RAJDHANI

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sactical ssessment G)E

Name Richa
Rollno. 191703t
Ceurse Mathematics ( Hons) V Sem.

As n case ot cdt Pb* Sons th selubilty

odut is hiq hn an ethe mombers
qseub I harose he Cencontratron S

sheuldmet be mad vesp lou So excaas

O Hc shauld be awaido d as tho Solutron
Sheule be diluted enough passuhg
Hs gas athe datedon o d and
PI2t ens
2
Ans Phosphatos are Solublo n dltestmg aads
but a e ins-luble n hecral a d lbdsie
3otutroms haretore otonaquetus ammmia
Setutrem s added to he tsata
u p II n t only ttho ydsacidles o
seup des o P
3

Cand
G3Ound Fed
e 3 t peipitate bt the luoidus
arate3 oxalatas bhesdhatns c cauens o
Crroup I to V also pAeiputaat
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n this way plhesblhate act as znteteing

ions

Kemsval Phosphate ious a

based ttho
Kemewal cplhasphate 1ns s
en
emewal
fact hat zircory plesplhat ZrO(HPOY)2
BALcibtated som a Solubom cont anngp

Hcl not excearding M Cencanttration

HPOlaq) Z o (2) 2r0(H PO4), (s)

The piecipitatu qvaialslo cembestin

olopondimg om he Concontatn e Zr0,t
PO3 and H iens anster he Ltrata o
moup T ina china dush and beil ett
Hs. Pdd a eD drops e Cenc HNO3and
odauet HC Concontraiti on So t dees not
eyceed M Add1-2g seld NHylThen
Add Zrcenyl ntrate Slutn daopwise and
Sti uth qgloss od Heat on a
ooiling octer bath 2 minutas Cot and
HteiAdd w daeps 2rcemyl tralo
Seluctim to make sue all phasbhate
hove been precpitated
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Hhmeniuum Cabomate sddded p r e c i -

tatien Gpollp V ens ib ha prosena
of NHcavd Qmmenia Splutren
The Coub -V Catrms cuepeibtated as
Hhni cabomatas usuh dLssolue
accie ocud olue to ho 9Rmatron
ocetatos
BaCDa 2CM CODH (MCoO),Ba tH,OHO2

(CH COD),Ba tkCrOy BaorOy +2gc0ok

1 So2
lake 1 ml Splutrom S.E ound a t i
ocid ith cdL H add acl&lutron
ppt ipseluble n cevnc H _
Con c HNO obtained
Acid
Audy S.E wuth acatie acid nd add
lead acut atuABlub n Appealance
wtito bht cenoms The presn
SOy ion
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2.ChloideCL
wdth Lwam cencHaSOq
treatment
(a a n
s a l t qivesaCaleusless wuth
ungent me preant
H l + NH NMyC
Nacl+ HasOy NaH SOy H2

Salt Saluuton oddiai ed wth lilut

HNO3 cddituo. E SNes urdta
Seutren gve a Cundy hil bredbta
ammewum ydss XLde S u b on

Nacl +AgnNO3 NaNNO3 + AgC

AgCl + 2NMOH atnHa)-) C 2H,0
J
iammune SLue chlmde

(5
Wth Na,S alsa wthogau
up 2 Somme
catrons ok aeu TI and L may get
recpAtateddue to hghe mcontatren
ioms obtainea
Na, S 9NatS
But gorub T oe Cencontraatm
Seauired ohud can lbe obtauned lay HaS
aulyH
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@Patasun tiouanate2
Chonmical imula ksCN

Magnetir Potassium
hexanititocobaltate (
Chomical emula kalco(NO)s

Q Magnesium amm enium hosphat

Chonmical eRmula maNH) POy

As Use e modoate exceiso HCC L due

Ulou Teaiers o
ekCAASA C on enceusag8 he
he
recpitotrnT .
unkhaon Comtauns Tor Sb
2 AlsD
H pAeventa tho eupitatrn s
chlonds
acd avoided
Howeve o langee x c e s s
oecous
Ser and Lead chlondasAssolved ay
Cemplex termctu en.
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Ans
Solucbr emaa [co(NO2)6 qes yellod
pneiputate ok betasum oy anutnto
Cebaltate(I)

3KT [coNO)3 Kal coCNO)

Yollow ppt
(Potoasiuwm hax aitito-
Cobaltate L)

imctlgtyoxuna
when dimethylgoxim is added totihe
agucOUS e l i t on e hickel chlomde
oliant red reipttato H
O

- C=N-OH

NQ9INHOH+HC-C=N-OH

HC

t9NH0 +2H, O
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Nelos Rengent
o
Hmm enia os evelued by ho adron
N a b H w i t HC gives menium hloidle-
N e s lorsS
On pa4sung he qoas thsough
Teagent a brmon Celeraum lbaa
Omiolo-lodune L3skomed

N HO NHy
dnso otuio umes)

kHa T4 NH3+koH Ha0 Rgln4)T+

Nosds
Reaaet 7KI 2H,0