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Designation: E948 − 15

Standard Test Method for


Electrical Performance of Photovoltaic Cells Using
Reference Cells Under Simulated Sunlight1
This standard is issued under the fixed designation E948; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope Determine the Precision of a Test Method


1.1 This test method covers the determination of the elec- E772 Terminology of Solar Energy Conversion
trical performance of a photovoltaic cell under simulated E927 Specification for Solar Simulation for Photovoltaic
sunlight by means of a calibrated reference cell procedure. Testing
E973 Test Method for Determination of the Spectral Mis-
1.2 Electrical performance measurements are reported with match Parameter Between a Photovoltaic Device and a
respect to a select set of standard reporting conditions (SRC) Photovoltaic Reference Cell
(see Table 1) or to user-specified conditions. E1125 Test Method for Calibration of Primary Non-
1.2.1 The SRC or user-specified conditions include the cell Concentrator Terrestrial Photovoltaic Reference Cells Us-
temperature, the total irradiance, and the reference spectral ing a Tabular Spectrum
irradiance distribution. E1362 Test Method for Calibration of Non-Concentrator
1.3 This test method is applicable only to photovoltaic cells Photovoltaic Secondary Reference Cells
with a linear response over the range of interest. G173 Tables for Reference Solar Spectral Irradiances: Direct
1.4 The cell parameters determined by this test method Normal and Hemispherical on 37° Tilted Surface
apply only at the time of test, and imply no past or future 3. Terminology
performance level.
3.1 Definitions—Definitions of terms in this test method
1.5 The values stated in SI units are to be regarded as may be found in Terminology E772.
standard. No other units of measurement are included in this 3.2 Definitions of Terms Specific to This Standard:
standard. 3.2.1 cell temperature, °C, n—the temperature of the semi-
1.6 This standard does not purport to address all of the conductor junction of a photovoltaic cell.
safety concerns, if any, associated with its use. It is the 3.2.2 junction temperature, n—synonym for cell tempera-
responsibility of the user of this standard to establish appro- ture.
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use. 3.2.3 light source, n—a source of radiant energy used for
cell performance measurements that simulates natural sunlight.
2. Referenced Documents 3.3 Symbols:
2.1 ASTM Standards:2 3.3.1 The following symbols and units are used in this test
E490 Standard Solar Constant and Zero Air Mass Solar method:
Spectral Irradiance Tables A—cell area, m2
E491 Practice for Solar Simulation for Thermal Balance αr—temperature coefficient of reference cell, °C−1
Testing of Spacecraft C—calibration constant of reference cell, Am2W−1
E691 Practice for Conducting an Interlaboratory Study to CT—transfer calibration ratio, dimensionless
E—irradiance, Wm−2
Eo—standard reporting irradiance, Wm−2
1
This test method is under the jurisdiction of ASTM Committee E44 on Solar, η—efficiency, %
Geothermal and Other Alternative Energy Sources and is the direct responsibility of FF—fill factor, %
Subcommittee E44.09 on Photovoltaic Electric Power Conversion.
Current edition approved Feb. 1, 2015. Published March 2015. Originally I—current, A
approved in 1993. Last previous edition approved in 2009 as E948 – 09. DOI: Im—monitor solar cell short-circuit current, A
10.1520/E0948-15.
2
Io—current with respect to SRC, A
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Ir—reference cell short-circuit current, A
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on Isc—short-circuit current, A
the ASTM website. M—spectral mismatch parameter, dimensionless

