Fiitjee All India Test Series: Concept Recapitulation Test - Iii JEE (Advanced) - 2019

FIITJEE
ALL INDIA TEST SERIES

CONCEPT RECAPITULATION TEST – III
JEE (Advanced)-2019
PAPER – 2
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. C
4
Sol. Use  Fdt  mv  m  5 
0
1 1 2
work F  mv 2  m  5 
2 2
2. D
a y1  y 2
Sol. tan θ  
g 4
 y1  y 2  0.5 ........  i a
Volume of water is q
y1
4  y1  y 2 
 3  18 y2
2
 y1  y 2  3 ........ ii
4
2.5
 y2 
2
 speed of liquid coming from orifice is
 at  2gy 2  10m / s
3. C
Sol. TP  40 N
TQ  30N
TP  TQ  10 N
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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2
4. BD
Sol. When a displacement wave strikes a fixed end, it gets inverted after reflection and when a
pressure wave strikes a fixed end, compression pulse gets reflected as compression pulse.
5. ABD
Sol. Speed will be maximum when the block passes through the equilibrium position. F
Fspring = mg Spring
 A is correct
(B) From conservation of energy
1 1
mg(  x)  Kx 2  mv max
2
(1)
2 2
mg mg 
Where x   
K 4mg 4 mg

putting x  in equation (1)
4
3
Vmax  gl
2

(C) is incorrect as in equilibrium compression is  which is more than
4 8
T 1 m
(D) Time taken is  2
4 4 K
 D is correct
6. ABC
Sol. Applying Snell’s law at face AB, we get
1  sin 60º  3  sin r
3 1
 3 sinr or sin r 
2 2
 1 
r  sin1    30º
 2
1
sin  c 
3
(where, c is the critical angle)
 1 
 c  sin1  or c  35º
 3 
From geometry, angle of incidence at Q is 45º. At face CD angle of incidence is greater than c .
Therefore, the rays gets totally internally reflected at face CD. Hence, option (a) is correct. From
geometry, angle of incidence at R is 30º. At face AD angle of incidence is less than c
So, the ray comes through face AD. Hence option (b) is correct.
Applying Snell’s law at face AD, we get
 3
e  sin1    60º
 2 
The angle between the incident ray and the emergent ray is 90º.
Hence, option (c) is correct and option (d) is incorrect.
7. AD
Sol. WA B  nRT1 ln 2
3 AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
U1  U0
W A B  In 2
2
dv
 2R
dT
dv  2RdT
C V  2R
CP  3R
8. BCD
Sol. Current through resistances remains constant.
9. B
 PV 
Sol. Q  nCP T  CP  
 R 
10. A
Mg/A
Sol. Po
Pgas
SECTION – C
11. 8
3
 4S  3  4S  5R 
Sol.  Po   R   0.5Po  0.8   
 R   R  4 
96S
P 
R
12. 4
C
Sol. Lmin   16 cm
4f
so resonance for length 16 cm, 48 cm, 80 cm i.e 3 cases.
13. 5
Sol. VS2  VR2  VC2  2VR VC cos 
VR
i
R
PC  i VC cos 
14. 3
Sol. each falling link collides with the fallen links with a relative velocity

v imp   vj F imp
  dm1
f imp  v rel m'
dt

f imp  v 2 j N m'g
from equation on heap
N  mg  fimp  0

N   v 2  gy 
 2 1 2
 10  0.05 
 2 1  0.5 
 3N
15. 5
Sol. PM  2P2  PM
1 1
P2  
f2 4R
1 1 2 5
  2  
fm 4R R 2R
2
fm   R
5
h  2 fm
2R
h  2 4
5
R  5m
16. 5
1 1 q2
Sol. E mv 2  kx 2 
2 2 2c
q
e  Bv  
c
1 1
 
E  m  B 2 2c v 2  kx 2
2 2
as E = constant
dE
0
dt
dv  k 
  x
dt  m  B 2 2c 
 = 20 rad/sec
17. 5
Sol. Angular momentum about P = t = mgsin30o R 1   N
f
o
mg sin 30
P o
mg cos 30
18. 3
Sol.

