Furniture Coatings

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Contacts

Worldwide
Asia North America

BASF (China) Co., Ltd. BASF Corporation


No. 300, Jiangxinsha Road, 24710 West Eleven Mile Road
Pudong, Shanghai 200137 Southfield, MI 48034
P.R. China USA

Phone: +86 21 2039-2916 Phone: +1 248 948-2316

dispersions-asiapacific@basf.com

Europe, Africa, West Asia South America Protecting


BASF SE
Resins & Additives
E-EDC/RF – J550
BASF S.A.
Av. das Nações Unidas 14171,
11° andar
what’s around us
67056 Ludwigshafen Morumbi
Germany

Phone: +49 621 60-22261


04794-000 São Paulo, SP
Brazil Resins and additives for
Phone: +55 11 2039-3637
furniture and floor coatings

www.basf.com/resins

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.

® = Registered trademark of the BASF Group


EDC 0715e
Water-based systems
Table of contents
Protecting what’s around us 3

Natural oil-based polyols


Table of contents

Crosslinkers
We create chemistry 04 Radiation-curable systems 30
Laromer® epoxy and polyester acrylates 32

Market technology matrix 06 Laromer® polyether and


amine-modified polyether acrylates 34
Laromer® urethane and water-based acrylates 36
Water-based systems 08
Laromer® unsaturated polyester
Joncryl® acrylic emulsions and specialties 38

Radiation-curable systems
and colloidal dispersions 10
Laromer® functional monomers 40
Joncryl® and Luhydran®
Irgacure® photoinitiators 42
self-crosslinking acrylic emulsions 12
Joncryl® OH-functional acrylic emulsions 14
Joncryl PU dispersions
® Performance additives 46
and PU acrylic hybrids 16 Tinuvin® light stabilizers: UV absorbers 48
Joncryl and Laropal grinding resins,
® ®
Tinuvin light stabilizers: HALS,
®

waxes, and crosslinker solutions 18 blends, and preparations 50

Performance additives
Natural oil-based polyols 20 Solvent-based systems 52
Sovermol natural oil-based polyols
®
22 Acronal® acrylic resins
and Laropal® aldehyde resins 54

Crosslinkers 24 Joncryl acrylic polyols


®
56

Luwipal® and Plastopal® amino resins 26


Basonat polyisocyanates for 2K PU coatings 28
® Formulation additives 58
FoamStar® and Efka® defoamers 60

Solvent-based systems
Hydropalat wetting agents and
®

Efka® surface modifiers 62


Dispex , Dispex Ultra,
® ®

and Efka® dispersing agents 64


Rheovis rheology modifiers
®
66

Formulation additives
4 We create chemistry
Protecting what’s around us

Get a head start


on sustainable development

Formulators serving the furniture and flooring industry aim to preserve the beauty of
coat­ed wood and, at the same time, face considerable pressure to manufacture in
a resource-efficient, socially responsible, and ecologically reasonable way. With our
Sustainable Solution Steering method we have evaluated the value chain from the
cra­dle to the grave considering industry- and region-specific views in our markets.
­After identifying key sustainability drivers, our resins and additives have been system­
ati­cally reviewed. This approach allows us to assess the sustainability performance
of each of our products in its specific application. We create chemistry that makes
performance love sustainable solutions.

For the furniture and flooring industry, we identified – Let’s take a joint look at your specific requirements and
among other things – chemical and mechanical re­sist- find out how we can further improve both your, as well
­ance, material efficiency, and emission reduction to be as our, sustainability profile!
the key drivers for more sustainable coating formulati- Learn more about BASF’s commitment to driving
ons. Resins and additives that contribute substantially sustainable solutions at: www.basf.com/sustainability
to these drivers along the value chain have been
­classified as Sustainability Accelerators.
Water-based systems
6 Market technology matrix
Protecting what’s around us
Market technology matrix
Protecting what’s around us 7

Natural oil-based polyols


A truckload of solutions
for your requirements

BASF has a broad range of products for both interior and exterior wood coatings. Our
portfolio consists of solutions for economic to high-end furniture and for many different

Crosslinkers
kinds of flooring. With our expertise, we help you to improve your coating formulations.
Take a look at our solutions below – and ensure your coatings make furniture and
flooring that is around us every day more resistant, long-lasting, and sustainable.

1 Suited 2 Well suited 3 Best suited

Radiation-curable systems
Technology Application segment Economic furniture Medium-quality furniture High-quality furniture Wood flooring PVC/linoleum/cork flooring Concrete flooring Page

Resins
Joncryl® acrylic emulsions and colloidal dispersions 3 2 - - - - 10
Joncryl® and Luhydran® self-crosslinking acrylic emulsions 2 3 3 2 1 1 12
Water-based Joncryl® PU dispersions and hybrids - 1 2 3 1 1 16
Basonat polyisocyanate crosslinkers
®
- 2 3 3 1 2 28

Performance additives
Luwipal amino resin crosslinkers
®
2 3 - - - - 26
Acronal acrylic resins
®
- 3 2 - - - 54

Basonat polyisocyanate crosslinkers


®
- 2 3 2 - 2 28

Solvent-based and high solid Joncryl acrylic polyols


®
- 2 3 1 - 2 56

Luwipal and Plastopal amino resin crosslinkers


® ®
2 3 3 - - - 26

Bio-based Sovermol polyols


®
- 1 1 1 1 3 22

Water-based Laromer resins for UV curing


®
2 2 3 3 2 1 36
UV
Laromer® resins and monomers for UV curing 2 3 3 3 2 1 32

Solvent-based systems
Additives
Light stabilizers 1 2 3 3 2 2 48

With/without solvent- and water-based Photoinitiators 3 3 3 3 3 3 42

Formulation additives 3 3 3 3 3 3 58

Formulation additives
Water-based systems
Water-based systems
Protecting what’s around us 9

Natural oil-based polyols


Water-based systems

Crosslinkers
Enabling long-lasting and resistant coatings while, at the same time, reducing the output
levels of volatile organic compounds (VOC) are key targets for coatings formulators.
BASF offers various solutions for water-based systems, ranging from acrylic emulsions
to polyurethane dispersions and polyurethane / acrylic hybrids. When assessed with
our Sustainable Solution Steering method, all those products have been classified as

Radiation-curable systems
Sustainability Accelerators, which contribute substantially to sustainable development
along the value chain.

Efficient production, low emissions Pure performance for durable coatings

Joncryl® 8225 is a water-based acrylic dispersion Joncryl® HYB 6340 is a water-based polyurethane
that can be formulated without any coalescing agent, acrylic hybrid designed to enable excellent abrasion-

Performance additives
allowing fast drying and early blocking in combination resistant parquet flooring. Furthermore, it exhibits fast
with excellent grain enhancement for primers and hardness development for fast processing or reuse
topcoats. compared to other market standards.

Solvent-based systems
Formulation additives
Water-based systems
10 Water-based systems
Protecting what’s around us
Water-based systems
Protecting what’s around us 11

Joncryl® acrylic emulsions


and colloidal dispersions

Natural oil-based polyols


1 Suited 2 Highly recommended

Coating layer Application segment


Solids by Viscosity Acid number on
Product Appearance pH MFT [°C] Tg [°C] Key properties Primer/ Detailed application
weight [%] [mPa·s] solids [mg KOH/g] Topcoat Stains Furniture Flooring
sealer

Acrylic emulsions
Medium-hard emulsion recommended as blending
Good balance of flexibility / hardness,
Joncryl® 77 Semi-translucent emulsion 46.0 8.1 550 12 62 35 partner to improve flexibility and adhesion in

Crosslinkers
2 - - 2 1
excellent pigment wetting
combination with colloidal emulsions

High pigment binding power, excellent cost Excellent cost-performing emulsion for pigmented
Joncryl® 79 White emulsion 50.0 7.5–9.0 700–1,500 20 23 22 2 - - 2 -
performance, high solid content primers, furniture backings

Very good block resistance, excellent adhesion,


Joncryl® 1915 Semi-translucent emulsion 44.0 8.5 700 <5 68 43 2 - - 2 - Emulsion for hardboard and other flat-stock coatings
low VOC, pigment dispersing capability

Excellent hot block resistance, excellent Emulsion to be applied with roller or curtain coaters
Joncryl® 1992 White emulsion 43.0 8.5 125 > 60 18 78 2 - - 2 -
sandability, good water resistance on, e.g., door skins

Radiation-curable systems
Good hardness development, good water
Joncryl® Pro 1537 Translucent emulsion 46.0 8.4 250 45 49 46 2 1 - 2 - Hard emulsion for wood and board primers
and chemical resistance, good adhesion

Good water resistance, good intercoat adhesion Emulsion for economic industrial wood and board
Joncryl® 8223 Semi-translucent emulsion 30.0 8.2 250 <5 100 21 2 - - 2 -
with 100% UV systems, good pigment wetting primers

Very fast drying, excellent block resistance


Joncryl® 8224 Translucent emulsion 45.0 7.7 70 10 53 - 2 2 1 2 1 Emulsion recommended for primers and topcoats
and stackability

Excellent clarity, very fast drying, good block Low VOC emulsion for use in fast industrially applied
Joncryl® 8225 Translucent emulsion 45.0 7.8 75 <5 57 - 2 2 1 2 1
resistance, good stackability, low VOC clear lacquers for furniture and flat-stock

Excellent scratch resistance and block


Emulsion for industrial interior wood coatings on fast
Joncryl® 8226 Semi-translucent emulsion 42.0 7.9 75 20 36 - resistance, fast drying, good chemical 1 2 1 2 1
lines

Performance additives
resistance and clarity

Good isolating properties on tropical Flexible emulsion for anti-bleeding industrial primer
Joncryl® 8227 Semi-translucent emulsion 40.0 9.0 160 <0 12 7 2 - 2 2 1
hardwoods and engineered wood types for tropical hardwoods and engineering wood

Emulsion for exterior and interior stains, high-gloss


Low VOC, good appearance and grain
Joncryl® 8228 Semi-translucent emulsion 48.0 7.9 600 <5 68 <0 - 1 2 2 2 brushing enamels, as well as industrially applied
enhancement
timber coatings

Colloidal dispersions
Excellent penetration, minimal grain raising,
Joncryl® 95 E Translucent emulsion 30.0 8.0 100 20 70 43 - - 2 2 2 Emulsion for quick-drying interior stains, wood sealers
excellent clarity and sandability, fast drying

Solvent-based systems
High viscosity at low solids content, Emulsion for use as a thickener in various
Joncryl® 663 Semi-translucent emulsion 40.0 6.2 450 - 131 30 high transfer with roller coaters, good flow 2 - - 2 2 acrylic water-based paints, especially for rollercoat
and leveling, good pigment wetting applications

High viscosity at low solids content, Emulsion for use as a thickener in various
Joncryl® 661 Semi-translucent emulsion 44.0 2.1 60 - 154 70 high transfer with roller coaters, good flow 2 - - 2 2 acrylic water-based paints, especially for rollercoat
and leveling, good pigment wetting applications

Formulation additives
New product
Water-based systems
12 Water-based systems
Protecting what’s around us
Water-based systems
Protecting what’s around us 13

Joncryl® and Luhydran®


self-crosslinking acrylic emulsions

Natural oil-based polyols


1 Suited 2 Highly recommended

Coating layer Application segment


Solids by Viscosity Acid number on
Product Appearance pH MFT [°C] Tg [°C] Key properties Primer/ Detailed application
weight [%] [mPa·s] solids [mg KOH/g] Topcoat Stains Furniture Flooring
sealer

Self-crosslinking acrylic emulsions


Economical, good clarity and warmth of wood,
Emulsion developed for use in industrial wood
Joncryl® 8322 Semi-translucent emulsion 41.0 8.6 500 30 18 - quick hardness development, good chemical