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States

1
E948 − 15
TABLE 1 Standard Reporting Conditions time. It does not provide for integrating the output power over
Reference Spectral Irradiance Total Irradiance Temperature a given period of time and conditions to predict an energy
Distribution (Wm−2 ) (°C) output.
Tables G173 Direct Normal 1000 25
Tables G173 Hemispherical 1000 25 5.4 This test method requires a reference cell calibrated with
Tables E490 1366.1 25 respect to an appropriate reference spectral irradiance
distribution, such as Tables E490, or G173. It is the responsi-
bility of the user to determine which reference spectral
irradiance distribution is appropriate for a particular applica-
Pm—maximum power, W tion.
Rs—series resistance, Ω
T—temperature,° C 6. Apparatus
To—standard reporting temperature, °C 6.1 Photovoltaic Reference Cell—A calibrated reference cell
Tr—temperature of reference cell, °C used to determine the total irradiance during the electrical
V—voltage, V performance measurement.
Vo—voltage with respect to SRC, V 6.1.1 Reference cells may be calibrated in accordance with
Voc—open-circuit voltage, V Test Methods E1125 or E1362, as is appropriate for a particular
application.
4. Summary of Test Method NOTE 1—No reference cell calibration standards presently exist for
4.1 The performance test of a photovoltaic cell consists of space applications, although procedures such as high-altitude balloon and
low-earth orbit flights are being used to calibrate such reference cells.
measuring the electrical current versus voltage (I-V) charac-
teristic of the cell while illuminated by a suitable light source. 6.1.2 The calibration constant, C, of the reference cell must
be with respect to the reference spectral irradiance distribution
4.2 A calibrated photovoltaic reference cell (see 6.1) is used of the desired SRC (see 1.2).
to determine the total irradiance during the test and to account 6.1.3 A current measurement instrument (see 6.3) shall be
for the spectral distribution of the light source. used to determine the Isc of the reference cell under the light
4.3 Simulated sunlight is used as the light source for the source.
electrical performance measurement, and solar simulation 6.2 Test Fixture—Both the cell to be tested and the reference
requirements are defined in Specification E927 (terrestrial cell are mounted in a fixture that meets the following require-
applications) and Practice E491 (space applications). ments.
4.4 The data from the measurements are corrected to stan- 6.2.1 The test fixture shall ensure a uniform lateral tempera-
dard reporting conditions, or to optional user-specified report- ture distribution to within 60.5°C during the performance
ing conditions. The standard reporting conditions are defined in measurement.
Table 1.3 6.2.2 The test fixture shall include a provision for maintain-
4.4.1 Measurement error caused by deviations of the irradi- ing a constant cell temperature for both the reference cell and
ance conditions from the SRC is corrected using the total the cell to be tested (see 7.10).
irradiance measured with the reference cell and the spectral NOTE 2—When using pulsed or shuttered light sources, it is possible
mismatch parameter, M, which is determined in accordance that the cell temperature will increase upon initial illumination, even when
with Test Method E973. the cell temperature is controlled.
4.4.2 Measurement error caused by deviation of the cell 6.2.3 The test fixture, when placed in the simulated sunlight,
temperature from the SRC is minimized by maintaining the cell shall ensure that the field-of-view of both the reference cell and
temperature close to the required value (see 7.10). the cell to be tested are identical.
NOTE 3—Some solar simulators may have significant amounts of
5. Significance and Use irradiation from oblique or non-perpendicular angles to the test plane. In
5.1 It is the intent of this test method to provide a recog- these cases, it is important that the cell to be tested and the reference cell
nized method for testing and reporting the electrical perfor- have similar reflectance and cosine-response characteristics.
mance of photovoltaic cells. 6.2.4 A four-terminal connection (also known as a Kelvin
connection, see Fig. 1) from the cell to be tested to the I-V
5.2 The test results may be used for comparison of cells
measurement instrumentation (see 6.3 – 6.5) shall be used.
among a group of similar cells or to compare diverse designs,
such as different manufacturers’ products. Repeated measure- 6.3 Current Measurement Equipment—Electrical instru-
ments of the same cell may be used to study changes in device mentation used to measure the current through the cell under
performance. test during the performance measurement. The instrumentation
shall have a resolution of at least 0.02 % of the maximum
5.3 This test method determines the electrical performance
current encountered, and shall have a total error of less than
of a cell based upon the output power at a single instant of
0.1 % of the maximum current encountered.
6.3.1 The instrumentation shall be capable of simultane-
3
Wehrli, C., Extraterrestrial Solar Spectrum, Publ. No. 615, Physikalisch-
ously measuring data points with the short-circuit current (see
Meteorologisches Observatorium and World Radiation Center, Davos Switzerland, 6.9) and voltage (see 6.4) measurement equipment, to within
1985. 10 µs.

