S

5. ZE¬MAN EFfECT

n eatenal
magnutc Keld
magnut eia th
he ine SpeclHun s placad
&Hect.

Split 'nto Componenls

is calleol eemu
Spe ctaal line

both Si das Ortoinal

hou been ohsoud On
These Components

caltud Loventa COmponunls.

Speet aal lint Thesc Compbrenl&

lina i placad 1n ectenal magnetil kield to

A Singlet spectaal
divection tplit into u e planepolasigecd
Aiqht angl
Componants i
callhd nlbrma Zeeman efect
Centsat unshi/ted line oitk eleetait Held wctoY vtbating paralel
fe
t Callo TCOm/lonlrtt
magnutic feld
to he
displated ethe siole vth
olhes wo Component s
rhe amoining calld
ibaatinqpeupendiculas
to magnettc held is

electaic Lcector

Component

C-Componurt) E B
E II B
Singlet -Componunt)

E 8.
om|pDhanty
(-C
Mognetic

plant pblazised .

component,Llectric
ield vec tor 1to maqneti'e
unshitted
Componin

e eld
ahciric uecti
Componectstao) T-Componenis
- -Componentty are shifted
magnetic held
T h Spluting Anekne structure Componetti ohen placad in an edesnal

nagneic feld is CaLlled Anamolta Zeamon eHect

COmponsnA a pla ced in
in eultnal
eulanal
For
tor
Cxomplt Salíum ,D, D
Compbntnt and
and o,
D, uina
ins
lin 9nto 4
maqnti feld, D 4plit

is Compbnenlk
spl into 6

ANote
teman etect splting Smalle "than spin-Ovbit Coupun
Th
du t spin Oybit Coupng)
Splitäing sbliting

(AE)

CAE) (AE)

dus to Ls Coupling OPoh RrD-LL+4)

En diHeren Ce
sS+1

&flerence du to Zttmon edfect t AeA-P

Entug

eeman
eeman&&flect
tect
he storte in
h Sne91
du t motion is
Zeeman eecl
ênurayf state in
Sn

H8
c dipole mbmerit dut tototal Ongulas momanlunr.
WhLu u i t magnti

B lostnal magnutie fe lal

 e-HBeut

T T 6CoLe

S C o s B) B

Me: Bohr magnttren o electadn

TLT )+lSt1) -LLtI)
+1)
 fs placad fn
hen tne struc-ture.
teana agntic feld
an
Ba-de Ls couplinq fine stTucue odus to eeman 8fHect)
L-S COupling

3, AE
EL+S

EL-S
-1 3.6 z2
E
Rche TlT+)-ll+)-S(S*H)
AE -t8.62

-Rch
(L+1)
 Anamelous Xeeman EHkct (nze)
NOrmaZeeman Hed alze)
lant pelteizationm)
0 . S#o T:743
2. Du to eiteanal magratic fe (d The pl? ting
2. u to ¬xtesnat maqntkeSela The splitë ng 2
3taTe (s{o) nto Seueaal
into Sevenal Componenls Ane structual
Singlet[S- 0 ) atate callec Anamolous Xeeman tfect.
3talaî
nölmal Teeman Edtect.
staTes is called
atunen magnetic alipole 3. nAZE, e îtaeactton helsten mognetic dipole
nteactitn
3. n NE, the
angulas momgyilin momenlun (j
omertl aue -te totad angulas
dut to Orbtta, merhen (Ht Ju hUa+1))
nOm magne tic feld
Both Orbital &
Orbita motton and extexnal
Ound ectasina magnetic held LYhe ith ettnal magmeti c
motion
nteoractt
ertesonal magnetic ala) Spin
itaroTis Orth

f-HLB Tha Stalt in AZE, ê : -

Bs
4The entotg ate in Nze, entY
T+1)+s(S +1)-L{L+) }
2T(T+1))

