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Mass Transfer Mechanism During Dehydration of Meat: School of Chemical Engineering (Scheme)
Mass Transfer Mechanism During Dehydration of Meat: School of Chemical Engineering (Scheme)
DEHYDRATION OF MEAT
A PROJECT REPORT OF J
COMPONENT
EQUILIBRIUM STAGED OPERATIONS
(CHE4001)
Slot: A1
Lab Slot: L43-L44
[1]
CERTIFICATE
This is to certify that the project report entitled “MASS TRANSFER MECHANISM
DURING DEHYDRATION OF MEAT” submitted by Sariga Reghunathan (18BCM0042),
Atishay Jain(18BCM0068), Samruddhi Kadam (18BCM0070), Abhay Yadav (18BCM0079),
Aditya Zawar (18BCM0121) as ‘J’ component for the course CHE4001 EQUILIBRIUM
STAGED OPERATIONS.
Date: 30/05/2021
Place: VIT
[2]
TABLE OF CONTENTS
1. ABSTRACTS 4
2. INTRODUCTION 5
6. PROCEDURE 11
7. OBSERVATION 12
8. READINGS 13-16
9. CALCULATIONS 17-20
11. RESULTS 23
12. CONCLUSION 24
13. REFERENCE 25
[3]
ABSTRACT
Drying conditions can greatly affect the physical and mechanical properties of meat. The
drying process must be controlled to reduce or minimize drying damage. In the last few
years, the demands of the meat and meat dried products have increased tremendously. In the
past drying was performed to preserve perishable foods with less emphasis on
multidimensional quality attributes a recent trend is to develop dried meat products
maintaining its quality, such as flavor, texture, convenience, and functionality with increased
nutritional quality and reduced anti-nutritional factor. At present, drying of meat has extreme
focus on maintaining its qualities and to increase the shelf life. The main purpose of this paper
is to give an overview on the drying of meat. It reduces storage and transportation costs and
makes handling stress-free by reducing size, weight, and risk of microbial contamination of
meat and meat products. Meat drying characteristics such as shrinkages/volumetric
shrinkage, rehydration ratio, apparent or effective diffusion coefficient or diffusivity, affects
the drying behavior of the meat.
Keywords: Drying, multidimensional quality, nutrition, shelf life, shrinkage, diffusivity,
rehydration ratio
[4]
INTRODUCTION
Dehydration of Food - Meat
[5]
AIMS AND OBJECTIVES
The aim of this work was to consider different types of fish meats and drying
them at a range of different temperatures and also at different conditions of mass. Then to
record the changes in moisture content during the process of drying. These readings were
then converted into moisture ratios. They we used this to explain the convective drying
behavior of meat. A second analysis was carried out, in this 2 different thin film drying
models and their statistical values were compared these are RMSE and χ2. The best model
was selected on the basis of low RMSE and low χ2 values. Among the models that were
evaluated, the Newton model showed the best fit to the observed data of moisture ratio.
The values that we got from the Newton equation were minimum as compared
with the other models of drying. After the numerical calculations were done it was figured
out that it leaded to the result that Newton was the optimal fit with the value of RMSE as
1.48 x 10−7 and χ2 as 5.39 x 10-4 for 1500 𝑐 Microwave Temperature and 60g Sample Load
and the value of RMSE as 6.39 x 10−8 and χ2 as 4.08 x 10-4 for 1000 𝑐 Microwave
Temperature and 25g Sample Load.
[6]
LITERATURE REVIEW
Dehydration of Onions was carried out by S. Khokar, G.R & Fenwick due to their high solids
content (18–20% and above). Onions were dehydrated at 75–60 °C, The final moisture content
of 4% is achieved through warm air circulation. The results were, 8– 10 kg of raw onions
produce 1 kg of dehydrated product. Experiences of hot- air drying have revealed problems
such as an undesirable flavor, texture, and color. Flash-freezing and drying have proved
effective in overcoming these problems.