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E948 − 15
6.7.1 Sensors used for the temperature measurement(s)
must be located in a position that minimizes any temperature
gradients between the sensor and the photovoltaic device
junction.
6.7.2 Time constants associated with these measurements
must be less than 500 ms.
6.8 Monitor Solar Cell (optional)—An uncalibrated photo-
voltaic solar cell that is positioned in the test plane such that it
is illuminated by the light source during the performance
measurement of the cell to be tested. The monitor solar cell is
used to measure the irradiance during the performance mea-
surement following a transfer-of-calibration procedure from
the photovoltaic reference cell. It is also used to correct current
measurement data points of the cell to be tested for temporal
instability of the light source.
FIG. 1 I-V Measurement Schematic 6.8.1 The monitor solar cell may be positioned anywhere in
the test plane of the light source, but shall not be moved after
the transfer-of-calibration procedure has been performed.
6.8.2 The spectral responsivity of the monitor solar cell is
6.4 Voltage Measurement Equipment—Electrical instrumen-
unimportant, but the wavelength range of its responsivity
tation used to measure the voltage across the cell under test
should include that of the cell to be tested. Crystalline-Si solar
during the performance measurement. The instrumentation
cells are recommended.
shall have a resolution of at least 0.02 % of the maximum
6.8.3 The monitor solar cell shall be mounted on a test
voltage encountered, and shall have a total error of less than
fixture that controls its cell temperature to within 61°C during
0.1 % of the maximum voltage encountered.
the performance measurement. It is recommended that the
6.4.1 The instrumentation shall be capable of simultane-
monitor solar cell have its own test fixture.
ously measuring data points with the current (see 6.3) and
short-circuit current (see 6.9) measurement equipment, to 6.8.4 The time constant of the monitor solar cell’s tempera-
within 10 µs. ture measurement must be less than 500 ms.

6.5 Variable Load—An electronic load, such as a variable 6.9 Short-circuit Current Measurement Equipment—
resistor or a programmable power supply, used to operate the Instrumentation used to measure the Isc of the photovoltaic
cell to be tested at different points along its I-V characteristic. reference cell and the monitor solar cell.
6.5.1 The variable load shall be capable of operating the cell 6.9.1 The instrumentation shall be capable of holding the
to be tested at an I-V point where the voltage is within 1 % of voltage across these cells to within 25 mV of zero.
Voc in the power-producing quadrant. 6.9.2 The instrumentation shall be capable of simultane-
6.5.2 The variable load shall be capable of operating the cell ously measuring current data points with the current (see 6.3)
to be tested at an I-V point where the current is within 1 % of and voltage (6.4) measurement equipment, to within 10 µs.
Isc in the power-producing quadrant.
6.5.3 The variable load must allow an output power (the 7. Procedure
product of cell current and cell voltage) resolution of at least 7.1 Determine the series resistance, Rs, of the cell to be
0.2 % of the maximum power. measured. An acceptable method is described in Annex A1.
6.5.4 The electrical response time of the variable load must 7.1.1 If the total irradiance during the performance mea-
be fast enough to sweep the range of I-V operating points surement as measured by the reference cell is within 62 % of
during the measurement period. the standard reporting total irradiance, the series resistance is
NOTE 4—It is possible that the response time of the cell to be tested may not needed.
limit how fast the range of I-V operating points can be swept, especially
when pulsed solar simulators are used. For these cases, it may be 7.2 Measure the cell area, A, using the definition of area,
necessary to measure smaller ranges of the I-V curve using multiple photovoltaic cell in Terminology E772.
measurements to obtain the entire range required.
7.3 Special Case—If the cell to be tested also qualifies as a
6.6 Light Source—Requirements of the solar simulation reference cell according to 6.1 so that its C is known prior to
used to illuminate the cell to be tested are defined in Specifi- test, the cell may be used to measure irradiance and the
cation E927 (terrestrial applications) and Practice E491 (space separate reference cell omitted. The self-irradiance measure-
applications). ment technique is typically used to determine the fill factor of
6.7 Temperature Measurement Equipment—Instrumentation a reference cell post-calibration, and as a check for damage or
used to measure the cell temperatures of the reference cell, the degradation.
cell to be tested, and the monitor solar cell shall have a 7.3.1 Set the spectral mismatch parameter, M, to one.
resolution of at least 0.1°C, and shall have a total error of less 7.3.2 Mount the cell to be tested in the test fixture.
than 61°C of reading. 7.3.3 Proceed to 7.6.

