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|HHS Chemical Process Economics Program | Report 261A, Pe rer IMajor equipment Capacity: 1,103 milli Ibi (500,000 Uy) of propylene (and ethylene) at a 0.90 stream factor Equipment umber Name ‘Size __Material of construction Remarks Reactors Rot ME reactor t6Rda shal: cs. 22 Rof aluminum oxide SENT-T Packing: aluminum oxe catalyst RA02AC —-MTPraactor(onof three) 38 laiaeach Sho 304 SS 6 bods of MTPROP-1 SERT-T each Packing: MTPROP-1@ catalyst columns cot Mothanel stripper thin Sho CS. en Taye CS, 102A —_Pre-quench tower 2oftdia each — Shel 3164, ‘95Meach intemal 376. e108 ‘Qvench ower Y8Rda Shel 3164, ‘OR intemal 376. 201 Demethanizer Sfidia Shel CS. wenTT Taye CS. c202 Deethanizer 12Rda shal CS. WO5NTT — Trays CS. e203 Depropanizer column 16Rda——_Shol CS. 250 Trays: CS 208 Debutarizar 15cm Sho CS. HSONTT — Trays CS. 205 Dehexanizer column 12Rda Shel CS. son Trays, 206 Gasoline stabitzer column 22Rda hal CS. fost Taye CS 207 Propylene column 26Rda Shel CS. 2k Trays: CS 208 Eniyione column 12Mda shalt CS. 2508 Trays. Comprssors Keot MTP ottuent compressor -«28,.9808HP- CS. Kot Deethanizer compressor 1208HP CS. Heat exchangers Exot Feed preheater 4500sqt Shel: CS. s2}MMBluhr Tubes: C'S, E402AC Feed evaporator 9.800 sqft esch Shalt Cs Bar unBtume Tubes: CS. E0380 Feed superheator 9,100 sq each Shall CS. ‘GEMMBtute Tubes: CS, EO6AT ——DMEAMTP exchanger 9.700 sqfesch Shall Cs. ‘S1@MMBIune Tubes: 304 SS E-05A8 Methanol stippereboller 9, 100sa Reach Shel: CS 302 MMBIuRe Tubes: CS. E4060. Recycle probeator 8.900 safteach Shall CS. 21 wMBluihe Tubes: C'S, EAO7AD Propylene column rebaler —9,750sa Reach Shel CS, Ys MMBtume Tubes: C5. ENOBAF —Pro-quonchtower cooler 8, 500sq each Sho CS ‘309 MMBtume Tubes: CS. A098 Quench tower coclor 6400 safteach Shall CS. ‘SeMBtuty Tubes: CS, December 2013 67 ©2013 IHS. 1niS Chemical Process Economies Program | Report 2618 oma Cemeetsana rey by the Lurgi MTP process Capacity Equipment number Name ‘Size Material of construction Remarks eat exchangars (concluded) EA10AB Intercooler 18700 sqft each Shell c'S ‘S2mMatume Tubes: C'S E111A8 ——Atrcooler 7400 sat each Shel: CS, 2SMMBtUhe Tubes: CS E2128 Ethylene condenser 41700 sqft each Shel CS. ‘euMotume Tubes: cS e213 Deethanizer condenser 7800sq" Shel: CS, SSMMBtUhe Tubes: CS e214 Deethanizrreboier 6.000 sat Sho CS. THMMBtUne Tubes: CS. e215 Deothanizer condenser 1.100sq Shel: CS, OS Mature Tubes C'S e216 Deethanizr food 100sqh shel: cs, O4NMBIuhr Tubes: C5, E217AB —— Depropanizerrboier 9.400 sat each Shot: CS. 130 MMB Tubes CS E21@AB —Depropanizer condenser __9.000.sqfteach Shall CS, 21 MMBLue Tubes: C8, e219 Gasatine cooler 350sqn Shek cs. TMMBIur Tubes C'S E-220RF Propylene condenser 9.700 sqfteach Shell CS, geMMBIURe Tubes: C.S E221 Debutanizer condenser 7100sqt Shel CS, 126 MMBtuh Tubes C'S e222 Debutanzerreboter 8600sqn Shel CS, 182 MMBlue Tubes! C'S 5223 Dehexanizerreboer 3,100sqt Shel cS SBME Tubes CS E204 Dehexanier condenser 5.900sqR shel CS, SS MMBtUte Tubes. C8 Directfred heaters Het Process heater ‘20MMBUI CS, Tanks T1516 Methancl storage tank 6,000,000 gal each CS. 1251 Gasoline storage tank 2.000.000 ga cs. 1252 Ethylene storage tank 40000093 Cs 1.253 LPG storage tank 600,000ga cs T-254A-C Propylene sloragetark 600,000 galeach CS. Pressure vessels voz ‘Quench water separator 8.000 ga! 3088S ve103 ‘Stage 1 compressor drum 23.0009 CS. ve104 Stage 2 compressor drum 19.000 9a cs, vos: Stage 3 compressor crum 72091 cs. ve106 Stage 4 compressor drum 56001 cs. vor stage phase soparator ——«12,000gal_-—CS, vez Depropanizer refx drum 1300091 cs. v202 Deethanizer refx drum 380091 cs. v.203 (: splitrretux rum 2000ga cs. December 2013, o8 ©2013 IHS Chemical Process Economics Program | Report 261A err oe (eer Capacity: 1,103 milion Ibfr (500,000 tyr) of propylene (and ethene) ata 0.90 stream factor Equipment umber Name Size___Materialof construction Remarks rossure vessas (concluded) v208 (Csplitrrotux rum 20.0009a CS. v205 Deothanizerrfux rum Tog CS. 206 Debutanizer refx rum 10.0009 cs. vor Dehexanizer refx dum 30000ga cS. ‘Special equipment $201 C0, removal $202 ‘Onygenates removal Pumps. Section Operating Spares Operating BHP 100 8 6 2070 200 8 6 “4.200 Poa reer mest ‘Capacity: 1,103 milion Ib/yr (500,000 Uyr) of propylene (and ethylene) at a 0.90 stream factor Units Battory limits total Section 100 Section 200 "Average consumptions Cooling water ‘pm 98,970 67.480 31,490 Electricity kW 41.270 785 505 Steam, 1,500 psig Mibme 485, 485 = Refrigeration, -31" tons. 470 = 470 Peak demands Cooting water 9pm 116,400 67,800 48,600 Electricity kw 1.450 950 600 Steam, 1,500 psig Mibine 600 600 = Refrigeration, -31"F tons 550 550 Process discussion ‘Our process design is for a standalone MTP facility with an assumed low cost crude methanol, While the water content of such a methanol grade is assumed to be above 2.0 w1%, this is not anticipated to be a critical feedstock specification. Even crude methanol with a water content as high as 20 wi%, as typical for un-fractionated methanol converter effluent, could represent an acceptable feed if available in the vicinity of the MTP unit. In view of the production of ethylene is desirable on a coproduct basis as a comonomer for captive polypropylene production, the overall process scheme includes recovering and purifying ethylene to polymer-grade ethylene as a by-product. December 2013 69 ©2013 KS.

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