Inhibex Bio 800 Bulk 1 000000000000828700 Rest of World (GHS) - English

Page: 1
SAFETY DATA SHEET Revision Date: 11.03.2017

Print Date: 04.11.2021
SDS Number: R0718491
Inhibex™ BIO 800 gas hydrate inhibitors Version: 1.0
™ Trademark, Ashland or its subsidiaries, registered
in various countries
828700
Conforms to EU Regulation 1907/2006/EC as amended. - SDSGHS_RW

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : Inhibex™ BIO 800
gas hydrate inhibitors
™ Trademark, Ashland or its subsidiaries, registered in
various countries
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.3 Details of the supplier of the safety data 1.4 Emergency telephone number
sheet 00-800-274-5263-3/001-859-357-3564, or contact
Ashland your local emergency telephone number at 111 -
P.O. Box 8619 ENG, SCO, CYM and 0808 808 8000 - NIE (Mo -
NL3009 AP, Rotterdam Fr, 08.00 - 18.00)
Netherlands
+31 10 497 5000 (in the Netherlands), or
contact your local CSR contact person Product Information
+31 10 497 5000 (in the Netherlands), or contact
your local CSR contact person
EUSMT@ashland.com
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4 H302: Harmful if swallowed.
Acute toxicity, Category 4 H332: Harmful if inhaled.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :
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Signal word : Warning
Hazard statements : H302 + H332 Harmful if swallowed or if inhaled
Supplemental Hazard : EUH066 Repeated exposure may cause skin

Statements dryness or cracking.
Precautionary statements : Prevention:

P261 Avoid breathing dust/ fume/ gas/ mist/
vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this
product.
P271 Use only outdoors or in a well-ventilated
area.
Response:
P304 + P340 + P312 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call
a POISON CENTER/doctor if you feel
unwell.
Disposal:
P501 Dispose of contents/ container to an
approved waste disposal plant.
Hazardous components which must be listed on the label:

2-butoxyethanol
Additional Labelling:
EUH208 Contains 1-vinylhexahydro-2H-azepin-2-one. May produce an allergic reaction.
2.3 Other hazards
Additional advice
No information available.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Hazardous components
Chemical name CAS-No. Classification Concentration
EC-No. (REGULATION (EC) (%)
Registration number No 1272/2008)
2-butoxyethanol 111-76-2 Acute Tox.4; H302 >= 50,00 - <
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203-905-0 Acute Tox.4; H332 60,00

01-2119475108-36-xxxx Acute Tox.4; H312
Skin Irrit.2; H315
Eye Irrit.2; H319
Acetic acid ethenyl 1204768-35-3 Skin Irrit.2; H315 >= 40,00 - <
ester, polymer with 1- Eye Irrit.2; H319 50,00
ethenylhexahydro-2H-
azepin-2-one,
hydrolyzed
1-vinylhexahydro-2H- 2235-00-9 Acute Tox.4; H302 >= 0,10 - <
azepin-2-one 218-787-6 Acute Tox.4; H312 0,50
01-2119977109-27-xxxx Eye Irrit.2; H319
Skin Sens.1B; H317
STOT RE1; H372
vinyl acetate 108-05-4 Flam. Liq.2; H225 >= 0,10 - <
203-545-4 Acute Tox.4; H332 0,25
Carc.2; H351
STOT SE3; H335
Aquatic Chronic3;
H412
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Move out of dangerous area.
Call a POISON CENTRE or doctor/physician if exposed or
you feel unwell.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : Move to fresh air.

IF INHALED: Call a POISON CENTER/doctor if you feel
unwell.
Keep patient warm and at rest.
If unconscious, place in recovery position and seek medical
advice.
In case of skin contact : If on skin, rinse well with water.

First aid is not normally required. However, it is
recommended that exposed areas be cleaned by washing
with soap and water.
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If on clothes, remove clothes.
In case of eye contact : Flush eyes with water as a precaution.

Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.
If swallowed : Obtain medical attention.

