Page 2 of & 1. Moving down group IV from carbon to lead in the modem periodi table, the first fonisation energies tend to ‘A. increase throughout. B. decrease throughout. C. vary and show an irregular pattern. D. decrease with a stight increase at the end. Which of the following oxides of period three elements has a tendency to react as both an acid anda base? A. SO B. SiO, Cc. MgO D. Al,O3 3. Beryllium differs from other group IIA elements due to its A. — characteristic taste and low melting point. B. large atomic size and low ionization energy. C. small atomic size and high electronegativity value. D. _ high ionisation energy and low electronegativity value. 4. The coordination number of copper in [Cu(NH;CH,CH,NH})2]** is A. B. G D. wane 5. The electronic configuration of 2,Fe”? is a. (Ara® B, [Ar3d® c,_ (Ar3d?4s” p, fArl3dS4s? 6. Which of the following statements is FALSE about E2 mechanism? ‘A. Primary alkyl halides generally follow E2 mechanism, B. The nucleophile attacks and the leaving group leaves at t C. The first step is the slow ioni: coer aaee D. ion of the substrate to give a carbocati ‘The rate of reaction can be expressed as Rate = k{Alky! halide][Nucleophile ‘gee SS DUWTVIVEW WILTL LWTILICPage 3 of 8 7. Inthe given reaction, the compound Y is a/ an R R-Mg-X + Y——> Z H30_ R-C-OH i R A. ketone. B, aldehyde. C. alkyl halide D. carbon dioxide. 8. _ Inthe preparation of Grignard’s reagent, the metal which reacts with alkyl halides in the presence of dry ether is A. iron. B. beryllium. C. aluminium. D. magnesium. 9. Which of the following compounds are distinguished using the Lucas reagent test? ‘A. Alcohols and phenols B. Aldehydes and ketones C. Primary, secondary and tertiary amines D. Primary, secondary and tertiary alcohols 10. Which compound on oxidation with sodium iodate gives a positive iodoform test? A. H,CCH,OH B, H,CC=CCH, Cc. H,CCH=CHCH, D. _H,CCH,CH,OCH, 11. Ethanol ean be manufactured from ethanal by A. hydration. B. oxidation. C. acidic hydrolysis. D. catalytic reduction. 12, The IUPAC name of the given compound is C,H,-O-CH, ethoxy ethane. methoxy ethane. ethoxy methane. methoxy methane. PI ‘TURN OVER THE PAG! T304-TRATITO SCUTTLED WILM LATNIC! pop>Page 4 of 8 13. 14, 15, 16. Chiral centre is absent in A. HjCCHONC,H, BL CiHy)CHON): C. (CyHg)CHEEINCHO D. (GHsycCHONCOCH, ‘The number of pi bonds in the given organic compound is AL B. GQ D. How many electrons are involved in the sigma bs framework of the given compound? A. 26 BL 28 cM D. 42 Which pair of reactants would produce acetaltehyde? A, CH,CH,ON +O] B. CH,C&N+H,0 Cc. CH,COOH +{1] D, HC#CH+O; Tits04-1821110 cy DEWTUILEW WILTL LUISE— page Sof 8 \ 17. The isomers of the given aldehyde are 9 4 HsC—CH,—CH,—C, \ H i P ‘OH |) cH; —cH L Cli CH CH | Hl ‘CH; | | T mn | o 7 U sc —CH,—CH,— CH —OH CH=CH ‘CH | a TV, | A. Landi. B. and Ill. C. TandIVv. D. MandIv. 18 Which of the following compounds is the MOST acidic? A. CHjCH,CH,COOH B. CH3CHjCHCICOOH C. CH3CHCICH;COOH D, _CH3CICH2CH,COOH 19. When acetyl chloride (CH3COCI) reacts with acetic acid (CH3COOH) in the presence of Pyridine, it forms acetone. acetamide. methyl acetate. acetic anhydride. por> PLEASE TURN OVER TI sorTRaTO DOWIVILEW WILTL UWTILIC!Page 6 of § 20. Which of the following is/ are homocyelie compound(s)? [ S| ie " C\ ZA N’ Br Gl T 7 ii v Vv A. Lonly B. IVonly CI llandIv D. [land Vv 21. Which characteristic is CORRECT about organic compounds? A. They dissolve in non-polar solvents. B. They possess fluorescent colours. C. They conduct electric current. D. They are non-combustible, 22, Triglycerides in the presence of lipase hydrolyses to A. glycerol tristearate. B, glycerol and soap. C. glycerol and glucose. D. glycerol and fatty acid. 23. Cholesterol is an essential precursor for the synthesis of all of the following EXCEPT A. bile. B, steroids. C, vitamin A. D. vitamin D. 24, Nail polish removers contain A. acetone. B. benzene. C, formalin. D. ethylene. Hi504-1821110 DLWTUILEW WILTy LUMSCLpage 70°8 Which of the following is TRUE? 25. Pesticide Target x ng 7 Rodents Te Cc Herbicides Tete D Nematicides Mounds 26, Which of the following encourages the desi and generation of hazardous substances? Posies and Droeesees hat mia the use A. TUPAC B. Green chemistry C. Nanotechnology D. Industrial chemistry 27, In sewage water treatment, air is continually pumped through th . i 7 ly he sludge from the aeration tank eI ig 1¢ bottom of the A. to remove bad smell. B. to produce methane gas. C. tokill harmful microorganisms. D. _ tooxidise harmful organic compounds. ‘molecule absorbs infrared radiations by showing all of the following types of bending 28. vibrations EXCEPT A. rocking. B. wagging. C. _ scissoring. D. stretching. 29. During crime investigation, analysts identify the quantity of any poison ingested in a victim using ‘A. mass spectroscopy. B. infrared spectroscopy: C. _ultraviolet-visible spectroscopy: D. nuclear magnetic resonance spectroscoPy- sunt of deflection by different pends jons in the magnetic field dey 30. Ina mass spectrometer, the amor upon A, SAEBE ratio. mass B, 755. atio. charge C. masses of ions only. D. charges of ions only- ENDO} DEWTUILEW WiLTy LMSC