Crosslinkers
1 2 - 2 1
coatings
resistance, hardness, and sandability

Emulsion for high-quality interior clear and pigmented


High clarity and chemical resistance, excellent
Joncryl® 8330 Semi-translucent emulsion 38.0 8.1 50 33 21 - 1 2 - 2 1 water-based wood coatings blending partner for UV
block, good hardness development
dispersions

Excellent chemical and scratch resistance,


Emulsion developed for use in industrial wood
Joncryl® 8331 Semi-translucent emulsion 38.5 8.1 80 59 17 - very good hot block resistance, quick hardness 1 2 - 2 1
coatings
development, excellent sandability

Good scratch resistance, superior plasticizer Emulsion for interior coatings with superior plasticizer

Radiation-curable systems
Joncryl® 8333 White emulsion 45.0 7.2 250 58 24 - 1 2 - 2 1
and hand cream resistance and hand cream resistance

Fast drying, good block resistance, good


Emulsion for industrial applied clear and pigmented
Joncryl® 8336 Semi-translucent emulsion 40.0 8.0 75 <5 25 - blending partner to reduce the solvent demand, - 2 - 2 -
finishes for primer and topcoat
balanced chemical resistance

Good chemical resistance, good scratch and


Joncryl® 1980 E Semi-translucent emulsion 39.0 8.6 150 56 18 - - 2 - 2 2 Emulsion for interior wood applications
mar resistance, low VOC, natural look

High chemical resistance, excellent grain


Luhydran® A 849 S2 White emulsion 44.0 7.0 200 39 20 37 1 2 - 2 1 Second-generation emulsion for interior wood coatings
enhancement and scratch resistance

Good block resistance, clarity, film forming,


Luhydran® A 875 S White emulsion 44.0 7.0 60 60 21 - sandability, excellent chemical, plasticizer, and - 2 - 2 2 All-round emulsion for industrial interior wood coatings

Performance additives
scratch resistance

Solvent-based systems
Formulation additives
New product
Water-based systems
14 Water-based systems
Protecting what’s around us
Water-based systems
Protecting what’s around us 15

Joncryl® OH-functional
acrylic emulsions

Natural oil-based polyols


1 Suited 2 Highly recommended

Coating layer Application segment


Solids by Viscosity Hydroxyl number on Acid value on
Product Appearance pH MFT [°C] Key properties Primer/ Detailed application
weight [%] [mPa·s] solids [mg KOH/g] solids [mg KOH/g] Topcoat Stains Furniture Flooring
sealer

OH-functional acrylic emulsions


Hydroxy-functional dispersion, excellent
Hydroxy-functional emulsion for ambient-curing
Joncryl® OH 8311 Translucent emulsion 42.0 7.6 40 50 120 30 adhesion, resistance to water, chemicals

Crosslinkers
- 2 - 2 2
water-based 2K PU wood coatings
and solvents

Hydroxy-functional dispersion, long pot life up


to 6 hours, low coalescing solvent demand, Hydroxy-functional emulsion for water-based 2K PU
Joncryl® OH 8312 White emulsion 44.0 8.2 300 48 100 9 excellent chemical resistance, good scratch - 2 - 2 2 systems applied for high-quality furniture and floor
resistance, good hardness development, block coatings
resistance, and adhesion

Hydroxy-functional dispersion, long pot life up


to 6 hours, low coalescing solvent demand, Hydroxy-functional emulsion for water-based 2K PU

Radiation-curable systems
Joncryl® OH 8313 White emulsion 45.0 2.7 360 48 100 9 excellent chemical resistance, good scratch - 2 - 2 2 systems applied for high-quality furniture and floor
resistance, good hardness development, block coatings
resistance, and adhesion

Hydroxy-functional dispersion, good chemical Economical emulsion for furniture foils or heat-curable
Luhydran® S 938 T White emulsion 45.0 2.0 25 60 100 - - 2 - 2 1
resistance and blocking coatings and 2K PU wood coatings

Performance additives
Solvent-based systems
Formulation additives
Water-based systems
16 Water-based systems
Protecting what’s around us
Water-based systems
Protecting what’s around us 17

Joncryl® PU dispersions
and PU acrylic hybrids

Natural oil-based polyols


1 Suited 2 Highly recommended

Coating layer Application segment


Solids by weight Acid number on solids
Product Appearance pH Viscosity [mPa·s] MFT [°C] Key properties Primer/ Detailed application
[%] [mg KOH/g] Topcoat Stains Furniture Flooring
sealer

Polyurethane dispersions and polyurethane acrylic hybrids


Solvent-free, intrinsic matt PU dispersion for
Especially suited for matt soft touch 1K PU coatings
Joncryl® U 4180 White emulsion 35.0 10.0 1,750 <0 - soft touch, flexible, and elastic, suitable for 2K

Crosslinkers
- - - - -
or as matting aid
application

Solvent-free, aliphatic water-based poly­


urethane dispersion, very good Taber®1 abrasion Ecological dispersion for high-quality water-based
Joncryl U 4190
®
Translucent emulsion 36.5 8.5 80 23 - - 2 - 2 2
resistance, film toughness, and chemical clear coats on wooden flooring
resistance, excellent adhesion

Aqueous polyurethane dispersion, elastic


Blending partner for acrylic primers and topcoats
Joncryl® U 4320 White emulsion 40.0 8.0 15–95 0 - behavior over a wide temperature range, high 1 2 - 2 -
with improved elasticity and adhesion
gloss and good adhesion

Radiation-curable systems
Cost-effective, solvent-free, excellent
Ecological aliphatic polyurethane acrylic hybrid for
Joncryl® HYB 6336 Translucent emulsion 38.0 8.0 50 40 26 ­appearance, clarity, chemical as well as ­scratch 1 2 - 2 2
high-quality water-based clear coats on wood
resistance, good grain enhancement

Solvent-free, high solid polyurethane


Hybrid for high-quality water-based clear coats
acrylic ­hybrid with excellent Taber®1 abrasion
Joncryl HYB 6340
®
White emulsion 40.0 7.6 50 45 12 1 2 - 1 2 on wood for parquet flooring applications and
­resistance, fast hardness development,
high-performance furniture topcoats
good chemical resistance

Performance additives
Solvent-based systems
Formulation additives
New product
®1 = Registered trademark of Taber Acquisitions Corporation
Water-based systems
18 Water-based systems
Protecting what’s around us
Water-based systems
Protecting what’s around us 19

Joncryl® and Laropal® grinding resins,


waxes, and crosslinker solutions

Natural oil-based polyols


Solids by weight Viscosity Acid value
Product Appearance pH Tg [°C] Mw Key properties Detailed application
[%] [mPa·s] [mg KOH/g]

Resin solutions for water-based coatings


Joncryl® HPD 71 E Clear liquid 31.0 8.5 200 221 120 17,000 Excellent viscosity stability, pigment wetting, and color development Very-low VOC MEA-neutralized resin solution of Joncryl® HPD 671

Very-low VOC ammonia-neutralized resin solution for highly concentrated


Joncryl® HPD 96 E Clear liquid 31.0 8.5 2,000 233 105 16,500 Excellent viscosity stability, pigment wetting, and color development
pigment dispersions

Crosslinkers
Joncryl® 8078 Clear liquid 32.0 8.3 1,750 224 101 8,500 Excellent pigment wetting, resolubility, compatibility, flow (ammonia solution of Joncryl® 678) Solution-stable pigment pastes

Grinding resins for water-based coatings


Laropal® LR 9008 Yellowish liquid 35.0 7.5–8.5 2,000–15,000 - - - Excellent pigment wetting, broad compatibility Solution of a modified urea-aldehyde resin for universal pigment dispersions

Radiation-curable systems
Solids by weight Viscosity Melting point
Product Product type Appearance pH Key properties Description and application
[%] [mPa·s] of wax [°C]

Waxes and crosslinker solutions


Zinc Oxide Solution #1 Additive Clear solution 25.0 11.4 5 - Water resistance, drying, hardness Crosslinker for carboxy-functional acrylics to improve early resistance properties

Joncryl® Wax 35 Additive Semi-translucent emulsion 34.5 9.8 25 130 Improves scratch, slip, and block resistance Polyethylene wax to improve scratch resistance, slip, and block resistance

Performance additives
Solvent-based systems
Formulation additives
Water-based systems
Natural oil-based polyols
Protecting what’s around us 21

Natural oil-based polyols


Natural oil-based polyols

Crosslinkers
Further reducing the outputs of volatile organic compounds (VOC) helps to lower ­the
impact of emissions on our climate as well as to improve indoor air quality for end
consumers, especially in the area of flooring. BASF offers a broad portfolio of natural
oil-based polyols for water-based and high solid 2K PU indoor concrete coatings.
When assessed with our Sustainable Solution Steering method, this Sovermol® range

Radiation-curable systems
has been classified as Sustainability Accelerator, which contributes substantially to
sustainable development along the value chain.

Next performance level with renewables

Sovermol® 830 feedstock comprises more than 90%


renewable raw materials. It impresses with benefits

Performance additives
such as low viscosity, excellent hydrophobicity, cold
flexible performance, as well as improved cost perfor-
mance. Its profile of mechanical properties also en­-
ables this new polyol to lift formulations to the next
performance level.

Solvent-based systems
Formulation additives
Water-based systems
22 Natural oil-based polyols
Protecting what’s around us
Natural oil-based polyols
Protecting what’s around us 23

Sovermol®
natural oil-based polyols

Natural oil-based polyols


3 65–80% 4 81–100%

Renewable raw Medium OH Medium viscosity


Product Type Functionality Medium OH value Application/properties
material content equivalent [weight] [mPa·s]
Co-polyol for floorings (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improvement of glass transition temperature Tg;
Sovermol® 45 - Branched polyether 4.0 570 98 3,000
high crosslinking density; hydrophilic; improvement of chemical resistance

Co-polyol for floorings (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improvement of glass transition temperature;
Sovermol® 100 - Branched polyether 3.0 880 64 6,000 high crosslinking density, hydrophilic; improvement of chemical resistance; raw materials are registered in EU Directive 2002/72/EG resp. 2007/19/EC
as amended

Crosslinkers
Polyol for UV stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 80); hydrophobic; high saponification stability; excellent
Sovermol® 750 3 Branched polyether/polyester 3.0 315 178 1,100 (20 °C)
chemical resistance; hydrolysis stable; high Tg-polyol

Sovermol® 805 3 Branched polyether/polyester 3.5 170 330 3,500 Universal polyol; excellent impact resistance; shore D hardness (D ~ 70)

Sovermol 815
®
4 Branched polyether/polyester 3.5 215 260 1,600 Low-viscous universal polyol binder for pigment pastes and crack-bridging floorings; good chemical resistance, hydrophobic, good elastic, memory effect

Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; excellent flexibility at temperatures below 0 °C; good bonding
Sovermol® 818 4 Fatty acid polyester 2.6 236 238 750
properties

Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; good bonding properties; raw materials are registered in EU Directive

Radiation-curable systems
Sovermol® 819 4 Fatty acid polyester 2.6 240 234 850
2002/72/EG resp. 2007/19/EC as amended

Low-viscous universal workhorse polyol; extremely hydrophobic; good self-leveling properties; good bonding properties; raw materials are registered
Sovermol® 830 4 Branched oleochemical polyether/polyester 2.6 241 233 875
in EU Directive 2002/72/EG resp. 2007/19/EC as amended

Sovermol® 1005 4 Slightly branched aliphatic diol 2.2 122 460 800 (20 °C) Hydrophobic; plasticizer for polyol; soft elastic performance; raw materials are registered in EU Directive 2002/72/EG resp. 2007/19/EC as amended

Sovermol® 1014 4 Aliphatic triol 2.5 160 350 700 Soft elastic performance; raw materials are registered in EU Directive 2002/72/EG resp. 2007/19/EC as amended

Sovermol 1058
®
4 Fatty acid polyester - - - 5 (20 °C) Non-reactive diluent; VOC-free acc. to 2004/42/EU; hydrophobic; plasticizer for polyols

High-performance polyol for coatings, putties, and adhesives, low viscosity; extremely hydrophobic; hardness similar to epoxy systems; hard elastic
Sovermol® 1092 3 Branched polyether/polyester 2.8 283 198 800
performance; good self-leveling properties

Performance additives
Sovermol® 1093 3 Branched polyether/polyester 2.8 229 245 2,500 Polyol; high hardness; hydrophobic performance; hard elastic; water repellency

Sovermol® 1102 4 Slightly branched polyether/polyester 2.1 230 245 400 (20 °C) Universal co-polyol; gel time prolonger; reactive diluent hydrophobic; UV-stable; soft elastic performance

Sovermol 1140
®
4 Fatty acid polyester 2.7 210 267 1,000 Universal polyol for adhesives; gel time prolonger; hard flexible performance; hydrophobic

Solvent-based systems
Formulation additives
New product
Water-based systems
Crosslinkers
Protecting what’s around us 25

Natural oil-based polyols


Crosslinkers

Crosslinkers
Window frames and wall claddings suffer from weathering, floors from abrasion, and
high-gloss kitchen cabinets from scratches and cleaning agents. Since recoating and
repair is time and material consuming or even impossible, BASF has developed a range
of solvent- and water-based crosslinkers to raise coatings’ resistance to a higher level.
Among these offerings are some solvent-based crosslinkers such as selected Luwipal®,

Radiation-curable systems
Plastopal®, and Basonat® grades, which meet the basic sustainability standards in
the market. Our solutions for water-based systems, however, have been classified as
Sustainability Accelerators and contribute substantially to sustainable development
along the value chain already today.

