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Sec IV, L 8-11: Oxidation: MEL G611: Ic Fabrication Technology
Sec IV, L 8-11: Oxidation: MEL G611: Ic Fabrication Technology
MEL G611 :
IC FABRICATION TECHNOLOGY
Section V: Lithography
Thu, 30 Aug; Sat, 1 Sept; Tue, 4 Sept;
BITS Pilani Thu, 6 Sept
Hyderabad Campus
Sanket Goel, EEE
• Learning Objectives
o To understand the Oxidation process during the IC
Fabrication
• Topics covered –
o Oxidation growth mechanisms
o Various techniques
o Properties
o Defects
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06-09-2018
• Learning Objectives
o Learn how to print the patterns on the wafer using
optical exposure systems
• Topics to be covered –
o Optical Lithography
o Electron Lithography
o X-ray Lithography
o Ion Lithography
Lithography
• Litho ⇒ Stone
• Graphy ⇒ Writing
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Lithography Requirements
BITS Pilani
Hyderabad Campus
Photolithography
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06-09-2018
Photolithography
• Photo ⇒ Light
• Litho ⇒ Stone
• Graphy ⇒ Writing
• A light sensitive photoresist is spun onto the wafer and coat the
silicon wafer
• The resistive is selectively exposed by shining light through a
mask
• Then developed the mask pattern, and Finally, etched
out the selectively area
Photolithography
• Creation of 3D structures using photographic techniques
• Derived from creation of printing plates
• Usually start with thin film on wafer (eg SiO2)
• Coat with photosensitive material (photoresist)
• Exposure: to UV Light through mask of structure
• Development of resist: leaves pattern of resist with openings
• Etching: removes film unprotected by resist
• Striping Resist: leave only patterned film
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Photolithography (1)
Photolithography (2)
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Photolithography - Process
Design ⇒ Mask ⇒ Wafer
Photolithography - Components
• Mask
• Photoresist
• Exposure System
• Chemicals
• Thickness control
• Temperature control
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06-09-2018
Photomask
• An opaque plate with
holes or transparencies
that allow light to shine
through in a defined
pattern.
• Plate quartz glass
• Black lines on glass
chrome
• Design is created and
transferred using a
pattern generator
Photomask (Cost)
Low Reflective Chrome (info) on Print Grade Soda Lime (S/L) Glass or
Quartz (spec's)
http://www.photoplotstore.com/pages/photomasks.html
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Photolithography - Mask
• Light field Mask: "islands" of lines in
clear field
• Dark field Mask: "holes" in mostly dark
area
Mask
• Type of resist determines mask type
polarity
Photomasking
Photolithography - Resist
Feature Positive Negative
Design on Mask Same as Mask Opposite to Mask
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Photolithography - Resist
• Positive: Exposure to UV light removes resist
• Negative: Exposure to UV light maintains resist
Mask
Photolithography - Resist
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Lithography Steps
• Wafer clean
• Pre-bake and primer coating
• Photoresist spin coating PR coating
Track- • Soft bake
stepper • Alignment and exposure
integrate • Post exposure bake
d system • Development
• Hard bake Development
• Pattern inspection
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06-09-2018
Lithography : Relative
Thickness
Primer
• Promotes adhesion of PR to wafer surface
• Widely used: Hexamethyldisilazane (HMDS)
• HMDS vapor coating prior to PR spin coating
• Usually performed in-situ with pre-bake
• Chill plate to cool down wafer before PR coating
MEL G611 : IC FABRICATION TECHNOLOGY 22 BITS Pilani, Hyderabad Campus
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06-09-2018
Primer
• Undoped-
Silicate-
Glass-(USG) Photoresist
• STI – Shallow
Trench Polysilicon
Isolation STI USG
P-Well
MEL G611 : IC FABRICATION TECHNOLOGY 23 BITS Pilani, Hyderabad Campus
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06-09-2018
Photoresist Applying
PR dispenser
nozzle
Wafer
Chuck
Spindle
To vacuum pump
PR dispenser nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
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06-09-2018
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
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06-09-2018
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
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06-09-2018
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
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06-09-2018
Wafer
Chuck
Spindle
To vacuum pump
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
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06-09-2018
PR dispenser
nozzle
PR suck back
Wafer
Chuck
Spindle
To vacuum pump
Wafer
Chuck
Spindle
To vacuum
pump
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Litho: Analysis
Relationship of PhotoresistThickness to Spin Rate and Viscosity
3.5
100 cst
3.0
50 cst
2.5
Thickness (mm)
2.0
27 cst
20 cst
1.5
1.0 10 cst
5 cst
0.5
0
2k 3k 4k 5k 6k 7k
Spin Rate (rpm)
Litho: Exposure
Viscosity
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06-09-2018
Litho: Exposure
• Need to cool down to ambient temperature
• For 8 inch (200 mm) wafer, 1 C change causes 0.5 mm