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E948 − 15
7.4 Determine the spectral mismatch parameter, M, using instability of the light source, and judgment should be used to
Test Method E973. establish the time needed for the transfer calibration.
7.4.1 Test Method E973 requires four spectral quantities: 7.9.3.3 Calculate the transfer calibration ratio using the
the spectral responsivities of the cell under test and the following equation, where n is the number of repetitions:
reference cell, the spectral irradiance of the light source, and 1 n Ir
the reference spectral irradiance distribution. Cr 5 Σ (1)
n 1 Im
7.4.2 Two of these quantities will be known prior to the
performance measurement: the reference cell spectral respon- 7.9.4 Replace the reference cell with the cell to be tested.
sivity (required as part of its calibration data), and the reference 7.9.5 Measure the temperature of the cell under test.
spectral irradiance distribution (selected or specified before- 7.9.5.1 The measured temperature of the cell under test shall
hand in 1.2). be within 61°C of the applicable SRC.
7.4.3 Measure the spectral responsivity of the cell to be 7.9.6 Measure the I-V characteristic of the cell under test by
tested according to 7.1 of Test Method E973. changing the operating point with the variable load so that the
7.4.4 The spectral irradiance of the light source should be provisions of 6.5.1 – 6.5.3 are met. At each operating point on
measured within the last 50 h of lamp time unless the solar the I-V characteristic, simultaneously measure the cell voltage,
simulator’s spectral stability has demonstrated that a longer V, cell current, I, and the monitor cell short-circuit current Im,
period causes no discernible error. within 10 µs.
7.4.5 Special Case—For the special case of 7.3, by defini- 7.10 Measure the temperature of the cell under test to verify
tion M will be equal to one, and the spectral measurements in that it is within 61°C of the applicable SRC.
7.4.3 and 7.4.4 are not necessary. 7.11 Optional—Disconnect the variable load and measure
7.5 Mount the reference cell in the test fixture. Connect it to the voltage across the cell to be tested. With no current flowing
the short-circuit current measurement equipment, and expose it through the cell, this voltage is the open-circuit voltage, Voc.
to the light source. 7.12 Remove the cell to be tested from the test fixture.
7.6 If possible, adjust the total irradiance of the light source
until it is equal to C × Eo. 8. Calculation
7.7 Measure the temperature of the reference cell, Tr. 8.1 Obtain the temperature coefficient of the reference cell
from its calibration report.
7.8 Stable Light Source—If the temporal instability of the
light source (as defined in Specification E927) is less than 8.2 Correct each I-V data pair using the following equa-
0.1 %, the total irradiance may be determined with the refer- tions:
ence cell prior to the performance measurement. In this case, 1 Eo 1
use the following steps to measure the total irradiance and the Io 5 I (2)
M E @ 1 2 α r~ T o 2 T r! #
I-V characteristic. Otherwise, proceed to 7.9.
V o 5 V 2 R s~ I o 2 I ! (3)
NOTE 5—The reference cell’s Isc is a convenient way to verify the
temporal instability of the light source. 8.2.1 Determine the irradiance E in Eq 2 as follows:
8.2.1.1 Stable Light Source—From the reference cell current
7.8.1 Measure the short-circuit current of the reference cell,
measured prior to the I-V curve sweep, Ir:
Ir.
7.8.2 Replace the reference cell with the cell to be tested. E 5 I r ⁄C (4)
7.8.3 Measure the temperature of the cell under test. 8.2.1.2 Unstable Light Source—From the monitor solar cell
7.8.3.1 The measured temperature of the cell under test shall current measured with each I-V data pair, Ir:
be within 61°C of the applicable SRC.
E 5 1 mC r (5)
7.8.4 Measure the I-V characteristic of the cell under test by NOTE 6—If the provision of 7.1.1 is met, it is not necessary to correct
changing the operating point with the variable load so that the the cell voltage using the series resistance.
provisions of 6.5.1 – 6.5.3 are met. At each operating point on 8.3 Calculate the short-circuit current from several Io − Vo
the I-V characteristic, measure the cell voltage, V, current, I, data pairs where Vo is close to zero using linear interpolation.
and Ir.
7.8.5 Proceed to 7.10. 8.4 Determine the open-circuit voltage using one of the
following procedures:
7.9 Unstable Light Source: 8.4.1 If an Io − Vo data pair exists where Io is within
7.9.1 Mount the monitor solar cell in its test fixture and 60.001Isc, Vo from this pair may be considered to be the
connect it to the short-circuit current measurement equipment. open-circuit voltage.
7.9.2 Measure the temperature of the reference cell, Tr. 8.4.2 If the condition in 8.4.1 is not met, calculate the
7.9.3 Transfer Calibration: open-circuit voltage from the several Io − Vo data pairs where
7.9.3.1 Measure the short-circuit currents of the reference Io is closest to zero using linear interpolation.
cell and the monitor solar cell simultaneously within 1 ms. 8.4.3 If the optional no-load measurement of 7.11 was
7.9.3.2 Repeat 7.9.3.1 a minimum of 10 times. The number performed, this voltage may be considered to be the open-
of needed repetitions will vary according to the temporal circuit voltage.

