JEE-Chemistry EXERCISE -A Le AL400 K, the root mean square (rms) speed of a gas X (molecular weig! 10) is equal to the most probable speed of gas Y at 60 K. The molecular weight of the gasY is [JEE 2009] (Vane) y = _(Vnrs)y BR oe {88 2. Toanevacuated vessel with movable piston under external pressure of I atm., 0.1 mol of He and 1,0 mole of an unknown compound (vapour pressure 0.68 atm, at 0°C) are introduced. Considering the ideal gas behaviour, the total volume (in litre) ofthe gases at 0°C is close to [EE 2011] «@ fe seh Phe + Piaf = tabn Pus 0.32 atm Pyv= ORT 0-32 KVe 0-[KO-08 21 2433 The atomic masses of He and Ne are 4 and 20 a.m.u. respectively. The value of the de Broglie wavelength of He gas at ~73 °C is "M" times that of the de Broglie wavelength of Ne at 727°C. Mis (EE 2013] as]Paragraph for Question 4 & § X and Y are two volatile iguds with molar weighs of 1g mo and 0g mol" respectively “Two coon plugs. one soaked in X and the oer soaked iY re simultaneously placed atthe ‘ends of tbe of lngth L.= 26cm, as shown in the fgus. The ee is ile wih an inert a8 4 amospee pressure and temperature of 300K, Napouts of X and Y react to form a product ‘which sist observed at a distance dem rom the plog soaked in X. Take X apd to ave equal molecule dames and assume del haviour fr the ioe 8 and he two vapours. luee 2014) con Shen embed x Iatedfomnonor Sen omer 4. The ale dine (own in te Sig), eins from Cea ws Hy erie 20 fm —© ty = Pry = |yo_ 9 x y Vv Mx 1° Ays 2% d 2 Bd=4g Ru-4d [d= teem S. _Theexperimental value of dis found to be smaller than the estimate obtained using Graham's law. ‘This is due to - (A) Larger mean free path for X as compared to that of Y 7 (B) Larger mean free path for Y as compared to that of X — (C) Increased collision frequency of Y with the inert gas as compared to that of X with the inert gas (D) Increased collision frequency of X with the inert gas as compared to that of Y with the inert gas - Colliav'o th ht go ak__tvavele fest than expected value.6. The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed. The absolute temperature of an ideal gas is increased 4 times and its pressure is increased 2 times. AS ‘a result, the diffusion coeflicient of this gas increases x times. The value of x is [JEE 2016] fm diffusion coefficient 9 Uneg We Know, Uavgs | &&r mm = x Jin N* diffurion coefficient of T (kK) Pe 3 New, Ka = Th (3) Ky PS Bz ah = p, aig i CH) Ser ee abr7. Which ofthe following statements) is (re) correct regarding the root mean square ped anu average transatonal kinetic enerpy 6) of molecule in a gas a equilibrium (EE 2019) AA) Ung, is doubled when its temperature is increased four times ABT e,, al a given temperature does not depend on its molecular mass 4eT,,, is inversely proportional to the square root of its molecular mass joubled when its temperature is increased four times Usme = [SRT 2 Dame «ST IA (A) TY timer Drm = 2 tng Gorvect (®) Fay 3 keT Cin dependenpor Mat) — Corruar = " © Deng 4 & Orwet © Ea x T Tyone8. Ifthe distribution of molecular speeds ofa gas is as per the figure shown below, then the ratio ofthe most probable, the average, and the root mean square speeds, respectively, is LEE 2020) Unos Fraction of molecules Speed (teh BFL: 11.224 (©1128: 1.224 (D) 1112821