Rinse mouth with water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
irritation (nose, throat, airways)
Bloody urine
Difficulty in breathing
Risks : Harmful if swallowed or if inhaled

Repeated exposure may cause skin dryness or cracking.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No hazards which require special first aid measures.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing : High volume water jet

media
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5.2 Special hazards arising from the substance or mixture

Specific hazards during : If product is heated above its flash point it will produce vapors
firefighting sufficient to support combustion. Vapors are heavier than air
and may travel along the ground and be ignited by heat, pilot
lights, other flames and ignition sources at locations near the
point of release.
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion : carbon dioxide and carbon monoxide

products Aldehydes
Ketones
Organic acids
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Specific extinguishing : Product is compatible with standard fire-fighting agents.

methods
Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Use a water spray to cool fully closed containers.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Remove all sources of ignition.
Use personal protective equipment.
Ensure adequate ventilation.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
Comply with all applicable federal, state, and local regulations.
Suppress (knock down) gases/vapours/mists with a water
spray jet.
6.2 Environmental precautions

Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
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If the product contaminates rivers and lakes or drains inform

respective authorities.
6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections

For further information see Section 8 and Section 13 of the safety data sheet.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Avoid formation of aerosol.
Provide sufficient air exchange and/or exhaust in work rooms.
Do not breathe vapours/dust.
Do not smoke.
Container hazardous when empty.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.
Advice on protection against : No sparking tools should be used. Keep away from open
fire and explosion flames, hot surfaces and sources of ignition.
Hygiene measures : Wash hands before breaks and at the end of workday. When
using do not eat or drink. When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place. Observe label precautions. No smoking.
Other data : No decomposition if stored and applied as directed.
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7.3 Specific end use(s)

Specific use(s) : No data available
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure Limits

Components CAS-No. Value type (Form Control parameters Basis
of exposure)
2-butoxyethanol 111-76-2 TWA 20 ppm 2000/39/EC
98 mg/m3
STEL 50 ppm 2000/39/EC
246 mg/m3
TWA 25 ppm GB EH40
STEL 50 ppm GB EH40
vinyl acetate 108-05-4 STEL 10 ppm 2009/161/EU

35,2 mg/m3
TWA 5 ppm 2009/161/EU
17,6 mg/m3
TWA 5 ppm GB EH40
17,6 mg/m3
STEL 10 ppm GB EH40
35,2 mg/m3
Biological occupational exposure limits
Substance name CAS-No. Control parameters Sampling time Basis
ETHYLENE GLYCOL 111-76-2 butoxyacetic acid: After shift GB EH40
MONOBUTYL ETHER 240 BAT
mmol/mol creatinine
(Urine)
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
1-vinylhexahydro-2H-azepin-2- : End Use: Workers
one Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 4,9 mg/m3
End Use: Workers
Exposure routes: Inhalation
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Potential health effects: Long-term local effects

Value: 0,17 mg/m3
End Use: Workers
Exposure routes: Skin contact
Value: 0,7 mg/kg
End Use: Workers
End Use: Workers

Exposure routes: Eye contact
Potential health effects: Local effects
End Use: Consumers

Value: 1,04 mg/m3
End Use: Consumers
Value: 0,04 mg/m3
End Use: Consumers
Value: 0,42 mg/kg
End Use: Consumers
End Use: Consumers

Exposure routes: Ingestion
Value: 0,4 mg/kg
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
1-vinylhexahydro-2H-azepin-2- : Fresh water
one Value: 0,1 mg/l
Marine water
Value: 0,01 mg/l
Fresh water
Value: 1 mg/lIntermittent use/release
Fresh water sediment

Value: 0,829 mg/kg
Marine sediment
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Value: 0,0829 mg/kg

Sewage treatment plant
Value: 262 mg/l
Soil
Value: 0,107 mg/kg
8.2 Exposure controls
Engineering measures
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse
effects.
Personal protective equipment
Eye protection : Not required under normal conditions of use. Wear splash-
proof safety goggles if material could be misted or splashed
into eyes.
Hand protection
Remarks : butyl-rubber
The suitability for a specific workplace should be discussed

with the producers of the protective gloves.
Skin and body protection : Wear as appropriate:

Impervious clothing
Safety shoes
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Respiratory protection : In the case of vapour formation use a respirator with an

approved filter.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : liquid
Colour : brown
Odour : No data available
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Odour Threshold : No data available
pH :
No data available
Melting point/freezing point : -40 °C
Boiling point/boiling range : 170 °C
Flash point : 62,8 °C
Evaporation rate : No data available
Flammability (solid, gas) : No data available
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapour pressure : < 1,33 hPa (20 °C)
Relative vapour density : No data available
Relative density : No data available
Density : 0,902 g/cm3
Solubility(ies)
Water solubility : No data available
Solubility in other solvents : No data available
Partition coefficient: n- : No data available

octanol/water
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : No data available
Oxidizing properties : No data available
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9.2 Other information

No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
No decomposition if stored and applied as directed.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Vapours may form explosive mixture with air.
10.4 Conditions to avoid

Conditions to avoid : Do not allow evaporation to dryness.
Heat, flames and sparks.
10.5 Incompatible materials

Materials to avoid : Acids
aluminum
Amines
Ammonia
Bases
chlorates
Chlorine
salts of strong bases
Strong oxidizing agents
10.6 Hazardous decomposition products

