Page 2 of $ 1. Which of the following periodic trends is TRUE as we go down group VIIA? Electronegativity | Reactivity A Increases Decreases B Decreases Remains same ic Increases Increases D Decreases Decreases 2. Which of the following elements has the highest boiling point? A Li B. Na Cc K D. Cs 3. In the network structure of SiO, each silicon atom is bonded with A. one oxygen atom. B. two oxygen atoms. C. three oxygen atoms. D. four oxygen atoms. 4. The coordination number of the central cation in [Cr(QNHs),CLBr2]"" is Amma) B. 4 Cc. 6 Dd 8 5. Elements which often show variable oxidation states and form coloured compounds are called A. _ halogens. B. noble gases. C. transition metals. D. alkaline earth metals. 6. — 2-Butanol (secondary alcohol) is formed wh j en ethyl magnesium bromide (CaHsMgBr) res with A. acetone. B. acetaldehyde. C. formaldehyde. D. methyl acetate. DEUTLIVEW WILTL UUTILC!page 3 0f8 4. When an ester eats with equivalents of Grignard reagent, it forms a A. tertiary alcohol. B. secondary alcohol. C._ tertiary alkyl halide, D. secondary alkyl halide. s, Thepolarnature ofthe N-H bond in amines results in ‘A. Towmelting point and low boiling point. B._ high melting point and low boiling point. C.__lowmelting point and high boiling point. D. high melting point and high boiling point. 4, Phenols are more acidic than alcohols due tothe stabilisation of A. carbocation. B._ phenolate ion. C. metho: D. carboxylate ion. 10. Ethyl alcohol reacts with acetic acid to form a/ an ‘A. acetone. B. diethyl ether. C. ethyl acetate. D. acetaldehyde. 11. Phenols are very reactive towards electrophilic aromatic substitution because the hydroxy group is strongly ‘A. activating and meta directing. and meta directing. and ortho para directing, D. deactivating and ortho para directing. 12. When an alkyl halide is heated with sodi 1m alkoxide, it results in the formation of a/ an A. ether. B. amine, C. alcohol, D. carboxylic acid. 13, 3. The general decreasing reactivity order of alkanes, alkenes and alkynes is alkanes > alkenes > alkynes . alkynes > alkenes > alkanes alkenes > alkynes > alkanes alkenes > alkanes > alkynes PLEASE TURN OVER. IE PAGE DEWTUILEW WiLTy LUMSCLPage d of & Which of the followin, $a meta benzene? A, °c BL -OCHy c, -€N Dd, -NCIb) 15. The chiral centre in the given molecule is CHy OW HW;C—CH—CH— COOH 4 3 2 1 AL Cl B. C2 c 63 D. C4 16, The IUPAC name of the given molecule is CH; 0 HyC—CH—C—cH,—CH,— CH, A. 2-methyl-3-hexanone. B. — 5-methyl-4-hexanone. C. 1, 1-dimethyl-2-pentanone, D. _ 5,5-dimethyl-4-pentanone, 17. OH dil NaOH HyC—CHO + HyC—CHO H,C—CH—CH,—CHO ‘The above chemical equation represents A, B. Ci D. polymerisation reaction, FI1604-1821110 DEWTUILEW WILTt LUMSCPage 5 of 8 18. 20. 21. 2, 23, Too TeTTTT Which of the following compounds is the most a A. CH,COOI B, FCCOOH C. FCHCOOH D,_ FCH,COOI Which of the following options is FALSE with reference to the presence of carboxylic acids in different natural products? "| type orCarhosylie Acid] Natural Product A Citric acid Lemon B. Tartaric acid Grapes c ‘Amino acid Meat D. Acetic acid Milk Coal tar is a by-product obtained in the destructive distillation of coal. It contains all of the following aromatic compounds EXCEPT A. petrol. B. toluene, C. benzene, D. naphthalene. Acid amide functional group is found in AL CgHisNO, B. CH;C=N . CH;CONH, D. HOOCCH,NH, Which of the following sugars are the major constituents of a nucleoside? A. Fructose and ribose B. - Glucose and maltose C. Ribose and deoxyribose D. Deoxyribose and glucose Hyperglycemia can be controlled by an increase in A. insulin, B. thyroxin, C. thrombin, D. adrenaline, PLEASE TURN OVER THE PAGE. DEUTLILEW WITTE UWPage 6 of 8 24, Polyvinyl chloride (PVC) is a/ an A. copolymer. B. _ biopolymer. C. addition polymer. D. condensation polymer. 25, The given equation shows a petrochemical and its derivative, nCH,=—=CH——> —cr—f{on— cH} CH Hs CoH CoH Which of the following pairs of monomer and polymer is shown in the given polymerisation process? Monomer Polymer. ‘A. | Vinylebloride | Polyvinyl chloride B. Styrene Polystyrene c. Ethylene Polyethylene Dz Butadiene Polybutadiene 26. Urban smog is produced by a complex series of photochemical reactions involving ‘A. _ sulphur dioxide and water vapours. B. _ hydrocarbons and pollens from plants. C. carbon dioxide and chlorofluorocarbons. D. nitric oxide and volatile organic compounds. 27. If the atmosphere contains excessive quantity of COs, then the Greenhouse Earth's Effect ‘Temperature A Decreases Decreases B Increases Decreases c Increases Increases D Decreases Increases F11604-1821110 DLWTLILEW WILTy LUMSCL 4page TOFS 2, Which of the following techniques is best suited to confirm the number of different types of protons ina molecule? A. Mass spectrometry B. _ Infrared spectroscopy CC. Ultraviolet-visible spectroscopy D. Nuclear magnetic resonance spectroscopy 29, The correct order for the five main stages of the working of a mass spectrometer is ‘A. _ acceleration, deflection, detection, ionisation, vaporisation. B. ionisation, deflection, vaporisation, acceleration, detection. CC. _ detection, acceleration, deflection, ionisation, vaporisation. D. _vaporisation, ionisation, acceleration, deflection, detection. 50. In the infrared (IR) spectrum of acetone, where would you expect the characteristic peak of C=O bond? A. 3100~3500 em? B. 2100-2150em"™ C. 1705-1725 em" D. 1620-1680 em™ END OF PAPER TooTETTTO DEWTUILEW WiLTy LUMSCL