫹ c兲
2
cT 0
Yarn modulus, Ê共 ␣ 兲 ⫽ E z
共2a ⫹ b ⫺ 冑b 2 ⫺ 4ac兲
冊
冥 冋冉 册
3T 0 ⫹ 1 共1 ⫺ d兲 2 共1 ⫺ d兲T 0 ⫹ d
共b 2 ⫺ 2ac兲 ⫻ 共2aT 0 ⫹ b ⫹ 冑b 2 ⫺ 4ac兲 ⫻
2dT 0
⫹ 3
d tan ␣
2 ln
T0
(7)
⫹ ln
2c 2
冑b 2
⫺ 4ac 共2aT 0 ⫹ b ⫺ 冑b ⫺ 4ac兲
2
Ê共 ␣ 兲 ⫽ E z ⫻ 冋冉 3T 0 ⫹ 1
2dT 0 冊
共1 ⫺ d兲
⫹ 3
d tan2␣
2 By inserting these fiber properties into the
equations, the twisted yarn behavior can be pre-
册冒冉 冊
dicted. Figure 3 shows good agreement between
共1 ⫺ d兲T 0 ⫹ d 1 ⫹ d2 the predicted yarn moduli by both the exact and
ln (7⬘)
T0 d2 approximate equations and the measured yarn
modulus for different twist angles.
2. The case of an isotropic material. In summary, in a twisted yarn, the anisotropic
ratio, which is the ratio between the axial modu-
Statement: E(␣) ⫽ Ez at all ␣’s for isotropic lus and radial shear modulus, determines how
materials. the degree of twist influences the yarn modulus,
The yarn modulus was predicted by the model and this also is important information for fiber-
equations and the data are illustrated in Figure 2 reinforced composites.
for an isotropic material. It is clear that eq. (5) In this study, the stress state was simplified
predicts a constant modulus for any twist angle into a unidirectional stress acting along the yarn
and eq. (7⬘), the approximate relation, gives a direction. As Allen12 already showed, because of
deviation less than 3%. Both predict that the ma- the cylindrical orthotropy, a simple uniaxial
terial properties for an isotropic material will not stress state is almost impossible. Hoop and radial
change with the material orientation, while the stresses are induced by the action of an axial
earlier models did predict a change. stress in any cylindrical anisotropic material to
INFLUENCE OF TWIST ON PROPERTIES OF FIBER YARNS 1945
Figure 8 Curve-fitting results of the change of the yarn modulus with the twist
degree for various fibers. In the plot, solid lines are the fitting curves and dots are the
experimental data; the fitting parameter is shown in the plot.
consider a more complicated heterogeneous Two forms of the geometry as shown by Figure 9
twisted yarn where the twisted yarn consists of were taken: One has Kevlar 149威 fiber as the core
two different types of fibers. The yarn modulus of and Technora威 as the outer layer; the other has
mixed fibers can be predicted according to the the opposite arrangement. To form a heteroge-
arrangement of the different fibers inside the neous twisted yarn with the same twist degree
yarn by using the model. A different response is to distribution as of a homogeneous twisted yarn,
be expected if the arrangements of the two fibers the core material was twisted first to a certain
inside the yarn are different, since the behavior is twist degree calculated by the radius of the core
determined by the material constants and their and the outer layer was twisted carefully around
radial placement. A heterogeneous yarn consist- the core layer. The yarn moduli of these two yarns
ing of Kevlar 149威 and Technora威 was examined. at different twist angles were measured and com-
1948 RAO AND FARRIS
Table I Anisotropic Ratio and Calculated Radial Shear Modulus For Different Fibers
Vectran HS威 Technora威 Kevlar 29威 Kevlar 49威 Kevlar 149威 Spectra 900威