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Striving for Quality MSDS


In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 1/10

1 IDENTIFICATION

Product's name:
Number CAS

Main recommended uses for


the substance:
POLYOL YF 330
25791-96-2
Industrial use:

Used in Chemical Industry


Company Name: POLINK INDÚSTRIA QUÍMICA COMÉRCIO LTDA.
Company Name: POLINK INDÚSTRIA QUÍMICA COMÉRCIO LTDA.
Rua Capitão Guynemer, 1710 - Xerém
Address:
Duque de Caxias – RJ. CEP 25250-000
Emergency telephones:
(21) 2679-1772 / (21) 2679-2325.
Contact phone and email (21) 2679-1772 / (21) 2679-2325 (Business hours).
(customer service): polink@polink.com.br

2 HAZARDS IDENTIFICATION

hazard classification of Product classified as non-hazardous according to


product: GHS classification criteria

Standard ABNT-NBR 14725-Part 4: 2014.


Classification system
adopted: Adoption of the Globally Harmonized System for the Classification
and Labeling of Chemicals, UN.
Emergency overview: NON-HAZARDOUS LIQUID FOR HUMAN HEALTH.
Appropriate elements of labeling

Pictograms:

Word of warning: CAUTION


Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 2/10

H303: May be harmful if swallowed.


H313: May be harmful in contact with skin.
H333: May be harmful if inhaled.
Danger phrases:
H320: Causes eye irritation.

P312: If you feel unwell, contact an Information Center


Toxicological / medical.
P304 + P312: In case of inhalation: If you feel unwell, contact
A toxicology/physician information center.
P305 + P351 + P338: IF IN CONTACT WITH THE
EYES: rinse carefully with water for several
minutes. If you wear contact lenses, remove them if possible.
Continue rinsing.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P301 + P312: In case of ingestion: if you feel unwell,
Precautionary phrases: Contact Toxicology Information Center / Physician.
P270: Do not eat, drink or smoke while using this product.
P261: Avoid breathing dust/smoke/gas/mist/vapours.
P271: Use only outdoors or in a well-ventilated area.

3 COMPOSITION AND INFORMATION ABOUT INGREDIENTS


Type Substance
Chemical or common name: Polyether polyol
Synonym: Polypropylene Glycol
25791-96-2
CAS No.:

500-039-8
CEE No.:
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 3/10

Impurities that contribute to This product is classified as non-hazardous.


the danger:
May be harmful in contact with skin. May cause irritation
Most important hazards: eye. May cause respiratory irritation (area irritation
respiratory). May cause drowsiness and dizziness (narcotic effects).
Environmental effects: There are no data for the mixture as a whole.

Physical and chemical hazards: Non-flammable and non-toxic liquid.

4 FIRST AID ACTIONS

disturbances.
Adverse effects on
human health: Headache, weakness, dizziness, ataxia, confusion, delirium. Nausea,
vomiting and diarrhea. Cough, sore throat and dyspnea. Redness on
the skin. Redness and pain in the eyes.
Main symptoms:
Remove victim to fresh air and keep at rest. Monitor respiratory
function. If victim is breathing hard, provide oxygen. If necessary,
give artificial respiration. Get medical attention. Take this MSDS.
Inhalation: Remove contaminated clothing and shoes. Wash exposed skin with
large amounts of water for at least 15 minutes. Get medical attention.
Take this MSDS.
Skin contact: Wash with running water for at least 15 minutes, keeping the eyelids
open. Remove contact lenses when appropriate. Get medical attention
immediately. Take this MSDS.
Eye contact: Wash victim's mouth with plenty of water. DO NOT INDUCE
VOMITING. Get medical attention. Take this MSDS.
Ingestion: Avoid contact with the product when helping the victim. Keep victim
at rest and warm. Do not offer anything orally to an unconscious
person. Symptomatic treatment should comprise, above all, supportive
measures such as correction of electrolyte and metabolic disorders, in
Protection of the rescuer addition to respiratory assistance.
and/or notes for the
doctor:
May cause irritation to
skin, eyes and
respiratory tract. May
cause gastrointestinal
5 FIRE FIGHTING MEASURES
Foam, carbon dioxide (CO2), chemical powder can be used
Appropriate extinguishing media: or water fog.
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 4/10

Unrecommended
Extinguishing Media:

Specific hazards related to


the measures:

Special fire fighting methods:


Protection of people
involved in fire
fighting:

Sprayed water jets.

Non-flammable product. Fire


can produce irritating and toxic
gases.

Cool closed containers with


water spray.

