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CL 409 - Quiz 1
CL 409 - Quiz 1
CL 409 - Quiz 1
For the images shown below of object(s) that have failed, use your best engineering
general knowledge to explain: (a) most likely reason for failure, and (b) which
engineering property of the material was responsible for the failure, assuming that the
material was responsible for the failure.
1.
a) The Pylon collapsed under the effect of stress generated by wind pressure and its
own weight. Failure could also be due to sabotage (bomb fixed to one side) or ice-
loading (although the weather does not seem like snow) or earthquake (seismic
loads).
b) Young’s Modulus, Yield strength.
2.
a) Sudden load or impact due to the fall to the floor, probably due to mishandling.
b) lack of ductility, or brittleness, or impact strength
4.
5.
a) Erosion of propeller blade due to cavitation. Pitting due to high speed of propeller
trip causing corrosion
b) Hardness/Strength of material/impact strength
Model Answer-Quiz-2-Cl-409-Material Science: (Total 8 marks)
1.
z
y
2 marks
We need the Miller Index of the Motif pointed by the red arrow.
For this, the x-coordinate: a, y-coordinate: a & z-coordinate: a
So the vector is: (a,a,a) and direction is: [1,1,1]
2 marks
Therefore, Miller Index is: [1,1,1].
2. (2 Marks)
. .
! + 2! + ! = √3 - (or) /
+ 0 + / = √3 -
1m
4! = √3 - (or) 20 = √3 -
4! 20
-= = 1m
√3 √3
3. (3 marks)
4! 1m
Volume of unit cell = a = $
√3
Packing fraction = 0.68
1m
Void fraction = 1 − Packing fraction = 0.32
4. (2 marks)
Approximate model assumption – Space filling model / Ball and stick model
mass of sand particles in unit cell true density of sand particles ρ5;<7=
1m
Voluem of sand particles in unit cell
ρ56789 ρ5;<7= ϕ
given that,
ρ5;<7= = 2270 @A/B ,
of separation, is proposed by Sir John Edward Lennard Jones. The potential equation represents
the difference between attractive forces (dipole dipole, dipole induced dipole, and interaction
1) Introduction
Consider two rubber balls that are separated by a significantly large distance. Both objects are
sufficiently apart to avoid interaction. The two balls may be pulled closer together with little
effort, allowing for interaction. The balls can be brought closer and closer together until they
contact. At this point, it becomes difficult to reduce the spacing between the two balls much
further and increased value of energy must be added to bring the balls closer together. This is
because, as the balls begin to invade each other's space, they repel each other; thus, the force
of repulsion is significantly larger than the force of attraction ((see Figure 1a-1d)).
a) Both the balls are at infinite distance and not interacting with each other
b) Two balls are coming close (distance r), now there is attractive force between them
ro
c) Attractive forces between brings the two balls even further close until they reach an
equilibrium distance ro, and represents a minimum bonding potential
d) To further decrease the distance between two balls, the additional energy is requires to
overcome as repulsive forces between these two balls which further implies that the
force of repulsion is significantly larger than the force of attraction
Figure 1. Two objects at a) infinite distance, b) finite distance (r), c) equilibrium distance (ro)
This situation is analogous to what happens in neutral atoms and molecules when they are bring
closer from infinite distance to their equilibrium distance. This situation is frequently described
The Lennard-Jones model contain a sharp repulsive term and a smoother attractive term is
commonly used in numerous force fields as an initial potential. The 12-6 Lennard-Jones model
is often used due to its computational ease. The following equation gives the Lennard-Jones
potential.
σ 12 σ 6
VLJ r 4ε -
r r
where,
VLJ (r) is the intermolecular potential between the two atoms or molecules (see Figure 2), ε is
the well depth and a measure of how strongly the two particles attract each other.
σ gives a measurement of how close two nonbonding particles can get and is thus referred to
as the van der Waals radius.
r is the distance of separation between both particles (measured from the center of one particle
to the center of the other particle).
r
F=repulsive
ro F = attractive
ro and F = 0
Figure 2. The variation in VLJ (ε) intermolecular potential with separation between the two
atoms. F stands for force acting between two particles them
The Lennard-Jones potential is a function of the distance between the centers of two particles.
