Name : _________________ Pre Mid Term-1 (2021-22) Date - 27.07.

2016
Date: 27.10.2021
Retest Time: 2hrs
Roll No.: _______________ M.M.: 60Time: - 1hr
Class - XI
Subject: Chemistry
General instructions:
1. All questions are compulsory.
2. Q.no. 1 to 25 are multiple choice questions and carry 1 mark each.
3. Q.no. 26 to 40 are assertion-reason questions and carry 1 mark each.
4. Q.no. 41 to 50 are short answer questions and carry 2 mark each.

Choose the correct option:

Q1. How many atoms are contained in one mole of sucrose (C12H22O11)
a. 45 x 6.02 x 1023 atoms/mole b. 5 x 6.02 x 1023 atoms/mole
c. 15 x 6.02 x 1023 atoms/mole d. none of these
Q2 . The electronic configuration, 1s 2s 2p 3s 3p63d9 , represents a
2 2 6 2

a. Metal atom b. Non-metal atom

c. Non-metallic ion d. Metallic cation
Q3 . For a reaction A + 2B --------> C, the amount of C formed by starting the reaction with 5 moles of A
and 8 moles of B is
a. 5 moles b. 8 moles
c. 16 moles d. 4 moles
Q4 . A sample of pure compound is found to have Na = 0.087 mole, O = 0.132 mole, C = 2.65 x 1022
atoms. The empirical formula of the compound is :
a. Na2CO3 b. Na3O2C5
22
c. Na0.087O0.132C2.65x10 d. NaCO

Q5 . The number of radial nodes in 3s and 2p respectively are :

a. 2 and 0 b. 1 and 2
c. 0 and 2 d. 2 and 1
Q6 . If 30 mL of H2 and 20 mL of O2 react to form water, what is left at the end of reaction ?
a. 10 mL of H2 b. 5 mL of H2
c. 10 mL of O2 d. 5 mL of O2

Q7 . The orbital diagram in which the Aufbau principle is violated is

Q8 . The atom of smallest atomic radius among the following is :

a. Na b. K
c. Br d. Li
Q9 . In which of the following substances will hydrogen bond be strongest ?
a.HCl b. H2O
c. HI d. H2S
Q10 . Which of the following transitions involves maximum amount of energy?
a. M- (g) --------> M (g) b. M (g) --------> M- (g)
c. M+ (g) --------> M2+ (g) d. M2+ (g) --------> M3+ (g)
Q11 . The electronic configuration of two elements X and Y are given below
X = 1s2 2s2 2p6 3s2 3p64s2 ;
Y = 1s2 2s2 2p6 3s2 3p5
The formula of ionic compound that can be formed between these elements is
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 a. XY b. XY2
c. X2Y d. XY3
Q12 . The correct order of decreasing ionic radii among the following isoelectronic species is:
a. K+> Ca2+>Cl-> S2- b. Ca2+>K+>S2->Cl-
c. Cl->S2->Ca2+>K+ d. S2->Cl->K+>Ca2+

Q13 . Which of the following statements is not correct from the view point of molecular orbital theory ?
a. Be2 is not a stable molecule
b. He2 Be2 is not stable but He2+ is expected to exist
c. Bond strength of N2 is maximum amongst the homonuclear diatomic molecules belonging
to the second period
d. The order of energies of molecular orbitals in N2molecule is
σ2s < σ*2s <σ2pz< (π2pz=  π2py) < ( π*2px = π*2py) < σ*2pz
Q14 . Which of the following angle corresponds to sp2hybridisation ?
a. 900 b. 1200
0
c. 180 d. 1090
Q15 . Which of the following have been arranged in decreasing order of oxidation number of sulphur?
a. Na2S4O6> H2S2O7> Na2S2O3>S8
b. H2SO4> SO2> H2S > H2S2O8
c. SO2+> SO42-> SO32-> HSO4-
d. H2SO5>H2SO3>SCl2> H2S
Q16. Hydrogen resembles halogens in many respects for which several factors are responsible. Of the
following factors which one is most important in this respect ?
a. Its tendency to lose an electron to form a cation
b. Its tendency to gain an electron in its valence shell to attain stable electronic configuration
c. Its low negative electron gain enthalpy value
d. Its small size
Q17 . In NO3- ion, the number of bond pair and lone pair of electrons on nitrogen atom are
a. 2, 2 b. 3, 1
c. 1, 3 d. 4, 0
Q18 . The values of x and y in the following redox reaction,
xCl2 + 6OH- -------> ClO3- + yCl- + 3H2O are
a. x = 2, y = 4 b. x = 5, y = 3
c. x = 3, y = 5 d. x = 4, y = 2
Q19. In which of the following, functional group isomerism is not possible ?
a. Alcohols b. Aldehydes
c. Alkyl halides d. Cyanides
Q20 . Identify disproportionation reaction
a. CH4 + 2O2 ---------> CO2 + 2H2O
b. CH4 + 4Cl2 ----------> CCl4 + 4HCl
c. 2F2 + 2OH- ---------> 2F- +OF2 +H2O
d. 2NO2 + 2OH- ---------> NO2- +NO3- + H2O

Q21. Which of the following hydrides is electron precise hydride ?

