OMS ARAF 101 FFE RGRAAER-REREEMERNE TAM on: _ bee me a aa 28} DARD AH BEM TIER» APE RIMAL 100 FH RAAT RK 1. Gold and silicon are mutually insoluble in the solid state and form a eutetc system with en eutectic temperature of 636K and a eutectic composition of Xz ~ 0.186 Caeulate the Gidbs fee energy of the eutectic mel relative to (a) unmixel quid Av and liquid Si, and (6) unmixed sold ‘Auand slid Si, with comesponding illustration. Knowing that, ABgaa’= 12600 Vinol_ at Taaye1338K Aas’ 2. Ata pressure of 1 atm the equilibrium melting temperature of silver is 961°C, and, at this temperature the latent het of meling of silvers 11200 To. Calculate the enthalpy, entopy and Gibbs fee energy of freezing 1 mole of supercooled liquid silver at 800°C, and explain if this ‘curs spontaneously Knowing that for silver, C212 48S5«10°T+15910°T? imo K Cy =305 nol K 3. Arigid container is pattoned into n compartments with individual volume faction of Vi, Ve, Ve, while ech compartment contains, me. moles of ideal zs A,B,C, respectively Calculate te entropy change wen th parttons are removed 4, ‘Tin obeys Henry’ aw in dilute liquid solutions of Sa and Cd and the Henran activity coefficient of Soy. yg, aves with temperature as ny, = —8407r-+1.58 CCaloulate the change in temperature when 1 mole of liquid Sn and 99 moles of liquid Cd are mixed in an adiabatic enclosre, The molar constant pressure heat capacity ofthe alloy formed is 29.5 1K. 5. When I mole of argon gas is bubbled through a large volume of an Fe-Mn melt of Xi = 0.5 at 1863 K evaporition of Mn into the Ar causes the mass ofthe melt to decease by 1.50 g. The gas leaves the melt at a pressure of 1 atm, Calculate the activi coefficient of Minin the liquid alloy ‘Knowing that the atomic mass of Mn is 54.94 g/mol, and th saturated vapor pressure of liquid Ma can be calelated as InP (atm) =~ 3844077 3.02 In T +3768 (4538.20 &)