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Chemistry - Worksheet 2 :Set 1

Custom Test:Chemistry - Worksheet 2

SET-1

DURATION: 50 min MAX. MARKS: 200

1.
 CHEMISTRY

I. When ice is melted hydrogen bond starts breaking molecule of water come closer by moving into vacant space. As a result density of
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water decreases upto 4°C.

II. Due to open cage like structure, ice has a relatively large volume for a given mass of liquid water.

III. In ice there are four water molecules attached tetrahedrally.

Which of the above statement is true. (Single Choice Question)

a I, II and III b I and III

c II and III d II only

Which of the following pairs will form same colour with phenyl hydrazine

Glucose and Mannose

Starch and Cellulose

Lactose and Maltose (Single Choice Question)

a I, II, IV b I and II

c I, II, III d I, III, IV

When glucose is treated with water then the product is (Single Choice Question)
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a b

c d
 The packing efficiency of the two-dimensional square unit cell shown below is

         (Single Choice Question)

a 39.27% b 68.02%

c 74.05% d 78.54%

A compound made up of particles A, B and C forms ccp lattice. Ions A are at lattice points, B occupy tetrahedral voids and C occupy
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octahedral voids. If all the ions along one of the edge are removed, then the formula of compound is- (Single Choice Question)

a b

c d

Which of the following aldohexoses give the same osazone derivative?

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(Single Choice Question)

a I and II b I and III

c II and III d III and IV

(Single Choice Question)

a b

c d
 Reduction of hexose A (Molecular formula ) with sodium borohydride gives compounds B and C. Compound B is optically
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inactive, whereas compound C is optically active. Which of the following is compound A? (D - psicose is - epimer of D - fructose, D -
mannose is the - epimer of D - glucose) (Single Choice Question)

a D - Fructose b D - Glucose

c D - Mannose d D - Psicose

One of the most common biodegradable polymers, polylactic acid (PLA) is not prepared by polyesterfication of lactic acid so as avoid
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water being formed in the reaction. It is in fact prepared by the polymerization of a compound with stannous compounds as catalysts. The
probable monomer is (Single Choice Question)

a b

c d

Which is correct structure of D-glucopyranose. (Single Choice Question)

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a b

c d

For which of the following cases answer is 4: (Multiple Choice Question)

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a Coordination no. of in Zinc blende b No. of body diagonal planes in cube

c Formula units in Rock salt structure d Formula units in salt structure

The cubic unit cell structure of a compound containing cation  and anion is shown below. When compared to the anion, the cation has
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smaller ionic radius. Choose the correct statement(s).

(Multiple Choice Question)

a The empirical formula of the compound is  . b The cation  and anion  have different coordination geometries.

c The ratio of  bond length to the cubic unit cell edge length is d The ratio of the ionic radii of cation  to anion   is
 What is/are true regarding (+)-lactose-a disaccharide? (Multiple Choice Question)
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a It on hydrolysis gives D-galactose and D-glucose b It is a reducing sugar

c It has ,  glycosidic linkage d Galactose is the reducing unit in lactose

Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain termination, respectively, are (Multiple
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Choice Question)

a and b and

c and d and

Identify the correct statements about sucrose. (Multiple Choice Question)

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a It is a disaccharide of glucose and fructose b It undergoes mutarotation

c It does not have a free aldehydic or ketonic group d Invert sugar, obtained by the hydrolysis of sucrose by enzyme, invertases the
negative rotation

The presence of group in glucose is inferred by its (Multiple Choice Question)

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a Reaction with to give cyanohydrin b Reaction with to give sorbitol

c Reaction with Fehling's solution d Reaction with Tollen's reagent

Aluminium metal has a density of 2.72 g cm –3 and crystallizes in a cubic lattice with an edge of 404 pm. Which is/are correct ? (Multiple
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Choice Question)

a It forms an fcc unit cell b It forms a bcc unit cell.

c Its coordination number is 8 d Its coordination number is 12.

The presence of group in glucose is inferred by its (Multiple Choice Question)

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a Reaction with to give cyanohydrin b Reaction with Na-Hg to give sorbitol

c Reaction with Fehling’s solution d Reaction with Tollen’s reagent

The correct functional group X and the reagent/reaction conditions Y in the following scheme are:

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(Multiple Choice Question)

a b

c d

Which of the following can be used as plasticisers ? (Multiple Choice Question)

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a Sodium hexametaphosphate b Di-n-butylphthalate

c Tricresyl phosphate d Diethyl phthalate

 For next two questions

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Disaccharides are carbohydrates those contain two monosaccharides molecules, each in the hemiacetal form, joined together by the
elimination of a water between two hydroxyl groups. Dehydration involves the anomeric carbon of one monosaccharide and may or may
not involve the anomeric carbon of the other monosaccharide when the hemiacetal hydroxyl group on an anomeric carbon is involved in a
dehydration, the resulting product is an acetal (in common) and glycoside (in carbohydrate).

