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06-09-2018

MEL G611 :
IC FABRICATION TECHNOLOGY
Section V: Lithography
Thu, 30 Aug; Sat, 1 Sept; Tue, 4 Sept;
BITS Pilani Thu, 6 Sept
Hyderabad Campus
Sanket Goel, EEE

Sec IV, L 8-11: Oxidation


• Sat, 18 Aug; Thu, 23 Aug; Sat, 25 Aug; Tues, 28 Aug;

• Learning Objectives
o To understand the Oxidation process during the IC
Fabrication

• Topics covered –
o Oxidation growth mechanisms
o Various techniques
o Properties
o Defects

MEL G611 : IC FABRICATION TECHNOLOGY 2 BITS Pilani, Hyderabad Campus

1
06-09-2018

Sec V, L 12-14: Lithography


• Thu, 30 Aug; Sat, 1 Sept; Tue, 4 Sept; Thu, 6 Sept

• Learning Objectives
o Learn how to print the patterns on the wafer using
optical exposure systems

• Topics to be covered –
o Optical Lithography
o Electron Lithography
o X-ray Lithography
o Ion Lithography

MEL G611 : IC FABRICATION TECHNOLOGY 3 BITS Pilani, Hyderabad Campus

Lithography
• Litho ⇒ Stone
• Graphy ⇒ Writing

Photolithography: Need photoresist, Mask, and UV light; allowed for >


0.1 µm technology node

e-beam lithography: Need e-beam and e-beam resist; No mask ; sub


10 nm or smaller dimension technology node

X-ray lithography: Same as optical lithography, but instead of UV used


X-ray beam; wavelength is very small, less than 1 nm!!

Ion-beam lithography: scanning a focused beam of ions in a patterned


fashion across a surface to create very small structures such as IC or
other nanostructures.
MEL G611 : IC FABRICATION TECHNOLOGY 4 BITS Pilani, Hyderabad Campus

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06-09-2018

Lithography Requirements

MEL G611 : IC FABRICATION TECHNOLOGY 5 BITS Pilani, Hyderabad Campus

BITS Pilani
Hyderabad Campus

Photolithography

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06-09-2018

Photolithography
• Photo ⇒ Light
• Litho ⇒ Stone
• Graphy ⇒ Writing

• A light sensitive photoresist is spun onto the wafer and coat the
silicon wafer
• The resistive is selectively exposed by shining light through a
mask
• Then developed the mask pattern, and Finally, etched
out the selectively area

MEL G611 : IC FABRICATION TECHNOLOGY 7 BITS Pilani, Hyderabad Campus

Photolithography
• Creation of 3D structures using photographic techniques
• Derived from creation of printing plates
• Usually start with thin film on wafer (eg SiO2)
• Coat with photosensitive material (photoresist)
• Exposure: to UV Light through mask of structure
• Development of resist: leaves pattern of resist with openings
• Etching: removes film unprotected by resist
• Striping Resist: leave only patterned film

MEL G611 : IC FABRICATION TECHNOLOGY 8 BITS Pilani, Hyderabad Campus

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06-09-2018

Photolithography (1)

MEL G611 : IC FABRICATION TECHNOLOGY 9 BITS Pilani, Hyderabad Campus

Photolithography (2)

MEL G611 : IC FABRICATION TECHNOLOGY 10 BITS Pilani, Hyderabad Campus

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06-09-2018

Photolithography - Process
Design ⇒ Mask ⇒ Wafer

MEL G611 : IC FABRICATION TECHNOLOGY 11 BITS Pilani, Hyderabad Campus

Photolithography - Components
• Mask
• Photoresist
• Exposure System
• Chemicals
• Thickness control
• Temperature control

MEL G611 : IC FABRICATION TECHNOLOGY 12 BITS Pilani, Hyderabad Campus

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06-09-2018

Photomask
• An opaque plate with
holes or transparencies
that allow light to shine
through in a defined
pattern.
• Plate  quartz glass
• Black lines on glass 
chrome
• Design is created and
transferred using a
pattern generator

