SAFETY DATA SHEET

Reagens™ 65
Issuing date 10-Dec-2010 Revision Date 22-May-2020 Revision Number 47

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

A. Product Identifier
SDS Code(s) 0519

Product Name Reagens™ 65

Synonyms 3-Chloro-2-hydroxypropyltrimethyl ammonium chloride 65%

Reach Registration Number 01-2119492622-35-0002

B. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Intermediate under Strictly Controlled Conditions and is mainly used for the cationization of
starch

C. Details of the supplier of the safety data sheet

Manufacturer Supplier
•SACHEM Eur opeBV •SACHEM Eur opeBV
Van Voordenpark 15 Van Voordenpark 15
5301 KP Zaltbommel 5301 KP Zaltbommel
The Netherlands The Netherlands
Telephone: 0031-4186-82000 Telephone: 0031-4186-82000
E-mail: msds@sachemeurope.nl E-mail: msds@sachemeurope.nl

D. Emergency telephone number

Emergency telephone number •SACHEM Eur
ope 0031-
6537-
70227

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SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

REGULATION (EC) No 1272/2008

Carcinogenicity Category 2
Chronic aquatic toxicity Category 3

2.2 Label Elements

Signal word
Warning

Hazard statements
•H351-Suspect edofcausi
ngcancer
•H412-Har mfultoaquat
icl
if
ewit
hl ongl
ast
ingef
fect
s

Precautionary statements
•P273-Av oi
dr eleasetotheenv i
ronment
•P281-Useper sonalprot
ecti
veequipmentasr equi
red
•P308+P313-I Fexposedorconcer ned:Getmedicaladv
ice/
att
enti
on
•P501-Di sposeofcont ents/contai
nertoanappr ov
edwastedisposalpl
ant

2.3 Other Information

None known

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Chemical nature Organic solvents and additives.

Chemical name EC No. CAS No. Weight-% Classification REACH Registration

according to Number
Regulation (EC) No.
1272/2008 [CLP]
3-Chloro-2-hydroxypropylam 222-048-3 3327-22-8 65-70 Carc. 2 (H351) 01-2119492622-35
monium chloride Aquatic Chronic 3
(H412)

For the full text of the H-Statements mentioned in this Section, see Section 16

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SECTION 4: FIRST AID MEASURES

A. Description of first aid measures

General advice Do not get in eyes, on skin, or on clothing

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
symptoms persist, call a physician.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. If symptoms persist, call a physician.

Ingestion Induce vomiting, but only if victim is fully conscious. Drink plenty of water. Never give
anything by mouth to an unconscious person. If symptoms persist, call a physician.

Inhalation Move to fresh air in case of accidental inhalation of vapors. If symptoms persist, call a
physician.

Self-protection of the first aider Avoid contact with eyes, skin and clothing.

B. Most important symptoms and effects, both acute and delayed

Symptoms No information available.

C. Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

SECTION 5: FIREFIGHTING MEASURES

A. Extinguishing media
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam.
Contains organic solvents. Water spray. Dry chemical. Carbon dioxide (CO2).

Extinguishing media which shall not be used for safety reasons

None.

B. Special hazards arising from the substance or mixture

Specific hazards arising from the chemical
Hazardous combustion products. Produce flammable and toxic gases on contact with water. Hydrogen chloride gas.

C. Protection of firefighters
Protective equipment and precautions for firefighters
Standard procedure for chemical fires. Evacuate personnel to safe areas. Evacuate area and fight fire from a safe distance. Wear
self contained breathing apparatus for fire fighting if necessary.

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SECTION 6: ACCIDENTAL RELEASE MEASURES

A. Personal precautions, protective equipment and emergency procedures

Avoid contact with eyes, skin and clothing.

B. Environmental precautions
Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Local
authorities should be advised if significant spillages cannot be contained. Try to prevent the material from entering drains or water
courses. Do not contaminate surface water.

C. Methods and materials for containment and cleaning up

Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Prevent product from entering
drains. Local authorities should be advised if significant spillages cannot be contained.

D. Reference to other sections

See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment
information.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Handling
Avoid contact with eyes, skin and clothing. Handle in accordance with good industrial hygiene and safety practice. Prevent spills
and avoid operations which contaminate clothing and work areas. Do not ingest. Wear personal protective clothing (see section 8).

7.2 Conditions for safe storage, including any incompatibilities

Storage
Incompatible with strong acids and oxidizing agents. Keep container tightly closed in a dry and well-ventilated place. Store in a
well-ventilated place. Keep cool. Store away from incompatible materials. Incompatible with strong bases and oxidizing agents.

7.3 Specific end use(s)

Specific use(s)
No information available

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Exposure limits We are not aware of any national exposure limit.

8.2 Exposure controls

Engineering Controls Ensure adequate ventilation, especially in confined areas.

Personal Protective Equipment

Eye Protection Tightly fitting safety goggles. Face protection shield.

Skin Protection Long sleeved clothing. Protective gloves.

Hand Protection Long sleeve gloves. Neoprene gloves. Nitrile rubber. PVC disposable gloves.