Which of the following fact(s) is/are incorrect about sucrose?

Fact A : It consists of two different monosaccharides -D-glucose and -D-fructose.

Fact B : Dehydration occurs between the hemiacetal of hydroxyl on carbon 1 of D-glucose and that of on carbon 2. of -D-fructose

Fact C : Common shorthand notation for sucrose is 1'G

Fact D : Dehydration occurs between the hemiacetal of hydroxyl on carbon 1 of D-glucose and that of also carbon 1 of -D-fructose thus
its notation is 1G

  (Linked Comprehension)

a A and B b B and C

c A only d D only

Disaccharides are carbohydrates those contain two monosaccharides molecules, each in the hemiacetal form, joined together by the
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elimination of a water between two hydroxyl groups. Dehydration involves the anomeric carbon of one monosaccharide and may or may
not involve the anomeric carbon of the other monosaccharide when the hemiacetal hydroxyl group on an anomeric carbon is involved in a
dehydration. The resulting product is an acetal (in common) and glycoside (in carbohydrate).

Sucrose is a non-reducing sugar (while its hydrolysis products glucose and fructose are reducing sugars) because : (Linked
Comprehension)

a Glucose has aldehyde and fructose has ketone group and aldehyde is reactive b It has no free aldehydic or ketonic group. Aldehyde group of glucose component
than ketone   is marked as a glucoside linkage

c Surrose solution do not exhibit Mutarotation d None of the above describes above abnormal behaviour

Valence shell electron-pair repulsion theory predicts the shape of a molecule by considering the most stable configuration of the bond
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angles in the molecule. The main points of the theory are

(i) Electron pairs in the valence shell of central atom of a molecule, whether bonding or lone pairs are regarded as occupying localised
orbitals. These orbitals arrange themselves so as to minimise the mutual electronic repulsions.

(ii) The magnitude of the different types of electronic repulsions follow the order given below:

Lone pair-lone pair-lone pair > lone pair-bonding pair > bonding pair-bonding pair-bonding pair. These repulsive forces alter the bond
angles of the molecule or ion.

(iii) The electron repulsion between two pairs of electrons will be minimum if they stay as far as possible. On this basis, several studied.
have been done

The correct order of bond angles for following species is (Linked Comprehension)

a NH3 > PH3 > AsH3 > SbH3 b PH3 > AsH3 > SbH3 > NH3

c AsH3 > SbH3 > NH3 > PH3 d NH3 > PH3 = AsH3 > SbH3

Valence shell electron-pair repulsion theory predicts the shape of a molecule by considering the most stable configuration of the bond
24
angles in the molecule. The main points of the theory are

(i) Electron pairs in the valence shell of central atom of a molecule, whether bonding or lone pairs are regarded as occupying localised
orbitals. These orbitals arrange themselves so as to minimise the mutual electronic repulsions.

(ii) The magnitude of the different types of electronic repulsions follow the order given below:

Lone pair-lone pair-lone pair > lone pair-bonding pair > bonding pair-bonding pair-bonding pair. These repulsive forces alter the bond
angles of the molecule or ion.

(iii) The electron repulsion between two pairs of electrons will be minimum if they stay as far as possible. On this basis, several studied
hane been done.

Which of the following statements is correct ? (Linked Comprehension)

a The bond angle of NCl3 is greater than NH3 as back-bonding is present b BF3 is more acidic than BCl3 due to presence of back bonding in BF3
in NCl3.

c When the bond multiplicity is increased, bond angle is decreased. d The bond angle of SiCl4 is greater than CCl4
 Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length d for
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the bond. Unit of dipole moment is debye. One debye is equal to 10 -18 esu cm.

Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative
orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole
moment helps to predict the geometry of a molecules. Dipole moment values can be used to distinguish between cis-and trans-isomers ;
ortho-, meta- and para-forms of a substance, etc.

Which is a polar molecule ? (Linked Comprehension)

a XeF4 b BF3

c I2Cl6 d PCl2F3

Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length d for
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the bond. Unit of dipole moment is debye. One debye is equal to 10 -18 esu cm.

Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative
orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole
moment helps to predict the geometry of a molecules. Dipole moment values can be used to distinguish between cis-and trans-isomers ;
ortho-, meta- and para-forms of a substance, etc.

