Edited by J.B. Kitto and S.C.

Stultz
 The Babcock & Wilcox Company

Copyright © 2005 by
The Babcock & Wilcox Company
a McDermott company
Forty-first edition
First printing

All rights reserved.

Reproduction or translation of any part of this work in any form or by any means beyond
that permitted by the 1976 United States Copyright Act without the permission of the
copyright holder is unlawful. Requests for permission or further information should be
addressed to: STEAM, The Babcock & Wilcox Company, 20 S. Van Buren Avenue, P.O. Box
351, Barberton, Ohio, U.S.A. 44203-0351.

Disclaimer

The information contained within this book has been obtained by The Babcock
& Wilcox Company from sources believed to be reliable. However, neither The
Babcock & Wilcox Company nor its authors make any guarantee or warranty,
expressed or implied, about the accuracy, completeness or usefulness of the
information, product, process or apparatus discussed within this book, nor
shall The Babcock & Wilcox Company or any of its authors be liable for error,
omission, losses or damages of any kind or nature. This book is published
with the understanding that The Babcock & Wilcox Company and its authors
are supplying general information and neither attempting to render engineering
or professional services nor offering a product for sale. If services are desired,
an appropriate professional should be consulted.

Steam/its generation and use. 41st edition.

Editors: John B. Kitto and Steven C. Stultz.
The Babcock & Wilcox Company, Barberton, Ohio, U.S.A.
2005

Includes bibliographic references and index.

Subject areas: 1. Steam boilers.
2. Combustion – Fossil fuels.
3. Nuclear power.

The editors welcome any technical comments, notes on inaccuracies, or thoughts on important omissions. Please direct these to the
editors at SteamBook@babcock.com.

© 1955, 1960, 1963, 1972, 1975, 1978, 1992, The Babcock & Wilcox Company. All rights reserved.

ISBN 0-9634570-1-2
Library of Congress Catalog Number: 92-74123
ISSN 1556-5173 Printed in the United States of America.

ii Steam 41
 The Babcock & Wilcox Company

Steam, Edition: 41

Steam/its generation and use is the longest continuously published engineer-

ing text of its kind in the world. It has always been, and continues to be, writ-
ten and published by The Babcock & Wilcox Company, the Original, head-
quartered in Barberton, Ohio, and incorporated in Delaware, The United States
of America.

Steam 41 iii
 The Babcock & Wilcox Company

The Babcock & Wilcox Company

iv Steam 41
 The Babcock & Wilcox Company

Preface
Dear Reader:

The founders of our company, George Babcock and Stephen Wilcox, invented
the safety water tube boiler. This invention resulted in the commercialization
of large-scale utility generating stations. Rapid increases in generation of safe,
dependable and economic electricity literally fueled the Industrial Revolution
and dramatically increased the standard of living in the United States and
industrialized economies worldwide throughout the twentieth century.

Advancements in technology to improve efficiency and reduce environmen-

tal emissions have continued for nearly 140 years, creating a unique and valu-
able body of applied engineering that represents the individual and collective
contributions of several generations of employees. As in other areas of science
and engineering, our field has continued to evolve, resulting in an extensive
amount of new material that has been incorporated into our 41st edition of
Steam/its generation and use. This edition required an extensive amount of
personal time and energy from hundreds of employees and reflects our com-
mitment to both our industry and our future.

Today it is clear that the challenge to generate power more efficiently from
fossil fuels, while minimizing impacts to our environment and global climate,
will require significant technological advancements. These advances will re-
quire creativity, perseverance and ingenuity on the part of our employees and
our customers. For inspiration, we can recall the relentless drive and imagi-
nation of one of our first customers, Mr. Thomas Alva Edison. For strength,
we will continue to embrace our Core Values of Quality, Integrity, Service and
People which have served us well over our long history as a company.

I thank our shareholders, our employees, our customers, our partners and
our suppliers for their continued dedication, cooperation and support as we move
forward into what will prove to be a challenging and rewarding century.

To help guide us all along the way, I am very pleased to present Edition: 41.