Self-contained breathing
apparatus (SCBA) with
positive pressure and full
protective clothing.
6 CONTROL MEASURES FOR SPILLS OR LEAKS
personal precautions
Non-flammable product
Removal of ignition
sources:
Do not touch damaged containers or spilled material without
wearing suitable clothing. Avoid inhalation, prolonged contact
Personal Precautions
with skin or eyes. Use personal protective equipment as
for Emergency Service
described in section 8.
Personnel:
Do not touch damaged containers or leaked material. Avoid
Personal precautions for contact with skin and eyes. Use personal protective
non-emergency equipment as described in section 8.
personnel:
Environmental precautions
Procedures to be Prevent the spilled product from reaching water courses and
adopted: sewers.
Cleaning methods
Use water mist or vapor suppressor foam to reduce
dispersion of vapours. Use natural or containment barriers
Procedures to be leakage. Collect spilled product and place in containers
adopted: themselves. Adsorb the remaining product, with dry sand, earth,
vermiculite, or any other inert material. put the material
adsorbed in suitable containers and remove to a safe place.
Do not dispose directly into the environment or into the sewer system.
hazard prevention You
secondary: materials used in fire control can cause pollution.
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 5/10

7 HANDLING AND STORAGE


Appropriate technical measures for handling
the product through pressurizers (example: pressure by
Prevention of worker compressed air)
exposure: - Decree 96.044/88, of the Ministry of Transport: “Art. 19. The
driver will not participate in the loading, unloading and
Fire and Explosion transshipment of the cargo, unless properly guided and
Prevention: authorized by the shipper or the recipient, and with the consent
of the carrier.”
Precautions and guidelines
for safe handling:

Hygiene measures:

Product download:
Handle in a ventilated area or
with a general
ventilation/local exhaust
system. Avoid formation of
vapours/mists. Do not smoke.
Non-flammable product.
Inspect containers for
damage or leaks before
handling.
Avoid contact with skin, eyes
and clothing. Avoid
breathing product
vapours/mists. Wear personal
protective equipment as
indicated in Section 8.
Do not eat, drink or smoke
while handling the product.
Wash your hands thoroughly
before eating, drinking,
smoking or using the
bathroom. Contaminated
clothing must be changed
and washed before reuse.
-It is NOT safe to discharge
Appropriate technical measures for storage
Keep the product in its original packaging and in a cool place.
keep the
Appropriate:
tightly closed containers and at a temperature in the range of 15 –
23°C.
Store away from food. Out of reach of children.
Inappropriate: High temperatures.
Products and materials
Strong oxidizing agents.
incompatibles:
Safe materials for packaging
Recommended: Not determined.

8 EXPOSURE CONTROL AND PERSONAL PROTECTION


Specific Control Parameters
Exposure limits
Components to Control in relation to the Workplace
occupational:
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 6/10

Engineering control
measures:

Provide ventilation
combined with local
exhaust if product
vapors/mists are likely
to form. It is
recommended to make
emergency showers
and eye washes
available in the work
area. Engineering
control measures are
most effective in
reducing product
exposure.
Appropriate personal protective equipment:
Eye/face Protective goggles.
protection: Protective gloves made of nitrile
Skin and rubber or PVC.
body
Respiratory protective
protection:
equipment against vapors/mists.
Breath Full protective clothing that
protection: covers the entire body. Wear
face shield.
Special
precautions:
9 PHYSICAL AND CHEMICAL
PROPERTIES

Aspect: Liquid.
Odor: Resin characteristic.
pH: 7.50 - 8.50.
Melting
Not determined
point/freezing
point:
Initial boiling point and  100°C
boiling temperature range:
 171 °C
Flash point:
Not applicable.
Evaporation rate:
Not applicable.
Flammability:
Not applicable
Explosive limits:
< 0.001 hPa at 20°C
Steam pressure: Not applicable.
Vapor Density: Approx. 1010 kg/m3 at
Relative density: 20°C

Solubility in water:
immiscible in water
Total solids
22.00 - 26.00%
Octanol/water Not determined
partition
coefficient (Kow): Not applicable
Auto-ignition temperature:
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 7/10

Decomposition temperature: Not available.


Viscosity: Not available

10 STABILITY AND REACTIVITY

Chemical stability:

Possibility of hazardous
reactions:

Conditions to avoid:

Incompatible materials
and substances:
Hazardous
decomposition
products:
Stable product

There are no dangerous


reactions as long as
storage instructions
And handling are
respected

Very high temperatures


.

Strong oxidizing agents.

