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Role of Coal Blend Moisture in by Product Coke Ovens
Role of Coal Blend Moisture in by Product Coke Ovens
Role of Coal Blend Moisture in by Product Coke Ovens
Surjit Kumar Das*, Ardhendu Sekhar Nandy**, Asit Paul**, Basant Kumar Sahoo*, Basudev
Chakraborty*, Arunabha Das*
* Authors are with R & D Centre for Iron and Steel, SAIL
** Authors are from Bokaro Steel Plant, SAIL
ABSTRACT
A byproduct coke making plant is required to supply coke of good quality and adequate gas of high
calorific value for the integrated steel plant. The one element that influences the handling of coal and
impacts the operation and efficiency of the plant is coal blend moisture. Compared to other important
properties of the coal blend, moisture can be easily manipulated. The coal moisture can be increased
simply by adding water. Also, it can be reduced to 5 - 6 mass % using Coal Moisture Control (CMC) and 2
- 4 mass % using Dry-cleaned & Agglomerated Pre-compaction System (DAPS).
Moisture content is one of the most important parameters among the many variables affecting the bulk
density of coal blend and those controlling the coke qualities and yields of coke and gas. Increase in
moisture reduces coal grindability, coking pressure and internal gas pressure; helps in dust suppression
during charging and hence reduces jamming of ascension pipes and hydraulic main. Batteries charging
coals with high moisture content are not troubled with roof carbon deposits. But it increases thermal
shock to the battery and specific energy consumption. It was observed that when moisture content in
coal blend of SAIL- Bokaro Steel Plant increased to more than 8.50%, the calorific value of coke oven gas
improved. Studies have shown, however, that the increase in moisture content of coal beyond 8%
hampers strong coke formation. In the working moisture range of 9- 11%, the increase of the yield of
coke oven gas per 1% of working moisture is 5.2 m 3. Precarbon preheating process generally showed an
increase in the proportion of 40 - 80 mm coke, compared with wet charges. For SAIL- Bokaro coke ovens,
driving out 1% moisture from coal blend requires 125000 Kcal of heat/ oven. With lesser moisture, the
emission of NOx in atmosphere will also be low. On using dry to low moisture coal blend, the swelling of
coke mass increases leading to difficulty in oven pushings.
Hence, an optimum level of moisture content of charge coal needs to be maintained for improving coke
oven productivity, coke quality and operational smoothness. The coke oven managers all around the
globe maintain this optimum level according to their requirement, the operating conditions, the quality
of product and by products, the oven health & age and the ease of handling.
KEY WORDS
Coal blend moisture, Bulk density, Coal quality, Roof carbon deposit, Coking pressure, Coke Oven Gas,
Coke Quality, Smooth operation, Heat consumption
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INTRODUCTION
Coke is one of the most important and expensive raw materials used in the production of hot metal
through Blast Furnace route. In order to ensure that a blast furnace can operate stably at a high rate of
productivity and at low cost, it is important for the coke production process to be able to supply
adequate amounts of coke of uniform quality in a stable manner and at low cost. The quality parameters
of coke are characterized by its chemical properties (Ash, Moisture, Volatile Matter, Fixed carbon),
Porosity, Cold Properties (Micum Indices- M 10 & M40), Hot Properties (Coke Strength after Reaction, Coke
Reactivity Index). A typical Coke quality at SAIL- Bokaro Steel Plant is tabulated below:
The above-mentioned quality parameters of coke are dependent on chemical properties (Ash, VM,
Moisture, and Fixed Carbon), Rheological properties (FSI, LTGK, Fluidity) and Rank parameters (RoR,
MMR, Vitrinite content etc.) of coal blend along with health of the coke oven batteries, its operational
discipline and heating regime. For ease of understanding, the moisture content in coal blend has been
categorized as follows:
The one element that influences the handling of coal and impacts the operation and efficiency of the
plant is moisture. Its contribution remains more or less unnoticed. The paper discusses the role of
moisture in good quality coke production and smooth operation in coke oven battery. Compared to
other important properties of the coal blend, moisture can easily be manipulated. The moisture content
of blend coal can be increased by installing a very simple system and with a great degree of ease.
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Systems (CMC, DAPS etc.) have also been developed for reducing moisture in coal blend and are in
practice in many places.