a. B2H6 b. NH3
c.H2O d. CH4
Q22 . The IUPAC name of
a. 1,1-dimethyl-3-bromoethyl-5-chloropentane
b. 3-bromomethyl-1-chloro-5-methylhexane
c. 1-bromomethyl-1,2-chloroethyl-4-methylpentane
d. 4-bromomethyl-1-chloro-6-mrthylheptane

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Q23. The IUPAC name for
a. 1-hydroxypentane-1,4-dione
b. 1,4-dioxopentanol
c. 1-carboxybutan-3-one
d. 4-oxopentanoic acid

Q24 . In hexa-1,3-dien-5-yne, the number of C-C  σ ,C-C π, and C-H σ bonds respectively are
a. 5, 4 and 6 b. 6, 3 and 5
c. 5,3 and 6 d. 6,4 and 5

Q25 . The state of hybridization of C2, C3, C5 and C6 of the hydrocarbon, is in the sequence
a. sp3, sp2, sp2 and sp
b.sp, sp2, sp2and sp3
c. sp, sp2, sp3and sp2
d. sp,sp3,sp2and sp3

Directions (Q. Nos. 26-40) In the followed questions a statement of Assertion (A) is followed by
a statement of Reason (R). Mark the correct choice as.
a. Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of
Assertion (A)
b. Both Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of
Assertion (A)
c. Assertion (A) is true but Reason (R) is false
d. Both Assertion (A) and Reason (R) are false

Q26 . Assertion (A) : Molecular nitrogen is less reactive than molecular oxygen.
Reason (R) : The bond length of N2 is shorter than that of O2.
Q27 . Assertion (A) : Pent-1-ene and pent-2-ene are position isomers.
Reason (R) : Position isomers differ in the position of functional group or a substituent.
Q28 . Assertion (A) : Beryllium hydride is a covalent hydride.
Reason (R) : The electronegativity difference between Be and H is very high.
Q29 . Assertion (A) :A substance which gets reduced can act as an oxidizing agent.
Reason (R) : In the reaction, 3ClO- ---------> ClO3- + 2Cl-, Cl atom is oxidized as well as reduced.
Q30 . Assertion (A) : H2O on decomposition gives H2 and O2.
Reason (R) : All decomposition reactions are redox reactions.
Q31 . Assertion (A) :Some metals like platinum and palladium, can be used as storage media for
hydrogen.
Reason (R) : Platinum and palladium can absorb large volumes of hydrogen.

Q32 . Assertion (A) :LiCl is covalent whereas NaCl is ionic.

Reason (R) : Greater the size of the cation, greater is its polarizing power.
Q33 . Assertion (A) : Butane and 2-methylbutane are homologues.
Reason (R) :Butane is a straight chain alkane while 2-methylbutane is a branched chain alkane.
Q34 . Assertion (A) :H2, Li2 and B2 each has a bond order of 1 and hence are equally stable.
Reason (R) : Stability of molecule/molecular ion depends only on bond order.
Q35 . Assertion (A) : Sixth period is the longest period in the periodic table.
Reason (R) : Sixth period involves the filling of all the orbitals of sixth energy level.
Q36 . Assertion (A) : Fe3+ ion is more stable than Fe2+ ion.
Reason (R) : Fe3+ ion has more number of unpaired electrons than Fe2+ ion.
Q37 . Assertion (A) : Pure water obtained from different sources such as river, well, spring etc. always
contains hydrogen and oxygen in the ratio of 1 : 8 by mass.
Reason (R) : Total mass of reactants and products during chemical or physical change is always the
same.

Q38 . Assertion (A) :All H-like particles contain only one electron.
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 Reason (R) : The radii of corresponding orbitals in all H-like particles are equal.
Q39 . Assertion (A) :A single C12 atom has a mass exactly 12 amu and a mole of these atoms has a mass
of exactly 12 grams.
Reason (R) : A mole of an atom of any element has a mass in grams equal to its atomic mass.
Q40 . Assertion (A) :The first ionization energy of Be is greater than that of B.
Reason (R) : 2p-orbital is lower in energy than 2s-orbital.

Answer the following questions

Q41 . If the density of methanol is 0.793 kgL-1, what is its volume needed for making 2.5 L of its 0.25 M
solution ?
Q42 . Write structural formulae for compounds named as
a. 3-Bromo-3-chlorocyclohex-1-ene
b. 5-Bromoheptanone
Q43 . Write down the quantum numbers n, l and m for the following orbitals:
a. 3dxy b. 4dz2
c. 2py d. 3dyz
Q44 . What do you understand by (give two examples of each)
a. metallic hydrides
b. ionic hydrides
Q45 . A golf ball has a mass of 40 g and a speed of 45 m/s. If the speed can be measured within accuracy
of 2%, calculate the uncertainty in position.
Q46 . Give reasons
a. H2O is amphoteric in nature
b. Density of Ice is less than water.
Q47 . Draw M.O.energy level diagram of N2, and show its electronic configuration, bond order and
magnetic behavior.
Q48. Explain why
a. Ionisation enthalpy decreases across group.
b. Atomic radii decreases across period.
Q49 . Balance the following equation in basic medium by oxidation number method:
MnO4-(aq) + I-(aq) ---------> MnO2 (s) + I2(s)
Q50 . Draw the resonance structures for the following:
a. C6H5OH b. C6H5NO2

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