MEL G611 : IC FABRICATION TECHNOLOGY 13 BITS Pilani, Hyderabad Campus

Photomask (Cost)
Low Reflective Chrome (info) on Print Grade Soda Lime (S/L) Glass or
Quartz (spec's)

http://www.photoplotstore.com/pages/photomasks.html

MEL G611 : IC FABRICATION TECHNOLOGY 14 BITS Pilani, Hyderabad Campus

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06-09-2018

Photolithography - Mask
• Light field Mask: "islands" of lines in
clear field
• Dark field Mask: "holes" in mostly dark
area
Mask
• Type of resist determines mask type
polarity

Photomasking

Mask & Photomasking Polarity result


MEL G611 : IC FABRICATION TECHNOLOGY 15 BITS Pilani, Hyderabad Campus

Photolithography - Resist
Feature Positive Negative
Design on Mask Same as Mask Opposite to Mask

Resist after exposure Stays Goes

Shows/goes rule Goes Doesn’t go

MEL G611 : IC FABRICATION TECHNOLOGY 16 BITS Pilani, Hyderabad Campus

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06-09-2018

Photolithography - Resist
• Positive: Exposure to UV light removes resist
• Negative: Exposure to UV light maintains resist

Mask

Positive Resist Negative Resist


MEL G611 : IC FABRICATION TECHNOLOGY 17 BITS Pilani, Hyderabad Campus

Photolithography - Resist

Characteristic Positive Negative


Adhesion to Silicon Fair Excellent
Relative Cost More Expensive Less Expensive
Developer Base Aqueous Organic
Minimum Feature 0.5 μm and below ± 2 μm
Step Coverage Better Lower
Wet Chemical
Fair Excellent
Resistance

MEL G611 : IC FABRICATION TECHNOLOGY 18 BITS Pilani, Hyderabad Campus

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06-09-2018

Relative Advantages of Resist


type
• Positive resists used in almost all processes now
• Positive resist has much higher resolution
• Resist is constantly changing: altered to fit the wavelength used
• Negative resists only used in specialized processes

MEL G611 : IC FABRICATION TECHNOLOGY 19 BITS Pilani, Hyderabad Campus

Lithography Steps

• Wafer clean
• Pre-bake and primer coating
• Photoresist spin coating PR coating
Track- • Soft bake
stepper • Alignment and exposure
integrate • Post exposure bake
d system • Development
• Hard bake Development
• Pattern inspection

MEL G611 : IC FABRICATION TECHNOLOGY 20 BITS Pilani, Hyderabad Campus

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06-09-2018

Lithography : Relative
Thickness

• Thickness function of resist type, viscosity, spin


speed
• Viscosity controlled by fraction of solids in resist
• Higher spin speed more centripetal force vs gravity
• Higher viscosity harder to throw off resist

MEL G611 : IC FABRICATION TECHNOLOGY 21 BITS Pilani, Hyderabad Campus

Lithography : Prebake &


Primer
Prebake
• Dehydration bake at ~1000C
• Remove moisture from wafer surface
• Promote adhesion between PR and surface
• Integration wit primer coating

Primer
• Promotes adhesion of PR to wafer surface
• Widely used: Hexamethyldisilazane (HMDS)
• HMDS vapor coating prior to PR spin coating
• Usually performed in-situ with pre-bake
• Chill plate to cool down wafer before PR coating
MEL G611 : IC FABRICATION TECHNOLOGY 22 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Wafer Cooling & Coating


• Wafer needs to cool down
• Water-cooled chill plate
• Temperature can affect PR viscosity  Affect PR spin
coating thickness

Primer
• Undoped-
Silicate-
Glass-(USG) Photoresist
• STI – Shallow
Trench Polysilicon
Isolation STI USG

P-Well
MEL G611 : IC FABRICATION TECHNOLOGY 23 BITS Pilani, Hyderabad Campus

Litho: Spin Coating -


background
• Wafer sit on a vacuum chuck
• Slow spin ~ 500 rpm
• Liquid photoresist applied at center of wafer
• Ramp up to ~ 3000 - 7000 rpm
• Photoresist spread by centrifugal force
• Evenly coat on wafer surface
Automated Spin Coater
• Wafer Coater/Developers cost
$0.3-1 Million
• Same wafer track design used for
coat or development
• Problem – if not used often resist
lines clog
MEL G611 : IC FABRICATION TECHNOLOGY 24 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Spin Coating

Photoresist Applying

PR dispenser
nozzle

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 25 BITS Pilani, Hyderabad Campus

Litho: Spin Coating

Photoresist Suck Back

PR dispenser nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 26 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 27 BITS Pilani, Hyderabad Campus