The main objective was to examine the influence of different osmotic parameters on the mass
transfer kinetics during osmotic treatment of pork meat. The system’s response parameters
observed were: water loss, solid gain, final dry matter content and water activity. Optimum
osmotic parameters: osmotic time of 4h, molasses solution concentration of 72% and solution
temperature of 45ºC. Conditions were determined using Response Surface Methodology, by
superimposing the contour plots of each process variable. The predicted responses for the
optimum drying conditions in sugar beet molasses solution were: DM of 64.5%, WL in the
close vicinity of 0.53, SG about 0.15 and aw in the range of 0.83 to 0.8
[7]
3. OSMOTIC DEHYDRATION OF FRUITS AND VEGETABLES: A REVIEW
In this review different methods, treatments, optimization and effects of osmotic dehydration
have been reviewed. Studied showed that combination of different osmotic agents was more
effective than sucrose alone due to combination of properties of solutes.During the experiments
it was found that optimum osmosis was found at approximately 40 °C, 40 °B of osmotic agent
and in near about 132 min. Pretreatments also leads to increase the osmotic process in fruits
and vegetables. Solid’s diffusivity was found in wide range (5.09–32.77 kl/mol) studied by
Fick’s laws of diffusion.
In traditional & innovative ways as water removal increases shelf life of the edible items.
Control of outward flow of water with utmost care is important to maintain high output prod.
& min. energy cost as drying is complex phenomenon. The available models are not so precise,
so future challenge is to obtain micro-structure information of biological tissue. During
dehydration process theoretical model that include the different concentration and pressure
gradients along with 3-D pathway inside which fluid moves are needed for best results.
[8]
• Comparison between Carbonium ion and Free radical mechanism (Pentane Cracking)
This comparison is done taking the reference of paper the roles of the free radical
and carbonium ion mechanisms in alkane cracking to produce light olefins by School of
Chemical Engineering, Changchun University of Technology students. This is carried
out over a zeolite catalyst at 600–800 °C
[9]
10 For the carbonium ion mechanism, the For the free radical mechanism, the mole
mole selectivity to the specific products selectivity to
was in a descending order of propene > the specific products were in a descending
ethane > ethylene > hydrogen. order of ethylene >hydrogen > propene >
methane > butylene.
11 The carbonium ion mechanism for The free radical mechanism for pentane
pentane cracking was initiated by the cracking was initiated by the homolysis of C-
heterolysis of C-C/C–H bond over B acid C/C–H bond, which was a highly energy-
sites on K-ZSM-22 zeolites, and it was demanding process, and led a high apparent
less energy-demanding compared to the activation energy.
homolysis.
12 If the kc/kt ratio is greater than one, If the kcp/(kc+kt) ratio is greater than one,
indicating that the carbonium ion route indicating that the concurrence of the
has surpassed the free radical route and carbonium ion and free radical routes led to the
taken over the dominant position synergistic effect, and thus the superiority of
pentane cracking.
[10]
MATHEMATICAL MODELS
Page model: Page model is an empirical modification to Newton’s model to remove the
errors of that model by the addition of a dimensionless empirical constant “n” to the time
term t. this constant parameter has an effect of moderating the time, and generally the model
in this case provides better results for the prediction of loss in moisture content.
MR = exp(−kt n )
[11]
Model Calculation:
The root mean square error (RMSE), reduced χ2, and correlation coefficient R2 were used for
determining the best suitable model.
1
1 N
2
RMSE =
N
i =1
( MRexp,i − MR pre,i )
2
N−z
N
N
N MR pre,i
MR pre,i − k =1
k =1 N
Where MRexp,I is the experimental moisture ratio of ith data, MRpre,I is the predicted moisture
ration of ith data, N is the number of observations, & z is the number of drying constants.
