Kinetic Molecular Theory – Diffusion and Effusion of Gases – Real Gases
State the assumptions of the kinetic molecular theory.
Describe how the assumptions of KMT explain the observations and behavior of ideal gases. Be able to describe the meaning of average kinetic energy and its relationship to Kelvin temperature. Be able to describe the kinetic energy distribution of gas molecules at a given temperature and how the distribution changes with temperature. Be able to describe the relation between velocity and temperature of a gas and between velocity and the molar mass of a gas. Be able to differentiate between average speed and root mean square (rms) velocity. Be able to describe the changes in the Maxwell-Boltzman molecular speed distribution of gases of different molar mass at the same temperature. Be able to describe the changes in the Maxwell-Boltzman molecular speed distribution of the same gas at different temperature. Differentiate between the terms diffusion and effusion. Relate the relative rate of effusion of two gases to their molar masses. Relate the relative rates of effusion of one gas to different temperatures. Relate the times it takes for effusion of two gases to their molar masses. Explain why gases exhibit non-ideal behavior and discuss the conditions under which the non-ideal behavior occurs. Explain what the “a” and “b” terms represent in the real gas equation and discuss the factors that affect their values. Use “a” and “b” to explain deviation from ideal behavior.