Saving resources in water-based

Performance additives
2K PU system
The 2K PU system comprising the Joncryl® OH 8312
dispersion crosslinked with Basonat® HW 1180 PC
for glossy clear and pigmented furniture topcoats is
known to be very efficient. Even when crosslinked at
an NCO:OH ratio of 0.75, high chemical and scratch
resistance can be achieved enabling a significant
reduction in system costs.

Solvent-based systems
Formulation additives
Water-based systems
26 Crosslinkers
Protecting what’s around us
Crosslinkers
Protecting what’s around us 27

Luwipal® and Plastopal®


amino resins

Natural oil-based polyols


Etherifying Non-volatile Max. free form- Viscosity Platinum-cobalt Baking Reactivity
Product Key properties Solvent Description and applications
alcohol at 2 h, 125 °C aldehyde [%] [mPa·s] color number reactivity with acids

Melamine-formaldehyde-amino resins
Coatings based on Luwipal® 044 have very high mechanical resistance (scratch
Developed for application in acid-curable coatings where it is extraordinarily highly reactive; when
Luwipal® 044 n-Butanol - 96.0 0.1 2.0–5.0 < 50 Low High and abrasion) and chemical resistance to water, alcohol, coffee, and household
higher temperatures are applied the curing speed even exceeds that of urea-formaldehyde resins
cleaners; suitable for both furniture and floor coatings

Crosslinkers
Developed for use in combination with water-thinnable alkyd or acrylic resins for the formulation of A highly reactive resin that can be used as a crosslinker for highly reactive
Luwipal® 063 highly reactive baking finishes. Combined with solvent-containing resins, it can also be used to formulate Methanol Water 70.0 0.6 0.5–0.8 ≤ 50 High Low water-based coatings based on acrylic dispersions for furniture foils and
conventional baking finishes decorative foils and sheets

A highly reactive resin that can be used as a crosslinker for acid-curable systems
Developed to formulate acid-curable finishes as well as baking finishes. Because of the low viscosity,
Luwipal® 066 Methanol Solvent-free 95.0 0.6 2.0–6.0 ≤ 50 Low High and water-based coatings based on acrylic dispersions for furniture foils and
this resin is particularly suited for high-solids coatings
decorative foils and sheets

A low-formaldehyde highly reactive resin that can be used as a crosslinker for


Developed to formulate acid-curable finishes as well as baking finishes. Because of the low viscosity,
Luwipal® 066 LF Methanol Solvent-free 95.0 0.3 2.0–6.0 ≤ 50 Low High acid-curable systems and water-based coatings based on acrylic dispersions for
this resin is particularly suited for high-solids coatings

Radiation-curable systems
furniture foils and decorative foils and sheets

A medium-reactive resin that can be used as a crosslinker for both water-based


Developed for use as a crosslinker for water-based coatings based on alkyd resins or acrylic dispersions Methanol/
Luwipal® 069 Methanol 81.0 1.5 2.5–3.5 ≤ 50 Medium to high Medium coatings based on alkyd resins or acrylic dispersions and in combination with
and, e.g., in combination with saturated polyesters for solvent-based coatings ethanol
saturated polyesters for a wide variety of furniture foil applications

A medium reactive resin for furniture foils and decorative foils or sheets. Luwipal®
Developed for use as a crosslinker for both water-based coatings based on alkyd resins or acrylic
Luwipal® 070 Methanol n-Butanol 81.0 <1 6.0–10.0 ≤ 50 Medium Medium 070 is soluble in a wide range of diluents used in the coatings industry for both
dispersions and, e.g., in combination with saturated polyesters for solvent-based coatings
water- and solvent-based formulations

Developed for use as a crosslinker for both water-based coatings based on acrylic dispersions or A medium reactive resin for furniture foils and decorative foils or sheets with good
Luwipal® 072 Methanol i-Butanol 75.0 <1 4.0–7.0 ≤ 50 High Medium
alkyds and, e.g., in combination with saturated polyesters for solvent-based coatings compatibility

A medium reactive resin for furniture foils and decorative foils or sheets with good
Luwipal® 073 Developed for use as a crosslinker for water-based coatings based on acrylic dispersions or alkyds Methanol Water 80.0 < 0.5 3.0–5.0 ≤ 50 High Medium
compatibility

Performance additives
Urea-amino resins
For use in acid-curable wood finishes, a large proportion of acid has to be added
Contains little free formaldehyde (max. 0.3%) and low amounts of solvent, it is especially suitable for use to the resin; a suitable catalyst is p-toluenesulfonic acid in proportions of up
Butanol/
Plastopal® H 85 B in low-odor acid-curable coatings. The resin contains a maximum of 5% n-Butanol; this has advantages in n-Butanol 88.0 0.3 3.0–6.0 ≤ 50 Low Medium to 5%, expressed in terms of the total binder; with lower additions of acid, the
ethanol
some countries with regard to the labeling of goods reactivity is relatively low; films based on Plastopal® H 85 EB have high gloss even
in white-pigmented acid-curable coatings

Used in highly reactive baking and rapidly curing acid-curable finishes; it contains very low amounts of free Films are outstandingly fast to light, hard, and resistant to abrasion, particularly
Plastopal® H 73 IB Isobutanol Isobutanol 61.0 0.4 4.0–7.0 ≤ 50 Medium High
formaldehyde and releases low amounts of formaldehyde during curing suitable for parquet floor coatings

Solvent-based systems
Cured films are pale, fast to light, and relatively flexible. If necessary, the flexibility can be increased by For use in acid-curable wood coatings, a large proportion of acid has to be added
Plastopal® EBS 400 I Isobutanol Isobutanol 61.0 ≤ 1.0 1.4–1.7 ≤ 50 Medium to low Medium
adding a polymer dispersion that is resistant to acids (Luhydran® S 938 T) to the resin

Plastopal® EBS 400 B Universal amino resins with low baking reactivity and medium acid reactivity n-Butanol Butanol 61.0 0.8 1.4–1.7 < 100 Low Medium Urea formaldehyde amino resins for standard wood applications

Films are outstandingly fast to light, hard, and resistant to abrasion; therefore,
Plastopal® BTB can be used as sole binder. Adding up to 10% of a Plastopal® EBS resin reduces curing time
Plastopal® BTB n-Butanol Butanol 61.0 ≤ 0.5 1.6–2.4 ≤ 50 Low Medium acid-curable coatings based on Plastopal® BTB are particularly suitable for
without notably impacting the flexibility of the cured film
parquet floor coatings

Tailored for acid-curable coatings for wooden panels, fiberboards, and decorative
Plastopal® BTM Water-thinnable, low backing reactivity as well as medium to high acid reactivity Methanol Water - < 2.1 2.5–3.7 ≤ 50 Low Medium to high
paper laminates

Tailored for acid-curable coatings with low release of formaldehyde for wooden
Plastopal® BTW Water-soluble, low backing reactivity as well as medium to high acid reactivity, low formaldehyde emissions Methanol Water 77.0 < 0.8 1.0–1.5 ≤ 50 Low Medium to high
panels, fiberboards, and decorative paper laminates

Formulation additives
Water-based systems
28 Crosslinkers
Protecting what’s around us
Crosslinkers
Protecting what’s around us 29

Basonat® polyisocyanates
for 2K PU coatings

Natural oil-based polyols


Product Type Key properties and applications Solids by weight [%] Viscosity [mPa·s] Solvent NCO [%]

Polyisocyanates for conventional 2K PU coatings


Basonat® HB 100 100 2,500–4,000 - 22.0–23.0

Basonat® HB 175 MP/X HDI biuret Basonat® HB polyisocyanates for general use in high-performance wood coatings 75 130–300 Methoxypropyl acetate/Xylene 1:1 16.0–17.0

Crosslinkers
Basonat® HB 275 B 75 100–180 n-Butyl acetate 16.0–17.0

Basonat HI 100
®
100 2,500–4,000 Solvent-free (allowing for broad range solvents) 21.5–22.5

Basonat HI 145 B
®
45 < 10 n-Butyl acetate 9.7–10.1
Basonat® HI aliphatic polyisocyanates for highly crosslinked, lightfast, and weather-resistant 2K PU coatings;
Basonat HI 180 B/S
®
HDI Isocyanurate compatible and crosslinkable with most hydroxy-acrylic resins, e.g., Joncryl® grades and polyesters resins containing 80 130–250 n-Butly acetate/Solvesso 100 1:1
®2
16.9–18.3
hydroxyl groups
Basonat HI 190 B/S
®
90 450–600 n-Butyl acetate/Solvesso 100 1:1
®2
19.3–20.3

Basonat HI 290 B
®
90 400–600 n-Butyl acetate 19.3–20.3

Radiation-curable systems
Polyisocyanates for high solids and water-based 2K PU coatings
Basonat® HA 1000 100 900–1,500 - 21.0–23.0
Low-viscous polyisocyanates for high solid solvent-based 2K PU coatings. It can also be combined with
Basonat® HA 2000 HDI-allophanate 100 500–900 - 18.5–21.5
water-emulsifiable Basonat® HW types and secondary dispersions for water-based 2K PU wood coatings
Basonat HA 3000
®
100 200–400 - 19.0–20.0

Low-viscous trimer for high solid 2K PU coatings without limitation in chemical resistance and reactivity. It can also
Basonat® HI 2000 HDI isocyanurate low-viscous be combined with water-emulsifiable Basonat® HW types and secondary dispersions for water-based 2K PU wood 100 900–1,500 - 22.5–23.5
coatings

Hydrophilic, fast-drying polyisocyanate for general use in water-based 2K PU coatings for low VOC systems providing
Basonat® HW 1000 - 100 2,000–6,000 - 16.5–17.5
excellent chemical resistance. For interior furniture and flooring applications

Performance additives
Basonat® HW 1180 PC - Diluted version of Basonat® HW 1000 for faster incorporation in water-based 2K PU systems 80 450–850 Propylene carbonate 13.2–14.0

Easy-mixing version of Basonat HW 1000 providing a combination of fast-drying and easy mixing, e.g.,
®
Basonat® HW 2000 - 100 1,500–3,000 - 17.5–18.5
for professional use

All-purpose, hydrophilic polyisocyanate for general use in water-based 2K PU coatings for low VOC systems with
Basonat® HW 2100 - 100 2,000–3,600 - 16.9–17.9
balanced properties regarding miscibility, resistance, and reactivity for interior furniture and flooring applications

A special polyisocyanate for fast-drying 2K PU systems, fast hardness development with primary and secondary
Basonat® HW 3180 B - 80 600–1,200 Butyl acetate 12.0–13.0
dispersions. In primary dispersions significantly enhanced pot life compared to standard systems

Solvent-based systems
Formulation additives
New product
®2 = Registered trademark of Exxon Mobil Corporation
Water-based systems
Radiation-curable systems
Protecting what’s around us 31

Natural oil-based polyols


Radiation-curable systems

Crosslinkers
Coatings curable by UV radiation, electron beam, or excimer are a growing field in the
area of furniture and flooring. The advantages are obvious: instant curing, low energy
consumption, direct further processing, high scratch and chemical resistance, as well as
low volatile organic compound (VOC) content. BASF offers radiation-curable resins from
the Laromer® series as well as photoinitiators from the Irgacure® series for a broad range

Radiation-curable systems
of applications. Our Laromer® range has been classified as Sustainability Accelerators
with substantial contribution to sustainable development along the value chain.