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 28 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 29 BITS Pilani, Hyderabad Campus

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 30 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 31 BITS Pilani, Hyderabad Campus

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 32 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Spin Coating

Photoresist Spin Coating


PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 33 BITS Pilani, Hyderabad Campus

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 34 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Spin Coating

Photoresist Spin Coating

PR dispenser
nozzle
PR suck back

Wafer

Chuck
Spindle

To vacuum pump

MEL G611 : IC FABRICATION TECHNOLOGY 35 BITS Pilani, Hyderabad Campus

Litho: Soft bake

Ready For Soft Bake

Wafer

Chuck
Spindle

To vacuum
pump

MEL G611 : IC FABRICATION TECHNOLOGY 36 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Analysis
Relationship of PhotoresistThickness to Spin Rate and Viscosity

3.5
100 cst
3.0
50 cst
2.5
Thickness (mm)

2.0
27 cst
20 cst
1.5

1.0 10 cst

5 cst
0.5

0
2k 3k 4k 5k 6k 7k
Spin Rate (rpm)

MEL G611 : IC FABRICATION TECHNOLOGY 37 BITS Pilani, Hyderabad Campus

Litho: Exposure

Viscosity

• Fluids stick on the solid surface


• Affect PR thickness in spin coating
• Related to PR type and temperature
• Need high spin rate for uniform coating

MEL G611 : IC FABRICATION TECHNOLOGY 38 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Exposure
• Need to cool down to ambient temperature
• For 8 inch (200 mm) wafer, 1 C change causes 0.5 mm
difference in diameter
• Wafers exposed within 2-3 days of soft bake otherwise strip and
recoat
• Several exposure systems: simplest mask aligner
• Wafers placed in mask aligner, moved under mask
• Mask very close to resist (possibly in contact with resist)
• Contact may cause resist to stick to mask  mask needs to be
cleaned
• But separation needs to be close otherwise shadow spreads
• Exposure to UV: mask blocks light to desired areas

MEL G611 : IC FABRICATION TECHNOLOGY 39 BITS Pilani, Hyderabad Campus

Diffraction

Place wave in
free space Light passing through Place wave through
a narrow aperture an aperture

Diameter of
central maximum

Image intensity of circular aperture Small aperture being imaged


MEL G611 : IC FABRICATION TECHNOLOGY 40 BITS Pilani, Hyderabad Campus

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06-09-2018

Diffraction

Image intensity of circular aperture Small aperture being imaged

Two types of Diffractions:


1. Fraunhofer Diffraction: far-field diffraction
2. Fresnel Diffraction: near field diffraction

MEL G611 : IC FABRICATION TECHNOLOGY 41 BITS Pilani, Hyderabad Campus

Methods of Wafer Exposure

Provides high resolution and low


Capable of high Cannot easily
defect densities and dominates today.
resolution but has print features
Typical projection systems use
unacceptable defect below a few
reduction optics (2X - 5X), step and
densities. µm
repeat or step and scan mechanical
systems, print ≈ 50 wafers/hour and
cost $5 - 10M

MEL G611 : IC FABRICATION TECHNOLOGY 42 BITS Pilani, Hyderabad Campus

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06-09-2018

Fraunhofer Diffraction
Resolution

0.6 < K1 < 0.8

Depth of Focus

k2 depends on resist

MEL G611 : IC FABRICATION TECHNOLOGY 43 BITS Pilani, Hyderabad Campus

Problem

MEL G611 : IC FABRICATION TECHNOLOGY 44 BITS Pilani, Hyderabad Campus

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06-09-2018

Fresnel Diffraction

W  mask feature size

Minimum resolvable
feature size

• A proximity exposure system operating with 10 µm gap and a


365 nm light source can resolve features < 2 µm
• Much smaller than used in IC chips
• These systems are not useful for manufacturing these chips
• However much less expensive than projection system
• For applications where feature size are compatible with them,
proximity printers are an economical solution
MEL G611 : IC FABRICATION TECHNOLOGY 45 BITS Pilani, Hyderabad Campus

Litho: UV Source
• Current aligner UV source mercury
vapour lamp
• Exposure time set by light intensity, resist
type and thickness, reflectivity of layer
below

• 436 nm ("g-line")
• 405 nm ("h-line")
• 365 nm ("i-line")