[12]
PROCEDURE
[13]
OBSERVATION
➢ Prawn Fish Meat
[14]
READINGS
King Fish Meat
[15]
Rate of Drying Curve
10
9
8
7
N (kg/hr*m2)
6
5
4
3
2
1
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6
X(kg of moisure/kg of dry meat)
Drying Curve
1.6
1.4
X(kg of moisture/kg of dry meat)
1.2
0.8
0.6
0.4
0.2
0
0 10 20 30 40 50 60 70 80
Time(minutes)
[16]
Prawn Fish
4
N(kg/hr.m^2)
0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
X(kg moisture/kg dry solid)
Drying Curve
4.5
3.5
X(kg moisture/kg dry solid)
2.5
1.5
0.5
0
0 10 20 30 40 50 60 70 80
Time(min)
[18]
CALCULATIONS
Chi^2 0.00053988
K 0.00015678
RSS 2.2083E-14
RSME 1.486E-07
[19]
Page MR Difference
MR=exp(-KT^n) Exp-Theoretical (Exp-Theoretical)^2
1 0 0
0.777503373 0.20582996 0.042365973
0.758428391 0.208238276 0.043363179
0.74665007 0.220016596 0.048407303
0.73800981 0.21199019 0.044939841
0.731143986 0.152189347 0.023161597
0.72542706 0.091239607 0.008324666
0.720517875 0.062815458 0.003945782
0.716209124 0.067124209 0.004505659
0.712365074 0.037634926 0.001416388
0.708891846 0.024441487 0.000597386
0.705721718 -0.005721718 3.27381E-05
0.70280418 -0.00280418 7.86343E-06
0.700100525 -0.033433858 0.001117823
0.697580413 -0.030913746 0.00095566
0.695219612 -0.045219612 0.002044813
0.692998449 -0.059665116 0.003559926
0.690900727 -0.057567393 0.003314005
0.688912947 -0.055579614 0.003089093
0.687023739 -0.087023739 0.007573131
0.68522343 -0.118556763 0.014055706
0.683503723 -0.133503723 0.017823244
0.681857445 -0.148524111 0.022059412
0.680278352 -0.146945018 0.021592838
0.678760973 -0.178760973 0.031955486
0.677300491 -0.177300491 0.031435464
8.48321E-13 0.381644976
Chi^2 0.01590187
k 0.12432715
n 0.13579769
RSS 3.2628E-14
RSME 1.8063E-07
[20]
Newton Model
1.2
Series1
1
Linear (Series1)
0.8
MR
0.6
0.4
y = -0.0001x + 0.9698
0.2 R² = 0.9912
0
0 1000 2000 3000 4000 5000
Time(sec)
Page Model
1.2
Series1
1
0.6
0.4
0.2
y = -3E-05x + 0.7875
R² = 0.4482
0
0 1000 2000 3000 4000 5000
Time(sec)
[21]
Prawn Fish
Chi^2 0.000408454
K 0.000215383
RSS 4.09E-15
RMSE 6.39453E-08
[22]
Page MR Difference
MR=exp(-KT^n) Exp-Theoretical (Exp-Theoretical)^2
1 0 0
0.664637212 0.308090061 0.094919486
0.656832612 0.281507309 0.079246365
0.652206904 0.250955151 0.062978488
0.648897993 0.208809517 0.043601414
0.646316048 0.167517944 0.028062262
0.644196508 0.127740251 0.016317572
0.6423975 0.095151907 0.009053885
0.640833981 0.063909102 0.004084373
0.639450898 0.040390999 0.001631433
0.638210545 0.017125423 0.00029328
0.637085956 -0.005070146 2.57064E-05
0.636057171 -0.026175748 0.00068517
0.635108998 -0.046966706 0.002205871
0.634229607 -0.065059646 0.004232758
0.6334096 -0.081630944 0.006663611
0.632641389 -0.097463524 0.009499138
0.631918759 -0.11255117 0.012667766
0.631236551 -0.127283982 0.016201212
0.630590441 -0.138890836 0.019290664
0.629976763 -0.149344352 0.022303736
0.629392387 -0.161803454 0.026180358
0.628834614 -0.172708132 0.029828099
0.628301105 -0.183241816 0.033577563
0.627789816 -0.193007207 0.037251782
1.0425E-13 0.560801992
Chi^2 0.024382695
K 0.329960413
n 0.041123649
RSS 4.17E-15
RSME 6.45755E-08
[23]
Newton Model
1.2
Series1
1
Linear (Series1)
0.8
MR
0.6
0.4
y = -0.0001x + 0.9351
R² = 0.9507
0.2
0
0 1000 2000 3000 4000 5000
Time(sec)
Page Model
1.2
Series1
1
Linear (Series1)
0.8
MR
0.6
0.4
y = -2E-05x + 0.7064
R² = 0.2029
0.2
0
0 1000 2000 3000 4000 5000
Time(sec)
[24]
ARTIFICIAL NEURAL NETWORKS
An artificial neural network (ANN) is an information processing paradigm that is
inspired by the way that biological nervous systems, such as the brain, process information.