Glove material Glove thickness Break through time Remarks

Nitrile rubber 1.1 mm Methanol > 30 minutes Protective gloves complying with
n-Heptane > 480 minutes EN 374.
Sodium hydroxyde > 480 minutes
Sulfuric acid > 60 minutes

Respiratory protection In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and
protective suit.

General Hygiene Considerations General industrial hygiene practice. Wash hands before breaks and immediately after
handling the product. Take off all contaminated clothing and wash it before reuse.

Environmental Exposure Controls Local authorities should be advised if significant spillages cannot be contained. Prevent
product from entering drains. Do not allow material to contaminate ground water system.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Physical state Liquid Appearance Colorless; White

Odor Slight.

Property Values Remar

ks •Met
hod
pH 2-6
Flash Point >200 °C
Autoignition Temperature 400 °C
Boiling point 190-209 C
Melting point No data available
Evaporation Rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air No data available

Explosive Limits No data available

Vapor pressure 1,5 kPa

Vapor Density No data available
Specific Gravity 1.15 - 1.16 g/ml
Water Solubility Soluble in water
Solubility in other solvents No data available
Solubility
Partition coefficient < - 1.5
Decomposition temperature °C No data available
Dynamic viscosity 20 - 40 mPa.s @ 20*C

Explosive properties None

Oxidizing Properties None under normal processing

9.2 Other Information

Freezing Point crystallisation point appr. -41,7°C
Molecular Weight 188.1
Bulk Density No data available

SECTION 10: STABILITY AND REACTIVITY

A. Reactivity
Reactivity No information available

B. Chemical Stability
Stability Stable under normal conditions.

C. Possibility of hazardous reactions

Hazardous Reactions None under normal processing.

D. Conditions to Avoid
Conditions to Avoid Temperatures above 50°C.

E. Incompatible Materials
Materials to avoid Strong bases. Strong oxidizing agents. Strong acids. Heavy metals.

F. Hazardous Decomposition Products

Hazardous Decomposition Products Hydrogen chloride gas, Amines

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SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute Toxicity
Product Information Product does not present an acute toxicity hazard based on known information.

Inhalation Not an expected route of exposure.

Eye Contact Avoid contact with eyes. non-irritant.

Skin Contact Non-irritating to the skin.

Ingestion Not an expected route of exposure. Do not taste or swallow.

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

3-Chloro-2-hydroxypropylammoniu 2170 mg/kg >2000 mg/kg >12.1 g/m3
m chloride

Chronic Toxicity
Carcinogenicity Category 2

Component EU Annex I Carcinogen Information United Kingdom

3-Chloro-2-hydroxypropylammonium chloride 612-238-00-8
3327-22-8 ( 65-70 )

Sensitization Did not cause sensitization on laboratory animals

Carcinogenic effects No information available.

Reproductive Toxicity However, based on avaiable data the product should not be classified for reproductive
effects

Mutagenic Effects Not regarded as mutagenic

Target Organ Effects No information available

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SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Ecotoxicity effects Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

Water hazard class (WGK) Hazardous to water/Class 2

Chemical name Algae/aquatic plants Freshwater Fish Microtox Crustacea

3-Chloro-2-hydroxypropylam No information available Leuciscus Idus/24h/>1000 No information available 367 mg/L
monium chloride mg/L

12.2 Persistence and degradability

Short term degradation products are unlikely while long term degradation products may arise. Biodegradation products are less
toxic than the product itself.

12.3 Bioaccumulative potential

Bioaccumulation is unlikely
Chemical name Partition coefficient
3-Chloro-2-hydroxypropylammonium chloride < -1,5

12.4 Mobility in soil

No information available

12.5 Results of PBT and vPvB assessment

12.6 Other Adverse Effects

No information available

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Disposal Considerations Dispose of in accordance with local regulations
Can be incinerated, when in compliance with local regulations

Waste from residues/unused Recover or recycle if possible, otherwise: incineration with wet scrubbing facilities
products

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal
Clean container with water

SECTION 14: TRANSPORT INFORMATION

IMDG/IMO Not classified as dangerous in the meaning of transport regulations

ADR Not classified as dangerous for conveyance in the meaning of the regulations for the
transport of dangerous goods by road and rail

ICAO Not classified as dangerous in the meaning of transport regulations

IATA Not classified as dangerous in the meaning of transport regulations

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SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This mixture is not classified as dangerous according to 1999/45/EC

Water hazard class (WGK) Hazardous to water/Class 2

International Inventories

Chemical name EINECS ELINCS TSCA DSL NDSL PICCS ENCS CHINA AICS KECL
3-Chloro-2-hydroxy X - 11233 X X X X X X KE05715
propylammonium
chloride

15.2. Chemical safety assessment

A Chemical Safety Assessment is not required for this substance when it is used in the specified applications.

SECTION 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3

H351 - Suspected of causing cancer
H412 - Harmful to aquatic life with long lasting effects

Labeling

Issuing date 10-Dec-2010

Revision Date 22-May-2020
Revision Note SDS sections updated, 8, 15

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. In case of any questions, please refer to the official document in
English and contact us in your region.

End of Safety Data Sheet

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