When heated, it releases


irritating gases.
11 TOXICOLOGICAL INFORMATION
Information according to the different exposure routes

Polypropylene glycol (MW Ca. 1000 -


Acute toxicity: 1100)

Skin corrosion
and irritation: Causes skin irritation with redness, pain
and dryness.
Serious
eye Causes eye irritation with redness and
damage/ey pain.
e
irritation:
The product is not expected to cause any
Respiratory or sensitization.
skin
sensitization: Based on animal studies, it is not
Germ cell considered to be mutagenic in germ
mutagenicity: cells.
Carcinogenicity: Not classified as a human carcinogen.
Reproductive Based on animal studies, it is not
and lactation considered toxic for reproduction.
toxicity:
May cause respiratory tract irritation with
Systemic toxicity coughing, sore throat and dyspnea. May
for cause central nervous system disorders
certain target with
organs – Single headache, muscle weakness, dizziness,
exposure: ataxia, confusion, delirium and coma.
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 8/10

Systemic toxicity to
There are no data for the mixture as a whole.
specific target organ -
Repeated exposures:
Aspiration hazard: There are no data for the mixture as a whole.
12 ECOLOGICAL INFORMATION
Environmental effects, behavior and product impacts
There are no data for the mixture as a whole.
Ecotoxicity:

Persistence and Not available


Degradability:

Not available
Bioaccumulative
potential:
Medium mobility

Mobility in soil
13 FINAL DESTINATION CONSIDERATIONS
Recommended methods for final disposal
Avoid occupational exposure or environmental contamination. Please recycle any unused portion of
the material for your approved use or Product: return it to the manufacturer or supplier. Other methods
consult federal and state legislation: CONAMA Resolution 005/1993, NBR

10,004/2004.

Product remains:
Keep product remains in their original containers and properly closed.
Disposal must be carried out as established for the product.
Do not reuse empty packaging. These may contain product remains and
must be kept closed and sent for proper disposal.
Used packaging:
14 TRANSPORT INFORMATION
National and international regulations

Terrestrial: Non-dangerous product according to transport regulation criteria


Striving for Quality MSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 9/10

Fluvial - Non-hazardous product according to the criteria of the


transport regulation
Waterway:
Maritime - Non-hazardous product according to the criteria of the
transport regulation

IATA / ICAO: Non-dangerous good according to transport


regulation criteria
Air:

UN No.: Product not covered by ANPP resolution


15 REGULATORY INFORMATION
Federal Decree No. 2,657, of July 3, 1998
Regulations: ABNT-NBR 14725-4: 2014 Standard
Directives 1999/45/EC

16 OTHER INFORMATION
This MSDS was developed based on current knowledge of the chemical and provides information
regarding protection, safety, health and the environment.
It is cautioned that the handling of any chemical substance requires prior knowledge of its dangers by
the user. It is up to the company that uses the product to promote the training of its employees and
contractors regarding the possible risks arising from the product.

Acronyms:
CAS - chemical abstracts service
EC - European Community
Striving for QualityMSDS
In compliance with NBR 14725-2/2010
NBR 14725-4/2014

CHEMICAL SAFETY INFORMATION SHEET


Product: POLYOL YF 330
Review: 01 Date: 22/10/21 Page: 10/10

EEC - European Economic Community

Bibliography:
[EPI-USEPA] ESTIMATION PROGRAMS INTERFACE Suite - United States Environmental
Protection Agency. Software.

[HSDB] HAZARDOUS SUBSTANCES DATA BANK. Available at: http://toxnet.nlm.nih.gov/cgi-


bin/sis/htmlgen?HSDB. Accessed on: October 2015.

[IPCS] INTERNATIONAL PROGRAM ON CHEMICAL SAFETY – INCHEM. Available at:


http://www.inchem.org/. Accessed on: October 2015.

[IUCLID] INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE. [sl]:


European Chemical Bureau. Available at: http://ecb.jrc.it/IUCLID-. Accessed on: October 2015.

[NIOSH] NATIONAL INSTITUTE OF OCCUPATIONAL AND SAFETY. International


Chemical Safety Cards. Available at: http://www.cdc.gov/niosh/. Accessed on: October 2015.

[TOXNET] TOXICOLOGY DATA NETWORKING. ChemIDplus Lite. Available at:


http://chem.sis.nlm.nih.gov/. Accessed on: October 2015.

[NITE – GHS JAPAN] National Institute of Technology and Evaluation.


http://www.safe.nite.go.jp/english/ghs_index.html. Accessed on: October 2015.

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