The flow of the DAPS process is shown in Fig. 2. A fluidized- bed dryer is used for drying and classifying
of coal and a system was devised by which the coal fines mechanically adhering to coarse grains are
washed off by the action of rubbing of particles within the fluidized bed. The classified fine coal is
collected by a dust collector and is fed to a roll compactor, where it is agglomerated. For the
agglomeration of fine coal, the maximum value of grain size of fine coal was set at 0.3 mm. The
agglomerated coal is mixed with the coarse- grain coal and fed to the coke oven as DAPS coal for coking.
It is considered that coke quality is improved in DAPS owing to the improvement in the bulk density of
charging coal, which is caused by a decrease in the moisture of charging coal, and the improvement in
dilatation, which is caused by the agglomeration of coal fines.
Fig. 3: Influence of moisture content and particle size Fig. 4: Effect of moisture content on the bulk density
on bulk density of selected Coal
On the average, the bulk density is 700- 780 kg/m 3 of dry coal in top charging, and 900- 1000 kg/m 3 in
stamping operations. A uniform bulk density of the coal charged in the ovens results in uniform coke
strength. For this the moisture in the coal must be uniform or oil is to be added to iron out the variations
and achieve uniformity. Though increase in bulk density of coal through moisture addition leads to
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higher coal throughput and easier pushing due to less swelling of the coal charge, it also requires higher
coking time and greater heat consumption to form the final coke.
The charge density of wet coal is always lower than that of dry coal. Whatever be the size of the coal
particles charged in an oven, the bulk density of the coal charge decreases up to 8- 9 % moisture content
and then again increases. Hence a balance needs to be struck for keeping the moisture in charge coal
such that all the parameters involved are optimized.
5. Coking Pressure:
For ensuring the quality of coke produced, the coking coal must have a certain swelling and shrinkage
behavior. As discussed earlier, the bulk density of coal charge depends on moisture content and particle
size. The maximum coking pressure can be decreased 3 considerably by decreasing the bulk density and
by fine grinding of coal (Fig. 5).
During coal carbonization in a coke oven chamber 9, the swelling of molten coal causes a load called
“coking pressure” on oven walls. Since excessive coking pressure increases the force needed for coke
cake pushing and in some cases leads to operational problems such as hard pushes or “stickers,” causing
wall damage, one of the most important aspects of the coke making process is to control and reduce the
coking pressure. With this in mind, Nippon Steel has developed dry coal-charging processes for coke
making, such as CMC and DAPS. With the coal moisture being reduced to 5- 6 mass % using CMC and 2-
4 mass % using DAPS, the advantages of less heat consumption for carbonization, higher productivity,
and better coke quality were gained. Since a decrease in coal moisture leads to an increase in coal bulk
density in the coke oven chamber, which increases coking pressure to a great extent, it is quite
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important to precisely control the coal moisture during the dry coal charging processes so as to avoid
wall damage.
The mechanism was fully explained as the escaping dry coke-oven gas is pyrolyzed with deposition of
carbon in the porous bulk of heating chamber walls and the hydrogen evolved is completely burned in
the heating system to form steam (H20). Afterwards, the oxidative steam gasification of the carbon
deposit in the porous volume of the walls leads to formation of Hydrogen and additional Carbon
monoxide with their subsequent combustion in the firing system to form Water vapor and Carbon di-
oxide. This result in increase of the volumes of coke-oven gas (particularly CO and H 2) produced with
increasing moisture of the coal blend coked.
The monograph of Kustov characterizes the relationship between the increase of the yield of coke-oven
gas and the increase of the moisture of the coal blend being carbonized. On coking moist coal blends (up
to Working Moisture = 11%) under industrial conditions the increase of the yield of coke-oven gas, due
to the gasification of carbon by the convertible working moisture of the coal blend to Carbon mono-
oxide and Hydrogen is ≤ 28 m 3/metric ton of moist coal blend (i.e., 2.5- 2.8 m 3 per 1% of working
moisture). In the working moisture range of 9- 11%, the increase of the yield of coke oven gas per 1% of
working moisture is 5.2 m3. On increasing working moisture of the coal blend (> 11 %), the growth of the
yield of additional volumes of coke-oven gas stops. The author opined that this could be due to the
attainment of the critical mass of coal-blend moisture which, with respect to energy consumption for
gasification, is comparable with the amount of heat accumulated by the brickwork of the heating wall,
which is required for its vaporization, overheating and providing the endothermic effect of its conversion
reaction, and with the decrease of the wall surface temperature (< 700 OC).