 P.E., U  .B    

I2 r 2  oI1R 2 
3
2 R 2  x2 2  
2 2
du 3o R r I1I2 x
F     5
, N  3
dx

2
2 R x 2 2

19. 3
 A
A 2 
sin  
 A  m 
sin    2 

Sol.    2  2   
A 3 A
sin   sin  
2 2
 3A 
sin  
2  4  , Let A  
 
3 A 4
sin  
2
 
2 sin3 3 sin   4 sin3  3  4 sin2 
   
3 sin2 2sin .cos  2cos 
 4 3 cos 2   4cos   3  0
1 2 3  1 
 cos    ,  
2 3 2  2 3
A 
   30o   30o 
4 6
2
A , C  3
3
20. 1
Sol. For maxima at P, path Diff.  n, n  int eger
d
  s2P  s1P      1 t  n  y     1 t  n
D
10 6
 n  106 m  n 

106 10 6
nmax   2.5& nmin
  1.42
4000  1010 7000  1010
 n  2, only one wavelength will give max ima at P for n  2
SECTION – D
21. 00001.53
Sol. The centre of mass of the rod is at distance

y  x from the brim.
2
 V y  x
 al gV   w g 2  x  mg 2
 
4
  1.53
x
22. 01057.50
Sol. Let the sound observed by the parachutist at t0 = 12s be produced

at t1s. Velocity of source at the instant of emitting sound = gt1 and 1 / 2  gt12
velocity of observer at the instant of observing same sound = gt0.
Hence the relation between apparent frequency f’ and original 1/ 2  gt20
frequency f will be h
 v  gt 0 
f'  f 
 v  gt1  Reflected
Here f = 800 Hz, g = 10 m/s2, v = 330 m/s Incident sound
Sound
T0 = 12s and f’ = 800 + 700 = 1500 Hz
Putting these, we get
T1 = 9s
Now the distance traveled by sound in (t0 – t1) sec
 1   1 
is v  t 0  t1    h  gt 02    h  gt12 
 2   2 
Putting the values, we get
H = 1057.5 m
23. 00772.00
Sol. Rate of formation of nuclei at time t is
dN
   N, where N = number of nuclei at that time
dt


N  1  et



Number of nuclei disintegrated in time t, Nd = t  1  e t

 
  
 Energy released till time t, E = E0Nd = E0 t  1  et  
  
20% of this energy is used for heating water,
  
0.2E0 t  1  et    ms
  
  
 

0.2E0  t  1  e t 


 
ms
At t = T1/2
 2  1 
0.2E0 2T1   1  
 2
  2 
 
ms
0.2E 0 0.386 
  772K
ms
Chemistry PART – II
SECTION – A
24. B
Sol. O O
HO S (S)n-2 S OH
O O
No. of S-S bond = (n-1)
25. C
Sol.
-
PhLi
-
(1) Aromatic
CH3
PhLi
-
CH3
(2) Anti Aromatic
26. C
Sol. pv 5 /2  const ; n  5 / 2 (Polytropic process)
no. of moles  1
3
Cv of Ar  R
2
q  nC  T
 R 
 n  Cv   T
 1 n 
3 R 
 1 R    26
2 1 5 / 2 
5
 R  26
6
5
  8.314  26  180 J
6
27. ABC
Sol. (a) Mechanical equilibrium
(b) Thermal equilibrium
(c) Chemical equilibrium
28. ABC

