Page 2 of &
1. Moving down group IV from carbon to lead in the modem periodi table, the first fonisation
energies tend to
‘A. increase throughout.
B. decrease throughout.
C. vary and show an irregular pattern.
D. decrease with a stight increase at the end.
Which of the following oxides of period three elements has a tendency to react as both an acid
anda base?
A. SO
B. SiO,
Cc. MgO
D. Al,O3
3. Beryllium differs from other group IIA elements due to its
A. — characteristic taste and low melting point.
B. large atomic size and low ionization energy.
C. small atomic size and high electronegativity value.
D. _ high ionisation energy and low electronegativity value.
4. The coordination number of copper in [Cu(NH;CH,CH,NH})2]** is
A.
B.
G
D.
wane
5. The electronic configuration of 2,Fe”? is
a. (Ara®
B, [Ar3d®
c,_ (Ar3d?4s”
p, fArl3dS4s?
6. Which of the following statements is FALSE about E2 mechanism?
‘A. Primary alkyl halides generally follow E2 mechanism,
B. The nucleophile attacks and the leaving group leaves at t
C. The first step is the slow ioni: coer aaee
D.
ion of the substrate to give a carbocati
‘The rate of reaction can be expressed as Rate = k{Alky! halide][Nucleophile
‘gee SS
DUWTVIVEW WILTL LWTILICPage 3 of 8
7. Inthe given reaction, the compound Y is a/ an
R
R-Mg-X + Y——> Z H30_ R-C-OH
i
R
A. ketone.
B, aldehyde.
C. alkyl halide
D. carbon dioxide.
8. _ Inthe preparation of Grignard’s reagent, the metal which reacts with alkyl halides in the
presence of dry ether is
A. iron.
B. beryllium.
C. aluminium.
D. magnesium.
9. Which of the following compounds are distinguished using the Lucas reagent test?
‘A. Alcohols and phenols
B. Aldehydes and ketones
C. Primary, secondary and tertiary amines
D. Primary, secondary and tertiary alcohols
10. Which compound on oxidation with sodium iodate gives a positive iodoform test?
A. H,CCH,OH
B, H,CC=CCH,
Cc. H,CCH=CHCH,
D. _H,CCH,CH,OCH,
11. Ethanol ean be manufactured from ethanal by
A. hydration.
B. oxidation.
C. acidic hydrolysis.
D. catalytic reduction.
12, The IUPAC name of the given compound is
C,H,-O-CH,
ethoxy ethane.
methoxy ethane.
ethoxy methane.
methoxy methane.
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13.
14,
15,
16.
Chiral centre is absent in
A. HjCCHONC,H,
BL CiHy)CHON):
C. (CyHg)CHEEINCHO
D. (GHsycCHONCOCH,
‘The number of pi bonds in the given organic compound is
AL
B.
GQ
D.
How many electrons are involved in the sigma bs
framework of the given compound?
A. 26
BL 28
cM
D. 42
Which pair of reactants would produce acetaltehyde?
A, CH,CH,ON +O]
B. CH,C&N+H,0
Cc. CH,COOH +{1]
D, HC#CH+O;
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DEWTUILEW WILTL LUISE—
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17. The isomers of the given aldehyde are
9
4
HsC—CH,—CH,—C,
\
H
i P ‘OH |)
cH; —cH L Cli CH CH |
Hl ‘CH; |
|
T mn |
o
7 U
sc —CH,—CH,— CH —OH CH=CH
‘CH |
a TV, |
A. Landi.
B. and Ill.
C. TandIVv.
D. MandIv.
18 Which of the following compounds is the MOST acidic?
A. CHjCH,CH,COOH
B. CH3CHjCHCICOOH
C. CH3CHCICH;COOH
D, _CH3CICH2CH,COOH
19. When acetyl chloride (CH3COCI) reacts with acetic acid (CH3COOH) in the presence of
Pyridine, it forms
acetone.
acetamide.
methyl acetate.
acetic anhydride.
por>
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DOWIVILEW WILTL UWTILIC!Page 6 of §
20. Which of the following is/ are homocyelie compound(s)?
[
S| ie " C\
ZA
N’ Br Gl
T 7 ii v Vv
A. Lonly
B. IVonly
CI llandIv
D. [land Vv
21. Which characteristic is CORRECT about organic compounds?
A. They dissolve in non-polar solvents.
B. They possess fluorescent colours.
C. They conduct electric current.
D. They are non-combustible,
22, Triglycerides in the presence of lipase hydrolyses to
A. glycerol tristearate.
B, glycerol and soap.
C. glycerol and glucose.
D. glycerol and fatty acid.
23. Cholesterol is an essential precursor for the synthesis of all of the following EXCEPT
A. bile.
B, steroids.
C, vitamin A.
D. vitamin D.
24, Nail polish removers contain
A. acetone.
B. benzene.
C, formalin.
D. ethylene.
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DLWTUILEW WILTy LUMSCLpage 70°8
Which of the following is TRUE?
25.
Pesticide
Target
x ng
7 Rodents
Te
Cc Herbicides Tete
D Nematicides Mounds
26, Which of the following encourages the desi
and generation of hazardous substances? Posies and Droeesees hat mia
the use
A. TUPAC
B. Green chemistry
C. Nanotechnology
D. Industrial chemistry
27, In sewage water treatment, air is continually pumped through th
. i 7 ly he sludge from the
aeration tank eI ig 1¢ bottom of the
A. to remove bad smell.
B. to produce methane gas.
C. tokill harmful microorganisms.
D. _ tooxidise harmful organic compounds.
‘molecule absorbs infrared radiations by showing all of the following types of bending
28.
vibrations EXCEPT
A. rocking.
B. wagging.
C. _ scissoring.
D. stretching.
29. During crime investigation, analysts identify the quantity of any poison ingested in a victim
using
‘A. mass spectroscopy.
B. infrared spectroscopy:
C. _ultraviolet-visible spectroscopy:
D. nuclear magnetic resonance spectroscoPy-
sunt of deflection by different
pends
jons in the magnetic field dey
30. Ina mass spectrometer, the amor
upon
A, SAEBE ratio.
mass
B, 755. atio.
charge
C. masses of ions only.
D. charges of ions only-
ENDO}
DEWTUILEW WiLTy LMSC