MEL G611 : IC FABRICATION TECHNOLOGY 46 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Exposure
Gate Mask

Photoresist

Polysilicon

STI USG

P-Well

MEL G611 : IC FABRICATION TECHNOLOGY 47 BITS Pilani, Hyderabad Campus

Litho: Exposure

Gate Mask

Photoresist

Polysilicon

STI USG

P-Well
MEL G611 : IC FABRICATION TECHNOLOGY 48 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Exposure

Ready for Post Exposure Bake

Photoresist
Polysilicon
STI USG
P-Well

MEL G611 : IC FABRICATION TECHNOLOGY 49 BITS Pilani, Hyderabad Campus

Litho: Exposure (caution)


Alignment of Layers
• Must get new mask aligned with devices
on after
• Use two objectives with large separation
• Structures aligned in both fields
• This prevents rotational errors

Alignment marks on the mask


MEL G611 : IC FABRICATION TECHNOLOGY 50 BITS Pilani, Hyderabad Campus

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06-09-2018

Resist Type
Contrast Q0  dose when exposure begins
Qf  dose when exposure ends

MEL G611 : IC FABRICATION TECHNOLOGY 51 BITS Pilani, Hyderabad Campus

Problem
To be developed properly, a 10 mm photoresist requires an
energy density of 100 mJ/cm2/ mm. If a UV source provides
a power density of 1000 W/m2, how long do you need to
expose the wafer with this photoresist?

MEL G611 : IC FABRICATION TECHNOLOGY 52 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Post Exposure Bake


• PEB normally uses hot plate at 110 to 130 C for about
1 minute.
• For the same kind of PR, PEB usually requires a higher
temperature than soft bake.
• Insufficient PEB will not completely eliminate the
standing wave pattern,
• Over-baking will cause polymerization and affects
photoresist development

MEL G611 : IC FABRICATION TECHNOLOGY 53 BITS Pilani, Hyderabad Campus

Litho: Post Exposure Bake

Purpose of Post Exposure Bake

• Baking temperature higher than the Photoresist glass


transition temperature Tg
• Thermal movement of photoresist molecules
• Rearrangement of the overexposed and underexposed
PR molecules
• Average out standing wave effect,
• Smooth PR sidewall and improve resolution

MEL G611 : IC FABRICATION TECHNOLOGY 54 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Development

PR
Polysilicon
STI USG
P-Well

MEL G611 : IC FABRICATION TECHNOLOGY 55 BITS Pilani, Hyderabad Campus

Litho: Development

Development: Immersion

Develop Rinse Spin Dry

MEL G611 : IC FABRICATION TECHNOLOGY 56 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Development

Applying Development Solution

Exposed Development solution


Photoresist dispenser nozzle
Wafer

Chuck
Spindle

To vacuum
pump
MEL G611 : IC FABRICATION TECHNOLOGY 57 BITS Pilani, Hyderabad Campus

Litho: Development

Applying Development Solution

Exposed
Photoresist
Wafer

Chuck
Spindle

To vacuum
pump

MEL G611 : IC FABRICATION TECHNOLOGY 58 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Development

Developer Spin Off

Edge PR Patterned
removed photoresist
Wafer

Chuck
Spindle

To vacuum
pump

MEL G611 : IC FABRICATION TECHNOLOGY 59 BITS Pilani, Hyderabad Campus

Litho: Development

DI Water Rinse

DI water
dispenser
nozzle
Wafer

Chuck
Spindle

To vacuum
pump

MEL G611 : IC FABRICATION TECHNOLOGY 60 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Development

Spin Dry

Wafer

Chuck
Spindle

To vacuum
pump

MEL G611 : IC FABRICATION TECHNOLOGY 61 BITS Pilani, Hyderabad Campus

Litho: Development

Ready For Hard Bake

Wafer

Chuck
Spindle

MEL G611 : IC FABRICATION TECHNOLOGY 62 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Development

Mask

PR PR
Film Film
Substrate Substrate
PR Coating Exposure

PR PR
Film Film
Substrate Substrate
Etching Development

MEL G611 : IC FABRICATION TECHNOLOGY 63 BITS Pilani, Hyderabad Campus

Litho: Development

PR PR

Substrate Substrate
Normal Incomplete
Development Development
PR PR

Substrate Substrate

Under Development Over Development

MEL G611 : IC FABRICATION TECHNOLOGY 64 BITS Pilani, Hyderabad Campus

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06-09-2018

Litho: Hard Bake

• Evaporating all solvents in PR


• Improving etch and implantation resistance
• Improve PR adhesion with surface
• Polymerize and stabilize photoresist
• PR flow to fill pinhole