S. Selection ule tor Az£

tule tor NE
5. SelectHon
m CO, t
Am O, t

. 0 allosec Af HeB ( ) :
Mgsnyn);)
0 7- Componenl
T-Componeitg (n t B)
Ami D A tl -Com pone+ls.
CompbnenS ( +o s)
8. eanzs(ad (2L+ 1) .the numb spluspuHing Compwnenu in Ae
A7E

e numbe 2T+I (s0)

splettng Componenls in NZE is

2+1 becausc S=0

9S+1 9. 2S*

9+1 2+ 1+)+s/s+)-L+1) 23+12*

or AEE
T:1 0
1+D=1
These Qsteth Condrti ons ge NE

80A

D
-sCouplin
Kcem@n det
29h./a20lo
AHengrle Method

9p3s

AL 0,t)

An 0,tl

tsanstiont allowed to D1anti ti on

Th
allowed
Thee aat. o
.anaitions fn D, tsandti

Th Rodition en n Ths anamobuy Retman 2tfect

ltne coRa eaponcin G sebeti on
Sodium D, line and 0

Sul Am 0,t)

P S

A-

A 0 AE:+ He B

Amy
 Speelxa : +H,"* |

/s2/
-

-MB

Amy

Amy- I
DE = Ng8
-

Am

Spectal

S-T
eHeY
2
3 S

Am1
 Eopla nJerme Xeeman kdec1)

12012

L3

AL:
AB0

Dn0,
-
2

AmT+

Am

èddect'fleuel is spllting into Sevece stales

. D u to Zeeman C1+1)
m3,2, ,D,-1,-3
uel is înto 5 *ueral slalas
2. u
2. uet to Zteman ffeet ' splHno
(a7+
2,',0,-
Hect k laantion line betuween F'b is
to to Zman
5-T polasiza.o inas
pletting into 15 Seueaal (ines (Hvanuti ong
0- polai 3ad linas
 .T T m
3HB

-I -H8B
-PB
-34

-HB

Ar 2 2

2 =A£ : HgB
0 De 0
- -|

-2 -2

r:
3 2 A -H8B

O De : -MgB
-) -=1 Af HgB
-

nanpla

As , O, I = 2 : , A 9 : - -
Pasehen Back Hect (stsong feld)
Culesnal magnttie ield i nteaart
In Th paichen hack Efect , he
motion The olecbon indiuiduall
oleclson induuideually
wi th Ovbital molion anod spin
l each othes )
Sepascedey
t paeken hack efect E = HL +Hs B

EHg5 (mi +2m)

Ene- stale

Se lec-ton ules

Am d, t
testms in paschan back e}fect (21+)is+1)
Wumbe a peetnal

iHerencu betweer Zeemon &/het Pascken ack foet

ZeemÁn Eeet pouchen hack fect
Eclasnol mogneie e l a dbut influrta t. Entesnal magnttie e ld distoY

ILaL-S Cuplng -9 Cupling

2.The daanal mognete Hee value is 2 .Yhe eotocnal magnetic held is Aale
han mdutd magneic el4 }n
Sma lles thon irducao magntkc Aeld
L- Coupin
tn-s Cbupling
Bent Bn
boyt Bndu
3. The
naqy stote n Zomann 3 he Encqt State tpasun

back ect E
IHg BmL +?gMe Bn
Ha6 (ml t ans)
4 Se lecion tule 4.Stehon tule
m , t) Ams:
Am, r
5 aunbea speetaad ints spliëng S. Numbes peclsol linas splitng
+ +1)6s+1)

lines
ines paichen baek eJtect
Sodium D D in

D,line
Ph Dy line)2 s

se
my mch
n,)}E m m
(o
(,)2.
4,1, )Senary
(o,)a-He o,
lo,)HsB
))=-HsB
)
2/
05/20Lo

CNL s )
M MS
2 HeB
O

o
(-) -HBB

-1
C-
o, h)
(o
D
D nd LEnDs fn
Poasible taontí tions SDolium

Om 0ns onS lam

Pauchenhack effect Amy 0,t1)
a llootc
o1.)
not atloued ( f o )

not allooee

) o 4) al tousec
o -
allowed

lo ) not allosed
(D fo
o1 not allouoed
1
O allous
lo allowed

not allotwe

not altouec
1
to
Mooe
0