Powerful alternatives to BPA-based Increased production efficiency


epoxy acrylates
UV water-based resins allow for increased production
Laromer® PR 9119 is one of the first products in the efficiency vs. conventional dispersions and solvent-­

Performance additives
market that achieves performance levels comparable based coatings due to the fast curing in UV light. In
to conventional epoxy acrylates – offering a powerful BASF’s UV water-based portfolio, Laromer® UA 9095
alternative to coatings based on bisphenol A (BPA). ­is a good all-round resin showing good grain enhance-
The substitution of BPA in coatings is already today ­the ment, low yellowing, high chemical resistance, and
requirement for several applications and will become good physical drying in clear coats. Also for pig­mented
more and more important in different areas in future. coatings, the product shows very good properties and
Additionally, Laromer® UP 9096 and Laromer® UP 9118 can be efficiently cured with Irgacure® 819 DW.
are efficient alternatives to BPA-based resins.

Solvent-based systems
Speedy curing, low odor

Irgacure® 127 and Irgacure® 754 are low VOC, thus


low-odor photoinitiators with Irgacure® 127 being the
best in class in cure speed.

Formulation additives
Water-based systems
32 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 33

Laromer® epoxy
and polyester acrylates

Natural oil-based polyols


1 Low 2 Medium 3 Good 4 Excellent

Hydroxy value
Type of thinner Functionality Viscosity Chemical Europe USA Canada Japan China Korea
Product Type of resin [mg KOH/g] DIN Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] resistance REACH TSCA DSL ENCS IECSC ECL
EN ISO 4629

Epoxy acrylates
Laromer® LR 8765 R Aliphatic None 2.0 0.6–1.2 330 1 3 3 1 Partially water-soluble, flexible, highly reactive 1 1 1 1 1 1

Laromer LR 8986
®
Aromatic None 2.4 3–6 170 Low viscosity, free of diluents, very good chemical resistance

Crosslinkers
4 3 2 4 1 1 1 1 1 1

Laromer® LR 9019 Aromatic None 2.4 12–20 175 3 3 4 4 Highly reactive, very good chemical resistance 1 1 - - 1 -

Laromer® LR 9023 Aromatic DPGDA [15%] 2.4 2–5 150 3 2 3 4 Diluted version of Laromer® LR 9019 1 1 - - 1 -

Laromer® EA 9081 Aromatic Monomer mix [75%] 2.5 0.2–0.5 126 4 2 3 4 Very low viscosity, easy to handle 1 1 1 1 1 1

Laromer EA 9097
®
Aromatic TPGDA [40%] 2.0 1.5–3.0 157 4 2 2 4 Low viscosity, very good chemical resistance 1 1 1 1 1 1

Laromer EA 9101
®
Soybean oil acrylate None 3.8 13–20 3.5 1 3 1 1 Flexibilizing co-resin, outstanding pigment wetting 1 1 1 1 1 -

Radiation-curable systems
Polyester acrylates
Laromer® PE 55 F - None 3.1 25–45 70 2 3 3 3 Well-balanced properties with high toughness 1 1 1 1 1 1

Laromer PE 56 F
®
- None 3.1 20–40 70 2 3 3 3 Improved compatibility with reactive diluents (versus Laromer PE 55 F)
®
1 1 1 1 1 1

Laromer PE 46 T
®
- TPGDA [30%] 2.8 2.0–2.5 60 2 2 2 3 Diluted version of Laromer PE 56 F
®
1 1 1 1 1 1

Laromer® LR 9004 - None 2.6 20–50 60 2 3 3 3 Tough with good adhesion, good chemical resistance 1 1 - - 1 -

Laromer® PE 9024 - None 2.6 10–30 70 2 3 3 3 Compatible with nitrocellulose 1 1 - - 1 -

Laromer® PE 9045 - TPGDA [20%] 2.5 2–7 60 2 3 3 3 Diluted version of Laromer® LR 9004 1 1 - - 1 -

Performance additives
Laromer PE 44 F
®
- None 3.0 2–5 80 1 3 2 3 Free of diluents, low viscosity, low odor, flexible 1 1 - 1 1 -

Laromer LR 8800
®
- None 3.0 4–8 80 3 2 2 4 Hard, chemical resistant, low odor 1 1 - 1 1 1

Laromer® LR 8907 - DPGDA [25%] 1.9 0.5–2.0 120 1 4 2 3 Highly flexible, use in combination with hard, less flexible binders 1 - - - 1 -

Laromer® LR 8981 - None 3.0 4–14 80 1 3 4 3 Highly reactive with good sanding properties 1 1 - - 1 -

Laromer® PE 9032 Modified None 4.0 15–25 50 2 3 3 3 Abrasion-resistant in parquet applications (falling sand) 1 1 - - - -

Laromer PE 9074
®
- None 3.2 7–13 50 2 3 3 3 Good adhesion, tough, reactive, resistant to chemicals 1 1 - 1 1 -

Laromer PE 9084
®
- None 3.3 16–26 70 2 3 3 3 Medium-viscous version of Laromer PE 9074
®
1 1 - 1 1 -

Solvent-based systems
Laromer® PE 9079 - None 3.4 2–4 (60 °C) 60 2 3 3 3 High-viscous version of Laromer® PE 9074 1 1 - 1 1 -

Laromer® PE 9105 - None 4.0 0.15–0.4 60 2 2 2 3 Good substrate wetting, low viscosity 1 1 1 1 1 1

Laromer® PE 9121 - None 3.4 7–13 44 2 3 3 3 Low yellowing, good abrasion resistance (falling sand) 1 - - - 1 1

Laromer PE 9123
®
- None 3.0 2–5 50 1 3 2 3 Low viscous, flexible, low yellowing 1 - - - 1 1

For further regulatory information, please contact: ED-PSR@basf.com

Formulation additives
New product
Water-based systems
34 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 35

Laromer® polyether and


amine-modified polyether acrylates

Natural oil-based polyols


1 Low 2 Medium 3 Good 4 Excellent

Hydroxy value
Type of thinner Functionality Viscosity Chemical Europe USA Canada Japan China Korea
Product Type of resin [mg KOH/g] DIN Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] resistance REACH TSCA DSL ENCS IECSC ECL
EN ISO 4629

Polyether acrylates
Laromer® PO 33 F Alkoxylated TMP triacrylate None 3.0 0.07–0.13 30 3 1 1 3 Low yellowing, low-odor diluent 1 1a) - 1 1 -

Laromer LR 8863
®

Crosslinkers
Ethoxylated TMP triacrylate None 3.0 0.05–0.1 10 3 1 1 3 Lower in viscosity than Laromer® PO 33 F 1 1 1 1 1 1
(TMPEOTA)

Propoxylated glycerin
Laromer® GPTA None 3.0 0.07–0.13 30 3 1 1 3 More hydrophobic than Laromer® LR 8863 1 1 1 1 1 1
triacrylate

Laromer® PO 43 F - None 2.4 0.2–0.4 100 3 2 2 3 Chemical resistance, all-round resin 1 1 1 1 1 1

Laromer® LR 8967 - None 2.6 0.12–0.19 50 3 2 2 3 Low-viscous version of Laromer® PO 43 F 1 1 1 1 1 1

Laromer® LR 8982 - None 2.7 0.15–0.3 70 3 2 2 2 Partially water-soluble (spray viscosity adjustable) 1 1 - 1 1 1

Radiation-curable systems
Laromer® LR 9007 - None 4.0 0.8–1.5 130 3 2 3 4 Lowest amount of extractables, scratch-resistant 1 1 - 1 1 -

Propoxylated (2.0)
Laromer® PO 9102 None 2.0 0.01–0.02 1 2 2 1 2 Good substrate and pigment wetting, low viscosity 1 1 1 1 1 1
neopentyl glycol diacrylate

Ethoxylated bisphenol-A
Laromer® PO 9114 None 2.0 0.8–1.6 18 4 2 3 3 High hardness, chemical resistance 1 1 - 1 1 1
diacrylate

Amine-modified polyether acrylates


Laromer® PO 9103 - None 2.0 2.5–4.0 163 2 3 3 2 Highly reactive, good adhesion to plastic 1 1 1 - 1 1

Laromer® PO 9106 - None 3.4 2.5–3.5 112 1 2 4 3 Highly reactive, good pigment / filler wetting 1 1 - - 1 -

Performance additives
Laromer® PO 77 F - None 2.9 1.0–3.0 120 1 3 3 3 Reactive all-round resin, good sanding properties 1 1 - - 1 -

Laromer PO 9067
®
- None 2.8 0.4–0.7 50 2 2 3 3 Reactive, good substrate wetting 1 - - - 1 -

Laromer PO 84 F
®
- None 3.5 0.4–0.7 50 2 2 3 3 Reactive, good pigment wetting 1 1 a)
- - 1 1

Laromer PO 94 F
®
- None 3.5 0.3–0.6 55 2 3 4 4 Highly reactive, very good chemical resistance 1 1 1 - 1 1

Laromer® LR 8997 - None 3.4 0.3–0.5 55 2 2 4 3 Highly reactive, very low in color 1 - - - 1 -

Laromer® PO 83 F - None 2.8 0.09–0.13 30 2 2 3 3 Good chemical resistance, low viscosity 1 1a) - - 1 -

Laromer LR 8889
®
- None 2.6 0.09–0.14 60 1 3 3 3 Reactive, low viscosity, flexible 1 - - - 1 -

Solvent-based systems
Laromer LR 8869
®
- None 2.8 0.06–0.11 30 2 2 3 3 Harder than Laromer LR 8889
®
1 1 - - 1 -

Laromer LR 8996
®
- None 2.9 0.05–0.09 30 2 2 3 3 Reactive, very low color and viscosity 1 1 - - 1 -

For further regulatory information, please contact: ED-PSR@basf.com


a) SNUR = significant new use rule

Formulation additives
New product
Water-based systems
36 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 37

Laromer® urethane
and water-based acrylates

Natural oil-based polyols


1 Low 2 Medium 3 Good 4 Excellent

Hydroxy value
Type of thinner Functionality Viscosity Chemical Europe USA Canada Japan China Korea
Product Type of resin [mg KOH/g] DIN Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] resistance REACH TSCA DSL ENCS IECSC ECL
EN ISO 4629

Urethane acrylates
Laromer® UA 19 T Aliphatic TPGDA [35%] 2.0 14–32 10 2 3 1 1 Elastic, low yellowing, flexible at temperatures below 0 °C 1 1 1 - 1 1

Laromer UA 9030
®
Aliphatic Laromer LR 8887 [30%]
®
1.7 80–150 12 Highly elastic, low yellowing, good adhesion