Hazardous decomposition : Aldehydes
products carbon dioxide and carbon monoxide
Organic acids
ketones
SECTION 11: Toxicological information

11.1 Information on toxicological effects
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Information on likely routes of : Inhalation

exposure Skin contact
Eye Contact
Ingestion
Acute toxicity
Harmful if swallowed or if inhaled
Product:
Acute oral toxicity : LD50 (Rat, female): 2.000 mg/kg
Method: OECD Test Guideline 425
Acute dermal toxicity : LD50 (Rabbit): > 2.000 mg/kg

Assessment: No adverse effect has been observed in acute
dermal toxicity tests.
Components:
2-butoxyethanol
Acute oral toxicity : LD50 (Guinea pig): 1.200 mg/kg
Acute inhalation toxicity : LC50 (Rat): 2,17 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The component/mixture is classified as acute
inhalation toxicity, category 4.
Acute dermal toxicity : Assessment: The component/mixture is classified as acute

dermal toxicity, category 4.
LD50 (Rabbit): 400 - 500 mg/kg
Components:
Acetic acid ethenyl ester, polymer with 1-ethenylhexahydro-2H-azepin-2-one, hydrolyzed
Acute oral toxicity : LD50 (Rat): > 2.000 mg/kg
Acute dermal toxicity : LD50 (Rabbit): > 2.000 mg/kg

Assessment: No adverse effect has been observed in acute
dermal toxicity tests.
Components:
1-vinylhexahydro-2H-azepin-2-one
Acute oral toxicity : LD50 (Rat): 1.114 mg/kg
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Acute inhalation toxicity : LC50 (Rat): > 1,6 mg/l

Exposure time: 8 h
Acute dermal toxicity : LD50 (Rabbit): 1.700 mg/kg
Components:
vinyl acetate
Acute oral toxicity : LD50 (Rat): 3.500 mg/kg
Acute inhalation toxicity : LC50 (Rat): 15.810 mg/m3

Exposure time: 4 h
Test atmosphere: vapour
Acute dermal toxicity : LD50 (Rabbit, male): 7.440 mg/kg

GLP: no
Skin corrosion/irritation
Repeated exposure may cause skin dryness or cracking.
Product:
Species: Rabbit
Result: Slight, transient irritation
GLP: yes
Result: Repeated exposure may cause skin dryness or cracking.
Components:
2-butoxyethanol
Species: Rabbit
Result: Irritating to skin.

Species: Rabbit
Result: irritating
Species: Rabbit
Result: Slight, transient irritation
vinyl acetate
Species: Rabbit
Result: No skin irritation
GLP: yes
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Serious eye damage/eye irritation

Not classified based on available information.
Product:
Species: Rabbit
Result: No eye irritation
GLP: yes
Remarks: Unlikely to cause eye irritation or injury.
Components:
2-butoxyethanol
Species: Rabbit
Result: Irritating to eyes.

Species: Rabbit
Result: irritating
Species: Rabbit
Result: Irritating to eyes.
vinyl acetate
Species: Rabbit
Result: No eye irritation
GLP: yes
Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Product:
Components:
2-butoxyethanol
Test Type: Maximisation Test
Species: Guinea pig
Assessment: Does not cause skin sensitisation.
Exposure routes: Dermal
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Assessment: May cause sensitisation by skin contact.

Method: Local lymph node assay
GLP: yes
vinyl acetate
Test Type: Local lymph node assay
Species: Mouse
GLP: yes
Germ cell mutagenicity

Components:
2-butoxyethanol
Genotoxicity in vitro : Test Type: Ames test
Test species: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Result: negative
Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro
Test species: Chinese hamster lung cells
Result: negative
GLP: yes
: Test Type: Ames test

Result: negative
GLP: yes
: Test Type: in vitro assay

Result: negative
GLP: yes
vinyl acetate
Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro
Test species: Human lymphocytes
Result: positive
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Result: negative

Metabolic activation: Metabolic activation
Method: Mutagenicity (Escherichia coli - reverse mutation
assay)
Result: negative
: Test Type: Micronucleus test

Test species: human lymphoblastoid cells
Result: positive
Carcinogenicity
Components:
vinyl acetate
Carcinogenicity - : Limited evidence of a carcinogenic effect.
Assessment
Reproductive toxicity
Components:
vinyl acetate
Effects on fertility : Test Type: Two-generation study
Species: Rat
Sex: male and female
Application Route: Oral
NOAEL: 100 mg/kg,
F1: 100 mg/kg,
F2: 100 mg/kg,
GLP: yes
Effects on foetal : Species: Rat, females

development Application Route: Oral
477 mg/kg
GLP: yes
Species: Rat, females
Application Route: Inhalation
205 mg/kg
GLP: yes
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STOT - single exposure