David L. Keller
President and Chief Operating Officer
The Babcock & Wilcox Company

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 The Babcock & Wilcox Company

Table of Contents
Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii to ix
System of Units: English and Système International . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . x
Editors’ Foreword . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xi
Introduction to Steam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Intro-1 to 17
Selected Color Plates, Edition: 41 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Plates 1 to 8
Section I – Steam Fundamentals
Chapter 1 Steam Generation – An Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1 to 1-17
2 Thermodynamics of Steam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 to 2-27
3 Fluid Dynamics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1 to 3-17
4 Heat Transfer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1 to 4-33
5 Boiling Heat Transfer, Two-Phase Flow and Circulation . . . . . . . . . . . . . . 5-1 to 5-21
6 Numerical Modeling for Fluid Flow, Heat Transfer, and Combustion . . . . 6-1 to 6-25
7 Metallurgy, Materials and Mechanical Properties . . . . . . . . . . . . . . . . . . . . 7-1 to 7-25
8 Structural Analysis and Design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-1 to 8-17
Section II – Steam Generation from Chemical Energy
Chapter 9 Sources of Chemical Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9-1 to 9-19
10 Principles of Combustion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-1 to 10-31
11 Oil and Gas Utilization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11-1 to 11-17
12 Solid Fuel Processing and Handling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12-1 to 12-19
13 Coal Pulverization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13-1 to 13-15
14 Burners and Combustion Systems for Pulverized Coal . . . . . . . . . . . . . . . 14-1 to 14-21
15 Cyclone Furnaces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15-1 to 15-13
16 Stokers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16-1 to 16-11
17 Fluidized-Bed Combustion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17-1 to 17-15
18 Coal Gasification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18-1 to 18-17
19 Boilers, Superheaters and Reheaters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19-1 to 19-21
20 Economizers and Air Heaters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20-1 to 20-17
21 Fuel Ash Effects on Boiler Design and Operation . . . . . . . . . . . . . . . . . . . . 21-1 to 21-27
22 Performance Calculations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22-1 to 22-21
23 Boiler Enclosures, Casing and Insulation . . . . . . . . . . . . . . . . . . . . . . . . . . 23-1 to 23-9
24 Boiler Cleaning and Ash Handling Systems . . . . . . . . . . . . . . . . . . . . . . . . 24-1 to 24-21
25 Boiler Auxiliaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25-1 to 25-23
Section Ill – Applications of Steam
Chapter 26 Fossil Fuel Boilers for Electric Power . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26-1 to 26-17
27 Boilers for Industry and Small Power . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27-1 to 27-21
28 Chemical and Heat Recovery in the Paper Industry . . . . . . . . . . . . . . . . . 28-1 to 28-29
29 Waste-to-Energy Installations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29-1 to 29-23
30 Wood and Biomass Installations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30-1 to 30-11
31 Marine Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31-1 to 31-13

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 The Babcock & Wilcox Company

Section IV – Environmental Protection

Chapter 32 Environmental Considerations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32-1 to 32-17
33 Particulate Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33-1 to 33-13
34 Nitrogen Oxides Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34-1 to 34-15
35 Sulfur Dioxide Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35-1 to 35-19
36 Environmental Measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36-1 to 36-15
Section V – Specification, Manufacturing and Construction
Chapter 37 Equipment Specification, Economics and Evaluation . . . . . . . . . . . . . . . . . 37-1 to 37-17
38 Manufacturing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38-1 to 38-13
39 Construction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39-1 to 39-19
Section VI – Operations
Chapter 40 Pressure, Temperature, Quality and Flow Measurement . . . . . . . . . . . . . . 40-1 to 40-25
41 Controls for Fossil Fuel-Fired Steam Generating Plants . . . . . . . . . . . . . . 41-1 to 41-21
42 Water and Steam Chemistry, Deposits and Corrosion . . . . . . . . . . . . . . . . . 42-1 to 42-29
43 Boiler Operations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43-1 to 43-17
Section VII – Service and Maintenance
Chapter 44 Maintaining Availability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44-1 to 44-21
45 Condition Assessment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45-1 to 45-21
Section VIII – Steam Generation from Nuclear Energy
Chapter 46 Steam Generation from Nuclear Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . 46-1 to 46-25
47 Fundamentals of Nuclear Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47-1 to 47-15
48 Nuclear Steam Generators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48-1 to 48-15
49 Nuclear Services and Operations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49-1 to 49-21
50 Nuclear Equipment Manufacture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50-1 to 50-13
Appendices
Appendix 1 Conversion Factors, SI Steam Properties and Useful Tables . . . . . . . . . . . T-1 to T-16
2 Codes and Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-1 to C-6
Symbols, Acronyms and Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . S-1 to S-10
B&W Trademarks in Edition: 41 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . TM-1
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I-1 to I-22

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 The Babcock & Wilcox Company

Acknowledgments
Steam/its generation and use is the culmination of the work of hundreds of B&W employees who have con-
tributed directly and indirectly to this edition and to the technology upon which it is based. Particular recogni-
tion goes to individuals who formally committed to preparing and completing this expanded 41st edition.