PR
Polysilicon
STI USG
P-Well

MEL G611 : IC FABRICATION TECHNOLOGY 65 BITS Pilani, Hyderabad Campus

Wafer Inspection
• Surface irregularities - scratches, pin
holes, stains, contamination, etc.
• Critical dimension (CD)
• Overlay or alignment
– run-out, run-in, reticle rotation, wafer
rotation, misplacement in X-direction,
and misplacement in Y-direction
•Fail inspection, stripped PR and
rework
- Photoresist pattern is temporary
-Etch or ion implantation pattern is
permanent.
• Scanning electron microscope (SEM)
• Optical microscope

MEL G611 : IC FABRICATION TECHNOLOGY 66 BITS Pilani, Hyderabad Campus

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06-09-2018

BITS Pilani
Hyderabad Campus

Direct Laser Writing

Direct Writing
• Direct writing with a narrow beam of charged particles or
photons uses a “software” mask or Grey-tone mask
• Software-based techniques
o Laser lithography
o Greyscale Lithography
o Electron-beam (e-beam) lithography
• E-beam lithography  electron dosage is given by the
product of current and dwell time and is varied across the
resist surface.
• Laser lithography --> pixel-by-pixel UV-laser scanning to
fabricate spherical and aspherical lenses in a positive
photoresist

MEL G611 : IC FABRICATION TECHNOLOGY 68 BITS Pilani, Hyderabad Campus

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06-09-2018

Laser Writing – Basics


-Norland Optical Adhesive (NOA)
- Refractive index ~1.5
- Used as –ve PR
- Can be cured by UV

- A He-Cd UV laser (325 nm from LiCONIX) is used to write


microchannel walls in spun-on NOA on glass substrates.

- The uncured adhesive is washed away

MEL G611 : IC FABRICATION TECHNOLOGY 69 BITS Pilani, Hyderabad Campus

Laser Writing – Schematic

MEL G611 : IC FABRICATION TECHNOLOGY 70 BITS Pilani, Hyderabad Campus

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06-09-2018

Laser Writing – Calculations

If the total energy required to cure NOA is 4.5 joule/cm2 then,

‘W’ is the laser output power


‘D’ is the diameter of laser spot
‘v’ motor speed

For a spot size of 0.1 mm and output power of 0.1 mW, the
motor speed is approximately 0.1 mm/sec.
MEL G611 : IC FABRICATION TECHNOLOGY 71 BITS Pilani, Hyderabad Campus

Laser Writing – Program

MEL G611 : IC FABRICATION TECHNOLOGY 72 BITS Pilani, Hyderabad Campus

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06-09-2018

Laser Writing – Device

100
mm

Laser-written channel master using Norland optical adhesive


Width = 150 µm, Depth = 60 µm

MEL G611 : IC FABRICATION TECHNOLOGY 73 BITS Pilani, Hyderabad Campus


73

Laser Writing – Device (ii)

MEL G611 : IC FABRICATION TECHNOLOGY 74 BITS Pilani, Hyderabad Campus

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06-09-2018

Laser Writing – Device app

• NOA (index of refraction =1.58) works as waveguide core and


walls for the microchannel.
• The chip can be capped by thin microscopic slide –cover
MEL G611 : IC FABRICATION TECHNOLOGY 75 BITS Pilani, Hyderabad Campus

Example- SU8 Biochip (Concept)

Microchannel

Output
Waveguide
Input waveguide
with air cladding

• Grooves in SU-8 (refractive index = 1.59) define air claddings


for waveguides and microchannels for fluids (left)
• Structure is capped with PDMS
MEL G611 : IC FABRICATION TECHNOLOGY 76 BITS Pilani, Hyderabad Campus

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06-09-2018

Example- SU8 Biochip (Concept)

Microchannel

Output
Waveguide
Input waveguide
with air cladding

• Grooves in SU-8 (refractive index = 1.59) define air claddings


for waveguides and microchannels for fluids (left)

