CHEMISTRY

Steric inhibition of resonance

DPP - 14

01. Which of the following carbocation is not resonance stabilized?

(a) (b) (c) (d)

02. In which of the following compound Steric inhibition of resonance effect will operate?

(a) (b)

(c) (d)

03. In which of the following lone pair of nitrogen is not involved in resonance?

(a) (b)

(c) (d)

04.

Dipole moments of given compound will be:

(a) (A) = 6.87D, (B) = 4.11D (b) (A) = 4.11D, (B) = 6.87D

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 (c) (A) = 4.11D, (B) 4.11D (d) (A) = 6.87D, (B) = 6.87D

05.

Dipole moments of given compound will be:

(a) (A) = 3.39D, (B) = 3.95D (b) (A) = 3.39D, (B) = 3.39D
(c) (A) = 3.95D, (B) 3.39D (d) (A) = 3.95D, (B) = 3.95D

06.

Compare bond lengths x and y:

(a) x > y (b) y > x (c) x = y (d) can’t be say

07.

Compare the stabilities in the given pair of carbocations.

(a) A > B (b) B > A (c) A = B (d) can’t be say

08. Which of the following statements would be true about this compound :

(A) All three C – N bonds are of same length.

(B) Cl – N and C3 – N bonds are of same length but shorter than C5 – N bond.
(C) Cl – N and C3 – N bonds are of same length but longer than C5 – N bond.
(D) Cl – N and C3 – N bonds are of different length but both are longer than C5 – N bond.

DPP - 14
1 2 3 4 5 6 7 8
D C B A C B B C

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