ABC-2 & Structure Identification

ONLY ONE OPTION CORRECT TYPE

1. The process of conversion of cumene in the presence of oxygen and light followed by hydrolysis lead to
the formation of _______ .

(A*) Phenol (B) Aniline (C) Anisole (D) Benzene

vkWDlhtu ,oa izdk'k dh mifLFkfr esa D;wehu ds lkFk vfHkfØ;k dj rRi'pkr~ tyvi?kVu ij izkIr mRikn -----------------
gSA
(A*) fQukWy (B) ,fuyhu (C) ,fulksy (D) cSathu

2. Identify the product of following reaction.

fuEu vfHkfØ;k dk mRikn igpkfu;s&

CH3–CH–CH3

(i) O / h

2

(ii) H3O

CH3

OH

(A*) (B) (C) (D) None of thesemijksä esa ls dksbZ ugh

CH3 CH3

3. Identify the product of the following reaction.

fuEu vfHkfØ;k dk mRikn igpkfu;s&

Cl
(i ) NaOH
  
(ii) HCl
350 º C NaCl
High pressure H2O

Cl OH OH OH
Cl
(A) (B) (C*) (D)

Cl Cl Cl

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ABC–2 & SI - 1
 ABC-2 & Structure Identification

SO3H
(i) NaOH/ 
4.   
 ?
(ii) H

CH3

SO3H SO3H OH CH3

OH
(A) (B) (C*) (D)
OH OH
CH3 CH3 CH3

5. Give the product for following reaction.

fuEu vfHkfØ;k dk mRikn igpkfu;s&

OH
COONa
  
Soda lime

C2H5

OH OH
COOH
(A) (B*) (C) (D) None of thesemijksä esa ls dksbZ ugha

C2H5 C2H5 C2H5

6. Identify the X and Y in the following reaction.

fuEu vfHkfØ;k esa X ,oa Y dks igpkfu;s&

NH2


   X 
NaNO 2 , HCl
Y
H2O, 5º C H2O

+ –
OH N2Cl OH

(A) X = Y= (B) X = Y=

+ –
N2Cl OH N2Cl

(C*) X = Y= (D) X = Y=

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ABC–2 & SI - 2
 ABC-2 & Structure Identification

7. What will be the product of following reaction?

fuEu vfHkfØ;k dk mRikn D;k gksxk\
OH

Cl
2

EtOH / H2O

OH OH OH OH
Cl Cl Cl
(A) (B) (C) (D*)
Cl
Cl Cl Cl
8. Find the product for the following reaction.
fuEu vfHkfØ;k dk mRikn D;k gksxk\
OH

Br

2

Cs2 , 5ºC

CH3
OH OH Br
Br
(A) (B*) (C) (D) None of these mijksä esa ls dksbZ ugh

Br CH3
9. Give the major product for the following reaction.
fuEu vfHkfØ;k dk eq[; mRikn D;k gksxk\
OH

  
CHCl3 / NaOH


Me
OH OH OH OH
CHO Me COOH
(A) (B*) (C) (D)

CHO Me Me Me
10. The reagent used for Reimer Tiemann carboxylation in order to form salicylic acid is _______ .

lsfylhfyd vEy ds fuekZ.k ds fy, jhej Vheku vfHkfØ;k esa dkSulk vfHkdeZd iz;qä gksrk gSA
(A) CHCl3 / NaOH / H+ (B*) CCl4 / NaOH / H+

(C) OH– / CO2 / HCl (D) None of these mijksä esa ls dksbZ ugh
11. Aspirin can be formed from following reaction using which reagent?

fuEu vfHkfØ;k esa dkSulk vfHkdeZd ,fLizu ds fuekZ.k esa iz;ksx fd;k tkrk gS\
O
OH O–C–CH3
COOH COOH


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ABC–2 & SI - 3
 ABC-2 & Structure Identification

O O
(A*) (CH3–C–)2O / H+ (B) (C2H5–C–)2O / H+ (C) CHCl3 / NaOH (D) None of these

mijksä esa ls dksbZ ugh

12. Give product for following reaction.

fuEu vfHkfØ;k dk mRikn crkb;sA

OH
 

CHCl3
KOH

CHO COOH
CHO OH OH
(A) (B*) (C) (D) None of these

mijksä esa ls dksbZ ugh

13. The reactant used in the reaction is

fuEu vfHkfØ;k esa vfHkdkjd gksxk\

OH
COOH

–
vfHkdkjd reactant   
OH / CO2
HCl

OH
OH OH
COOH
(A) (B) (C*) (D)

Anilne ,fuyhu
NO2

14. Sn/HCl
R, R is gS&
+ 6H
CH3

NO2 NH2 NH2 NH2

(A) (B) (C*) (D)

CH3 CH3
Cl

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ABC–2 & SI - 4
 ABC-2 & Structure Identification

NH2

Fe/HCl
15. R + 6H
, R is gS&

NO2 NO2 NO2

NO2

(A) (B) (C*) (D)

NH2

Ni/H2
16. R , R is gS&

CH3

NO2 NO2 NO2 NO2

(A) (B*) (C) (D)

CH3
Br2/NaOH
17. R C2H5–NH2 , R is gS&

CH3
(A) C2H5–CH2–C–NH2 (B) C2H5–CH–C–NH2
O O
CH3
(C*) C2H5–C–NH2 (D) C2H5–CC–NH2
O CH3 O

+ –
N2Cl
H3C CH3
NaNO2/HCl R, is-
18. R (0–5°C)
gS&

CH3

NO2 NH2
H3 C CH3 H3 C CH3 CH3 H3C CH3
(A) (B*) (C) (D)

CH3 CH3 CH3 CH3

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ABC–2 & SI - 5
 ABC-2 & Structure Identification

19. Which of them produces diazonium cation at 0°C ?

buesa ls fdlds }kjk 0°C ij MkbZ,stksfu;e /kuk;u dk fuekZ.k laHko gSS

NH2 NH–CH3
CH3
(A*) (B) (C) CH3–CH2–NH2 (D) CH3–C–NH2
CH3
+
–
N2Cl

P
20. , P is gSa ?

C2H5 C2H5

(A) Cu2Cl2/HCl (B) Cu/HCl (C*) C2H5OH (D) HBF4

NC
CHCl3 + 3KOH/
21. R R is - gSa ?
C2H5

–
N2Cl NO2 NH2 CN
(A) (B) (C*) (D)

C2H5 C2H5 C2H5 C2H5

NH2 OH

NaNO2/HCl
22. (X) NaOH (pH=8-10) (Y)
(0-5°C)

SO3H

Y is gSa -
+ –
(A) HO3S O N2Cl (B*) HO N=N SO3Na

+ – + –
(C) HO N2Cl (D) HO SO2 N2Cl

Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC–2 & SI - 6