When two non-bonding particles are an infinite distance apart, the possibility of them coming
together and interacting is minimal. At infinite distance, their bonding potential energy is
considered zero (for the sake of simplicity). However, as the distance of separation decreases,
the probability of interaction increases. The particles come closer together until they reach a
region of separation where the two particles become bound; their bonding potential energy
If the two bonded particles are pressed farther together after their equilibrium distance: the
particles are so close together that their electrons are compelled to occupy the orbitals of one
another. Repulsion happens as both particle tries attempts to retain the space in their respective
orbitals. Their potential binding energy rapidly increases with the decrease in spacing despite
a) b)
Figure 3. Lennard jones potential a) equation and b) graph with labelling of repulsive and
attractive force
Like the bonding potential energy, the stability of an atomic arrangement depends on the
separation distance Lennard-Jones. The energy potential gets increasingly positive as the
distance is reduced below equilibrium (indicating a repulsive force). Such a large potential
However, the potential energy is negative over large distances, approaching zero as the
separation distance rises to infinity (indicating an attractive force). It shows that the pair of
atoms or molecules has a small stabilizing influence on extended distances (indicating zero
force). Finally, as the distance is slightly more than σ between the two particles, the potential
energy has a minimum value (indicating zero force). The pair of particles at this location is
most stable and will continue in that direction until it is exerted by an external force.
The Lennard jones potential can be given by equation
σ 12 σ 6
VLJ (r) = 4ε - ………………….( )
r r
where, VLJ (r) is the intermolecular potential between the two atoms, ε is the well depth, σ
referred to as the van der Waals radius, and r is the distance of separation between both particles
Calculation of the force from VLJ (r), by calculating the first derivative of VLJ (r) with respect
to r,
( ) ( )
V'LJ (r) = and F = − = - V'LJ (r) ( 0 at equlibrium distance)……(2)
! !
σ 12 σ 6
d(4ε r - r )
V'LJ (r) = −
dr
1 13 1 7
Putting ( r )-13 = , and ( r )-7=
r r
12
2 σ 1 σ 6
V'LJ = 24ε 7− × + × 9 … … … … (:)
r r r r
As F= - V'LJ therefore,
12
2 σ 1 σ 6
F = 24ε 7 × − × 9 … … … … (;)
r r r r
As at equilibrium distance r = ro, F = 0 or -V'
V'LJ (<= ) = 0 , therefore using equation 4,
2 σ 12 1 σ 6
0 = 24ε 7 ×? @ − ×? @ 9
r> r> r> r>
2 σ 12 1 σ 6
×? @ = ×? @
r> r> r> r>
σ 1 1/6
? @= ? @
r> 2
ro = 21/6 σ (5)
σ 12 σ 6 1 2 1 1
VLJ(min) (rB ) = 4ε 7? @ -? @ 9 = 4ε 7? @ - ? @ 9 = −ε ……………(6)
(6)
r> r> 2 2
Thus, ro = 21/6 σ where the potential energy has the value V = −ε at minima
Similar results can be derived by calculating first derivative of VLJ (r) with respect to σ,
1 12 1 6
V'LJ (r) = 4ε 712 × (σ)11 × ? @ - 6 × (σ) × ? @ 9
5
r r
11 5
1 σ 1 σ
V'LJ (r) = 4ε 712 × × -6× × 9 … … … . (J)
r r r r
5
1 σ σ 6
V'LJ (r) = 24ε × × 2× - 1 … … … … . . (K)
r r r
As -V'LJ (r) = F thus,
5
1 σ σ 6
F = −24ε × × 2× - 1 … … … … … … ( L)
r r r
At equilibrium position, r = ro
1 σ 5 σ 6
24ε × × ? @ 72 × ? @ -19 = 0
r> r> r>
σ 6
2×? @ =1
r>
6
σ 1
? @ =? @
r> 2
Thus, ro = 21/6 σ where the potential energy has the value V = −ε similar to equation 6
Step 3 Calculation of second derivative of VLJ (r) with respect to r, using V'LJ (r) from
equation 3
δ
V''LJ (r) = (V' (r))
δr LJ
12
δ 2 σ 1 σ 6
= 24ε 7 - × + × 9
δr r r r r
4ε σ 12 σ 6
= 12 × 13 × − 42 ×
rN r r
σ 1 1/6
At minimum, r = ro and =
!O 2
4ε 1 1
= N 12 × 13 × 4 − 42 × 2
PB
4ε
= 339 − 21 4
PBN
72ε
V''LJ(min) (rB ) = > 0
rBN
Step 4. Calculation of second derivative of VLJ (r) with respect to σ, using equation 8
δN
V''LJ (r) = FV (r)G
δσN LJ
11 5
δ 1 σ 1 σ
= 4ε 712 × × -6× × 9
δσ r r r r
1 12 1 6
= 4ε 7 11 × 12 × STB ? @ − 6 × 5 × SU × ? @ 9
r> r>
T 12 1 6
=4ε 132 × S TB × !O
− 30 × S U × !O
VW VY
= 24 ε × Z22 × − 5[
ro Y ro Y
σ 1 1/6
At minimum, r = ro and =
!O 2
VW T
=24 ε × Z22 × − 5[
ro Y N
VW
=24 ε × 311 − 5 4
ro Y
εVW
> 0
ro Y
= 144
1. Consider a material whose atoms are 0.25 nm apart at equilibrium at room temperature
0.25 × 10\]
= T_
2 ^
= 0.223 nm
As V''LJ(min) (r) is a positive number, there it first derivative VLJ (r) at ro corresponds to minima.
