E2661 , ORGANO CORPORATION, GHS-JCIA2,

[ORPERSION E2661A, GHS Sep./2017, 1/66]

01/Sep

Prepared: Aug. 17, 2015

5
Revised: Nov. 21, 2018
8

Safetyy Data Sheet (SDS)

１．Infor
ormation of Product and Manufacturer
Commodity Name： ORPERSION E22661A
Manufacturer： Organo Corporation
Address： 1-2-8, Shin-suna, Koto-ku, Tokyo
Division： Perform mance Products Division cheemicals sectionn
TEL：： 81-3-56
5635-5214
FAX： 81-3-36
3699-7244
Recommendation and Restriction on Use： An agent for RO system

２．Summary of Hazard
Hazards
GHS Classification
Physical and Flammable liquid Not classified
Chemical Hazard
Hazard： Pyrophoric liquid Not classified
Substances and mixtures, which in Not classified
contact with water, emit flammable
gases
Corrosive to metal Category
ategory 1
Health Hazard
Hazard：： Acute (Oral)
toxicity(Oral) Not classified
Skin corrosion/ irritation Category
ategory 1
Serious eye damage/ eye irritation Category 1
Specific target organ systemic Category 2(respiratory
respiratory organ
organ)
toxicity(single exposure)
Hazard： Aquatic environmental acute toxicity Category
Environmental Hazard ategory 2
＊ Hazard
ard not listed above cannot be applicable or cannot be classified.

GHS Label Elements

Pictogram or Symbol
Symbol：

Signal word
word： Danger
Hazard Statement
Statement： ・ Severe
evere skin burns and eye damage
・ Severe
evere eye damage
organs（Respiratory
・May cause damage to internal organs（ Respiratory organ if inhaleded）
・ May be armful
harmful if swallowed
・ May be corrosive to metals
・ Harmful to aquatic life
Precautionary 【Prevention】
【 ・Do not handle until all safety precautions have been read and understood.
Statement
Statement： ・ Use only in a well ventilated area or outdoor.
well-ventilated
・Wear protective gloves/ protective clothing/ protective
protect ive glasses
glasses// protective
protecti
mask.
・Do not eat, drink or smoke when using this product.
・ Wash hands thoroughly and ggargle after handling.
・ Avoid mixing with acids or other substances
substance
・ Avoid releasing to the environment (unless it is necessary
necessary).
【
【Response】 ・Absorb spillage to prevent material damage.
・IF INHALED: Remove victim to fresh air and Keep at rest in a position
breathing. Immediately
comfortable for breathing mmediately call a doctor.
 [ORPERSION E2661A, ORGANO CORPORATION, GHS-JCIA2, 01/Sep./2017, 2/6]

・ IF SWALLOWED: Rinse mouth, and get immediate medical advice/

attention. Do NOT induce vomiting.
・ IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Get immediate medical advice/ attention.
・ IF ON SKIN (OR CLOTHING): Remove/ Take off immediately all
contaminated clothing. Rinse SKIN with water/ shower. Wash
contaminated clothing before reuse. Get medical advice/ attention if the
victim feels unwell.
【Storage】 ・ Store in corrosive resistant container with a resistant inner liner.
Keep container tightly closed. Store in a well-ventilated place.
Store locked up.
【Disposal】 ・ Consign contents and the container to a professional industrial waste
disposer who has the local governor's permission on business.
Hazard not applicable to ： Alkaline aqueous solution. Generates heat intensely if mixed with acids.
GHS category

３．Composition
３． and Information on Ingredients
Chemical substance or ： Mixture
mixture
Chemical name or common ： As follows
name, etc.

Concentration Reference Number in

Chemical
Ingredient Gazetted List in Japan CAS No.
(％) formula
*1 *2
Sodium hypobromite 9.0-15.0 NaOBr - - 13824-96-9
Sodium hydroxide Less than 5 NaOH (1)-410 - 1310-73-2
Others Proprietary Proprietary Proprietary Proprietary Proprietary
*1: Chemical Substances Control Law (CSCL)
*2: Occupational Safety and Health Act

４．First
４． Aid Measure
IF INHALED ： Remove victim to fresh air and keep at rest in a position comfortable for
breathing and keep warm. When breathing stops, do artificial respiration
on victim after loosening clothing and securing the breathing respiratory
tract by using a pocket mask with the countercurrent prevention and other
appropriate medical respiratory apparatus. Immediately call a doctor.
IF ON SKIN ： Wash skin immediately and remove the product sticking completely.
May cause skin damage if washing is late or insufficient. Take off all
contaminated clothing immediately and wash with plenty of running water.
Rinse skin with plenty of running water and soap. Get medical advice/
attention.
IF IN EYES ： Wash eyes immediately and remove the product completely. May cause
eye damage if washing is late or insufficient. Rinse cautiously with
enough water for more than 15 minutes.Get immediate medical advice/
attention. Open the eyelid fully by using finger, and rinse with water in
every corner of eye.
Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED ： Rinse mouth. Give the victim one or two glasses of water or milk. Do
not induce vomiting. Get immediate medical advice/ attention. If
necessary, do artificial respiration or oxygen inhalation on victim by using
a pocket mask with the countercurrent prevention and other appropriate
medical respiratory apparatus. If the victim is unconscious, do not anything
from a mouth. Lean the victim not to come into the trachea when the
victim vomits.
Protection of a person ： Wear rubber gloves and gas mask. Remove all the contaminated clothing
taking an emergency and protective equipment. Avoid touching the hazard by wearing gloves.
measure If the victim swallows the product, do not use mouth-to-mouth breathing.
Use a pocket mask with the countercurrent prevention and other
 [ORPERSION E2661A, ORGANO CORPORATION, GHS-JCIA2, 01/Sep./2017, 3/6]