• Structure is capped with PDMS


MEL G611 : IC FABRICATION TECHNOLOGY 77 BITS Pilani, Hyderabad Campus

SU8 Biochip (Fabrication)

UV
Mask
SU-8
Glass Substrate

Glass Substrate

• Spin-coat 50 mm of SU-8 on glass substrates and pre-bake


• Pattern using standard lithography
• UV-exposed SU-8 is cross-linked, unexposed part is developed
away
MEL G611 : IC FABRICATION TECHNOLOGY 78 BITS Pilani, Hyderabad Campus

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06-09-2018

SU8 Biochip (Fabrication)

Y-shaped and T-shaped


microchannel –
For detecting and separating
different particle types

Split waveguides-
For combining light of different
wavelengths for particle
sorting experiments

Chip C-
To observe continuous
Electroosmotic flow.

MEL G611 : IC FABRICATION TECHNOLOGY 79 BITS Pilani, Hyderabad Campus

SU8 Biochip (Fabrication)


Split waveguides-
For combining light of different wavelengths for particle sorting
experiments

MEL G611 : IC FABRICATION TECHNOLOGY 80 BITS Pilani, Hyderabad Campus

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06-09-2018

SU8 Biochip- Optical Microscope


Split waveguides for combining light of different wavelengths for
particle sorting experiments.

Different points in the microchannel

MEL G611 : IC FABRICATION TECHNOLOGY 81 BITS Pilani, Hyderabad Campus

SU8 Biochip- App

PMT 1
Laser
PMT 2

Flow by pressure-driven flow

MEL G611 : IC FABRICATION TECHNOLOGY 82 BITS Pilani, Hyderabad Campus

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06-09-2018

SU8 Biochip- App


300 mm

Video showing the flowing microparticles at one waveguide-


microchannel intersection
Flow by pressure-driven flow
MEL G611 : IC FABRICATION TECHNOLOGY 83 BITS Pilani, Hyderabad Campus

SU8 Biochip- App


Labview screenshot showing 6 microparticles passing by the
intersection

MEL G611 : IC FABRICATION TECHNOLOGY 84 BITS Pilani, Hyderabad Campus

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06-09-2018

SU8 Biochip- App

3500

3000
Time
k

2500 Peak between Vel


Particle number # peaks (s) (mm/s)
2000
PMT Signal (mV)

1 2 3 4 5 6
1 1.43 209.79
1500

2 1.2 250.00
1000

500
3 1.37 218.98

0
4 1.74 172.41
68 73 78 83 88 93 98
Time (sec) 5 1.78 168.54

6 1.75 171.43

MEL G611 : IC FABRICATION TECHNOLOGY 85 BITS Pilani, Hyderabad Campus

BITS Pilani
Hyderabad Campus

Grayscale Lithography

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06-09-2018

Grayscale Lithography
• Normal photolithography 
o a binary image transfer process
o developed pattern consists of regions with resist (1) and
regions without resist (0).
• Grayscale lithography 
o partial exposure of a photoresist renders it soluble to a
developer in proportion to the local exposure dose
o consequence, after development, the resist exhibits a
surface relief.
• Gray-tone masks (GTMs) (physical / software based) 
o lets varying amounts of light pass through
o micromachines with varying topography

MEL G611 : IC FABRICATION TECHNOLOGY 87 BITS Pilani, Hyderabad Campus

Conventional vs Grayscale
Lithography
Normal mask Grayscale
• Low exposure dose  mask
cross-linking acid in the
regions closer to the light
source.
• Stronger exposure doses
 penetrate further and
induce cross-linking in the
photoresist further away
from the light source.
• Partial exposure  renders it soluble to a developer in
proportion to the local exposure dose and as a consequence,
after development, the resist exhibits a surface relief or 3D
topography
MEL G611 : IC FABRICATION TECHNOLOGY 88 BITS Pilani, Hyderabad Campus

44
06-09-2018

Conventional vs Grayscale
Lithography Same Mask is used

MEL G611 : IC FABRICATION TECHNOLOGY 89 BITS Pilani, Hyderabad Campus

Grayscale Lithography
• Smart filter with a
several micro-mirrors
contained in a
rectangular array, to
render patterns from
software masks.