The key element of this paradigm is the new structure of the information processing system8.
It is made up of a large number of highly interconnected processing elements (neurons).
ANN, learn by example. An ANN is configured for a specific application, such as pattern
recognition or data classification, through a learning process.
To form a network structure, the inputs and outputs of neurons are connected in some
or the other way. According to the connection method, neural networks can be divided into
two main categories: Feed Forward neural networks (FNN), in which their representative
graphs do not have loops, and RNN (recurrent neural networks), in which loops occur due to
the feedback connection. Feedback networks are static, which means that a given input can
only produce one set of outputs, and therefore cannot carry memory. In contrast, recurring
network architectures allow temporary storage of information on networks
[25]
Progress of ANN model in MATLAB:
The training is done by Levenberg-Marquardt method. The 70 percent of the total readings
are used for training the ANN model and 30percent is used for prediction of the moisture
content present in the meat. Performance here is the rmse value of the system.
The ‘x’ points are the trained values and ‘o’ are the predicted values. The x axis has the true
value of moisture content and y axis contains the predicted value of moisture content. To
check the validation of the model we need to see the how far are the points from the linear
plot. As we see all the points are close to the linear plot so the prediction is reasonable with
the performance i.e rmse of 1.1739e-08.
[26]
RESULTS
[27]
CONCLUSION
In the experiment, different meats (fish) were dried at different drying temperatures and mass
conditions, and the changes in moisture content during drying were recorded. They were
converted into moisture ratios and used to explain the convective drying behavior of meat. In
the analysis, 2 different thin film drying models and their statistical values were compared,
namely RMSE and χ2. The best model is obtained, based on low RMSE and low χ2 values.
Among the evaluated models, Newton showed the best fit to the observed data of moisture
ratio. The values obtained with Newton equation are minimum when compared with other
drying models. As per the numerical calculations it leads to the result that Newton was the
optimal fit with the value of RMSE as 1.48 x 10−7 and χ2 as 5.39 x 10-4 for 1500 𝑐
Microwave Temperature and 60g Sample Load and value of RMSE as 6.39 x 10−8 and χ2 as
4.08 x 10-4 for 1000 𝑐 Microwave Temperature and 25g Sample Load
[28]
REFERENCE
• Khokar, S., & Fenwick, G. R. (2003). Onions and related crops. Encyclopedia of Food
Sciences and Nutrition, 4267– 4272. doi:10.1016/b0-12-227055-x/00862-2
• Antonio Derossi , Carla Severini, Davide Cassi, Mass Transfer Mechanisms during
Dehydration of Vegetable Food: Traditional and Innovative Approaches, Research gate,
February 2011, 14.
• Derossi A., Severini C. and Cassi D. Mass Transfer Mechanisms during Dehydration of
Vegetable Food: Traditional and Innovative Approaches February 21st 2011, 9.
• Effects of Different Drying Methods and Storage Time on Free Radical Scavenging Activity
and Total Phenolic Content of Cosmos caudatus Ahmed Mediani 1, Faridah Abas 1,2,*, Chin
Ping Tan 3 and Alfi Khatib 2,4 Received: 17 February 2014; in revised form: 7 April 2014 /
Accepted: 24 April 2014 / Published: 7 May 2014
• Irwin A. Taub Food Technology Division, Food Engineering Laboratory, US Army Natick
R&D Center, Natick, MA 01760
• Carbonium reactions a study of their rates & mechanism By J. L. FRANKLIN Humble Oil
and Refining Co., Refining Department, Technical and Research Divisions, Baytown, Texas,
U.S.A. Received 19th June, 1951 ; in final form, 10th December, 1951
THANK YOU
[29]