4
E948 − 15
8.5 Calculate the cell output power P for each data pair from 9.3.8 Calibration constant, C.
the product of Io and Vo, and determine the maximum power 9.4 Test Conditions:
point Pm along with the corresponding Vm from the P vs. Vo 9.4.1 Description and classification of light source,
table. Because of random fluctuations and the probability that 9.4.2 Standard reporting conditions (see Table 1) or user-
one point in the tabular I-V data will not be exactly on the specified conditions,
maximum power point, it is recommended that the following 9.4.3 Date and time of test,
procedure be used to calculate the maximum power point, 9.4.4 Spectral mismatch parameter (see 7.4),
especially for devices with fill factors greater than 80 %. 9.4.5 Reference cell short-circuit current, Ir, and
8.5.1 Perform a fourth-order polynomial least-squares fit to 9.4.6 Measured cell temperature.
the P vs. Vo data that are within the following limits. These
limits are guidelines that have been found to be useful for this 9.5 Test Results:
procedure and need not be followed precisely. This results in a 9.5.1 Short-circuit current, Isc,
polynomial representation of P as a function of Vo . 9.5.2 Open-circuit voltage, Voc,
9.5.3 Maximum power, Pm,
0.75I m # I o # 1.15I m (6)
9.5.4 Voltage at Pm,
0.75V m # V o # 1.15V m (7) 9.5.5 Fill factor, FF,
9.5.6 Efficiency, η, and
8.5.2 Calculate the derivative polynomial of the polynomial
9.5.7 Io − Vocharacteristic, in plotted or tabular form.
obtained from 8.5.1.
8.5.3 Find the root of the derivative polynomial obtained
10. Precision and Bias5
from 8.6.2 using Vm as an initial guess. An appropriate
procedure is the Newton-Horner method with deflation.4 This 10.1 Interlaboratory Test Program—An interlaboratory
root now becomes Vm. study of cell performance measurements was conducted be-
8.5.4 Calculate Pm by substituting the new Vm into the tween 1992 and 1994. Six laboratories performed three repeti-
original polynomial from 8.5.1. tions on each of ten cells circulated among the participants. The
design of the experiment, similar to that of Practice E691, and
8.6 Calculate the efficiency η using the following equation:
a within-between analysis of the data are given in ASTM
Pm Research Report No. RR:E44-1002.
η 5 100 3 (8)
AEo
10.2 Test Result—Because I-V measurements produce a
8.7 Calculate the fill factor FF using the following equation: table of current vs. voltage points rather than a single numeric
Pm result, the precision analysis was performed on the maximum
FF 5 100 3 (9) power point data submitted by the participants. The precision
V ocI sc
information given below is in percentage points of the maxi-
9. Report mum power in watts.
9.1 The end user ultimately determines the amount of 10.3 Precision:
information to be reported. Listed in 9.2 – 9.5.7 are the 95 % repeatability limit (within-laboratory) 1.5 %