Crosslinkers
1 4 1 1 1 1 1 - 1 -

Laromer® LR 8987 Aliphatic HDDA [30%] 2.3 4–6 11 3 2 2 3 Scratch- and weather-resistant, for outdoor applications 1 1 - - - -

Laromer® UA 9029 Aliphatic Butyl acetate [30%] 2.4 0.3–1 5 2 2 3 3 Monomer-free version of Laromer® LR 8987 1 1 - - - -

Laromer® UA 9033 Aliphatic Laromer® LR 8887 [30%] 1.7 15–25 6 1 4 3 2 Highly elastic, reactive, good adhesion, low shrinkage 1 1 1 - 1 -

Laromer UA 9047
®
Aliphatic Butyl acetate [30%] 8.0 2–7 10 3 2 1 4 Physical drying, best performance when cured at high temperature 1 - - - - -

Laromer UA 9048
®
Aliphatic DPGDA [25%] 6.5 10–20 10 4 1 3 4 Excellent scratch and abrasion resistances, highly functional 1 1 - 1 - 1

Radiation-curable systems
Laromer® UA 9050 Aliphatic Butyl acetate [20%] 8.0 1.5–5 10 4 1 3 4 Lowest yellowing, excellent scratch resistance 1 1 - 1 - 1

Laromer® UA 9072 Aliphatic TBCH [30%] 1.7 2–15 (60 °C) 6 1 4 1 2 Extremely flexible, best strain-stress behavior 1 - - - - -

Laromer® UA 9089 Aliphatic - 2.0 10–30 3 2 3 2 2 High elasticity, excellent PVC adhesion, and weather resistance 1 1 1 - 1 -

Laromer UA 9065
®
Aromatic DPGDA [35%] 2.0 7–9 5 2 4 4 2 Very reactive, very flexible, good abrasion resistance (falling sand) 1 - - - - -

Laromer UA 9073
®
Aromatic - 2.0 2–15 (60 °C) 9 2 3 2 2 Flexible and tough with high viscosity 1 1 1 1 1 1

Performance additives
Type of thinner Functionality Viscosity pH value DIN Chemical Europe USA Canada Japan China Korea
Product Type of resin Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] ISO 976 EN resistance REACH TSCA DSL ENCS IECSC ECL

Water-based acrylates
Laromer® PE 22 WN Polyester acrylate emulsion Water [50%] 2.2 0.15–0.5 pH 4.0–6.0 2 2 2 4 Hard, excellent chemical resistance, good sanding properties 1 1 - - 1 1

Laromer PE 55 WN
®
Polyester acrylate emulsion Water [50%] 2.2 0.25–0.65 pH 4.0–6.0 2 3 3 3 Flexible, easy to matt, adhesion to PVC 1 1 - - 1 1

Aliphatic urethane acrylate


Laromer® LR 8949 Water [60%] 1.7 0.015–0.18 pH 7.0–9.0 2 3 2 4 Good grain enhancement, very good chemical and weather resistance 1 1 - - - -
dispersion

Aromatic urethane

Solvent-based systems
Laromer® LR 8983 Water [60%] 0.7 0.05–0.3 pH 6.0–8.0 2 4 2 2 Excellent physical-drying properties, easy to formulate 1 1 - 1 - -
acrylate dispersion

Aromatic urethane
Laromer® LR 9005 Water [60%] 2.0 0.02–0.25 pH 7.0–9.0 4 2 2 4 Excellent scratch and chemical resistance 1 1 1 - - 1
acrylate dispersion

Aromatic urethane
Laromer® UA 9060 Water [60%] 2.0 0.005–0.15 pH 7.0–9.0 4 2 2 4 Very good chemical and scratch resistance, fast drying, very hard 1 1 1 - - 1
acrylate dispersion

Laromer® UA 9064 Urethane acrylate dispersion Water [62%] 2.6 0.02–0.25 pH 6.5–7.5 4 2 2 4 Low-yellowing version of Laromer® UA 9060 1 1 - - - -

Laromer® UA 9095 Urethane acrylate dispersion Water [60%] 2.2 0.05–0.5 pH 7.3–8.3 4 2 2 4 Good grain enhancement on wood, excellent adhesion to PVC 1 1 - - - -

Laromer® WA 9057 Acrylic UV dispersion Water [64%] - 0.01–0.2 pH 7.6–8.2 3 3 2 3 Good chemical and scratch resistances, excellent block resistance 1 1 1 1 - 1

Formulation additives
Laromer® UA 9059 Aliphatic urethane acrylate Water [30%] 1.8 6.0–11.0 pH 6.5–8.0 1 4 3 1 Excellent adhesion on wood, very flexible, excellent coin-test results 1 1 - - - 1

For further regulatory information, please contact: ED-PSR@basf.com

New product
Water-based systems
38 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 39

Laromer® unsaturated
polyester and specialties

Natural oil-based polyols


1 Low 2 Medium 3 Good 4 Excellent

Hydroxy value
Type of thinner Functionality Viscosity Chemical Europe USA Canada Japan China Korea
Product Type of resin [mg KOH/g] DIN Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] resistance REACH TSCA DSL ENCS IECSC ECL
EN ISO 4629

Unsaturated polyesters
Laromer® UP 35 D Unsaturated polyester DPGDA [45%] 3.5 3.0–6.0 11 2 3 2 3 Good chemical resistance, good sanding properties 1 1 1 1 1 1

Laromer UP 9096
®
Unsaturated polyester GPTA* [60%] 4.8 5.0–10.0 26 Good leveling, high gloss

Crosslinkers
2 2 2 3 1 1 1 1 1 1

Laromer® UP 9115 Unsaturated polyester TPGDA [38%] 3.5 13.0–19.0 8 2 3 2 3 Balanced mechanical profile 1 1 1 - 1 1

Laromer® UP 9118 Unsaturated polyester DPGDA / TMPTA [42%] 4.5 26.0–31.0 7 3 1 3 3 Hard, good chemical resistance 1 1 1 1 1 1

Special radiation-curable products


Laromer® LR 9013 Inert resin solution None 3.0 45–70 25 3 1 1 2 Excellent pigment wetting properties, low shrinkage 1 1 1 1 1 1

Laromer® LR 8985 Inert resin solution None 3.0 60–80 25 3 1 1 2 More hydrophobic than Laromer® LR 9013 1 1a) - 1 1 -

Radiation-curable systems
Nano-modified polyether
Laromer® PO 9026 N None 1.5 0.6–1.5 - 4 1 2 3 Contains 50% nano particles, very good scratch resistance 1 1 - 1 1 1
acrylate

Laromer® PR 9052 Polyester resin TMPTA [60%] 6.0 4–8 - 3 1 2 3 Abrasion-resistant in flooring application (S42, S33), hard, scratch-resistant 1 1 1 1 1 1

Laromer® PR 9058 Modified aromatic None 2.3 3–6 170 3 2 3 3 Excellent pigment wetting, good filler acceptance, low viscosity 1 1 1 1 1 1

Laromer® PA 9083 Adhesion promoter None 1.0 1.2–3.5 - Co-binder to increase adhesion on metal and plastic 1 1 - 1 1 1

Laromer® PR 9099 Modified epoxy acrylate Monomer mix 1.6 0.4–1.3 147 3 2 2 3 Anti-corrosion properties, excellent leveling 1 - - - - -

Laromer PR 9120
®
Modified polyether acrylate Monomer mix 2.0 Gel 36 2 2 1 2 Self-matting, gloss-level depending on dosage level 1 - - - 1 -

Laromer PR 9119
®
Polyester resin TMPTA [62%] 5.5 5–8 18 3 1 2 3 Scratch and chemical resistance, easy to matt 1 1 1 1 1 1

Performance additives
Type of thinner Functionality Viscosity Chemical Europe USA Canada Japan China Korea
Product Type of resin NCO value [%] Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] resistance REACH TSCA DSL ENCS IECSC ECL

Dual-cure products
Laromer® LR 9000 Aliphatic urethane acrylate None 2.0 + 2.0 NCO 1.0–1.4 14–15 2 1 1 2 Contains NCO- and UV-reactive groups within one molecule 1 1 1 1 1 1

Solvent-based systems
Type of thinner Functionality Viscosity Amine value Chemical Europe USA Canada Japan China Korea
Product Type of resin Hardness Elasticity Reactivity Characteristics
[content] calculated [Pa∙s, 23 °C] [mg KOH/g] resistance REACH TSCA DSL ENCS IECSC ECL

Amine-synergists / co-initiators
Laromer® PO 8956 M - None < 1.0 0.015–0.03 200 1 3 4 2 Highly reactive in combination with type II photoinitiators 1 1 1 - 1 -

For further regulatory information, please contact: ED-PSR@basf.com


a) SNUR = significant new use rule

Formulation additives
New product
* No monomer according to CEFIC definition
Water-based systems
40 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 41

Laromer® functional monomers

Natural oil-based polyols


Mol. mass Density Color [APHA DIN Viscosity [mPa·s, Europe USA Canada Japan China Korea
Product Structure Stenomeric CAS number
[g/mol] approx. [g/cm3] ISO 6271] 23 °C] approx. REACH TSCA DSL ENCS IECSC ECL

Laromer® functional monomers

Laromer® PPTTA
No 51728-26-8 572 1.14 max. 100 130–190 1 1 - - 1 1
Ethoxylated (5.0) pentaerythritol tetraacrylate

Crosslinkers
Laromer® LR 8863 (TMPEOTA)
No 28961-43-5 429 1.1 max. 100 50–100 1 1 1 1 1 1
Ethoxylated (3.0) trimethyl propane triacrylate

Laromer® GPTA
No 52408-84-1 429 1.08 max. 150 70–120 1 1 1 1 1 1
Propoxylated (3.8) glycerol triacrylate

Radiation-curable systems
Laromer® TMPTA
Yes 15625-89-5 300 1.102 (25 °C) max. 150 130 1 1 1 1 1 1
Trimethylolpropane triacrylate

Laromer® HDDA
Yes 13048-33-4 230 1.015 (25 °C) max. 150 6 1 1 1 1 1 1
Hexanediol diacrylate

Laromer® TPGDA
Yes 42978-66-5 300 1.036 (25 °C) max. 150 11 1 1 1 1 1 1
Tripropylene glycol diacrylate

Performance additives
Laromer® DPGDA
Yes 57472-68-1 240 1.046 (25 °C) max. 150 8 1 1 1 1 1 1
Dipropylene glycol diacrylate

Laromer® PO 9102 (PONPGDA)


No 84170-74-1 252 1.01 max. 200 10–20 1 1 1 1 1 1
Propoxylated (2.0) neopentyl glycol diacrylate

Solvent-based systems
Laromer® POEA
Yes 48145-04-6 190 1.100 (25 °C) max. 250 8 1 1 1 1 1 1
Phenoxyethyl acrylate

Laromer® LR 8887
Yes 66492-51-1 200 1.094 (25 °C) max. 200 40 1 1 1 - 1 -
Trimethylolpropane formal monoacrylate

Laromer® TBCH 84100-23-2


Yes 210 0.940 (25 °C) max. 100 9 1 1 - 1 1 -
4-T-butylcyclohexyl acrylate 282-104-8

Formulation additives
Water-based systems
42 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 43

Irgacure® photoinitiators

Natural oil-based polyols


1 Difficult to dissolve 2 Medium solubility 3 Good solubility

UV/VIS absorption
Product Product type Chemical name Structure Appearance Solubility Key properties
peaks [nm]

Irgacure® 184 1-Hydroxy-cyclohexyl-phenyl-keton 246, 280, 333 Solid 3 Low yellowing, medium volatility, highly efficient for surface cure

Crosslinkers
With good solvent properties, highly suitable for blends with other PI, highly efficient for surface cure,
Irgacure® 1173 2-Hydroxy-2-methyl-1-phenyl-1-propanone 245, 280, 331 Liquid 3
slightly more reactive than Irgacure® 184