difference in diameter
• Wafers exposed within 2-3 days of soft bake otherwise strip and
recoat
• Several exposure systems: simplest mask aligner
• Wafers placed in mask aligner, moved under mask
• Mask very close to resist (possibly in contact with resist)
• Contact may cause resist to stick to mask mask needs to be
cleaned
• But separation needs to be close otherwise shadow spreads
• Exposure to UV: mask blocks light to desired areas
Diffraction
Place wave in
free space Light passing through Place wave through
a narrow aperture an aperture
Diameter of
central maximum
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Diffraction
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Fraunhofer Diffraction
Resolution
Depth of Focus
k2 depends on resist
Problem
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Fresnel Diffraction
Minimum resolvable
feature size
Litho: UV Source
• Current aligner UV source mercury
vapour lamp
• Exposure time set by light intensity, resist
type and thickness, reflectivity of layer
below
• 436 nm ("g-line")
• 405 nm ("h-line")
• 365 nm ("i-line")
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06-09-2018
Litho: Exposure
Gate Mask
Photoresist
Polysilicon
STI USG
P-Well
Litho: Exposure
Gate Mask
Photoresist
Polysilicon
STI USG
P-Well
MEL G611 : IC FABRICATION TECHNOLOGY 48 BITS Pilani, Hyderabad Campus
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Litho: Exposure
Photoresist
Polysilicon
STI USG
P-Well
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Resist Type
Contrast Q0 dose when exposure begins
Qf dose when exposure ends
Problem
To be developed properly, a 10 mm photoresist requires an
energy density of 100 mJ/cm2/ mm. If a UV source provides
a power density of 1000 W/m2, how long do you need to
expose the wafer with this photoresist?
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Litho: Development
PR
Polysilicon
STI USG
P-Well
Litho: Development
Development: Immersion
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Litho: Development
Chuck
Spindle
To vacuum
pump
MEL G611 : IC FABRICATION TECHNOLOGY 57 BITS Pilani, Hyderabad Campus
Litho: Development
Exposed
Photoresist
Wafer
Chuck
Spindle
To vacuum
pump
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06-09-2018
Litho: Development
Edge PR Patterned
removed photoresist
Wafer
Chuck
Spindle
To vacuum
pump
Litho: Development
DI Water Rinse
DI water
dispenser
nozzle
Wafer
Chuck
Spindle
To vacuum
pump
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Litho: Development
Spin Dry
Wafer
Chuck
Spindle
To vacuum
pump
Litho: Development
Wafer
Chuck
Spindle
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Litho: Development
Mask
PR PR
Film Film
Substrate Substrate
PR Coating Exposure
PR PR
Film Film
Substrate Substrate
Etching Development
Litho: Development
PR PR
Substrate Substrate
Normal Incomplete
Development Development
PR PR
Substrate Substrate
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PR
Polysilicon
STI USG
P-Well
Wafer Inspection
• Surface irregularities - scratches, pin
holes, stains, contamination, etc.
• Critical dimension (CD)
• Overlay or alignment
– run-out, run-in, reticle rotation, wafer
rotation, misplacement in X-direction,
and misplacement in Y-direction
•Fail inspection, stripped PR and
rework
- Photoresist pattern is temporary
-Etch or ion implantation pattern is
permanent.
• Scanning electron microscope (SEM)
• Optical microscope
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06-09-2018
BITS Pilani
Hyderabad Campus
Direct Writing
• Direct writing with a narrow beam of charged particles or
photons uses a “software” mask or Grey-tone mask
• Software-based techniques
o Laser lithography
o Greyscale Lithography
o Electron-beam (e-beam) lithography
• E-beam lithography electron dosage is given by the
product of current and dwell time and is varied across the
resist surface.
• Laser lithography --> pixel-by-pixel UV-laser scanning to
fabricate spherical and aspherical lenses in a positive
photoresist
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For a spot size of 0.1 mm and output power of 0.1 mW, the
motor speed is approximately 0.1 mm/sec.
MEL G611 : IC FABRICATION TECHNOLOGY 71 BITS Pilani, Hyderabad Campus
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06-09-2018
100
mm
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Microchannel
Output
Waveguide
Input waveguide
with air cladding
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Microchannel
Output
Waveguide
Input waveguide
with air cladding
UV
Mask
SU-8
Glass Substrate
Glass Substrate
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Split waveguides-
For combining light of different
wavelengths for particle
sorting experiments
Chip C-
To observe continuous
Electroosmotic flow.
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PMT 1
Laser
PMT 2
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3500
3000
Time
k
1 2 3 4 5 6
1 1.43 209.79
1500
2 1.2 250.00
1000
500
3 1.37 218.98
0
4 1.74 172.41
68 73 78 83 88 93 98
Time (sec) 5 1.78 168.54
6 1.75 171.43
BITS Pilani
Hyderabad Campus
Grayscale Lithography
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06-09-2018
Grayscale Lithography
• Normal photolithography
o a binary image transfer process
o developed pattern consists of regions with resist (1) and
regions without resist (0).