12
2 σ 1 σ 6
F = 24ε 7 × − × 9
r r r r
Or,
11 5
1 σ 1 σ
F = −4ε 712 × × -6× × 9
r r r r
3) Estimate the Young’s modulus of the material under tension by building a model (make a
sketch and describe the model; to keep it simple try a simple cubic arrangement), and making
assumptions that reduce the problem to a two-body interaction between two atoms.
Thus,
\ ef \ ef \ ef j T ef
E= gh
= gh
= × =− ×
jh ej j ej
ig ig
g g
T ef
=− ×e
1 12 6
= − r × dr (24ε
d 2 σ 1 σ
× − × )
r r r r
ε d
= −24 r 3 2 × ( σ )12 × ( r )-13 × − ( σ )6 × ( r )-8 4
dr
ε
=−24 3 2 × −13 × ( σ )12 × ( r )-14 × − (-7)( σ )6 × ( r )-8 4
r
26 σ 12 7 σ 6
=24ε × − ×
!k r !k r
ε σ 12 σ 6
=24 × 26 × − 7× at r = ro
!k r r
.
(o,l,0) Co
C1,0,0)
K00).
Cho,)
CI,0,1)
(o,0,1
plama ttZ=
aod a *2
he intrut o plamo. tai tho ais uitl e a,a
h Reiprotals, ( a , a
frem
y , he plano sll u ++z sa :P
D ax t b , * c21 t+d|
a ++C
h + ky t i z 2a
D hto) +
K() +A (o) -20,
h+k+
Quiz 6 - Model Answer
Given that ,
, !"# = , !"#
Hence assume,
(Force exerted on the steel rod when strain goes from 0.01 to x )
= (force exerted on the concrete when strain goes from 0 to x)
Stress in the beam = Y > = 9.6 × 10F GH and Stress in rod = Y > = 5.76 × 10J GH
The final stress in the concrete is compressive and steel rod is tensile
CL409-2021-A1
Friday, 10 September, 2021 11:19 AM
Typical model solution (for rubber lettering of a date stamp), each answer will be different.
Journal Page 1
Journal Page 2
Background and Explanations for the Assignment A1
Materials Properties
1.1) Acidity and alkalinity: They are opposites in nature that are measured on a scale of
pH with a scale of 0 to 14 (see Figure 2). 7 is considered neutral. When the pH drops
below 7, the solution has entered an acidic state and alkaline above 7. An example would
be water. If it has chemicals that contains a high amount of reactive Hydrogen atoms, the
If the solution contains hydroxides it would be alkaline (OH-). Here is the interesting
part. H+ is acidic and OH- is alkaline. If you put these 2 atoms together, you have water.
A single molecule of water is theoretically neutral because the acid H+ and the alkaline
1.2) Corrosion resistance: Corrosion resistance refers to the resistance a material offers
against a reaction with adverse elements that can corrode the material. Various materials
have this property intrinsically, depending upon their corrosion resistance rate.
Alternatively, some methods or treatments can be used to resist corrosion, such as painting
that cause the material to lose electrons. Corrosion resistance is the capacity to hold the
binding energy of a metal and withstand the deterioration and chemical breakdown that
2.1) Density: Density of a material or substance is defined as “the mass per unit volume”.