2-Hydroxy-1-{4-[4-(2-hydroxy-2-methyl-propionyl)- Superior reactivity over a-HK like Irgacure® 184 or Irgacure® 1173, low sensitivity to oxygen inhibition,
Irgacure® 127 260, 320 Solid 1
benzyl]-phenyl}-2-methyl-propan-1-one low emission / odor after curing

α-Hydroxy ketone

2-Hydroxy-1-[4-(2-hydroxyethoxy)phenyl]- Low yellowing, low odor, low volatility, low migration, reactive OH group enabling use as building block for

Radiation-curable systems
Irgacure® 2959 276, 331 Solid 1
2-methyl-1-propanone MFPI, FDA-approved for indirect food contact in adhesive applications

Dual function, low-migration photoinitiator for UV-curable inks and overprint varnishes for
Acrylated, polymeric, multifunctional
Irgacure® LEX 201 Polymeric; > 1000 g/mol 273 Viscous liquid 2 packaging applications; due to the polymeric structure approximately 4 times higher concentration
α-hydroxyketone derivative
needed compared to, e.g., Irgacure® 2959

Low yellowing, low viscosity provides advantage of lowering the viscosity of formulation, highly efficient for
Irgacure® 500 Irgacure® 184 (50%) benzophenone (50%) - 250, 332 Liquid 3
surface cure, synergistic effect with amines

Performance additives
Oxy-phenyl-acetic acid 2-[2-oxo-2-phenyl-acetoxy-
Irgacure® 754 ethoxy]-ethyl ester and Oxy-phenyl-acetic acid - 260, 345 Liquid 3 Highly efficient in surface cure, low emission, low residual odor, lowest yellowing after cure
2-[2-hydroxy-ethoxy]-ethyl ester
Phenylglyoxylate

Low yellowing after cure / aging, excellent surface curing properties (stain resistance), enabling development
Irgacure® MBF Phenyl-glyoxylic acid methyl ester 255, 325 Liquid 3
of clearcoat with superior adhesion

Low initial yellowing, low oxygen inhibition, performance can significantly be improved in combination with
Irgacure® BP Benzophenone (BP) Benzophenone 256, 340 Solid 3
amine synergists

Solvent-based systems
Formulation additives
Water-based systems
44 Radiation-curable systems
Protecting what’s around us
Radiation-curable systems
Protecting what’s around us 45

Irgacure® photoinitiators

Natural oil-based polyols


1 Difficult to dissolve 2 Medium solubility 3 Good solubility

UV/VIS absorption
Product Product type Chemical name Structure Appearance Solubility Key properties
peaks [nm]

Good solubility in common UV systems, significantly lower through cure performance than Irgacure® 819,
Irgacure® TPO 2-, 4-, 6-Trimethylbenzoyl-diphenylphospine oxide 295, 380, 393 Solid 2
low yellowing, low odor, efficient radical photoinitiator for LED exposure

Crosslinkers
Easy to incorporate, low yellowing, photosensitivity at longer wavelength, efficient radical photoinitiator for
Irgacure® TPO-L 2-, 4-, 6-Trimethylbenzoyl-diphenyl phosphinate - Liquid 3
LED exposure

Limited yellowing after cure, improved through cure and reactivity over Lucirin® TPO, photosensitivity at
Irgacure® 2100 Liquid blend of acylphosphine oxides - 275, 370 Liquid 3
longer wavelength, efficient radical photoinitiator for LED exposure

Radiation-curable systems
Irgacure® 819 Acylphosphine oxide Bis(2-, 4-, 6-trimethylbenzoyl)-phenylphosphine oxide 360, 365, 405 Solid 1 Low odor, low volatility, photosensitivity at longer wavelength, efficient radical photoinitiator for LED exposure

Easy to incorporate in water-based UV systems, low odor, low volatility, photosensitivity at longer wavelength,
Irgacure® 819 DW Irgacure® 819 (45% active) dispersed in water - 360, 365, 405 Liquid 3
efficient radical photoinitiator for LED exposure

Good solubility in common UV systems, Irgacure® 4265 can be incorporated in water-borne systems,
Irgacure® 4265 Irgacure® TPO (50% wt%) Irgacure® 1173 (50% wt%) - 240, 290, 380 Liquid 3
photosensitivity at longer wavelength, efficient radical photoinitiator for LED exposure

Performance additives
Lower through cure performance than Irgacure® 819, well-balanced ratio surface cure and through-cure,
Irgacure® 2022 Irgacure® 819 (20% wt%) Irgacure® 1173 (80% wt%) - 246, 282, 370 Liquid 3
lower degree of photo bleaching, photosensitivity at longer wavelength

O
C O
Irgacure 651
®
Benzildimethyl ketal 2.2-Dimethoxy-1.2-diphenylethan-1-one 254, 337 Solid 2 Yellowing after cure tends to limit use for primers or intermediate coats
O

Solvent-based systems
Formulation additives
Water-based systems
Performance additives
Protecting what’s around us 47

Natural oil-based polyols


Performance additives

Crosslinkers
Coatings are exposed to a variety of detrimental phenomena such as solar radiation,
humidity, temperature change, microbiological attack, air pollutants, and many more.
With its comprehensive portfolio of stabilizers and other performance additives for UV
protection, BASF contributes to long-lasting coated products. One of our tailor-made
solutions to ensure long service life for coatings is the Tinuvin® range. When assessed

Radiation-curable systems
with our Sustainable Solution Steering method, it has been classified as Sustainability
Accelerator, which contributes significantly to sustainable development along the value
chain.

Prolonging coatings’ life spans

Performance additives
Tinuvin® 5333 DW, our innovative light stabilizer, has
been designed to meet high performance and durabili-
ty requirements of exterior water-based coatings, in­-
clud­ing energy-curable systems for low to zero VOC
requirements and / or where a traditional Benzotriazole
UV absorber needs to be upgraded.

Solvent-based systems
Formulation additives
Water-based systems
48 Performance additives
Protecting what’s around us
Performance additives
Protecting what’s around us 49

Tinuvin® light stabilizers:


UV absorbers

Natural oil-based polyols


0 Suited 1 Highly recommended

Indoor Outdoor
Radiation curing Radiation curing
Solvent-based Water-based Solvent-based Water-based
(transparent) (transparent)
Active
Physical
Product Description and applications content

solvent-based

solvent-based
form

Pretreatment

Pretreatment
Water-based

Water-based
[%]

Transparent

Transparent

Transparent

Transparent
transparent

transparent

transparent

transparent
systems

systems

systems

systems
Opaque

Opaque

Opaque
100% &

100% &
(primer)
Semi-

Semi-

Semi-

Semi-

Crosslinkers
Benzophenone
UV absorber suitable for solvent-based systems providing only UV-B ray protection.
Chimassorb® 81 Solid 100 - - 0 0 - - - - - - 0 0 - - - - -
Classic protection

Benzotriazoles

Radiation-curable systems
Multipurpose UV absorber for medium durability requirements and standard industrial
Tinuvin® 99-2 Liquid 95 0 - 1 1 - - - - 0 - 1 1 0 - - - -
and DIY solvent-based coatings, i.e., for wood furniture and parquet applications

Tinuvin® 99 DW Multipurpose UV absorber dispersion for water-based architectural and industrial coatings Liquid 45 - 0 - - - 1 1 0 - 0 - - - - 1 1 0

Universal UV absorber for medium durability requirements suitable for solvent- and
Tinuvin® 1130 Liquid 88 0 0 1 1 - 0 0 0 0 0 1 1 0 - 0 0 0
water-based systems

Hydroxyphenyl triazines
Blue-shifted UV absorber for high durability requirements in clear-coat applications including
Tinuvin® 400 industrial solvent-based and UV-curable coatings. Especially suited to flooring applications Liquid 85 1 - 1 1 - - - - 1 - 1 1 0 - - - -
(acrylates, PUR, and epoxies, non-yellowing in alkaline environment)

Performance additives
Blue-shifted UV absorber dispersion for water-based, high-performance coatings
Tinuvin® 400 DW Liquid 20 - 1 - - - 1 1 0 - 1 - - - - 1 1 0
(PUR and epoxies, non-yellowing in alkaline environment)

Red-shifted UV absorber with high extinction coefficient for high durability, solvent-based
Tinuvin® 477 Liquid 80 0 - 1 1 - - - - 0 - 1 1 0 - - - -
wood coatings, allows < 1% transmittance up to 370 nm (extended UV-A ray absorbance)

Red-shifted UV absorber dispersion for water-based, high-performance wood coatings


Tinuvin® 477 DW Liquid 20 - 0 - - - 1 1 0 - 0 - - - - 1 1 0
and for coatings providing efficient protection of substrates sensitive to UV-A rays

Solvent-based systems
Formulation additives
New product
Water-based systems
50 Performance additives
Protecting what’s around us
Performance additives
Protecting what’s around us 51

Tinuvin® light stabilizers:


HALS, blends, and preparations

Natural oil-based polyols


0 Suited 1 Highly recommended

Indoor Outdoor
Radiation curing Radiation curing
Solvent-based Water-based Solvent-based Water-based
(transparent) (transparent)
Active
Physical
Product Description and applications content

solvent-based

solvent-based
form

Pretreatment

Pretreatment
Water-based

Water-based
[%]

Transparent

Transparent

Transparent

Transparent
Semi-trans-
transparent

transparent

transparent
systems

systems

systems

systems
Opaque

Opaque

Opaque
100% &

100% &
(primer)

parent
Semi-

Semi-

Semi-

Crosslinkers
HALS
General-purpose N-alkyl HALS minimizing surface defects such as cracking and gloss loss
Tinuvin® 292 Liquid 100 0 0 0 0 - 0 0 0 1 0 1 1 1 - 0 0 0
(not suitable for acid-catalyzed systems)

Tinuvin® 123 Non-basic N-OR HALS for improved coating durability Liquid 100 - - 0 0 - - - - 1 - 1 1 1 - - - -

Tinuvin 123 DW
®
N-OR HALS dispersion for water-based coatings for improved coating durability Liquid 30 - 0 - - - 0 0 0 - 1 - - - - 1 1 1

Radiation-curable systems
N-OR HALS (non-acid-sensitive) especially for LO alkyd solvent systems providing cracking
Tinuvin® 5100 Liquid 100 - - 0 0 - - - - 1 - 1 1 1 - - - -
and gloss resistance to clear coats and reduced chalking to pigmented systems

Blends
Tinuvin® 5050 Blend of BTZ UV absorber and basic HALS Liquid 100 - - 0 0 - - - - - - 1 1 0 - - - -

Blend of BTZ UV absorber and non-basic N-OR HALS suitable in particular for long-oil
Tinuvin® 5060 Liquid 100 - - 0 0 - - - - - - 1 1 0 - - - -
alkyd-based wood-coating applications

Tinuvin® 5151 Blend of BTZ UV absorber and basic HALS Liquid 92 - - 0 0 - 0 0 0 - - 1 1 0 - 0 0 0

Blend of HPT UV absorber and a basic HALS for exterior, solvent-based industrial coatings
Tinuvin® 5251 Liquid 100

Performance additives
0 - 0 0 - - - - 1 - 1 1 0 - - - -
including UV-curable paints

Blend of HPT UV absorber and non-basic N-OR HALS suitable in particular for concrete-floor
Tinuvin® 5460 Liquid 92 0 - - - - - - - 1 - 1 1 0 - - - -
applications

Blend of high-performance UV absorber and non-reacting HALS with broad spectral coverage for
Tinuvin® 5333 DW Liquid 40 - 0 - - - 0 0 0 - 1 - - - - 1 1 0
high-durability requirements in water-based joinery, GIP, plastic, glass, and decorative coatings

Lignin stabilizers
Lignin-stabilizing HALS that prevents color change in natural, tinted, or stained pale woods
Lignostab® 1198 Solid 100 - - - - 1 - - - - - - - - 1 - - -
(to be used in wood-impregnating primers)

Solvent-based systems
Lignostab® 1198 L Lignin stabilizer solution Liquid 20 - - - - 1 - - - - - - - - 1 - - -

Formulation additives
New product
Water-based systems
Solvent-based systems
Protecting what’s around us 53

Natural oil-based polyols


Solvent-based systems

Crosslinkers
To enable long-lasting wood coatings, BASF offers a range of solvent-based disper­
sions as well as polyols for solvent-based 2K PU systems. Solvent-based systems
still represent a high share of the furniture and flooring industry. When assessed with
our Sustainable Solution Steering method, we identified our portfolio to meet basic
sustainability standards in the market.