9. Heat Consumption:
With coal moisture control equipment at Chiba Works 14, it was observed that the reduction of charging
coal moisture down to a level of 6.0% leads to a reduction in heat consumption to approximately 74
Kcal/kg-coal. With the coal quality having 97% RoR (Random Reflectance) and 70% Maximum fluidity of
the base/ original blend, the same level of coke strength was achieved employing CMC techniques. In
another study, waste heat was recovered and utilized to reduce the moisture content of coal to 4% and
saving of 80000 kcal heat/ton of coal was reported 15.
For SAIL- Bokaro coke ovens, driving out 1% moisture from coal requires 125000 kcal of heat/ ovens.
This needs a supply of 31 Nm 3 of Coke Oven Gas. On monetizing, this is equivalent to `9.5 million/
annum towards energy cost. With lesser moisture, the emission of NO x in atmosphere will also be low
owing to the less requirement of heating gas.
Page 9 of 12
mm was observed. The general conclusion from BCRA's large- scale trials was that preheating of the
charge had no effect on coke size for a representative range of British coals.
A test oven study in West Germany with coals of 20 and 30% Volatile Matter content, found that the
proportions of >100 and >80 mm coke decreased when the charge was dried or preheated. With the
higher-volatile coal, the >I00 mm content was 45% for a wet charge but 25% after preheating.
Preheating was found to increases coke mean size by 3 - 6 mm for coal blends from the USA, but it did
not affect the mean size for a Polish good-coking blend. In commercial practice at Orgreave coking plant,
preheating was reported to have practically no effect on the mean size or the >75, >50 and >25 mm
contents of the coke.
Bergbau- Forschung's development of the Precarbon preheating process, reported in several papers,
generally showed an increase in the proportion of 40 - 80 mm coke, compared with wet charges. Similar
results have been announced from the use of the Precarbon process in the USA and by INCAR in Spain 14.
CONCLUSION
The one element that influences the handling of coal and impacts the operation and efficiency of the
plant is moisture. Compared to other important properties of coal blend, moisture can easily be
manipulated. The optimum level of moisture content of charge coal improves the coke oven
productivity, coke quality and operation smoothness.
The coal moisture can be reduced to 5- 6 mass % using Coal Moisture Control (CMC) and 2- 4
mass % using Dry-cleaned & Agglomerated Pre-compaction System (DAPS).
Moisture content affects the bulk density of coal blend and hence coke qualities and yield.
Increase in moisture reduces coal grindability, coking pressure and internal gas pressure.
Increase in coal blend moisture helps in dust suppression during charging and hence reduces
jamming of gas carrying equipment like ascension pipes and hydraulic main.
Batteries charging coals with high moisture content are not troubled with roof carbon deposits.
It was observed that during rainy season when moisture content in coal blend of SAIL- Bokaro
increases to more than 8.50%, the calorific value of coke oven gas improved.
Studies have shown that the increase in moisture content of coal beyond 8% decreases the
plastic layer thickness and consequently hampers strong coke formation.
In the working moisture range of 9- 11%, the increase of the yield of coke oven gas per 1% of
working moisture is 5.2 m3.
Precarbon preheating process, reported in several papers, generally showed an increase in the
proportion of 40 - 80 mm coke, compared with wet charges.
For SAIL- Bokaro coke ovens, driving out 1% moisture from coal requires 125000 kcal heat/
ovens. This is equivalent to `9.5 million/ annum towards energy cost.
With lesser moisture, the emission of NOx will also be low.
On using dry to low moisture coal blend, the swelling of coke mass increases; reducing the
shrinkage of coke and leading to difficulty in oven pushings.
Using DAPS, total manufacturing cost can be reduced to the tune of 8- 11%.
The coke oven managers all around the globe maintain this optimum level according to their
requirement, the operating conditions, and the quality of product and by products, the oven health &
age and the ease of handling. It is important, therefore, to select the moisture content at such a level
that provides the greatest economic benefit evaluated by considering the air pollution, recovered
energy, and other expected effects.
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ACKNOWLEDGEMENT
Authors are grateful to management of SAIL- RDCIS and SAIL- BSL specially Sri B. C. Roy, GM- RDCIS
Bokaro Centre; Sri M. P. Reddy, GM (Coal & Energy) - RDCIS Ranchi; Sri S. Pal, GM (Quality), Bokaro Steel
Plant and Sri B. P. Verma, GM & In-charge (Coke Oven & By Product), Bokaro Steel Plant for providing
necessary trigger and impetus in writing the paper. Authors are also thankful to Late Sri Prashant Gupta,
Ex- Manger, RDCIS Bokaro Centre for providing some useful articles related to the topic.