• Micro-mirror corresponds to a pixel of image to be transferred to substrate


and is individually addressable

• Micro-mirror ON position can reflect light coming from the light source onto
the photoresist and transfers a bright pixel.
• Micro-mirror in the OFF position directs the light elsewhere and a dark pixel
is seen by the photoresist.
• Grayscale images are obtained by toggling the mirrors between ON and
OFF states rapidly (typically 20 μs) and the ratio of ON time to OFF time
determines the shade produced.
MEL G611 : IC FABRICATION TECHNOLOGY 90 BITS Pilani, Hyderabad Campus

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06-09-2018

GSL – Software Mask Design


• Design  any graphics drawing software including MS Paint
• Check pixel  ? area on PR
• Exposure light intensity  RGB code of the color
• Grayscale is implemented (set RGB between 0 and 255)
o Higher RGB  lighter shade (closer to white)
o Lower RGB  darker shade (closer to black)
• Software mask design assigns proper grayscale values to the
appropriate regions of the image based on PR type (+/-)
• For –ve PR (SU-8)
o Regions where less thickness is required were assigned a
lower grayscale value, i.e., a dark shade
o Regions of high thickness were assigned a high grayscale
value, i.e., a lighter shade.

MEL G611 : IC FABRICATION TECHNOLOGY 91 BITS Pilani, Hyderabad Campus

GSL – Processes

1. Substrates and spin coating


2. Soft baking and post exposure baking
3. Exposure
4. Developing
5. Pattern characterization
6. characterization

MEL G611 : IC FABRICATION TECHNOLOGY 92 BITS Pilani, Hyderabad Campus

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06-09-2018

GSL – Characterization

• Power density increases proportional to the RGB value.


• Pattern height is expected to increase with the RGB grayscale
value.
MEL G611 : IC FABRICATION TECHNOLOGY 93 BITS Pilani, Hyderabad Campus

GSL – Characterization

• SU-8 structure is characterized using optical profilometry as


well as SEM.
• Structure is also symmetrical on both the x- and y-axis as
shown in
MEL G611 : IC FABRICATION TECHNOLOGY 94 BITS Pilani, Hyderabad Campus

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06-09-2018

GSL – Characterization:
Exposure Time

400 s exposure
time 800 s exposure
time

• Exposure time increases


o Sufficient exposure energy to
polymerize the SU-8 film even at 1200 s
low RGB value areas (dark exposure
shades). time
o Sharp needles to cones to
truncated to mesas.
MEL G611 : IC FABRICATION TECHNOLOGY 95 BITS Pilani, Hyderabad Campus

GSL – Application: Bridges and


Cantilevers
• Suspended bridges
at different grayscale
values from 130 (A)
to 230 (D).
• Cantilevers of
different lengths at
grayscale 130 and 15
μm width and
• Cantilevers of
different lengths at
grayscale 130 and 45
μm width.

MEL G611 : IC FABRICATION TECHNOLOGY 96 BITS Pilani, Hyderabad Campus

48
06-09-2018

GSL – Application: Micromixers

Two ports Embedded Embedded


connected by a microchannel with microchannel with
microchannel alternating obstructions
alternating ridges
Mask used

SEM images

MEL G611 : IC FABRICATION TECHNOLOGY 97 BITS Pilani, Hyderabad Campus

BITS Pilani
Hyderabad Campus

Electron Beam Lithography (EBL)

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06-09-2018

EBL: Introduction
• Conventional Photolithography is limited by the wavelength of light
E  1/
• Higher E can cause unwanted side effects
• Solution?
• Use electrons instead of light
• E-beam lithography

• Used for making mask and reticles


• Smallest geometry achieved: 14 nm
• Direct print possible, no mask is required
– Low throughput
• Scattering exposure system (SCALPEL) looks promising
– Tool development
– Reticle making
– Resist development

MEL G611 : IC FABRICATION TECHNOLOGY 99 BITS Pilani, Hyderabad Campus

EBL: Mechanism
To “shoot” a beam of electrons in a
Electron Gun
direction
•The emitter is heated to produce and
excite electrons on the surface.
Lens • When a high voltage is applied, the
excited electrons accelerate towards a
Blanking Plate structure called the anode.
•By varying this voltage, the trajectory
Lens and the focus of the beam can be
manipulated

Stigmator
Optics  to focus the electrons into a
concentrated beam in a desired direction.
Deflection
•Two parallel plates inside the column
Coils
Lens can be electrostatically charged to a
precise degree
•The resulting electric field is able to bend
Wafer
the beam in a desired direction.