Radiation-curable systems
High resistance and long durability Efficient mixing processes

Acronal® acrylic resins are used particularly in combi- Laropal® grinding resin with its outstanding compat­
nation with nitrocellulose systems for wood coatings. ibility with all the main binders and organic solvents
Our wide range of hydroxyl functional acrylic copoly- makes it the preferred solution for universal mixing
mers is mainly cross-linked with polyisocyanates such systems and pigmented pastes alike. Furthermore, ­
as Basonat® for solvent-based 2K PU coatings. this highly flexible product reduces inventory.

Performance additives
Solvent-based systems
Formulation additives
Water-based systems
54 Solvent-based systems
Protecting what’s around us
Solvent-based systems
Protecting what’s around us 55

Acronal® acrylic resins


and Laropal® aldehyde resins

Natural oil-based polyols


Solids by Viscosity OH number on Iodine color Flash point
Product Type of resin Physical form Key properties and applications Tg [°C]
weight [%] [mPa·s, 25 °C] solids [mg KOH/g] number [°C]

Acrylic resins for solvent-based systems


Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and
Acronal® 4 F Liquid 99 50% in ethyl acetate –40 - 0–1 150
chlorine-containing binders for coatings with good flexibility and excellent adhesion

Acronal® 4 L Poly n-butyl acrylate Polymer of butyl acrylate, dissolved in acetate; soft acrylic resin, resistant to light and

Crosslinkers
Approximately 50% aging, for plasticizing cellulose nitrate and chlorine-containing binders for coatings with 50 1.6–2.6 –40 - - –6
in ethyl acetate good flexibility and excellent adhesion
Solution in ethyl acetate
Acronal® 700 L Copolymer of vinyl isobutyl ether and n-butyl acrylate, dissolved in ethyl acetate;
Copolymer of n-butyl acrylate
Approximately 50% soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and 51 500–800 - - 0–2 –4
and vinyl isobutyl ether
in ethyl acetate chlorine-containing binders for coatings with good flexibility and excellent adhesion

Grinding resins for solvent-based systems


Condensation product of urea with Excellent compatibility with common coating resins. Excellent solubility. Good pigment

Radiation-curable systems
Laropal® A81 Solid 100 - 57 40 - -
aliphatic aldehydes wetting. Improves hardness, gloss, and adhesion. Resistance to yellowing

Condensation product of urea with Excellent compatibility and solubility with common coating resins. Good pigment wetting.
Laropal® A101 Solid 100 - 73 35 - -
aliphatic aldehydes Improves hardness, gloss, and adhesion. Resistance to yellowing

Performance additives
Solvent-based systems
Formulation additives
Water-based systems
56 Solvent-based systems
Protecting what’s around us
Solvent-based systems
Protecting what’s around us 57

Joncryl® acrylic polyols

Natural oil-based polyols


Solids by Viscosity OH number OH number on
Product Appearance Key properties Solvent Tg [°C] Description and applications
weight [%] [mPa·s] on solids [%] solids [mg KOH/g]

SGO acrylic polyols


Narrow molecular weight distribution, outstanding application properties, improves Acrylic polyol with good hardness, stain resistance, and pigment dispersibility, broad resin compatibility and useful as a
Joncryl® 500 Clear liquid 80.0 3,900 Methyl n-amyl ketone 4.2 140 –5
application properties of polyesters-based systems low VOC modifier for office furniture and general metal coatings

Joncryl® 504 Clear liquid Very low VOC, very good chemical resistance, low initial color 80.0 7,500 Xylene 4.2 140 –7 Low VOC polyol, useful as sole binder or modifier for higher Tg polyols for 2K PU temperature-cured systems

Crosslinkers
4.2% OH on solid resin, low VOC capability, excellent flow and leveling, broad
Joncryl® 507 Clear liquid 80.0 4,000 Butyl acetate 4.2 145 7 Alternate solvent version of Joncryl® 500 for low-odor, non-HAPs applications
compatibility and excellent outdoor durability

Narrow molecular weight distribution, outstanding application properties, improves


Joncryl® 510 Clear liquid 80.0 7,600 Xylene 4.2 140 –4 Good QUV gloss retention and exterior durability with excellent flow and spray application properties
application properties of polyesters-based systems and improved durability

Acrylic polyol with good hardness, stain resistance, and pigment dispersibility, broad resin compatibility and useful as a
Joncryl® 551 Clear liquid Joncryl® 500, in an alternative low-cost solvent 60.0 6,000 Xylene 2.7 90 49
low VOC modifier for office furniture and general metal coatings

Acrylic polyol with good hardness, stain resistance, and pigment dispersibility, broad resin compatibility and useful as a

Radiation-curable systems
Joncryl® 552 Clear liquid Joncryl® 500, in a non-HAPS solvent 62.0 5,500 n-Butyl acetate 2.7 90 49
low VOC modifier for office furniture and general metal coatings

100% solids polyol used in both 2K PU urethane and acid-curable coatings offering
Joncryl® 581 Clear solid resin 100.0 Solid - 4.7 155 62 Solid polyol suitable for high-quality furniture and floor coatings in solvent-based systems
good chemical resistance and hardness

Conventional-solids workhorse polyol, very fast drying with long pot life and excellent UV and chemical resistance, solid
Joncryl® 587 Clear solid resin Good outdoor durability, high gloss, and gloss retention 100.0 Solid - 2.8 94 60
form provides cost benefit and formulator versatility

High equivalent weight for low NCO demand, can be used to formulate economical 2K PU coatings, solid form provides
Joncryl® 804 Clear solid resin Fast drying, high hardness, low OH value > 98.5 Solid - 1.3 45 60
cost benefit and formulator versatility, can also be used as a modifier

SGO fast-curing acrylic polyols


Excellent early hardness development and fast drying time, excellent gloss and color

Performance additives
Joncryl® 909 Clear liquid 68.0 6,500 n-Butyl acetate 3.5 117 25 For versatile 2K PU for industrial applications
retention, good chemical resistance and outstanding durability

Lower VOC higher equivalent weight acrylic polyol with good hardness development
Joncryl® 911 Clear liquid 77.0 7,000 n-Butyl acetate 2.1 70 7 Recommended for 2K PU high-build coatings
and durability

Joncryl® 915 Clear liquid Low VOC, fast-drying polyol allowing lower polyisocyanate dosage 77.0 7,500 - 2.9 95 13 Low VOC, low polyisocyanate demand, and low odor for industrial coatings

Joncryl 934
®
Clear liquid Low VOC, higher equivalent weight polyol 77.0 5,000 n-Butyl acetate 2.1 70 7 Low VOC polyol for 2K PU coatings

Solvent-based systems
Formulation additives
Water-based systems
Formulation additives
Protecting what’s around us 59

Natural oil-based polyols


Formulation additives

Crosslinkers
From defoamers to surface modifiers, from dispersing agents to rheology modifiers:
BASF’s portfolio of formulation additives comprises a broad technology base for you to
formulate high-performance coatings. Furthermore, with our know-how, we support you
in solving formulation challenges for higher throughput during manufacturing, and advise
on how to achieve improved durability of your specific coatings, in an efficient way.

Radiation-curable systems
Enabling longer-lasting coatings Reducing emissions

Efka® SL 3299, our highly efficient, low VOC leveling Low VOC dispersing agents such as Dispex® Ultra ­
agent for improved scratch resistance for UV-curable PX 4575 and Dispex® Ultra PX 4585 provide both
systems, allows you to save time and material re­sou­rces higher efficiency in pigment grinding and maximum
on recoating and repair. color development – driving forward your water-based
coating technologies.

Performance additives
Preserving resources
Looking for further innovative solutions where little
More efficient formulation additives enable you to helpers make all the difference for your high-quality
achieve your production time while consuming fewer coatings? Please visit our solution finder tool at
resources. For example, FoamStar® ST 2438, one of www.basf.com/formulation-additives.
our highly efficient defoamers, shortens paint produc- This tool is a
­ lso available as an iPad app.
tion time – allowing an increase in your overall pro­duc­-
tion capacity.

Solvent-based systems
Formulation additives
Water-based systems
60 Formulation additives
Protecting what’s around us
Formulation additives
Protecting what’s around us 61

FoamStar® and Efka®


defoamers

Natural oil-based polyols


1 Recommended

Dosage* Solids** VOC content** Solvent-based Water-based Solvent-free/ Silicone-


Product Chemical nature Incorporation Silicone-free Description and applications
[%] [%] [%] coatings coatings radcure containing

Defoamers
High-performance, ultra-low SVOC silicone emulsion defoamer for premium water-based paints, clear
FoamStar® ED 2522 Emulsion defoamers At any stage of the production process 0.1–1.0 ~ 20 < 0.1 - 1 - - 1
coats and inks; excellent storage stability; extremely low SVOC content

Ultra-low SVOC, emulsion defoamer for medium- to high-PVC systems based on acrylic, styrene acrylic

Crosslinkers
FoamStar® ED 2523 Emulsion defoamers Grinding stage / let-down 0.2–0.6 ~ 27 < 0.1 - 1 - - 1
dispersions

Modified polydimethylsiloxane-based 100%-active-content defoamer for non-pigmented and low-pigmented aqueous coatings and UV-curable
FoamStar® SI 2210 At any stage of the production process 0.1–0.5 100 < 0.5 - 1 1 - 1
defoamers systems; provides a strong spontaneous defoaming effect; outstanding long-term defoaming persistency

Solvent-based solution of defoaming Water-based coatings and pigment concentrates where high-shear processing or application exists; most
FoamStar® SI 2250 Grinding stage / final production 0.1–0.3 100 ~ 70 - 1 - - 1
substances, silicone-free effective in the range

Modified polydimethylsiloxane-based Highly compatible silicone-based defoamer solution for high-gloss paints and varnishes based on acrylics
FoamStar® SI 2292 At any stage of the production process 0.5–3.0 10 90 - 1 - - 1
defoamers and polyurethane dispersions; minimized risk of cratering

Radiation-curable systems
Modified polydimethylsiloxane-based VOC-free, highly compatible silicone-based defoamer solution for high-gloss paints and varnishes based on
FoamStar® SI 2293 At any stage of the production process 0.5–1.5 100 < 0.5 - 1 - - 1
defoamers acrylics and polyurethane dispersions; minimized risk of cratering

Silicone-based defoamer for high-quality water-based paints, delivering excellent long-term persistency
FoamStar® ST 2438 Star polymer-based defoamers Grinding stage / let-down 0.25–0.5 100 < 0.5 - 1 1 - 1
and foam knock down

Solvent-based solution of defoaming Silicone-free defoamer for broad use in solvent-based systems; well suited for clear systems due to the
Efka® PB 2010 Before or after processing 0.1–0.7 100 ~ 80 1 - - 1 -
substances, silicone-free improved compatibility when compared to Efka® PB 2020

Solvent-based solution of defoaming


Efka® PB 2020 Before or after processing 0.1–0.7 - ~ 80 1 - - 1 - Acid-cured and NC-curtain coating systems, broad use silicone-free defoamer
substances, silicone-free

Solvent-based solution of defoaming


Efka® PB 2720 Before or after processing 0.1–10.0 - ~ 60 1 - - 1 - Epoxy and polyurethane systems
substances, silicone-free