REFERENCES
1. New Control System of Coal Moisture at Coke Oven, Wakuri, S; Ohno, M; Hosokawa, K, Author Affiliation:
Nippon Steel, Conference: Ironmaking Proceedings. Vol. 45. II, Washington, D.C., USA, 6-9 Apr. 1986, Publ: Iron
and Steel Society, Inc., 410 Commonwealth Dr., Warrendale, Pennsylvania 15086, USA, 1986 pp. 303-314
2. Operation of dry-cleaned and agglomerated precompaction system (DAPS); Tanaka, S; Okanishi, K; Kikuchi, A;
Yamamura, Y. Author Affiliation: Nippon Steel Conference: Ironmaking Conference Proceedings. Vol. 56,
Chicago, Illinois, USA, 3-16 Apr. 1997. Publ: Iron & Steel Society Ironmaking Division, 1997, pp. 139-142 ISSN:
1-886362-23-8
3. Chemistry of Coal Utilization, Second Supplementary Volume; Martin A Elliott
4. The Making, Shaping and Treating of Steel, 11 th Edition; Editor: David H Wakelin; Publ: USA, 1999; ISBN: 0–
930767–03–9
5. Applied Coal Petrology; Isabel Suarez-Ruiz & John C Crelling
6. The role of Spherulitic Carbon in coke oven roof deposits; R. C. Zavitz - Research metallurgist; Dominion
Foundries and Steel Limited, Hamilton, Canada
7. Influence of coal moisture control on carbon deposition in the coke oven chamber, Furusawa, A; Nakagawa, T;
Maeno, Y; Komaki, I Author Affiliation: Nippon Steel Chemical Publ: Japan, 1998 ISIJ INTERNATIONAL 38,
(12), 1320-1325 1998 ISSN: 0915-1559
8. Fuel, 73 (1994), 1904; V. Krebs, l. F. Mareche, G. Furdin and D. Dumay
9. Coking Pressure Control by Selective Crushing of High Coking Pressure Coal; Seiji NOMURA, Takashi ARIMA,
Atsushi DOBASHI and Kazuhide DOI, ISIJ International, Vol. 51 (2011), No. 9, pp. 1425–1431
10. The Mechanism of Carburization- Decarburization of Chamber Walls of Coke- Oven Batteries; I. G. Zubilin, V.
I. Rudyka, A. A. Tarakanov and A. I. Zubilina, Coke and Chemistry, No. 10, 2001, pp. 7- 10
11. Effect of coal blend and operating variables on internal gas pressure during coking in a coke oven; Lee, W J ;
Lee, Y K Publ: South Korea, 2000 RIST JOURNAL OF R&D 14,(1), pp. 107-113 Mar. 2000 ISSN: 1225-486X
12. Coking Pressure and Coal Moisture - Effects During Carbonization - Implications for a New Coking Reactor
Design; Rohde, W; Habermehl, D; Kolitz, V; Author Affiliation: Bergbau-Forschung Conference: 47th
Ironmaking Conference, Toronto, Canada, 17-20 Apr. 1988 Publ: Iron and Steel Society, Inc., USA, 1988, pp.
135-143
13. Wall pressure determination by measurement and interpretation of internal gas pressures in a six-meter coke
battery; G M Latshaw, H R McCollum, R W Stanley, United States Steel Corporation, pp. 373- 380
14. Operation of Coal Moisture Control Equipment of Coke Oven Batteries at Chiba Works; Katayama, T;
Kobayashi, T; Tanaka, T; Takahashi, H; Obata, H Author Affiliation: Kawasaki Steel Conference: 48th Ironmaking
Conference, Chicago, Illinois, USA, 2-5 Apr. 1989 Publ: Iron and Steel Society, Inc., 410 Commonwealth Dr.,
Warrendale, Pennsylvania 15086, USA, 1989 pp. 103-107
15. Recent Heat Recovery Techniques in Ichi Kan Iron Incorporation; WORLD STEEL (JPN.) (6), 1986, pp. 2- 9
16. Coke Lump Size: Some of the Influencing Factors (a Literature Review); D. G. Edwards and K. G. Barber,
Cokemaking International 1/2000, pp. 87- 92
17. Principles for Blending Coals; T G Callcott, BHP Technical Bulletin Volume 23 No. 2 November 1979
18. Monograph on Coal & Coke at Tata Steel
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