minimum, mandatory reporting requirements. 95 % reproducibility limit (between-laboratory) 7.1 %
9.2 Test Cell Description: 10.4 Bias—The contribution of bias to the total error will
9.2.1 Identification, depend upon the bias of each individual parameter used for the
9.2.2 Physical description, determination of the cell performance. However, it has been
9.2.3 Area, as determined in 7.2, shown that the total bias is dominated by three sources: the
9.2.4 Series resistance, if used (see 7.1), and reference cell calibration, spatial uniformity of the light source,
9.2.5 Spectral response in plotted or tabular form, as deter- and the total area measurement.6 Bias contributions from
mined for spectral mismatch parameter calculation (see 7.4). instrumentation tend to be, at most, a few tenths of a percent,
9.3 Reference Cell Description: while the bias from the three sources listed here can be as much
9.3.1 Identification, as ten times greater if the bias is not minimized.
9.3.2 Physical description,
9.3.3 Calibration laboratory, 11. Keywords
9.3.4 Calibration procedure (see 6.1.1), 11.1 cell; performance; photovoltaic; testing
9.3.5 Date of calibration,
9.3.6 Reference spectral irradiance distribution (see 5.4),
9.3.7 Spectral response, in plotted or tabular form, as 5
Supporting data have been filed at ASTM International Headquarters and may
required for Test Method E973, and be obtained by requesting Research Report RR:E44-1002.
6
Emery, K. A., Osterwald, C. R., and Wells, C. V., “Uncertainty Analysis of
Photovoltaic Efficiency Measurements,” Proceedings of the 19th IEEE Photovolta-
4
Burden, R. L., and Faires, J. D., Numerical Analysis, 3rd. ed., Prindle, Weber ics Specialists Conference— 1987, Institute of Electrical and Electronics Engineers,
& Schmidt, Boston, MA, 1985 , p. 42 ff. New York, NY, pp. 153–159.

5
E948 − 15
ANNEX

(Mandatory Information)

A1. METHOD OF DETERMINING THE SERIES RESISTANCE OF A PHOTOVOLTAIC DEVICE

A1.1 The series resistance Rs is determined from measure- Values at irradiances E1 E2


ments of the I-V curve data at two different values of the Short-circuit current Isc1 Isc2
Voltage at I1 = 0.9 Isc1 V1
effective irradiance while the temperature of the device is kept Voltage at I2 = 0.9 Isc2 V2
constant at approximately 25°C. Obtain two sets of I-V data
from the device at two different levels of irradiance, for A1.3 From these data, Rs is calculated as follows:
example, E1 = 800 Wm−2 and E2 = 1200 Wm−2 (these values
R s 5 ~ V 2 2 V 1! / ~ I 1 2 I 2 ! (A1.1)
are given only as an example and need not be established
exactly). Temperature variations during the I-V curve measure-
ments must be less than 61°C.
A1.2 At the two irradiance levels, E1 and E2, the following
values are extracted from the two I-V curves, as shown in Fig.
A1.1:

FIG. A1.1 Series Resistance Measurement

6
E948 − 15

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