appropriate medical respiratory apparatus.

Special instructions to ： The influence (symptoms of the edema of the lungs) by the inhalation of
doctors the halogen gas often appears later on and turns worse if not keeping rest.
Rest and follow-up are indispensable.

５．Fire
５． Fighting Measure
Appropriate fire
extinguishing media
Inappropriate fire
extinguishing media
Specific hazard at fire
Specific Firefighting
Measure
Protection for the person
extinguishing fire
： Plenty of water. This product itself is not flammable.
： Because harmful halogen gas is generated by contact with the acid, avoid
using carbon dioxide and the acid dry chemicals.
： Harmful halogen gas is generated because of thermal decomposition.
Prevent leakage or scattering.
： Evacuate the people in the disastrous and dangerous area to safety zone.
Prohibit enter of people around the area with fire, except for the authorized
personnel. Control the released product or fire-fighting water not to flow
directly into sewer, river, or marine area. Extinguish the fire from the
windward. Attention should be given because harmful hydrogen halide gas
is generated by thermal decomposition. If possible, move the container
from the area with fire to a safe area promptly. If impossible to move the
container, sprinkle water on and around the container to cool down.
： Wear heat resistant gloves, goggle-type protective glasses and air
respirator.

６．Accidental
６． Release Measure
Caution to human ： Wear rubber gloves, goggle-type protective glasses, protective clothing,
rubber protective boots and gas mask when treating leakage.
Prohibit enter of people into the site where the product leaks by putting a
rope. Only the authorized personnel can enter. Work from the
windward.
Protective Equipment and ： Wear proper protective equipment to avoid the contact of splash with
Measure for Emergency skin and the inhalation of gas. See “8. Exposure Control and Personal
Protection”.
Caution to Environment ： Take care that the released or spilled product does not flow directly into
river or environment and contaminate them.
Enclosure and Depuration ： If the released product is not much, use sawdust or waste cloth to absorb
Measure/Machinery and the leakage. If the large amount of product is released, surround it by
Materials mounds to prevent its outflow and handle it after bringing it to the safe
place. Keep collected leakage in an airtight polyethylene container.
Pay attention not to let the thick waste fluid flow into the sewerage and
river.

７．Handling
７． and Storage
Handling
Technical Measure ： Prevent leakage, overflow and splash, and also do not produce mist.
Prepare an appropriate facility, and wear protective apparatus not to
touch the product with eyes, skin and clothing. See “8. Exposure
Control and Personal Protection”.
Local or Whole Area ： Prepare local ventilation and whole ventilation as required.
Ventilation See “8. Exposure Control and Personal Protection”.
Caution ： Use the product only outside or in a well ventilated area.
Understand the content of “2. Summary of Hazards” well, and avoid the
product contacting with human body.
Precautions for Safe ： Avoid contact with acids, as the product is alkaline. Wear rubber
Handling gloves, goggle-type protective glasses, protective clothing, rubber
protective boots and gas mask when handling. Halogen gas is
produced by contact with acid or decrease of pH. Seal the container
after handling, and wash hands and face well and gargle. Dispose
products immediately after the warranty expires.
Storage
 [ORPERSION E2661A, ORGANO CORPORATION, GHS-JCIA2, 01/Sep./2017, 4/6]

Technical Measure ： Store the product in an airtight container with avoiding direct sunlight.
Keep it in a cool and dark place.
Because decomposition is promoted by heavy metal (cobalt, nickel,
chrome, copper, iron), prevent heavy metal from getting into the stored
container.
Proper Storage ： See “10 ． Stability and Reactivity”. Contact with the dangerous
Condition substance for mixing is prohibited. Store in airtight container, in
well-ventilated cool and dark place, avoiding direct sunlight. Store
the product with keeping away from acid, metal and combustibles.
Safe Packing Material ： Do not use iron container because the product has corrosiveness to iron.
Use vinyl chloride or polyethylene.
Avoid storing the product for a long term in a thin polyethylene
container such as the bag-in-box.