Gas Very much further apart than a solid or liquid Oxygen gas = 0.0014
It is represented as the ratio of mass with volume of a material. It is denoted by “ρ”. Its
2.2) Melting point: It is the temperature (in oC or K) at which the substance changes from
solid state to liquid state. Melting point for cobalt is 1,495 °C and for iron is 1,538 °C.
2.3) Boiling point: It is the temperature (in oC or K) at which the substance changes from
2.4) Freezing point: It is the temperature (in oC or K) at which a liquid change from liquid
to solid state. Theoretically it is equal to the melting point. However, practically there may
be observed some difference. The freezing point at which water a liquid turns to ice (a
solid) is 0°C.
2.5) Thermal conductivity: It is the property of a material which represents that how
by unit thickness of material normal to the unit area surface in unit time when the
temperature gradient across the material piece is unity in steady state condition”.
Its unit in SI system is watts per meter per K. Some materials and their thermal
Diamond – 2000 – 2200 W/mK, Silver – 429 W/mK, Copper – 398 W/mK, Gold – 315
W/mK, Silicon carbide – 270 W/mK, Beryllium Oxide– 255 W/mK, Aluminum – 247
that how easily the electricity can be conducted by the material. It is denoted by ‘σ’. It is
2.7) Thermal expansion: When a material is heated, it expands, due to which its dimensions
change. Coefficient of thermal expansion, represents the expansion in material with increase
Table 3. Listed values of Coefficient of Linear Thermal Expansion for some materials
It is denoted by “αL”
Where, ‘l’ is the initial length of object, ‘Δl’ is the change in length, ‘Δt’ is the change in
Where, ‘l’ is the initial length of object, ‘ΔA’ is the change in length, ‘Δt’ is the change in
Where, ‘l’ is the initial length of object, ‘ΔV’ is the change in length, ‘Δt’ is the change in
2.8) Optical properties: It is defined as how material it interacts with light The optical
A basic distinction is between isotropic materials, which exhibit the same properties
regardless of the direction of the light, and anisotropic ones, which exhibit different
properties when light passes through them in different directions. The optical properties
2.8.1) Transparency: It is the physical property of allowing light to pass through the
material without appreciable scattering of light. On a macroscopic scale (one in which the
dimensions are much larger than the wavelengths of the photons in question), the photons
2.8.2) Translucency: It allows light to pass through, but does not necessarily (again, on
the macroscopic scale) follow Snell's law; the photons can be scattered at either of the two
interfaces, or internally, where there is a change in index of refraction. In other words, a
Transparent materials appear clear, with the overall appearance of one colour, or any
translucency is opacity.
2.8.3) Materials which do not transmit light are called opaque. The related property is
called opacity.
burn as a result of fire or chemical reaction. The term 'flammable' may be used to describe
substances that ignite more easily, whilst substances that are harder to ignite or that burn
pyrolysis products. The maximum amount of heat released per unit mass per degree of
`flammability'.
3.1) Elasticity: It is defined as the property of a material to regain its original shape after
defamation when the external forces are removed it can also be referred as the power of
material to come back to its original position after defamation when the stress or load is
a)
b)
Figure 3. Young's modulus is the slope of the linear part of the stress-strain curve for a
3.2) Proportional limit: it is defined as the maximum stress under which a material will
Though its value is difficult to measure yet it can be used as the important applications for
Many metals can be put under stress slightly above the proportional limit without taking
a permanent set. Beyond this limit the metal does not regain its original form and
3.4) Yield point: It is the load at which a solid material that is being stretched begins to
Divided by its original cross-sectional area or the amount of stress in a solid at the onset
of permanent deformation the yield point marks the end of elastic behaviour and the
beginning of plastic behaviour when stress is less than the yield point are removed the
3.5) Strength: It is defined as the ability of a material to resist the externally applied forces
with breakdown or yielding. This property of material therefore determines the ability to
The capacity of bearing load by metal and to withstand destruction under the action of
The stronger the material the greater the load it can withstand. This property of material
Strength varies according to the type of loading it is always possible to assess tensile,
compressive, shearing, and torsional strengths. The maximum stress that any material can
withstand before destruction is called its ultimate strength. The tenacity of the material is
3.6) Stiffness: It is defined as the ability of a material to resist defamation under stress.
rigidity.
