Ardon, Veronica Roselle C.

Ph-301

1. If 0.2800 g sample of sodium bicarbonate (96.5% NaHCO3) is

titrated with 0.9165 N sulfuric acid, what volume of the acid
should be required to produce an endpoint?

96.5
 0.965
100
84
 0.084
100

0.2800 x0.965
=3.51mL
0.9165 x 0.084

2. The disodium salt of a dibasic organic acid has a molecular

weight of 215; what weight of sample would be used for titration
to bromophenol blue endpoint with 0.2500 N acid in order that
35mL of the latter will be required?
0.2500 x 215
=1.54mg
25

3. Calculate the MgO content of milk of magnesia, 12.32 g of

which was dissolved in 50.00mL of 1.0340 N sulfuric acid,
producing a mixture that required 24.60mL of 1.1255 N sodium
hydroxide.
40.30
 20.15
MgO= 2

(50.00)(20.15)=1007.5
1007.5
=974.37
1.0340

4. Calculate the percent of CH4N2O in a 0.5000g sample urea, if

15.35mL of 0.4967 N sodium hydroxide were required in the
titration after the ammonia from the sample had been distilled
into 50.00 mL of 0.4861 N sulfuric acid.
CH4N2O 64.08
 21.36
3
(15.35)(21.36) = 327.88
Ardon, Veronica Roselle C.
Ph-301
496.7
 =1.52
1.52
327.88

5. A 4.0520 g sample of HCl, specific gravity 1.18 required 44.15

mL of 0.9035 N NaOH in a titration. Calculate

a. HCl content in percent

36.45
0.9035 x 44.15 x
1000 x100 =35.88
4.0520 )

a. Normality
(0.9035 N)(1) =0.9035

b. Na2CO3 titer of the sample

105.98 =52.99
2

6. A HCl acid solution has an AgCl titer of 0.1265; What is its

Na2CO3 titer?
105.98 =52.99
2

7. A 0.2182 g sample of NaCl was assayed by the Volhard

Method using 50.00mL of 0.0985 N silver nitrate and 11.75mL
of 0.1340 N ammonium thiocyanate. Calculate the percent NaCl
in the sample.
0.2500 x 215
=1.54 mg
35

8. A 200mg sample of pure calcium carbonate was acidified and

dissolved in 500 mL of solution. A 50mL sample required 25.0
mL of an EDTA solution for titration. Find the molarity of the
EDTA solution.
200
=3.99
100.1(0.5)
Ardon, Veronica Roselle C.
Ph-301
9. How many grams of disodium ethylendiaminetetraacetate
(C10H14N2Na2O8 . 2H20) is required to prepare 250mL of a
0.025M solution? what would the titer of this solution be in
terms of CaCl2. 2H2O, MgSO4 and ZnCl4?

CaCl2. 2H2O
147.01
=73.51
2

MgSO4
120.37
=60.19
2

ZnCl4

10. Calculate the weight of a sample 2-phenoxyethanol to be

used so that 20.00mL of 1N sodium hydroxide will be required
to titrate the acetic acid formed on hydrolyzing the excess acetic
anhydride.

102.09
 102.09
1
102.09 =25.52
4