H
Sol. A2On  MnO4  AO3  Mn 2
Eq. of A2On  Eq. of MnO4
1.5  10 3  10  2n   60  0.03  10 3  5
no. of moles   n  factor 

n  2
formula  A2O2
Empirical formula  AO
29. ABCD
Sol. ABCD
I=Trans form but both methyl on equational position
IV=III=cis form one methyl on axial position and one on equational position
II=Trans form but both methyl on axial position
30. AB
Sol. In hyper conjugation  electron interact with vacant orbital.
31. ACD
Sol. (A) NH3 Cl
NH3 NH3
Cl NH3
Pt Pt
NH3 Cl NH3
NH3
NH3 Cl
cis trans
Plane of symmetry optically in active Plane of symmetry optically in active
(B)
ox
-3
- Optically active
ox Fe
- no geometrical isomerism
ox
(C) a n
d
Square planer
Plane of symmetry
M
Optically inactive
c b - GI occurs
(D) If ligand is optically active then complex is optically active.
32. D
Sol. In polymerisation isomerism; ratio of metal and different ligand should be same.
33. B
SECTION – C
34. 8
Sol. PtCl 2  NH3  4  PtCl 2 SCN 4  c
PtCl  SCN  NH3   PtCl SCN 3 


ambidentate ligand
so two isomer possible
 
Total SCN  ligand  4
Total isomer  4  2  8
35. 3
Sol. O
O
O3/ C H
H +
+
Zn/H2O O C H
O O H
O
O
C H
= 2CH 3CHO +
C H
O
O
O3/ O O C H
+
Zn/H2O H3C C C CH3
C H
O
So, no. of different pdt are
O O O O
H3C CHO + H3C C C CH3 + H C C H
36. 3
Sol. 1.03 O
2.Zn/H2O 2 CHO C CHO

(X)
No. of  bond = 3
37. 6
Sol. 10  4
9  4 
8  4 
Total 6 spectral lines
7  4
6  4

5  4 
38. 2
15 / m
Sol. f  K f m  kf   1000
100
15
1  kf   10   (1)
m
if mass of solute  30g
30 / m
f  K f   1000
100
15
 2  kf   100
m
 21  2
39. 4
Sol. HA  NaOH  NaA  H 2O;   6900 cal / eg
HB  NaOH  NaB  H 2O;   2900 cal / eg
Let x eq of NaOH react with HA and y eg NaOH react with HB
x y 1
6900 x  x   2900  y  3900
 x  1/ 4
y 3/4
x : y  1: 3
x  y  1 3  4
40. 1
Sol. SO42 ion is present in solution; no electrolysis of SO42
[ SO42 ]=0.1 M
Decimolar concentration of SO42  1
41. 6
rMg 2 0.65
Sol.   0.35
rS 2 1.84
Co-ordination no.=4
rMg 2 0.65
  0.464
rO 2 1.4
Co-ordination no.=6
rCs  1.69
  0.933
rCs  1.81
Co-ordination no.=8
Co  ordination no.
r
0.225   0.414 4
r
r
0.414   0.732 6
r
r
0.732  1 8
r
42. 7
Sol. a, c, d , g, j , l , m
43. 7
Sol. 1 2
SH O
HO C OEt
1 O O
C Cl
H2C CH2 O
Cl 2
1
SECTION – D
44. 00002.68
Z M
Sol. Density 
NA  a3
Z M
a3 
NA  d
a
Dis tan ce between K  and F  
2
45. 00040.00
  6  8 2
Sol. Rate after 10 minutes = 
10 8
  4  6 2
Rate after 20 minutes = 
10 8
Reaction of 1st order
At = Ao – kt
0=8–kt
8
t=
k
6 = 8 – k  10
2
 k
10
8 8
t= =  40 min
k 2
10
46. 00000.11
0.5  40  60
Sol. no of equivalent of Al =
96500
0.5  40  60 1
No of moles of Al = 
96500 3
0.5  40  60 27
Mass of Al deposited =   0.11 g
96500 3
Mathematics PART – III

SECTION – A
47. A
1
1 1 1  16 1
Sol. A 1   2  .....    sq. unit
16  4 4  1 1 12
4
48. C
Sol. Area of required region is half of the area of circle.
49. C
Sol. x  1  h, h0
log  2  h  log2  3.4h
 3  3h 
lim 1 1
h 0  
  8  h    4  3h     sin h 
3 2
 