Editor-in-Chief/Project Manager
S.C. Stultz

Technical Editor/Technical Advisor

J.B. Kitto

Art Director/Assistant Editor

G.L. Tomei

Assistant Technical Editors

J.J. Gaidos
M.A. Miklic

Lead Authors
M.J. Albrecht G.H. Harth D.K. McDonald B.C. Sisler
G.T. Bielawski T.C. Heil R.M. McNertney Jr. J.W. Smith
K.P. Brolly D.A. Huston J.E. Monacelli R.E. Snyder
P.A. Campanizzi B.J. Jankura T.E. Moskal W.R. Stirgwolt
P.L. Cioffi C.S. Jones N.C. Polosky J.R. Strempek
R.A. Clocker K.L. Jorgensen E.F. Radke S.C. Stultz
P.L. Daniel J.B. Kitto K.E. Redinger J.M. Tanzosh
R.A. Detzel D.L. Kraft J.D. Riggs G.L. Tomei
J.A. Dickinson A.D. LaRue D.E. Ryan D.P. Tonn
W. Downs M.P. Lefebvre D.P. Scavuzzo S.J. Vecci
D.D. Dueck P. Li S.A. Scavuzzo P.S. Weitzel
S.J. Elmiger G.J. Maringo W.G. Schneider R.A. Wessel
J.S. Gittinger W.N. Martin T.D. Shovlin L.C. Westfall
J.E. Granger* E.H. Mayer* T.A. Silva P.J. Williams
G.R. Grant

* The editors offer special acknowledgment to authors J.E. Granger and E.H. Mayer who passed away
during the preparation of Edition: 41.

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 The Babcock & Wilcox Company

Primary Support Authors

S.A. Bryk B.L. Johnson G.J. Lance G.M. Pifer
D.E. Burnham N. Kettenbauer R.C. Lenzer K.J. Rogers
D.S. Fedock T.P. Kors E.P.B. Mogensen B.J. Youmans
J.T. Griffin

Executive Steering Committee

B.C. Bethards J.S. Kulig J.W. Malone R.E. Reimels
E.M. Competti D.C. Langley M.G. Morash

Production Group Outside Support

J.L. Basar P.L. Fox P.C. Lutjen (Art)
L.A. Brower L.M. Shepherd J.R. Grizer (Tables)

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 The Babcock & Wilcox Company

System of Units
English and Système International
To recognize the globalization of the power industry, the 41st edition of Steam
incorporates the Système International d’Unitès (SI) along with the contin-
ued use of English or U.S. Customary System (USCS) units. English units
continue to be the primary system of units with SI provided as secondary units
in parentheses. In some instances, SI units alone have been provided where
these units are common usage. In selected figures and tables where dual units
could detract from clarity (logarithmic scales, for example) SI conversions are
provided within the figure titles or as a table footnote.
Extensive English-SI conversion tables are provided in Appendix 1. This
appendix also contains a complete SI set of the Steam Tables, Mollier diagram,
pressure-enthalpy diagram and psychrometric chart.
The decision was made to provide exact conversions rounded to an appro-
priate number of figures. This was done to avoid confusion about the original
source values.
Absolute pressure is denoted by psi or kPa/MPa and gauge pressure by psig
or kPa/MPa gauge. The difference between absolute pressure and pressure
difference is identified by the context. Finally, in Chapters 10 and 22, as well
as selected other areas of Steam which provide extensive numerical examples,
only English units have been provided for clarity.
For reference and clarity, power in British thermal units per hour (Btu/h)
has typically been converted to megawatts-thermal and is denoted by MWt
while megawatts-electric in both systems of units has been denoted by MW.
The editors hope that these conversion practices will make Steam easily usable
by the broadest possible audience.

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Editors’ Foreword
When we completed the 40th edition of Steam in 1992, we had a sense that
perhaps our industry was stabilizing. But activity has again accelerated. To-
day, efficiencies are being driven even higher. Emissions are being driven even
lower. Many current technologies are being stretched, and new technologies
are being developed, tested and installed. We have once again changed much
of Steam to reflect our industry’s activity and anticipated developments.
Recognizing the rich history of this publication, we previously drew words
from an 1883 edition’s preface to say that “we have revised the whole, and
added much new and valuable matter.” For this new 41st edition we can draw
from the 1885 edition to say “Having again revised Steam, and enlarged it by
the addition of new and useful information, not published heretofore, we shall
feel repaid for the labor if it shall prove of value to our customers.”
We hope this new edition is of equal value to our partners and suppliers,
government personnel, students and educators, and all present and future em-
ployees of The Babcock & Wilcox Company.

Steam 41 xi