• Grayscale lithography
o partial exposure of a photoresist renders it soluble to a
developer in proportion to the local exposure dose
o consequence, after development, the resist exhibits a
surface relief.
• Gray-tone masks (GTMs) (physical / software based)
o lets varying amounts of light pass through
o micromachines with varying topography
Conventional vs Grayscale
Lithography
Normal mask Grayscale
• Low exposure dose mask
cross-linking acid in the
regions closer to the light
source.
• Stronger exposure doses
penetrate further and
induce cross-linking in the
photoresist further away
from the light source.
• Partial exposure renders it soluble to a developer in
proportion to the local exposure dose and as a consequence,
after development, the resist exhibits a surface relief or 3D
topography
MEL G611 : IC FABRICATION TECHNOLOGY 88 BITS Pilani, Hyderabad Campus
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06-09-2018
Conventional vs Grayscale
Lithography Same Mask is used
Grayscale Lithography
• Smart filter with a
several micro-mirrors
contained in a
rectangular array, to
render patterns from
software masks.
• Micro-mirror ON position can reflect light coming from the light source onto
the photoresist and transfers a bright pixel.
• Micro-mirror in the OFF position directs the light elsewhere and a dark pixel
is seen by the photoresist.
• Grayscale images are obtained by toggling the mirrors between ON and
OFF states rapidly (typically 20 μs) and the ratio of ON time to OFF time
determines the shade produced.
MEL G611 : IC FABRICATION TECHNOLOGY 90 BITS Pilani, Hyderabad Campus
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GSL – Processes
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GSL – Characterization
GSL – Characterization
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GSL – Characterization:
Exposure Time
400 s exposure
time 800 s exposure
time
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SEM images
BITS Pilani
Hyderabad Campus
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EBL: Introduction
• Conventional Photolithography is limited by the wavelength of light
E 1/
• Higher E can cause unwanted side effects
• Solution?
• Use electrons instead of light
• E-beam lithography
EBL: Mechanism
To “shoot” a beam of electrons in a
Electron Gun
direction
•The emitter is heated to produce and
excite electrons on the surface.
Lens • When a high voltage is applied, the
excited electrons accelerate towards a
Blanking Plate structure called the anode.
•By varying this voltage, the trajectory
Lens and the focus of the beam can be
manipulated
Stigmator
Optics to focus the electrons into a
concentrated beam in a desired direction.
Deflection
•Two parallel plates inside the column
Coils
Lens can be electrostatically charged to a
precise degree
•The resulting electric field is able to bend
Wafer
the beam in a desired direction.
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EBL: Methods
When the beam hits the surface,
either an additive or subtractive
reaction takes place.
Additive writing method
uses the electrons to induce a
deposition of a compound on the
surface.
Subtractive writing method
• uses the e-beam to remove the
sections of the resist and surface.
• common in creating masks for
other lithographic techniques
EBL: Scanning
Raster Scan: The e-beam is swept across entire
surface, pixel by pixel, with the beam being
turned on and off according to desired pattern.
• Easy to design and calibrate
• Time consuming [because the beam is scanned
across the entire surface]
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06-09-2018
EBL” Challenges
Electron Backscattering
- Direct electron bombardment on the surface Quick scattering
- Unwanted reactions outside of the focused e-beam
- E-beam resolution is not limited to only the size of the beam
Proximity Effect
- Focused e-beam can produce Secondary electrons (SEs)
- SEs expose the resist several mms away from exposure point
- Critical variations on surfaces on the sub-micron level
Efficiency
- Complex and expensive equipments Not feasible on mass
production
- Slow exposure time
- Need to perform in vacuum (e- are charged particle)
- Scanning may avoid this, still…
MEL G611 : IC FABRICATION TECHNOLOGY 103 BITS Pilani, Hyderabad Campus
20 nm phase
change bridge
5 nm lines waveguides
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BITS Pilani
Hyderabad Campus
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06-09-2018
Ion-beam Lithography
• Scanning a focused beam of ions in a patterned fashion
• Higher resolution patterning than UV, X-ray, or electron beam
lithography as heavier ions have more momentum.
• Smaller wavelength than even an e-beam and therefore
almost no diffraction (ions move in straight line)
• Momentum reduces scattering in target and any residual gas.
• Reduced potential radiation effect to sensitive underlying
structures compared to x-ray and e-beam lithography.
• Secondary particles have very short range, because of the
lower speed of the ions.
• Fast-moving ions interact differently with matter than electrons
do, and, due to their higher momentum, their optical properties
are different.
• Learning Objectives
o Learn how to print the patterns on the wafer using
optical exposure systems
• Topics covered –
o Optical Lithography
o Electron Lithography
o X-ray Lithography
o Ion Lithography
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06-09-2018
• Learning Objectives
o Learn different etching techniques involved in device
fabrication
• Topics covered –
o Wet Etching
o Dry Etching
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