８．Exposure
８． Controls and Personal Protection
Facility ： Equip a shower room, hand washer and eye washer near the working area and
ensure that the location of the facility is well announced to the workers.
Ensure a local exhausting if fume or mist occurs.
Control ： Not determined
concentration
Allowable ： Not determined
concentration
Protective ： Respiratory organ ： If mist occurs, use a supplied-air respirator:
Equipment gas mask for halogen gas, supplied-air
respirator, air breathing apparatus, and so on.
Hands ： Impermeable gloves (rubber gloves, etc.)
Eyes ： Goggle-type safety glasses
Skin and Body ： Vinyl protective cloth, rubber protective
boots
Proper sanitation ： Wash hands and gargle after handling the product, then drink, eat, and so on.

９．Physical
９． and Chemical Properties
Appearance ： Yellow to brown liquid
Odor ： Characteristic odor
pH ： 11.8 (1w/w%)
Melting/ freezing point ： < -5℃
Flash point ： Not applicable
Flammability and Explosion ： Not applicable
limit
Vapor pressure ： No data available
Vapor density ： No data available
Specific gravity ： 1.3 (25℃)
Solubility ： Soluble（water）
Octanol／water partition ： No data available
coefficient
Decomposition temperature ： No data available

．Stability and Reactivity

10．
Stability
Possibility of Hazardous
Reactions
Conditions to be avoided
Dangerous substance to be
mixed with
Hazardous Decomposition
： Instable with air, heat, light and metal. Compound of the product is
decomposed gradually to produce harmful/corrosive halogen gas.
： Heat is generated when mixed with acids, as the product is alkaline.
Harmful/corrosive halogen gas is prodused by reaction with acids.
Contact with water prohibitive substance may cause fire or explosion
because the product contains water.
： Avoid direct sunlight or contact with high temperature liquids.
Because the product is corrosive, do no use an iron container.
： Metals, acids, organic materials, oxidants, reducing agents, amines
： Halogen gas（when heated or combustion occurs）
 [ORPERSION E2661A, ORGANO CORPORATION, GHS-JCIA2, 01/Sep./2017, 5/6]

Product

．Toxicological Information
11．
Acute Toxicity ： Not classified (>2000mg/kg)
Skin corrosiveness/ ： Category 1 (skin corrosiveness) because of high pH (more than 12)
Irritation
Serious eye damage/ ： Category 1 (serious eye damage) because of high pH (more than 12)
Irritation
Specific target organ ： Inhalation of mist may cause respiratory irritation, damage on respiratory
systemic toxicity(single organ, dyspnea.（Category 2：respiratory organ）
exposure)
Respiratory or Skin ： No data available
Sensitization
Germ Cell Mutagenicity ： No data available
（Mutagenicity）
Carcinogenicity ： No data available
Reproductive Toxicity ： No data available

．Environmental Information
12．
Ecotoxicity ： Fishes ：LC50＝1～10mg/L (96h)
Crustaceans：EC50＝1～10mg/L (48h)
Persistence/ ： Decomposed easily by light (sunlight)
Degradation
Bioaccumulation ： Decomposed product by light has no bioaccumulation potential.
Mobility in the soil ： No data available
Other hazardous ： Since there are not enough knowledge and information, do not dispose the
influence substance into the general environment.

．Disposal Considerations
13．
As an industrial waste, consign to a professional industrial waste disposer who has the local governor's
permission on business. When you dispose an empty container, the contents should be removed from the
container before you dispose. If you need to entrust the disposal of contaminated container to an outside
disposer, the collector or disposer must be a professional and have the local governor’s permission on
business.

．Transport Information
14．
International Regulation
UN Classification
UN Number
Name（UN proper
shipping name）
Class of container
Specific Safety Measure and
Conditions
： As follows
： Class 8（Corrosive substance）
： 3266（Other corrosive substance: inorganic substance, liquid, alkaline
substance）
： -
： III
： Make sure that there is no leakage from the container. Load as there
are no fall, tumble and damage, and make sure to prevent the leakage
and load collapse. Follow the applicable legal provisions for
packing, labeling and transporting.

．Regulatory Information
15．
（The following are regulations in Japan. Observe national/local regulations.）

Fire Services Act ： Not applicable

Poisonous and ： Not applicable（classified substance for preventing hazards which includes
Deleterious Substances some poisonous substance (Act No. 38)）
Control Law
Pollutant Release and ： Class 1 designated chemical substance：Not applicable
Transfer Register Law Class 2 designated chemical substance：Not applicable
 [ORPERSION E2661A, ORGANO CORPORATION, GHS-JCIA2, 01/Sep./2017, 6/6]

Occupational Safety ： Labeled substance：Sodium hydroxide = less than 5%

Health Act Noticed substance：Sodium hydroxide = less than 5%
Dangerous substance：Oxidizing substance
Regulations for the ： Corrosive substance
carriage and Storage of
Dangerous Goods in
Ships
Act on Port Regulations ： Corrosive substance
Civil Aeronautics Act ： Corrosive substance
Wastes Disposal and ： Industrial waste subject to special control（waste alkali）
Public Cleansing Act

．Other Information
16．
* This data seat is being made based on the information available in the present as information for safe
handling of the product, but accuracy of the information and integrity are not guaranteed.
* This data seat may be revised based on new knowledge.
* This data seat is made for a usual handling of the product, therefore, for special handling, take appropriate
safety measures according to the use or usage.