Components:
vinyl acetate
Assessment: May cause respiratory irritation.
STOT - repeated exposure

Components:
Target Organs: Respiratory Tract, Liver
Assessment: Causes damage to organs through prolonged or repeated exposure.
Repeated dose toxicity

Components:
vinyl acetate
Species: Mouse, female
NOAEL: 281 mg/kg
Exposure time: 90-day
GLP: yes
Species: Mouse, male

NOAEL: 285 mg/kg
GLP: yes
Species: Rat, female

NOAEL: 810 mg/kg
GLP: yes
Species: Rat, male

NOAEL: 684 mg/kg
GLP: yes
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Aspiration toxicity
Product:
No aspiration toxicity classification
Further information
Product:
Remarks: No data available
SECTION 12: Ecological information
12.1 Toxicity
Components:
2-butoxyethanol
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 1.474 mg/l
Exposure time: 96 h
Test Type: static test
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.550 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 911

mg/l
End point: Growth inhibition
Exposure time: 72 h
Toxicity to fish (Chronic : NOEC: > 100 mg/l

toxicity) Exposure time: 21 d
Species: Danio rerio (zebra fish)
Test Type: semi-static test

Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
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Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): > 100

mg/l
Exposure time: 72 h
Toxicity to fish : LC50 (Danio rerio (zebra fish)): 318 mg/l
Exposure time: 96 h
GLP: yes
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
Method: Directive 67/548/EEC, Annex V, C.2.
GLP: yes
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l
Exposure time: 72 h
GLP: yes
NOEC (Desmodesmus subspicatus (green algae)): 25 mg/l

Exposure time: 72 h
GLP: yes
Toxicity to bacteria : EC50 (Pseudomonas putida): 622 mg/l

End point: Growth rate
Exposure time: 16 h
Test Type: Static
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Method: DIN 38 412 Part 8

GLP: yes
vinyl acetate
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 14 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 12,6 mg/l
Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (microalgae)): 12,7

mg/l
Exposure time: 72 h
GLP: yes
Toxicity to fish (Chronic : NOEC: 0,16 mg/l

toxicity) Exposure time: 34 d
Species: Pimephales promelas (fathead minnow)
Test Type: flow-through test
12.2 Persistence and degradability
Components:
2-butoxyethanol
Biodegradability : Result: Readily biodegradable.
Biodegradation: 90,4 %
Exposure time: 28 d
Method: OECD Test Guideline 301B

Biodegradability : Test Type: aerobic
Inoculum: Microbial inoculum
Result: Not readily biodegradable.
Biodegradation: 42,20 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Biodegradability : Test Type: aerobic
Inoculum: activated sludge
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Concentration: 30 mg/l
Result: Not readily biodegradable.
Biodegradation: 30 - 40 %
Method: OECD Test Guideline 301A
vinyl acetate
Biodegradability : Inoculum: activated sludge
Result: Readily biodegradable.
Biodegradation: 82 - 92 %
Exposure time: 14 d
Method: OECD Test Guideline 301C
12.3 Bioaccumulative potential
Components:
2-butoxyethanol
Partition coefficient: n- : log Pow: 0,83
octanol/water
Bioaccumulation : Remarks: No bioaccumulation is to be expected (log Pow <=
3).

octanol/water
vinyl acetate
Bioaccumulation : Bioconcentration factor (BCF): 3,16
Method: see user defined free text

octanol/water
12.4 Mobility in soil
Components:
Distribution among : Koc: 46,88
environmental compartments
12.5 Results of PBT and vPvB assessment
Components:
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Assessment : This substance is not considered to be persistent,

bioaccumulating and toxic (PBT).. This substance is not
considered to be very persistent and very bioaccumulating
(vPvB)..
12.6 Other adverse effects
Product:
Additional ecological : No data available
information
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14: Transport information
SECTION 14: Transport information
14.1 UN number
ADN: Not dangerous goods

ADR: Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: Not dangerous goods
INTERNATIONAL MARITIME DANGEROUS GOODS: Not dangerous goods
RID: Not dangerous goods
14.2 UN proper shipping name
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14.3 Transport hazard class(es)

14.4 Packing group

14.5 Environmental hazards
ADN: Not applicable

ADR: Not applicable
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: Not applicable
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: Not applicable
INTERNATIONAL MARITIME DANGEROUS GOODS: Not applicable
RID: Not applicable
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Ship Type: Not applicable