Which of the following statement is correct regarding C 2 H 2 F 2 molecule? (Linked Comprehension)

a One isomer is polar, one is non-polar b Two isomers are polar, one is non-polar

c Two isomers are planar, one is non-planar d Two isomers are only possible and planar

VSEPR theory predicts the shapes of the molecules. The other methods of determining the shapes of the molecules are by hybridizations
27
technique and dipole moment of the molecules.

If A represents the total number of hybrid orbitals, P represents total number of valence electrons, then

A = P - 3 (number of atoms surrounding the central atom excluding H - atom)

The number of bond pairs (b) = number of atoms surrounding the central atom)

Then the total number of lone pairs of electrons n = A - b

The VSEPR notations of a molecule can be written as XS b E n

Where X = Central atom ; S b = Number of bond pairs; E n = Number of lone pairs

Hence a molecule of ClF 3 can be represented as (Linked Comprehension)

a XSE b XS3E2

c XS2E3 d XS4E2

VSEPR theory predicts the shapes of the molecules. The other methods of determining the shapes of the molecules are by hybridizations
28
technique and dipole moment of the molecules.

If A represents the total number of hybrid orbitals, P represents total number of valence electrons, then

A = P - 3 (number of atoms surrounding the central atom excluding H - atom)

The number of bond pairs (b) = number of atoms surrounding the central atom)

Then the total number of lone pairs of electrons n = A - b

The VSEPR notations of a molecule can be written as XS b E n

Where X = Central atom ; S b = Number of bond pairs; E n = Number of lone pairs

The one which has linear arrangement of all atoms is (Linked Comprehension)

a CH3 - C ≡ CH b CH3 - C ≡ C - CH3

c CH2 = CH2 d CH ≡ CH

Ionic compounds occur in crystalline forms. Ionic crystals are made of cations and anions. These ions are arranged in 3 dimensional array
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to form an aggregate of the type (A + B – ). If one of the ion is much larger than the other, it is common for larger ions alone to approach a
closest packed structures and smaller ions to fit into holes in this structure.

For magnesium telluride crystal radius of cation and anion are 0.65 Å and 2.21 Å, then what is the correct arrangement ? (Linked
Comprehension)

a Mg constitutes c.c.p. lattice and Te is present in octahedral voids b Mg constitutes c.c.p. lattice and Te is present in tetrahedral voids

c Te constitutes c.c.p. lattice and Mg is present in octahedral voids d Te constitutes c.c.p. lattice and Mg is present in tetrahedral voids
 Ionic compounds occur in crystalline forms. Ionic crystals are made of cations and anions. These ions are arranged in 3 dimensional array
30
to form an aggregate of the type (A + B – ). If one of the ion is much larger than the other, it is common for larger ions alone to approach a
closest packed structures and smaller ions to fit into holes in this structure.

A fcc system contains 4 octahedral and 8 tetrahedral voids. Nearest distance possible between octahedral and tetrahedral void is (a is
edge length of unit cell) (Linked Comprehension)

a b

c d

A meta crystallizes into two cubic lattices, FCC and BCC respectively. If the ratio of densities of FCC and BCC is 0.544 'X' then value of 'X'
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is ___________. (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

An element X (Atomic weight = 125) crystallises in simple cubic structure. If diameter of the largest atom which can be placed without
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disturbing unit cell is 366 pm. Find the density of pure element X in g/cm 3 . Answer multiplying it with 3.

[Given, N A = 6 x 10 23 ] (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

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The sum of total number of moles of PhNHNH 2 used with A & B _______. (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

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pKa

Find isoelectric point of the above amino acid.

(Integer Type Question)

0 1 2 3 4 5 6 7 8 9
 Metal element 'M' of radius 50 nm is crystallized FCC format and make cubical crystal such that face of unit cells aligned with face of
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cubical crystal. If total number of metal atoms of 'M' at face of cubical crystal is then area of one face of cubical crystal is
then area of one face of cubical crystal is , the value of A is (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

If a solid A B  having ZnS structure is heated so that the ions along two of the axis passing through the face center particles are lost and
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bivalent ion(Z) enters here to maintain the electrical neutrality, so that the new formula unit becomes A x B y Z c , Report the value of
x y c . (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

In a metal oxide, the oxide ions are arranged in hexagonal close packing and metal ions occupy two-third of the octahedral voids. The
37
formula of the oxide is then the value of is? (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

If a solid having ZnS structure is heated so that the ions along two of the axis passing through the face centre particles are lost and
38
bivalent ion (z) enters here to maintain the electrical neutrality, so that the new formula unit becomes , report the value of
. (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

the number of diamagnetic species is -

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(Atomic number :

  (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

The substituents R 1 and R 2  for nine peptides are listed in the table given below. How many of these peptides are positively charged at pH =
40
7.0 ?