A material that suffers slight or very less defamation and the load has a high degree of
stiffness or rigidity For instance, suspended beams of steel and aluminium may both be
strong enough to carry the required load but the aluminium beam will sag or deflect further
that means the steel beam is stiffer or more rigid than aluminium beam if the material
behaves elastically with linear stress-strain relationship under Hooke’s law its stiffness is
measured by the Youngs modulus of elasticity. The higher is the value of the Young's
modulus the stiffer is the material in tensile and compressive stress it is called modulus of
stiffness or modulus of elasticity in shear the modulus of rigidity and this is usually 40%
of the value of young's modulus for commonly used materials in volumetric distortion the
bulk modulus.
3.7) Plasticity: It is defined the mechanical property of a material which retains the
defamation produced under load permanently. This property of the material is required in
forging in stamping images on coins and in ornamental work. It is the ability or tendency
of material to undergo some degree of permanent deformation without its failure. Plastic
deformation takes place only after the elastic range of material has been exceeded. Such
property of material is important in forming, shaping, extruding and many other hot or
cold working processes materials such as clay lead etc are plastic at room temperature and
steel is plastic at forging temperature. This property generally increases with increase in
temperature of materials.
Manufacturing goods from raw materials involves a great deal of plastic deformation. For
example, rolling steel into a particular shape (like rebar for construction) involves plastic
3.8) Ductility: It is termed as the property of a material enabling it to be drawn into wire
A ductile material must be strong in plastic. The ductility is usually measured by the term’s
percentage elongation and percent reduction in area which is often used as empirical
measures of ductility.
The materials those possess more than 5% elongation are called as ductile materials.
ductility a mild steel, copper, aluminium, nickel, zinc, tin, and lead.
3.9) Malleability: It is the ability of the material to be flattened into thin sheets under
applications of heavy compressive forces without cracking by hot or cold working means.
It is a special case of ductility which permits materials to be rolled or hammered into thin
sheets. A malleable material should be plastic but it is not essential to be so strong the
ability a lead soft steel, iron, copper and aluminium, tin lead steel etc are recognized as
A harder metal can always cut output impression to the softer metals by virtue of its
hardness. it is a very important property of the metals and has a wide variety of meanings.
The materials having less than 5% elongation and the loading behaviour are said to be
brittle materials. Brittle materials when subjected to tensile loads snap off without giving
any sensible elongation. Glass cast, iron, brass, and ceramics are considered as brittle
material thus brittleness is the property of a material to snap off without giving any
polymers that can behave differently at different temperatures. Some metals exhibit brittle
characteristics due to their slip systems. Ceramics are generally brittle due to the difficulty
3.12) Creep: When a metal part when is subjected to a high constant stress at high
temperature for a longer period of time it will undergo a slow and permanent deformation
in form of a crack which may further propagate further towards creep failure called creep
dot in other words. Creep sometimes called as cold flow, is the tendency of a solid material
stresses.
It can occur as a result of long-term exposure to high levels of stress that are still below
Several different types of creep tests are available to assess high temperature deformation
of materials. Typical examples are tensile creep, compressive creep, flexural creep,
deformation without being damaged. It is the property of metals which denotes the ease in
The different factors that affect the form ability are crystal structure of metal, grain size
of metal, hot and cold working alloying element present in the parent metal.
Metals with small grain size are suitable for shallow forming while metal with high size
are suitable for heavy forming. hot working increases formability, low carbon steel
3.14) Castability: It is defined as the property of metal which indicates the ease with it
3.15) Weldability: It is defined as the property of a metal which indicates the too similar
or dissimilar metals are joined by fusion with or without the application of pressure and
with or without the use of filler metal welding efficiently. Metals having weld ability
in the descending order Orien steel > cast steels > stainless steels
surrounding environment during the useful life without damage or unexpected maintenance.
4.2) Recyclability: Recycling is the process of converting waste materials into new materials
and objects. The recovery of energy from waste materials is often included in this concept. ...
Recyclable materials include many kinds of glass, paper, cardboard, metal, plastic, tires,
4.3) Biodegradability: Biodegradable material generally includes wood, wool, cotton, animal
waste or any other organic material which can be broken down into carbondioxide, methane or
any other simple organic molecules with the help of micro-organisms. They are often referred
to as 'Bio-waste'. Examples of Biodegradable material are: Human and animal waste, Plant