MEL G611 : IC FABRICATION TECHNOLOGY 100 BITS Pilani, Hyderabad Campus

50
06-09-2018

EBL: Methods
When the beam hits the surface,
either an additive or subtractive
reaction takes place.
Additive writing method
uses the electrons to induce a
deposition of a compound on the
surface.
Subtractive writing method
• uses the e-beam to remove the
sections of the resist and surface.
• common in creating masks for
other lithographic techniques

MEL G611 : IC FABRICATION TECHNOLOGY 101 BITS Pilani, Hyderabad Campus

EBL: Scanning
Raster Scan: The e-beam is swept across entire
surface, pixel by pixel, with the beam being
turned on and off according to desired pattern.
• Easy to design and calibrate
• Time consuming [because the beam is scanned
across the entire surface]

Vector Scan: The e-beam “jumps” from one


patterned area to the next, skipping unwanted
areas.
• Much faster
• Beam adjustments easy
• It takes longer for the beam to settle  more
difficult to maintain accurate placing for the
beam.
MEL G611 : IC FABRICATION TECHNOLOGY 102 BITS Pilani, Hyderabad Campus

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06-09-2018

EBL” Challenges
Electron Backscattering
- Direct electron bombardment on the surface Quick scattering
- Unwanted reactions outside of the focused e-beam
- E-beam resolution is not limited to only the size of the beam
Proximity Effect
- Focused e-beam can produce Secondary electrons (SEs)
- SEs expose the resist several mms away from exposure point
- Critical variations on surfaces on the sub-micron level
Efficiency
- Complex and expensive equipments Not feasible on mass
production
- Slow exposure time
- Need to perform in vacuum (e- are charged particle)
- Scanning may avoid this, still…
MEL G611 : IC FABRICATION TECHNOLOGY 103 BITS Pilani, Hyderabad Campus

EBL: Few Patterns

20 nm phase
change bridge

5 nm lines waveguides

MEL G611 : IC FABRICATION TECHNOLOGY 104 BITS Pilani, Hyderabad Campus

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06-09-2018

BITS Pilani
Hyderabad Campus

X-ray and Ion Lithography

X-ray Lithography: Introduction


• Used to selectively remove parts of a thin film by X-rays to
transfer a geometric pattern from a mask to a photoresist
• A series of chemical treatments then engraves the produced
pattern into the material underneath the photoresist.

• As  < 1 nm), X-rays overcome


the diffraction limits of optical
lithography, allowing smaller
feature sizes.
• Mask pattern is written by direct-
write EBL onto a resist that is
developed by conventional
semiconductor processes.

MEL G611 : IC FABRICATION TECHNOLOGY 106 BITS Pilani, Hyderabad Campus

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06-09-2018

Ion-beam Lithography
• Scanning a focused beam of ions in a patterned fashion
• Higher resolution patterning than UV, X-ray, or electron beam
lithography as heavier ions have more momentum.
• Smaller wavelength than even an e-beam and therefore
almost no diffraction (ions move in straight line)
• Momentum reduces scattering in target and any residual gas.
• Reduced potential radiation effect to sensitive underlying
structures compared to x-ray and e-beam lithography.
• Secondary particles have very short range, because of the
lower speed of the ions.
• Fast-moving ions interact differently with matter than electrons
do, and, due to their higher momentum, their optical properties
are different.

MEL G611 : IC FABRICATION TECHNOLOGY 107 BITS Pilani, Hyderabad Campus

Sec V, L 12-14: Lithography


• Thu, 30 Aug; Sat, 1 Sept; Tue, 4 Sept; Thu, 6 Sept

• Learning Objectives
o Learn how to print the patterns on the wafer using
optical exposure systems

• Topics covered –
o Optical Lithography
o Electron Lithography
o X-ray Lithography
o Ion Lithography

MEL G611 : IC FABRICATION TECHNOLOGY 108 BITS Pilani, Hyderabad Campus

54
06-09-2018

Sec VI, L 16-17: Etching


• Sat, 8 Sept; Tue, 11 Sept

• Learning Objectives
o Learn different etching techniques involved in device
fabrication

• Topics covered –
o Wet Etching
o Dry Etching

MEL G611 : IC FABRICATION TECHNOLOGY 109 BITS Pilani, Hyderabad Campus

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