1  h
 2 log  1  2    4h  1 
3    1
4 
  h 
 2 
lim  
h 0  1 1
1 1 
 8  h  3  8 3
3  4  3h  2  4 2   sin h 
     
 h 3h  h 
 
1 3
3    log4  1  log4  1
 2  2
1 1 1 1 
 3 . 4  3  2  2     4
3
 
9
 log 4  1
4
50. C
     
Sol. r  c  b  r  c  b

 a.c   8  7 
r.a  0         5
a.b 2  0  1
  
  
r  c   b  4iˆ  3 ˆj  7kˆ  5 ˆi  ˆj  kˆ 

r   ˆi  8ˆj  2kˆ
 x  y  z  7
51. C
 1 
 tan   
m  m2 a tan  
Sol. tan    1   2
1  m1m2 b a
1 2
b
cot   
a 2

 b2 sin .cos 
a.b

2cot 


a  b2  a  2
 
e2 
b
sin 2 a2   1  e2
52. A
Sol. The line x – y + a = 0 tangent at P. then PR  PQ will be maximum   RQ 
53. ACD
Sol. focus  6,  3  and equation of tangent at vertex is 5x  3y  15.
30  9  15 24
 Length of latus rectum  4 
34 34
54. BD


Sol. As x  ,  cot x is positive  being in I quadrant  
2
thus cot x   0 lim f  x   e0  1

x
2
f  x   ecot xas cot x is negative in 2nd quadrant


and cot  0  cot x   1
2
1
lim f  x  
x
 e
2
55. C
A C
cot  cot
Sol. A G 2 2  cot B  3
2 2
B
cot  3
2
56. C
B 1 
Sol. tan  B
2 3 3
SECTION – C
57. 1
Sol. Ellipse in internally tangent to the circle at point of intersection.
58. 6
3
 1 1
Sol. Let  x    a and x 3  3  b
 x x
3
a2  b 2  1 1
f x   a  b   x    x3  3
ab  x x
1
3 x  6.
x
59. 0
Sol. use property
60. 4
2 2  c
Sol. H  xy  c 2 , S   x      y     r 2 let P  ct, 
 t
S 1  t12  t 22  t 32  t 24  2
 2
 2   2 
c2
1 1 1 1
S2  2  2  2  2  2
2   2   2  
t1 t 2 t 3 t 4 c2
c2 c 2 4r 2
2  1
 S  S2   2  2
r r c
61. 5
Sol. Let y  cotx; 3y 2  8y  3  0, y1, y 2 be roots
8
y1  y 2   , y1y 2  1
3
y  cot x is a bijection on  0,   R
and also  , 2   R
    3 
cot x  0 when x   ,     , 2 
2   2 
   3 
 x1, x 2   ,   &  x 3 , x 4    , 2 
2   2 
y1  cot x1  cot x 3 , y 2  cot x 2  cot x 4
y1y 2  1  cot x1 cotx 2  cot x 3 .cot x 4  1
 x1  x 2  x 3  x 4  5 
62. 3
n 1
Sol. B  adj  2A   B  2A
n n 1
1024  4n 1  2
2
210  2n n  2
n3
63. 6
Sol. Let  h, k  lies on hyperbola
h  x1 k  y1 2  2h  k 
   hk  1
2 1 5
12x 2  7xy  12y 2  25  0.
64. 5
Sol. Use Homogenization.
65. 3
Sol. Properties of G.I.F.
66. 0
Sol. Use L.M.V.T
SECTION – D
67. 02008.00
Sol. t n   t n   t n 1
68. 01008.00
Sol. Use fundamental principle of counting.
69. 01210.00
Sol. (AM > GM)

Fiitjee All India Test Series: Concept Recapitulation Test - Iii JEE (Advanced) - 2019

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FIITJEE

ALL INDIA TEST SERIES

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