Hazard code(s): Not applicable
Pollutant Category: Not applicable
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Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate List of Substances of Very High : Not applicable
Concern for Authorisation (Article 59).
REACH - List of substances subject to authorisation : Not applicable

(Annex XIV)
REACH - Restrictions on the manufacture, placing on : vinyl acetate

the market and use of certain dangerous substances,
preparations and articles (Annex XVII)
Regulation (EC) No 850/2004 on persistent organic : Not applicable

pollutants
The components of this product are reported in the following inventories:

TSCA : Not On TSCA Inventory
DSL This product contains one or several components that are not
on the Canadian DSL and have annual quantity limits.
AICS Not in compliance with the inventory
ENCS Not in compliance with the inventory
KECI Not in compliance with the inventory
PICCS Not in compliance with the inventory
IECSC Not in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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15.2 Chemical safety assessment

No data available
SECTION 16: Other information

Further information
Revision Date: 11.03.2017
Classification procedure:
H302 Harmful if swallowed. On basis of test data.
H332 Harmful if inhaled. Calculation method
Full text of H-Statements

H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure if
inhaled.
H412 Harmful to aquatic life with long lasting effects.
Other information : The information accumulated herein is believed to be accurate

but is not warranted to be whether originating with the
company or not. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable
to their circumstances. This SDS has been prepared by
Ashland's Environmental Health and Safety Department (+31
10 497 5000).
Sources of key data used to compile the Safety Data Sheet

Ashland internal data including own and sponsored test reports
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The UNECE administers regional agreements implementing harmonised classification for labelling
(GHS) and transport.
List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data
sheet :
ACGIH : American Conference of Industrial Hygienists
BEI : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement : Hazard Statement
IATA : International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO : International Civil Aviation Organization
ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”
IMDG : International Maritime Code for Dangerous Goods
ISO : International Organization for Standardization
logPow : octanol-water partition coefficient
LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Development
OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT : Persistent , Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TLV : Threshold Limit Value
TWA : Time-weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL : Workplace Exposure Level
GAM : Water Hazard Class for the Netherlands

ADR : Agreement concerning the International Carriage of Dangerous Goods by Road.
ADNR: Regulation for the Carriage of Dangerous Substances on the Rhine
CLP : Classification, Labelling and Packaging
CSA : Chemical Safety Assessment
CSR : Chemical Safety Report
26 / 27
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828700
DNEL : Derived No Effect Level.

EINECS : European Inventory of Existing Commercial Chemical Substances.
ELINCS : European List of Notified Chemical Substances
GV: Exposure limits (DK)
PEC : Predicted Effect Concentration
PEL : Permissible Exposure Limits
PNEC : Predicted No Effect Concentration
REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals
RID : Regulation Concerning the International Transport of Dangerous Goods by Rail
WGK : German Water Hazard Class
27 / 27

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SAFETY DATA SHEET Revision Date: 11.03.2017

Conforms to EU Regulation 1907/2006/EC as amended. - SDSGHS_RW

1.1 Product identifier

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4 H332: Harmful if inhaled.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

SAFETY DATA SHEET Revision Date: 11.03.2017

Signal word : Warning

Hazard statements : H302 + H332 Harmful if swallowed or if inhaled

Supplemental Hazard : EUH066 Repeated exposure may cause skin

Precautionary statements : Prevention:

Hazardous components which must be listed on the label:

SECTION 3: Composition/information on ingredients

SAFETY DATA SHEET Revision Date: 11.03.2017

203-905-0 Acute Tox.4; H332 60,00

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

In case of skin contact : If on skin, rinse well with water.

SAFETY DATA SHEET Revision Date: 11.03.2017

If on clothes, remove clothes.

In case of eye contact : Flush eyes with water as a precaution.

If swallowed : Obtain medical attention.

Risks : Harmful if swallowed or if inhaled

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : High volume water jet

SAFETY DATA SHEET Revision Date: 11.03.2017

5.2 Special hazards arising from the substance or mixture

Hazardous combustion : carbon dioxide and carbon monoxide

5.3 Advice for firefighters

Specific extinguishing : Product is compatible with standard fire-fighting agents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

SAFETY DATA SHEET Revision Date: 11.03.2017

If the product contaminates rivers and lakes or drains inform

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

Other data : No decomposition if stored and applied as directed.

SAFETY DATA SHEET Revision Date: 11.03.2017

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

STEL 50 ppm GB EH40

vinyl acetate 108-05-4 STEL 10 ppm 2009/161/EU

SAFETY DATA SHEET Revision Date: 11.03.2017

Potential health effects: Long-term local effects

End Use: Workers

End Use: Consumers