H N CH CO NH CH CO NH CH CO NH CH CO O

| | | |

H R R H

 
Peptide R1 R2
I H H
II H CH 3
III CH 2 COOH H
IV CH 2 CONH 2 (CH 2 ) 4 NH 2
V CH 2 CONH 2 CH 2 CONH 2
VI (CH 2 ) 4 NH 2 (CH 2 ) 4 NH 2
VII CH 2 COOH CH 2 CONH 2
VIII CH 2 OH (CH 2 ) 4 NH 2
IX (CH 2 ) 4 NH 2 CH 3
​   (Integer Type Question)

0 1 2 3 4 5 6 7 8 9

  Column – I   Column – II
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(A) Molecule is planar (P)
(B) Tetrahedral shape of molecule (Q)
(C) At least 2 lone pairs at * marked element (R)

(D) Molecule has bonds (S)

(Matrix Type Question)

 P Q R S

A P Q R S

B P Q R S

C P Q R S

D P Q R S

Match the following.

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Column I
Column II

   
(Crystal structure) (Arrangement)
(a) Rock salt (p) Fraction of voids occupied
(b) Zinc blend (q) Anions constitute lattice
(c) Antifluorite (r) Cations in tetrahedral voids
(d) CsCl type (s) Coordination no. for cation and anion is same.

and select the correct choice from the codes given below. (Matrix Type Question)

P Q R S

A P Q R S

B P Q R S

C P Q R S

D P Q R S

Match the following:

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  Column I   Column II
  (Pair of complexes)   (Property which is similar in given pair)
A. p. Magnetic moment

B. q. Geometry

C. r. Hybridisation

D. s. Number of d electrons at central atom

    t. EAN
(Matrix Type Question)

P Q R S T

A P Q R S T

B P Q R S T

C P Q R S T

D P Q R S T
 Match the orbital overlap figures shown in List-I with the description given in List-II and select the correct

44

answer using the code given below the lists.

 
  List – I   List - II

A. P antibonding

B. Q bonding

C. R bonding

D. S antibonding

(Matrix Type Question)

P Q R S

A P Q R S

B P Q R S

C P Q R S

D P Q R S

Match the molecular species in Column 1 with their structural characteristics in Column-II.
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(Matrix Type Question)

P Q R S

A P Q R S

B P Q R S

C P Q R S

D P Q R S

Match the column

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  Column I   Column II
(A) Bakelite (P) Natural Polymer
(B) Natural Rubber (Q) Addition Polymer
(C) BUNA – N (R) Linear Polymer
(D) Cellulose (S) Co- Polymer
    (T) Thermosetting plastic
(Matrix Type Question)
 P Q R S T

A P Q R S T

B P Q R S T

C P Q R S T

D P Q R S T

Match the Column I (Compound) and Column II (Property)

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  Column I   Column II

(a) (p) will form osazone

(b) (q) Molecular mass increases by 120 when treated

(c) (r) Reduces Tollen’s reagent

(d) (s) Is -glucopyranose

    (t) Non reducing sugar

(Matrix Type Question)

P Q R S T

A P Q R S T

B P Q R S T

C P Q R S T

D P Q R S T

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(Matrix Type Question)

 P Q R S T

A P Q R S T

B P Q R S T

C P Q R S T

D P Q R S T

Match the following.

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  Column I   Column II
  Mixture   Reagents for distinction
(a) Glucose and Fructose (p) Br 2 water
(b) Glucose (q) Tollen's reagent
(c) Fructose (r) Fehiling solution
(d) Benzaldehyde + acetaldehyde (s) Iodine/OH -
(Matrix Type Question)

P Q R S

A P Q R S

B P Q R S

C P Q R S

D P Q R S

Entries of Column-I are to be matched with entries of Column-II, Each entry of Column-I may have the matching with one or more than one
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entries of Column-II.

 
Column-I
Column-II

(Pair of species)
(a) PCl 3 F 2 , PCl 2 F 3
(b) BF 3 and BCl 3
(c) CO 2 and CN
(d) C 6 H 6 and B 3 N 3 H 6
(Matrix Type Question)
(Identical Property in pairs of species)
(p) Hybridisation of central atom
(q) Shape of molecule/ion
(r) (dipole moment)
(s) Total number of electrons

P Q R S

A P Q R S

B P Q R S

C P Q R S

D P Q R S

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