Performance additives
Solvent-based solution of defoaming
Efka® SI 2022 Before or after processing 0.1–1.0 - > 90 1 - - - 1 Polyurethane curtain coatings
substances with modified silicone compounds

Solvent-based solution of defoaming


Efka® SI 2035 Final production 0.5–1.0 - > 95 1 - - - 1 Physically drying systems and medium- to long-oil air-drying alkyds
substances with modified silicone compounds

Solvent-based solution of defoaming


Efka® SI 2040 Final production 0.1–0.7 - > 95 1 - - - 1 Solvent-based industrial and decorative finishes, including roller, brush, and airless spray applications
substances with modified silicone compounds

Solvent-free solution of defoaming UV-curing and EBC systems; highly effective defoaming in clear and matted systems; defoaming
Efka® SI 2721 At any stage of the production process 0.5–1.0 - > 95 - - 1 1 -
substances with modified silicone compounds substances in 2-ethylhexyl acrylate

Solvent-based solution of defoaming


Efka® SI 2723 Prior to processing 0.5–1.5 - < 25 1 - 1 - 1 Polyurethane systems, low odor, high solid 2-pack systems and solvent-free radiation-curing systems

Solvent-based systems
substances with modified silicone compounds

Formulation additives
New product
* W/w on total formulation
** Typical values, not intended as specification
Water-based systems
62 Formulation additives
Protecting what’s around us
Formulation additives
Protecting what’s around us 63

Hydropalat® wetting agents


and Efka® surface modifiers

Natural oil-based polyols


1 Recommended

Dosage* Solids** VOC content** Solvent-based Water-based Solvent-free/ Silicone-


Product Chemical nature Incorporation Silicone-free Description and applications
[%] [%] [%] coatings coatings UV coatings containing

Substrate wetting agents


Hydropalat® WE 3120 Alkoxylated surfactants At any stage of the production process 0.5–5.0 > 99.5 < 0.5 - 1 - 1 - Low-foaming wetting agent for aqueous formulations; excellent reduction of dynamic surface tension

Excellent substrate wetting, leveling, and anti-cratering; problem solver in water-based systems, against
Hydropalat® WE 3370 Fluorinated polyacrylates At any stage of the production process 0.5–1.5 60 < 10 - 1 - 1 -
cissing and has pronounced effect on leveling

Crosslinkers
Hydropalat® WE 3475 Sulfosuccinates At any stage of the production process 0.1–1.0 75 ~6 - 1 - 1 - Highly efficient sulfosuccinate wetting agent; strong reduction of dynamic surface tension

Excellent surface leveling and substrate wetting agent; avoids side effects like cratering, foam stabilization,
Hydropalat® WE 3500 Fluorinated polyacrylates At any stage of the production process 0.1–0.75 60 < 20 - 1 - 1 -
and effects on intercoat adhesion

Highly effective, low-foaming wetting agent, excellent performance in coatings applications for reduction
Hydropalat® WE 3650 Surfactant blend At any stage of the production process 0.5–2.0 > 99.5 < 0.5 - 1 - 1 -
of dynamic surface tension; high formulation flexibility due to solvent-free delivery form

Flow and leveling agents

Radiation-curable systems
Efka® FL 3741 Copolyacrylates At any stage of the production process 0.2–1.0 > 95 < 0.5 1 - 1 1 - Silicone- and solvent-free flow and leveling agent with air-release properties; excellent compatibility

Slip and leveling agents


Efka® SL 3030 Modified polysiloxanes At any stage of the production process 0.1–0.3 52 48 1 1 - - 1 Organically modified polysiloxane; improved slip and mar resistance, very compatible

Efka® SL 3031 Modified polysiloxanes At any stage of the production process 0.1–0.3 52 48 1 - 1 - 1 Organically modified polysiloxane; solvent-based metal, wood, and paper coatings including UV-cured

Efka® SL 3033 Modified polysiloxanes At any stage of the production process 0.1–1.0 15 85 1 - - - 1 Organically modified polysiloxane; improved surface flow, excellent compatibility in clear coats

Efka SL 3034
®
Modified polysiloxanes At any stage of the production process 0.05–0.2 52 48 1 1 - - 1 Fluorocarbon-modifified polysiloxane; strong substrate wetting and anti-cratering

Efka SL 3035
®
Modified polysiloxanes At any stage of the production process 0.1–0.5 52 48 1 1 1 - 1 Organically modified polysiloxane; solvent- and water-based coatings

Performance additives
Efka® SL 3210 Modified polysiloxanes At any stage of the production process 0.1–0.3 100 <1 1 1 1 1 - Broad spectrum and efficient flow and slip enhancer; economic solutions

Solvent-free modified polysiloxane; solvent-based wood finishes, industrial coatings, and solvent-free
Efka® SL 3236 Modified polysiloxanes At any stage of the production process 0.04–0.4 100 <1 1 - 1 - 1
floor coatings

Highly effective solvent-free slip additive and leveling agent; specifically designed for aqueous and
Efka® SL 3258 Modified polysiloxanes At any stage of the production process 0.05–1.0 > 95 < 0.5 1 1 1 - 1
UV-curable formulations

Organically modified polysiloxane; strong slip and surface smoothness effect for high-gloss industrial
Efka® SL 3299 Modified polysiloxanes At any stage of the production process 0.05–0.3 100 <1 1 1 1 - 1
coatings

Efka® SL 3883 Reactive polysiloxanes Final production 0.2–1.0 70 30 - - 1 - 1 Polysiloxane-modified with unsaturated terminal groups; UV-curing systems for wood, paper coatings

Solvent-based systems
Formulation additives
New product
* W/w on total formulation
** Typical values, not intended as specification
Water-based systems
64 Formulation additives
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Formulation additives
Protecting what’s around us 65

Dispex®, Dispex® Ultra,


and Efka® dispersing agents

Natural oil-based polyols


1 Recommended

Amine number* Acid value* VOC content* Water-


Product Chemical nature Solids* [%] Solvent-based Description and applications
[mg KOH/g] [mg KOH/g] [%] based

Low-molecular-weight dispersing agents


Dispex® Ultra FA 4425 Fatty-acid-modified emulsifier (FAME) 100 47 46 <1 1 1 Dispersing agent for universal colorant systems; improves color acceptance of colorants and compatibility in base-resin system

Dispersing agent for inorganic fillers and pigments; also suitable as codispersing agent with high-molecular-weight dispersing agents; will improve compatibility and color
Dispex® Ultra FA 4480 Fatty-acid-modified emulsifier (FAME) 101 36 23 <2 1 1
acceptance of universal colorants in base paints

Crosslinkers
Efka® FA 4609 Acidic copolymer 52 - 50 48 1 - Copolymeric wetting and dispersing agent; strong reduction of mill-base viscosity; high pigment and filler loading; increased hiding power

High-molecular-weight dispersing agents


Dispex® Ultra PA 4560 Modified polyacrylate polymer 40 25 - <1 - 1 Water-based industrial coatings, pH-independent; broad compatibility; suitable for making resin-containing and resin-free pigment concentrates

Dispex Ultra PA 4580


®
Modified polyacrylate polymer 40 19 - <1 - 1 High-end industrial coatings; suitable for making resin-free and resin-containing pigment concentrates

Dispex Ultra PX 4275


®
Copolymer 37.5 - - < 0.5 - 1 High-performance wetting and dispersing agent; specifically designed for semi-gloss and high-gloss paint formulations and pigment concentrates

Radiation-curable systems
Acrylic block copolymer made by controlled
Dispex® Ultra PX 4575** 40 32 - < 0.1 - 1 High-end water-based industrial coatings; broad compatibility with different binder systems; pH-independent; suitable for making resin-free pigment concentrates
free radical polymerization (CFRP)

Acrylic block copolymer made by controlled


Dispex® Ultra PX 4585** 50 20 - <1 - 1 High-end water-based industrial coatings; broad compatibility with different binder systems; pH-independent; suitable for making resin-free pigment concentrates
free radical polymerization (CFRP)

New generation of modified polyurethane


Efka® PU 4010 51 6 12 49 1 - General industrial coatings, wood coatings for stabilization of TiO2 and matting agents
polymer

Efka® PU 4046 Modified polyurethane polymer 40 19 - 60 1 - General industrial coatings

Efka PU 4047
®
Modified polyurethane polymer 35 17 - 65 1 - High-quality industrial finishes

Efka PU 4063
®
Modified polyurethane polymer 45 10 - 55 1 - Polymeric dispersing agent for the deflocculation of inorganic and organic pigments in high-quality solvent-based pigment pastes

Performance additives
Acrylic block copolymer made by controlled
Efka® PX 4330 70 28 - 30 1 - Solvent-based industrial coatings; excellent (broad compatibility) for industrial colorants (pigment pastes) in combination with grinding resins such as Laropal® A 81
free radical polymerization (CFRP)

Acrylic block copolymer made by controlled


Efka® PX 4340 55 4 - 45 1 - Solvent-based high-end industrial coatings, 2-pack PUR, 2-pack epoxy and NC
free radical polymerization (CFRP)

Highly efficient dispersing agent for a broad variety of pigments; high gloss due to excellent compatibility; for high-quality solvent-based industrial coatings; also suitable for
Efka® PX 4751 Advanced polymer 51 12 - 49 1 -
high-performance organic pigments

Solvent-based systems
Active Water-based High-PVC Low-PVC Average molecular
Product Chemical nature Supplied pH Description and applications
content* [%] coatings paints paints weight

Ionic dispersants for inorganic pigments


Dispex® AA 4140 Sodium polyacrylate 40 1 1 - 4,000 7.5 Standard dispersing agent for inorganic fillers and pigments; low polydispersity leading to most efficient dispersing properties and liquefying effect

Ammonium polyacrylate
Dispex® CX 4240 40 1 1 1 6,000 7.5 For inorganic pigments and extenders; more hydrophobic than Dispex® AA 4040
copolymer

Formulation additives
New product
Incorporation: Dispersant should be added to the mill-base prior to the addition of the pigment.
* Typical values, not intended as specification
** Controlled free radical polymerization
Water-based systems
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Rheovis® rheology modifiers

Natural oil-based polyols


1 Recommended

Water-based VOC
Product Chemical nature Solids* [%] Chemical type** Viscosity [mP·as] Description and applications
coatings content [%]

HEUR / HMPE
Rheovis® PE 1330 Associative thickener: hydrophobic modified polyether (HMPE) 30 HMPE 1 < 0.1 4,500 Excellent high-shear thickener; imparts excellent flow

Rheovis® PU 1331 Associative thickener: hydrophobic modified ethoxylated urethane (HEUR) 18 HEUR 1 < 0.1 4,500 Next-generation high-shear thickener; ultra efficient; best-in-class ICI performance

Crosslinkers
ASE / HASE
Non-associative pure acrylic thickener; highly efficient low-shear thickener; high-shear thinning, anti-sagging and anti-settling; used in pigment and filler
Rheovis® AS 1130 Anionic polyacrylate copolymer 30 ASE 1 - ~5
slurries but also highly successful in industrial formulations for spray application

Acrylic thickener with associative and non-associative thickening; thixotropic flow behavior; low water uptake; no impact on wet adhesion even after long
Rheovis® HS 1162 Anionic polyacrylate copolymer 35 HASE 1 - < 50
water contact

Associative thickener: anionic polyacrylate copolymer, hydrophobically Acrylic thickener with associative thickening; mid-shear thickener; improves flow; excellent efficiency; all-round product that can be used in most paint
Rheovis® HS 1212 40 HASE 1 - -
modified (HASE) systems

Radiation-curable systems
Performance additives
Solvent-based systems
Formulation additives
* Typical values, not intended as specification
** ASE: alkali-swellable emulsions; HASE: hydrophobically modified alkali-swellable emulsions; HMPE: hydrophobic modified polyether;
HEUR: hydrophobic modified ethoxylated urethane

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